RU2006114748A - Носители из диоксида титана для катализаторов процесса фишера-тропша - Google Patents
Носители из диоксида титана для катализаторов процесса фишера-тропша Download PDFInfo
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- RU2006114748A RU2006114748A RU2006114748/04A RU2006114748A RU2006114748A RU 2006114748 A RU2006114748 A RU 2006114748A RU 2006114748/04 A RU2006114748/04 A RU 2006114748/04A RU 2006114748 A RU2006114748 A RU 2006114748A RU 2006114748 A RU2006114748 A RU 2006114748A
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- Prior art keywords
- catalyst
- titanium dioxide
- compound
- carrier
- crystalline titanium
- Prior art date
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims 27
- 239000003054 catalyst Substances 0.000 title claims 14
- 239000004408 titanium dioxide Substances 0.000 title claims 10
- 238000000034 method Methods 0.000 title claims 5
- 239000000969 carrier Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims 8
- 229910052751 metal Inorganic materials 0.000 claims 7
- 239000002184 metal Substances 0.000 claims 7
- 239000012018 catalyst precursor Substances 0.000 claims 5
- 239000000203 mixture Substances 0.000 claims 4
- 229930195733 hydrocarbon Natural products 0.000 claims 3
- 150000002430 hydrocarbons Chemical class 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 239000011230 binding agent Substances 0.000 claims 2
- 238000001354 calcination Methods 0.000 claims 2
- 229910017052 cobalt Inorganic materials 0.000 claims 2
- 239000010941 cobalt Substances 0.000 claims 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 2
- 238000001125 extrusion Methods 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 2
- 239000011572 manganese Substances 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 150000002736 metal compounds Chemical class 0.000 claims 2
- 150000002739 metals Chemical class 0.000 claims 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- 229910052702 rhenium Inorganic materials 0.000 claims 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- 229910020599 Co 3 O 4 Inorganic materials 0.000 claims 1
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 238000004517 catalytic hydrocracking Methods 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 229910000428 cobalt oxide Inorganic materials 0.000 claims 1
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 claims 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims 1
- 229910021472 group 8 element Inorganic materials 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 230000001151 other effect Effects 0.000 claims 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 238000003825 pressing Methods 0.000 claims 1
- 239000011164 primary particle Substances 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 238000001694 spray drying Methods 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 229910001928 zirconium oxide Inorganic materials 0.000 claims 1
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
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- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
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- B01J35/00—Catalysts, in general, characterised by their form or physical properties
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- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C01G23/047—Titanium dioxide
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- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
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- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
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Claims (14)
1. Формованный носитель катализатора, содержащий кристаллический диоксид титана, в котором, по меньшей мере, 50 мас.% кристаллического диоксида титана присутствует в виде брукита, и в котором носитель включает в себя между 40 и 100 мас.% кристаллического диоксида титана, в расчете на суммарную массу носителя, предпочтительно между 70 и 100 мас.%, причем формованный носитель катализатора не представляет собой покрытый носитель катализатора.
2. Носитель по п.1, в котором, по меньшей мере, 60 мас.% кристаллического диоксида титана присутствуют в виде брукита.
3. Носитель по пп.1 и 2, в котором кристаллический диоксид титана имеет содержание брукита не более 90 мас.%, предпочтительно не более 80 мас.%.
4. Носитель по любому пп.1 и 2, в котором кристаллический диоксид титана присутствует в виде рутила в диапазоне от 0 до 50 мас.%, предпочтительно в диапазоне от 5 до 30 мас.%, и в котором кристаллический диоксид титана присутствует в виде анатаза в диапазоне от 0 до 10 мас.%, предпочтительно в диапазоне от 0 до 5 мас.%.
5. Носитель по любому пп.1 и 2, в котором размер первичных частиц брукита находится в диапазоне от 10 до 100 нм, предпочтительно от 20 до 70 нм.
6. Носитель по любому пп.1 и 2, в котором также присутствует связующий агент, предпочтительно диоксид кремния, оксид алюминия или их сочетание, и в котором связующий агент составляет от 0 до 20% от массы носителя, предпочтительно от 0 до 10 мас.%.
7. Катализатор или предшественник катализатора, содержащий металл VIII группы или соединение металла VIII группы, и носитель по пп.1-6, причем элемент VIII группы предпочтительно представляет собой Ru, Fe, Co или Ni, более предпочтительно Со.
8. Катализатор или предшественник катализатора по п.7, который дополнительно содержит один или несколько металлов или соединений металлов из групп IIa, IIIb, IVb, Vb и VIb, предпочтительно марганец и оксид циркония, или который дополнительно содержит один или несколько металлов из VIIb или VIII групп, предпочтительно рений, платину и палладий.
9. Способ получения формованного носителя катализатора по пп.1-6 путем распылительной сушки, прессования, экструзии или другого воздействия на гранулированный или порошкообразный материал катализатора с получением различных форм, предпочтительно путем экструзии.
10. Способ получения катализатора или предшественника катализатора по любому пп.7-8, путем пропитывания или осадительного покрытия формованного носителя катализатора по пп.1-9 из раствора одной или нескольких солей металла, с последующей сушкой и прокаливанием.
11. Способ получения катализатора или предшественника катализатора по п.7 или 8, который включает в себя стадии
(a) смешивание (1) диоксида титана, в котором, по меньшей мере, 50 мас.% кристаллического диоксида титана присутствует в виде брукита, (2) жидкости и
(3) соединения металла из группы VIII, которое, по меньшей мере, частично не растворимо в использованном количестве жидкости, с образованием смеси,
(b) формование и сушка полученной таким образом смеси, и
(c) прокаливание смеси, полученной таким образом.
12. Способ по п.11, в котором соединение металла из группы VIII представляет собой соединение, содержащее металлический кобальт, соединение, содержащее гидроксид кобальта или оксид кобальта, предпочтительно соединение, содержащее Со(ОН)2 или Со3O4, и в котором соединение, содержащее кобальт, дополнительно содержит соединение элемента из группы IVb и/или группы VIIb, предпочтительно соединение циркония, марганца или рения.
13. Активированный катализатор, подходящий для производства углеводородов, который получают путем восстановления водородом при повышенной температуре катализатора или предшественника катализатора по п.7 или 8.
14. Способ получения углеводородов, который включает в себя контактирование смеси монооксида углерода и водорода с катализатором по п.13, необязательно с последующей гидроизомеризацией/гидрокрекингом полученного углеводородного продукта, для того, чтобы получить продукты среднего дистиллята.
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EP (1) | EP1667948A1 (ru) |
AU (1) | AU2004276016A1 (ru) |
CA (1) | CA2540353A1 (ru) |
MX (1) | MXPA06003360A (ru) |
NO (1) | NO20061877L (ru) |
RU (1) | RU2006114748A (ru) |
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Cited By (1)
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RU2678206C1 (ru) * | 2017-12-20 | 2019-01-24 | Федеральное государственное бюджетное учреждение науки Институт металлургии и материаловедения им. А.А. Байкова Российской академии наук (ИМЕТ РАН) | Способ получения фотокаталитического диоксида титана модификации анатаз и брукит на поверхности керамического изделия из рутила, полученного окислительным конструированием |
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AU2006325209B2 (en) * | 2005-12-16 | 2010-11-04 | Shell Internationale Research Maatschappij B.V. | Process for preparing a hydrocarbon synthesis catalyst |
AU2006327030B2 (en) * | 2005-12-22 | 2010-09-02 | Shell Internationale Research Maatschappij B.V. | Zirconium stabilised Fischer Tropsch catalyst and catalyst support |
EP2097167A2 (en) * | 2006-12-12 | 2009-09-09 | Shell Internationale Research Maatschappij B.V. | Process for preparing a catalyst |
US7825204B2 (en) | 2006-12-19 | 2010-11-02 | Lyondell Chemical Technology, L.P. | Inorganic oxide extrudates |
EP2008714A1 (en) * | 2007-06-19 | 2008-12-31 | BASF Catalysts LLC | Process for the preparation of a cobalt-zinc oxide Fischer-Tropsch catalyst |
CN102277608A (zh) * | 2011-07-12 | 2011-12-14 | 大连理工大学 | 一种制备二氧化钛纳米管粉末的工艺 |
MX349068B (es) * | 2012-06-21 | 2017-06-28 | Inst Mexicano Del Petróleo | Material semiconductor de titania nanoestructurada y proceso de obtencion. |
WO2014140973A1 (en) * | 2013-03-14 | 2014-09-18 | Sasol Technology (Pty) Limited | A hydrocarbon synthesis process using a cobalt-based catalyst supported on a silicon carbide comprising support |
WO2015010941A1 (en) * | 2013-07-24 | 2015-01-29 | Shell Internationale Research Maatschappij B.V. | Process for preparing a chlorine comprising catalyst, the prepared catalyst, and its use |
EP3024577A1 (en) | 2013-07-24 | 2016-06-01 | Shell Internationale Research Maatschappij B.V. | Process for preparing a chlorine comprising catalyst, the prepared catalyst, and its use |
US20160160128A1 (en) * | 2013-07-24 | 2016-06-09 | Shell Oil Company | Method for starting up a fischer tropsch process |
WO2015124149A1 (de) * | 2014-02-21 | 2015-08-27 | Sachtleben Chemie Gmbh | Katalysatorprecursormaterial auf TiO2-Basis, dessen Herstellung und dessen Verwendung |
US11691127B2 (en) * | 2014-12-19 | 2023-07-04 | Bp P.L.C. | Process for preparation of a supported cobalt-containing Fishcer-Tropsch synthesis |
EA033748B1 (ru) * | 2015-02-25 | 2019-11-21 | Sasol Tech Pty Ltd | Способ синтеза углеводородов |
CN106466591A (zh) * | 2015-08-20 | 2017-03-01 | 吉林化工学院 | 一种用于富集微囊藻毒素的磁性纳米粒子的制备方法 |
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CN106622198B (zh) * | 2016-11-29 | 2019-07-23 | 湖北大学 | 一种复合纳米结构二氧化钛光催化剂及其制备方法 |
CN108906078B (zh) * | 2018-07-20 | 2021-05-11 | 上海理工大学 | 一种高效Pd/Co3O4块体催化剂的制备方法 |
CN110028108A (zh) * | 2019-05-24 | 2019-07-19 | 江苏特丰新材料科技有限公司 | 一种新型的钛酸盐功能材料制备工艺 |
CN111604042B (zh) * | 2020-04-10 | 2023-04-11 | 安徽迪诺环保新材料科技有限公司 | 一种金红石晶型脱硝催化剂载体及其制备方法 |
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- 2004-09-30 EP EP04787264A patent/EP1667948A1/en not_active Withdrawn
- 2004-09-30 US US10/573,795 patent/US20070123594A1/en not_active Abandoned
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RU2678206C1 (ru) * | 2017-12-20 | 2019-01-24 | Федеральное государственное бюджетное учреждение науки Институт металлургии и материаловедения им. А.А. Байкова Российской академии наук (ИМЕТ РАН) | Способ получения фотокаталитического диоксида титана модификации анатаз и брукит на поверхности керамического изделия из рутила, полученного окислительным конструированием |
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CA2540353A1 (en) | 2005-04-07 |
US20070123594A1 (en) | 2007-05-31 |
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MXPA06003360A (es) | 2006-06-08 |
AU2004276016A1 (en) | 2005-04-07 |
NO20061877L (no) | 2006-04-28 |
WO2005030680A1 (en) | 2005-04-07 |
ZA200602003B (en) | 2007-05-30 |
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