RU2006114748A - Носители из диоксида титана для катализаторов процесса фишера-тропша - Google Patents

Носители из диоксида титана для катализаторов процесса фишера-тропша Download PDF

Info

Publication number
RU2006114748A
RU2006114748A RU2006114748/04A RU2006114748A RU2006114748A RU 2006114748 A RU2006114748 A RU 2006114748A RU 2006114748/04 A RU2006114748/04 A RU 2006114748/04A RU 2006114748 A RU2006114748 A RU 2006114748A RU 2006114748 A RU2006114748 A RU 2006114748A
Authority
RU
Russia
Prior art keywords
catalyst
titanium dioxide
compound
carrier
crystalline titanium
Prior art date
Application number
RU2006114748/04A
Other languages
English (en)
Inventor
Рональд Ян ДОГТЕРОМ (NL)
Рональд Ян ДОГТЕРОМ
Маринус Йоханнес РЕЙНХОУТ (NL)
Маринус Йоханнес Рейнхоут
Original Assignee
Шелл Интернэшнл Рисерч Маатсаппий Б.В. (Nl)
Шелл Интернэшнл Рисерч Маатсаппий Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Шелл Интернэшнл Рисерч Маатсаппий Б.В. (Nl), Шелл Интернэшнл Рисерч Маатсаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсаппий Б.В. (Nl)
Publication of RU2006114748A publication Critical patent/RU2006114748A/ru

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063Titanium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066Zirconium or hafnium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889Manganese, technetium or rhenium
    • B01J23/8892Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00Compounds of titanium
    • C01G23/04Oxides; Hydroxides
    • C01G23/047Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00Compounds of zirconium
    • C01G25/02Oxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00Compounds of manganese
    • C01G45/02Oxides; Hydroxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G47/00Compounds of rhenium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00Compounds of cobalt
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00Compounds of cobalt
    • C01G51/006Compounds containing, besides cobalt, two or more other elements, with the exception of oxygen or hydrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00Compounds of cobalt
    • C01G51/04Oxides; Hydroxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/006Compounds containing, besides nickel, two or more other elements, with the exception of oxygen or hydrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12Inorganic carriers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12Inorganic carriers
    • C10G47/14Inorganic carriers the catalyst containing platinum group metals or compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/462Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/75Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/61310-100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/50Solid solutions
    • C01P2002/52Solid solutions containing elements as dopants
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/62Submicrometer sized, i.e. from 0.1-1 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/64Nanometer sized, i.e. from 1-100 nanometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/12Surface area
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/14Pore volume
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/32Thermal properties
    • C01P2006/37Stability against thermal decomposition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Nanotechnology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (14)

1. Формованный носитель катализатора, содержащий кристаллический диоксид титана, в котором, по меньшей мере, 50 мас.% кристаллического диоксида титана присутствует в виде брукита, и в котором носитель включает в себя между 40 и 100 мас.% кристаллического диоксида титана, в расчете на суммарную массу носителя, предпочтительно между 70 и 100 мас.%, причем формованный носитель катализатора не представляет собой покрытый носитель катализатора.
2. Носитель по п.1, в котором, по меньшей мере, 60 мас.% кристаллического диоксида титана присутствуют в виде брукита.
3. Носитель по пп.1 и 2, в котором кристаллический диоксид титана имеет содержание брукита не более 90 мас.%, предпочтительно не более 80 мас.%.
4. Носитель по любому пп.1 и 2, в котором кристаллический диоксид титана присутствует в виде рутила в диапазоне от 0 до 50 мас.%, предпочтительно в диапазоне от 5 до 30 мас.%, и в котором кристаллический диоксид титана присутствует в виде анатаза в диапазоне от 0 до 10 мас.%, предпочтительно в диапазоне от 0 до 5 мас.%.
5. Носитель по любому пп.1 и 2, в котором размер первичных частиц брукита находится в диапазоне от 10 до 100 нм, предпочтительно от 20 до 70 нм.
6. Носитель по любому пп.1 и 2, в котором также присутствует связующий агент, предпочтительно диоксид кремния, оксид алюминия или их сочетание, и в котором связующий агент составляет от 0 до 20% от массы носителя, предпочтительно от 0 до 10 мас.%.
7. Катализатор или предшественник катализатора, содержащий металл VIII группы или соединение металла VIII группы, и носитель по пп.1-6, причем элемент VIII группы предпочтительно представляет собой Ru, Fe, Co или Ni, более предпочтительно Со.
8. Катализатор или предшественник катализатора по п.7, который дополнительно содержит один или несколько металлов или соединений металлов из групп IIa, IIIb, IVb, Vb и VIb, предпочтительно марганец и оксид циркония, или который дополнительно содержит один или несколько металлов из VIIb или VIII групп, предпочтительно рений, платину и палладий.
9. Способ получения формованного носителя катализатора по пп.1-6 путем распылительной сушки, прессования, экструзии или другого воздействия на гранулированный или порошкообразный материал катализатора с получением различных форм, предпочтительно путем экструзии.
10. Способ получения катализатора или предшественника катализатора по любому пп.7-8, путем пропитывания или осадительного покрытия формованного носителя катализатора по пп.1-9 из раствора одной или нескольких солей металла, с последующей сушкой и прокаливанием.
11. Способ получения катализатора или предшественника катализатора по п.7 или 8, который включает в себя стадии
(a) смешивание (1) диоксида титана, в котором, по меньшей мере, 50 мас.% кристаллического диоксида титана присутствует в виде брукита, (2) жидкости и
(3) соединения металла из группы VIII, которое, по меньшей мере, частично не растворимо в использованном количестве жидкости, с образованием смеси,
(b) формование и сушка полученной таким образом смеси, и
(c) прокаливание смеси, полученной таким образом.
12. Способ по п.11, в котором соединение металла из группы VIII представляет собой соединение, содержащее металлический кобальт, соединение, содержащее гидроксид кобальта или оксид кобальта, предпочтительно соединение, содержащее Со(ОН)2 или Со3O4, и в котором соединение, содержащее кобальт, дополнительно содержит соединение элемента из группы IVb и/или группы VIIb, предпочтительно соединение циркония, марганца или рения.
13. Активированный катализатор, подходящий для производства углеводородов, который получают путем восстановления водородом при повышенной температуре катализатора или предшественника катализатора по п.7 или 8.
14. Способ получения углеводородов, который включает в себя контактирование смеси монооксида углерода и водорода с катализатором по п.13, необязательно с последующей гидроизомеризацией/гидрокрекингом полученного углеводородного продукта, для того, чтобы получить продукты среднего дистиллята.
RU2006114748/04A 2003-09-30 2004-09-30 Носители из диоксида титана для катализаторов процесса фишера-тропша RU2006114748A (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP03103612.2 2003-09-30
EP03103612 2003-09-30

Publications (1)

Publication Number Publication Date
RU2006114748A true RU2006114748A (ru) 2007-11-10

Family

ID=34384672

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2006114748/04A RU2006114748A (ru) 2003-09-30 2004-09-30 Носители из диоксида титана для катализаторов процесса фишера-тропша

Country Status (9)

Country Link
US (1) US20070123594A1 (ru)
EP (1) EP1667948A1 (ru)
AU (1) AU2004276016A1 (ru)
CA (1) CA2540353A1 (ru)
MX (1) MXPA06003360A (ru)
NO (1) NO20061877L (ru)
RU (1) RU2006114748A (ru)
WO (1) WO2005030680A1 (ru)
ZA (1) ZA200602003B (ru)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2678206C1 (ru) * 2017-12-20 2019-01-24 Федеральное государственное бюджетное учреждение науки Институт металлургии и материаловедения им. А.А. Байкова Российской академии наук (ИМЕТ РАН) Способ получения фотокаталитического диоксида титана модификации анатаз и брукит на поверхности керамического изделия из рутила, полученного окислительным конструированием

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2006325209B2 (en) * 2005-12-16 2010-11-04 Shell Internationale Research Maatschappij B.V. Process for preparing a hydrocarbon synthesis catalyst
AU2006327030B2 (en) * 2005-12-22 2010-09-02 Shell Internationale Research Maatschappij B.V. Zirconium stabilised Fischer Tropsch catalyst and catalyst support
EP2097167A2 (en) * 2006-12-12 2009-09-09 Shell Internationale Research Maatschappij B.V. Process for preparing a catalyst
US7825204B2 (en) 2006-12-19 2010-11-02 Lyondell Chemical Technology, L.P. Inorganic oxide extrudates
EP2008714A1 (en) * 2007-06-19 2008-12-31 BASF Catalysts LLC Process for the preparation of a cobalt-zinc oxide Fischer-Tropsch catalyst
CN102277608A (zh) * 2011-07-12 2011-12-14 大连理工大学 一种制备二氧化钛纳米管粉末的工艺
MX349068B (es) * 2012-06-21 2017-06-28 Inst Mexicano Del Petróleo Material semiconductor de titania nanoestructurada y proceso de obtencion.
WO2014140973A1 (en) * 2013-03-14 2014-09-18 Sasol Technology (Pty) Limited A hydrocarbon synthesis process using a cobalt-based catalyst supported on a silicon carbide comprising support
WO2015010941A1 (en) * 2013-07-24 2015-01-29 Shell Internationale Research Maatschappij B.V. Process for preparing a chlorine comprising catalyst, the prepared catalyst, and its use
EP3024577A1 (en) 2013-07-24 2016-06-01 Shell Internationale Research Maatschappij B.V. Process for preparing a chlorine comprising catalyst, the prepared catalyst, and its use
US20160160128A1 (en) * 2013-07-24 2016-06-09 Shell Oil Company Method for starting up a fischer tropsch process
WO2015124149A1 (de) * 2014-02-21 2015-08-27 Sachtleben Chemie Gmbh Katalysatorprecursormaterial auf TiO2-Basis, dessen Herstellung und dessen Verwendung
US11691127B2 (en) * 2014-12-19 2023-07-04 Bp P.L.C. Process for preparation of a supported cobalt-containing Fishcer-Tropsch synthesis
EA033748B1 (ru) * 2015-02-25 2019-11-21 Sasol Tech Pty Ltd Способ синтеза углеводородов
CN106466591A (zh) * 2015-08-20 2017-03-01 吉林化工学院 一种用于富集微囊藻毒素的磁性纳米粒子的制备方法
CN106367809B (zh) * 2016-10-31 2019-01-11 南昌大学 一种制备超亲水性能的单晶锐钛矿TiO2纳米棒阵列的方法
CN106622198B (zh) * 2016-11-29 2019-07-23 湖北大学 一种复合纳米结构二氧化钛光催化剂及其制备方法
CN108906078B (zh) * 2018-07-20 2021-05-11 上海理工大学 一种高效Pd/Co3O4块体催化剂的制备方法
CN110028108A (zh) * 2019-05-24 2019-07-19 江苏特丰新材料科技有限公司 一种新型的钛酸盐功能材料制备工艺
CN111604042B (zh) * 2020-04-10 2023-04-11 安徽迪诺环保新材料科技有限公司 一种金红石晶型脱硝催化剂载体及其制备方法
CN113751017B (zh) * 2020-06-05 2024-01-19 北京低碳清洁能源研究院 费托合成催化剂及其制备方法和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1541928A (en) * 1975-12-23 1979-03-14 Sakai Chemical Industry Co Production of shaped catalysts or carriers comprising titanium oxide
US4595703A (en) * 1984-06-29 1986-06-17 Exxon Research And Engineering Co. Preparation of hydrocarbons from synthesis gas
EP0833807B1 (en) * 1995-06-16 2004-04-14 Shell Internationale Researchmaatschappij B.V. Catalyst and process for the preparation of hydrocarbons
EP0826633B1 (en) * 1996-08-30 2002-03-13 Showa Denko Kabushiki Kaisha Particles, aqueous dispersion and film of titanium oxide, and preparation thereof
EP1083152B1 (en) * 1998-05-14 2006-01-25 Showa Denko Kabushiki Kaisha Titanium oxide sol, thin film, and processes for producing these
JP2002173370A (ja) * 2000-12-01 2002-06-21 Toyota Central Res & Dev Lab Inc チタニア系多孔体及び触媒
US7378371B2 (en) * 2001-12-21 2008-05-27 Show A Denko K.K. Highly active photocatalyst particles, method of production therefor, and use thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2678206C1 (ru) * 2017-12-20 2019-01-24 Федеральное государственное бюджетное учреждение науки Институт металлургии и материаловедения им. А.А. Байкова Российской академии наук (ИМЕТ РАН) Способ получения фотокаталитического диоксида титана модификации анатаз и брукит на поверхности керамического изделия из рутила, полученного окислительным конструированием

Also Published As

Publication number Publication date
CA2540353A1 (en) 2005-04-07
US20070123594A1 (en) 2007-05-31
EP1667948A1 (en) 2006-06-14
MXPA06003360A (es) 2006-06-08
AU2004276016A1 (en) 2005-04-07
NO20061877L (no) 2006-04-28
WO2005030680A1 (en) 2005-04-07
ZA200602003B (en) 2007-05-30

Similar Documents

Publication Publication Date Title
RU2006114748A (ru) Носители из диоксида титана для катализаторов процесса фишера-тропша
Li et al. Mechanism of the Mn promoter via CoMn spinel for morphology control: formation of Co2C nanoprisms for Fischer–Tropsch to olefins reaction
Hernández Mejía et al. Cobalt–Nickel Nanoparticles Supported on Reducible Oxides as Fischer–Tropsch Catalysts
Keyvanloo et al. Supported iron Fischer–Tropsch catalyst: superior activity and stability using a thermally stable silica-doped alumina support
AU2001281920B2 (en) Catalyst and process for the preparation of hydrocarbons
JP2849134B2 (ja) 改良チタニア触媒、その製造およびフィッシャー・トロプシュ合成における使用
CN103582525B (zh) 水-煤气变换催化剂
AU2010291054A1 (en) Fischer-Tropsch catalysts
AU2005308788B2 (en) Catalytic process for the conversion of Co (II)hydroxide in Co (III)oxidehydroxide
BR112012009623B1 (pt) produção de olefinas inferiores a partir de gás de síntese
CN103201030A (zh) 关于费-托催化剂的改进
EP2740534A1 (en) Core-shell particles with catalytic activity and the proces of their preparation. Method of preparation of Fischer-Tropsch catalyst comprising said paricles.
CN106457221A (zh) 用于制备具有改善的活性和寿命性能的费托催化剂的方法
AU2005318138B2 (en) Process for preparing a catalyst
Barrientos et al. Fischer–Tropsch Synthesis Over Zr-Promoted Co/γ-Al 2 O 3 Catalysts
Niamnuy et al. Synthesis of dimethyl ether via CO2 hydrogenation: Effect of the drying technique of alumina on properties and performance of alumina-supported copper catalysts
WO2008090105A2 (en) Process for preparing a catalyst
Lee et al. Physicochemical attributes of oxide supported Mo2N catalysts synthesised via sulphide nitridation

Legal Events

Date Code Title Description
FA94 Acknowledgement of application withdrawn (non-payment of fees)

Effective date: 20090817