RU2004132347A - Цианидные катализаторы на основе двух металлов, способ их получения и способ получения полиола - Google Patents
Цианидные катализаторы на основе двух металлов, способ их получения и способ получения полиола Download PDFInfo
- Publication number
- RU2004132347A RU2004132347A RU2004132347/04A RU2004132347A RU2004132347A RU 2004132347 A RU2004132347 A RU 2004132347A RU 2004132347/04 A RU2004132347/04 A RU 2004132347/04A RU 2004132347 A RU2004132347 A RU 2004132347A RU 2004132347 A RU2004132347 A RU 2004132347A
- Authority
- RU
- Russia
- Prior art keywords
- catalyst
- carbon
- atoms
- carbon atom
- unsaturated
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims 31
- 229910052751 metal Inorganic materials 0.000 title claims 12
- 239000002184 metal Substances 0.000 title claims 12
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 title claims 6
- 150000002739 metals Chemical class 0.000 title claims 4
- 229920005862 polyol Polymers 0.000 title claims 3
- 150000003077 polyols Chemical class 0.000 title claims 3
- 238000004519 manufacturing process Methods 0.000 title 2
- 229910052799 carbon Inorganic materials 0.000 claims 39
- 238000000034 method Methods 0.000 claims 25
- 150000001721 carbon Chemical group 0.000 claims 24
- 229920000642 polymer Polymers 0.000 claims 21
- 150000003509 tertiary alcohols Chemical class 0.000 claims 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 15
- 125000004429 atom Chemical group 0.000 claims 15
- 125000004432 carbon atom Chemical group C* 0.000 claims 15
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 7
- HNVRRHSXBLFLIG-UHFFFAOYSA-N 3-hydroxy-3-methylbut-1-ene Chemical compound CC(C)(O)C=C HNVRRHSXBLFLIG-UHFFFAOYSA-N 0.000 claims 6
- -1 cyanide compound Chemical class 0.000 claims 5
- 239000007864 aqueous solution Substances 0.000 claims 4
- BZAZNULYLRVMSW-UHFFFAOYSA-N 2-Methyl-2-buten-3-ol Natural products CC(C)=C(C)O BZAZNULYLRVMSW-UHFFFAOYSA-N 0.000 claims 3
- CEBKHWWANWSNTI-UHFFFAOYSA-N 2-methylbut-3-yn-2-ol Chemical compound CC(C)(O)C#C CEBKHWWANWSNTI-UHFFFAOYSA-N 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 3
- 150000002009 diols Chemical class 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- 150000002825 nitriles Chemical class 0.000 claims 3
- 229920005906 polyester polyol Polymers 0.000 claims 3
- 150000003839 salts Chemical class 0.000 claims 3
- 239000000725 suspension Substances 0.000 claims 3
- 238000005406 washing Methods 0.000 claims 3
- 229910052725 zinc Inorganic materials 0.000 claims 3
- 239000011701 zinc Substances 0.000 claims 3
- 238000002955 isolation Methods 0.000 claims 2
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 239000011949 solid catalyst Substances 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
- B01J27/26—Cyanides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/08—Simple or complex cyanides of metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/08—Simple or complex cyanides of metals
- C01C3/11—Complex cyanides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
- B01J2531/26—Zinc
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyethers (AREA)
- Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Epoxy Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/703,928 US20050101477A1 (en) | 2003-11-07 | 2003-11-07 | Unsaturated tertiary alcohols as ligands for active dmc catalysts |
| US10/703,928 | 2003-11-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2004132347A true RU2004132347A (ru) | 2006-04-20 |
Family
ID=34435583
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2004132347/04A RU2004132347A (ru) | 2003-11-07 | 2004-11-05 | Цианидные катализаторы на основе двух металлов, способ их получения и способ получения полиола |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US20050101477A1 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1529566A1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP2005139456A (cg-RX-API-DMAC7.html) |
| KR (1) | KR20050044276A (cg-RX-API-DMAC7.html) |
| CN (1) | CN100434176C (cg-RX-API-DMAC7.html) |
| BR (1) | BRPI0406100A (cg-RX-API-DMAC7.html) |
| CA (1) | CA2486444A1 (cg-RX-API-DMAC7.html) |
| MX (1) | MXPA04010982A (cg-RX-API-DMAC7.html) |
| RU (1) | RU2004132347A (cg-RX-API-DMAC7.html) |
| SG (1) | SG112032A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007002555A1 (de) | 2007-01-17 | 2008-07-24 | Bayer Materialscience Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE102010040517A1 (de) * | 2010-09-09 | 2012-03-15 | Bayer Materialscience Aktiengesellschaft | Verfahren zur Herstellung von Polyetherpolyolen |
| KR101404702B1 (ko) | 2011-03-08 | 2014-06-17 | 에스케이이노베이션 주식회사 | 에테르 결합 단위체를 함유한 이산화탄소/에폭사이드 공중합체의 제조 방법 |
| EP2604641A1 (de) * | 2011-12-16 | 2013-06-19 | Bayer Intellectual Property GmbH | Verfahren zur Herstellung von Polyetherestercarbonatpolyolen |
| GB201515350D0 (en) | 2015-08-28 | 2015-10-14 | Econic Technologies Ltd | Method for preparing polyols |
| GB201717441D0 (en) | 2017-10-24 | 2017-12-06 | Econic Tech Ltd | A polymerisation process |
| GB201814526D0 (en) | 2018-09-06 | 2018-10-24 | Econic Tech Ltd | Methods for forming polycarbonate ether polyols and high molecular weight polyether carbonates |
| GB201906214D0 (en) | 2019-05-02 | 2019-06-19 | Econic Tech Ltd | A polyol block copolymer, compositions and processes therefor |
| GB201906210D0 (en) | 2019-05-02 | 2019-06-19 | Econic Tech Limited | A polyol block copolymer, compositions and processes therefor |
| GB202003003D0 (en) | 2020-03-02 | 2020-04-15 | Econic Tech Ltd | A polyol block copolymer |
| GB202003002D0 (en) | 2020-03-02 | 2020-04-15 | Crane Ltd | Method of preparation of a polyol block copolymer |
| GB202017531D0 (en) | 2020-11-05 | 2020-12-23 | Econic Tech Limited | (poly)ol block copolymer |
| MX2024001871A (es) | 2021-08-11 | 2024-03-04 | Econic Tech Ltd | Metodo para preparar tensoactivos mediante copolimerizacion de epoxidos y co2 utilizando una mezcla de un catalizador bimetalico macrociclico y un catalizador de cianuro bimetalico. |
| GB202115335D0 (en) | 2021-10-25 | 2021-12-08 | Econic Tech Ltd | Surface-active agent |
| GB2626546A (en) | 2023-01-25 | 2024-07-31 | Econic Tech Ltd | Surface-active agent |
| GB2626989A (en) | 2023-02-10 | 2024-08-14 | Econic Tech Ltd | Surface-active agent |
| WO2024223596A1 (en) | 2023-04-25 | 2024-10-31 | Unilever Ip Holdings B.V. | Compositions |
| GB2629367A (en) | 2023-04-25 | 2024-10-30 | Econic Tech Ltd | Surface-active agent |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1063525A (en) * | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
| US3829505A (en) * | 1970-02-24 | 1974-08-13 | Gen Tire & Rubber Co | Polyethers and method for making the same |
| US3941849A (en) * | 1972-07-07 | 1976-03-02 | The General Tire & Rubber Company | Polyethers and method for making the same |
| US5158922A (en) * | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| US5470813A (en) * | 1993-11-23 | 1995-11-28 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts |
| US5712216A (en) * | 1995-05-15 | 1998-01-27 | Arco Chemical Technology, L.P. | Highly active double metal cyanide complex catalysts |
| US5482908A (en) * | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5545601A (en) * | 1995-08-22 | 1996-08-13 | Arco Chemical Technology, L.P. | Polyether-containing double metal cyanide catalysts |
| US5783513A (en) * | 1997-03-13 | 1998-07-21 | Arco Chemical Technology, L.P. | Process for making double metal cyanide catalysts |
| US6505503B1 (en) * | 1998-12-21 | 2003-01-14 | Teresi Publications, Inc. | Stationary drag racing simulation system |
| ATE323119T1 (de) * | 1999-07-09 | 2006-04-15 | Dow Global Technologies Inc | Polymerisierung von ethylenoxid mit der verwendung von metallcyanidkatalysatoren |
| WO2001004177A1 (en) * | 1999-07-09 | 2001-01-18 | The Dow Chemical Company | Metal cyanide catalysts on inorganic supports |
| US6376645B1 (en) * | 1999-07-09 | 2002-04-23 | The Dow Chemical Company | Complexing agent-modified hexacyanometallate hexanitrometallate catalysts |
| US6642423B2 (en) * | 1999-07-09 | 2003-11-04 | Dow Global Technologies, Inc. | Polymerization of ethylene oxide using metal cyanide catalysts |
-
2003
- 2003-11-07 US US10/703,928 patent/US20050101477A1/en not_active Abandoned
-
2004
- 2004-10-26 EP EP04025430A patent/EP1529566A1/en not_active Ceased
- 2004-11-01 CA CA002486444A patent/CA2486444A1/en not_active Abandoned
- 2004-11-05 SG SG200406425A patent/SG112032A1/en unknown
- 2004-11-05 MX MXPA04010982A patent/MXPA04010982A/es not_active Application Discontinuation
- 2004-11-05 KR KR1020040089636A patent/KR20050044276A/ko not_active Withdrawn
- 2004-11-05 RU RU2004132347/04A patent/RU2004132347A/ru not_active Application Discontinuation
- 2004-11-08 BR BR0406100-4A patent/BRPI0406100A/pt not_active IP Right Cessation
- 2004-11-08 CN CNB200410088381XA patent/CN100434176C/zh not_active Expired - Fee Related
- 2004-11-08 JP JP2004323391A patent/JP2005139456A/ja not_active Withdrawn
-
2005
- 2005-01-07 US US11/031,733 patent/US20050143606A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005139456A (ja) | 2005-06-02 |
| BRPI0406100A (pt) | 2005-11-08 |
| CN1628905A (zh) | 2005-06-22 |
| SG112032A1 (en) | 2005-06-29 |
| MXPA04010982A (es) | 2005-10-26 |
| CA2486444A1 (en) | 2005-05-07 |
| EP1529566A1 (en) | 2005-05-11 |
| KR20050044276A (ko) | 2005-05-12 |
| US20050143606A1 (en) | 2005-06-30 |
| HK1079723A1 (zh) | 2006-04-13 |
| CN100434176C (zh) | 2008-11-19 |
| US20050101477A1 (en) | 2005-05-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20090116 |