RO79816B - Procedeu de preparare a unor carboxamide substituite - Google Patents
Procedeu de preparare a unor carboxamide substituiteInfo
- Publication number
- RO79816B RO79816B RO99706A RO9970679A RO79816B RO 79816 B RO79816 B RO 79816B RO 99706 A RO99706 A RO 99706A RO 9970679 A RO9970679 A RO 9970679A RO 79816 B RO79816 B RO 79816B
- Authority
- RO
- Romania
- Prior art keywords
- beta
- carboxylic acid
- acid amides
- unsaturated
- alpha
- Prior art date
Links
- 150000003857 carboxamides Chemical class 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- -1 N-substituted carboxylic acid amides Chemical class 0.000 abstract 5
- 238000000034 method Methods 0.000 abstract 3
- 229920000642 polymer Polymers 0.000 abstract 3
- 239000000654 additive Substances 0.000 abstract 2
- 230000003311 flocculating effect Effects 0.000 abstract 2
- 230000014759 maintenance of location Effects 0.000 abstract 2
- 239000002480 mineral oil Substances 0.000 abstract 2
- 150000003141 primary amines Chemical class 0.000 abstract 2
- 238000004062 sedimentation Methods 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229920006317 cationic polymer Polymers 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000013067 intermediate product Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000007056 transamidation reaction Methods 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F20/60—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M149/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
- D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
- D21H17/45—Nitrogen-containing groups
- D21H17/455—Nitrogen-containing groups comprising tertiary amine or being at least partially quaternised
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
Inventia se refera la un procedeu pentru prepararea unor carboxamide substituite, nesaturate în pozitia alfa, beta cu formula generala I: (vezi formula) în care R1 si R2 reprezinta hidrogen sau metil, Y reprezinta un radical bivalent liniar cu 2...18 atomi de carbon sau un radical bivalent ramificat: (vezi formula) în care R6 si R7 reprezinta fiecare grupe alchil inferioare cu 1...4 atomi de carbon sau fenil sau formeaza împreuna un radical ciclohexil sau ciclopentil, n reprezinta un numar cuprins între 0 si 10, X reprezinta un hidrogen sau radicalul -N R4, R5, în care R4 si R5 sunt radicali alchil cu 1...4 atomi de carbon sau cicloalcoxi cu 3...8 atomi de carbon prin transmiterea amidelor beta-substituite cu formula generala II: (vezi formula) în care R1 si R2....
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782856383 DE2856383C2 (de) | 1978-12-27 | 1978-12-27 | Verfahren zur Herstellung von alpha, beta -ungesättigten N-substituierten Säureamiden und ihre Verwendung zur Herstellung von Polymerisaten sowie das N-(2,2-Dimethyl-3-dimethylaminopropyl)-crotonsäureamid |
| DE19792911642 DE2911642C2 (de) | 1979-03-24 | 1979-03-24 | Verfahren zur Herstellung von α,β-ungesättigten N-substituierten Carbonsäureamiden und ihre Verwendung zur Herstellung von Polymerisaten sowie das N-(N',N',2,2 Tetramethyl-3-aminopropyl)-methacrylamid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO79816B true RO79816B (ro) | 1983-01-30 |
| RO79816A RO79816A (ro) | 1983-02-01 |
Family
ID=25777091
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO7999706A RO79816A (ro) | 1978-12-27 | 1979-12-26 | Procedeu de preparare a unor carboxamide substituite |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US4408073A (ro) |
| EP (2) | EP0013416B1 (ro) |
| AT (1) | ATE15377T1 (ro) |
| BR (1) | BR7908569A (ro) |
| CA (1) | CA1129883A (ro) |
| DD (2) | DD148213A5 (ro) |
| DE (2) | DE2967510D1 (ro) |
| PL (1) | PL130693B1 (ro) |
| RO (1) | RO79816A (ro) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3209800C2 (de) * | 1982-03-18 | 1990-03-08 | Chemische Fabrik Stockhausen GmbH, 4150 Krefeld | Verfahren zur Herstellung von N-(tert. Aminoalkyl)acrylamiden |
| DE3402599C2 (de) * | 1984-01-26 | 1986-02-27 | Chemische Fabrik Stockhausen GmbH, 4150 Krefeld | Verfahren zur Herstellung von N-substituierten α,ß-ungesättigten Carbonsäureamiden |
| US4754056A (en) * | 1985-04-05 | 1988-06-28 | Desoto, Inc. | Radiation-curable coatings containing reactive pigment dispersants |
| US4673705A (en) * | 1985-04-05 | 1987-06-16 | Desoto, Inc. | Radiation-curable coatings containing reactive pigment dispersants |
| GB8512937D0 (en) * | 1985-05-22 | 1985-06-26 | Allied Colloids Ltd | Water treatment |
| DE3544909A1 (de) * | 1985-12-19 | 1987-06-25 | Stockhausen Chem Fab Gmbh | Copolymere aus acrylamid und dimethylaminopropylacrylamid als flockungsmittel und verfahren zum entwaessern von klaerschlaemmen unter verwendung dieser flockungsmittel |
| DE3800199A1 (de) * | 1988-01-07 | 1989-07-20 | Sandoz Ag | Seitenkettenhaltige vinylpolymere |
| US4954538A (en) * | 1988-12-19 | 1990-09-04 | American Cyanamid Company | Micro-emulsified glyoxalated acrylamide polymers |
| CA2040996A1 (en) * | 1990-05-02 | 1991-11-03 | Robert L. Albright | Composition and method for controlling cholesterol |
| US5451397A (en) * | 1992-12-21 | 1995-09-19 | Rohm And Haas Company | Bile acid sequestrant |
| US5498678A (en) * | 1992-12-21 | 1996-03-12 | Rohm And Haas Company | Suspension polymerization process for water-soluble monomers |
| US5858886A (en) * | 1996-07-02 | 1999-01-12 | Milliken Research Corporation | Low permeability airbag fabric |
| WO1999057162A1 (en) * | 1998-05-02 | 1999-11-11 | Bp Chemicals Limited | Polymers and their uses |
| GB9810370D0 (en) * | 1998-05-14 | 1998-07-15 | Bp Exploration Operating | Polymer products and their uses in oil |
| DE19829757A1 (de) | 1998-07-03 | 2000-01-05 | Stockhausen Chem Fab Gmbh | Wässrige Klebemitteldispersionen und deren Verwendung zur Herstellung von mehrlagigen Papieren |
| US7425595B2 (en) * | 2003-12-15 | 2008-09-16 | Absorbent Technologies, Inc. | Superabsorbent polymer products including a beneficial additive and methods of making and application |
| BRPI0417597B1 (pt) * | 2003-12-15 | 2021-07-27 | Upl Limited | Método para formação de um produto de polímero superabsorvente e produto de polímero superabsorvente |
| CA2576967A1 (en) * | 2004-08-27 | 2006-03-09 | Absorbent Technologies, Inc. | Superabsorbent polymers in agricultural applications |
| US20070167330A1 (en) * | 2006-01-17 | 2007-07-19 | Savich Milan H | Superabsorbent polymer applicator |
| US20070163172A1 (en) * | 2006-01-17 | 2007-07-19 | Savich Milan H | Biodegradable mat containing superabsorbent polymers |
| US7607259B2 (en) * | 2006-01-17 | 2009-10-27 | Absorbent Technologies, Inc. | Superabsorbent polymer root dip |
| US7687661B2 (en) * | 2006-03-15 | 2010-03-30 | Battelle Memorial Institute | Method for conversion of β-hydroxy carbonyl compounds |
| US20070219397A1 (en) * | 2006-03-15 | 2007-09-20 | Battelle Memorial Institute | Method for conversion of beta-hydroxy carbonyl compounds |
| US9596801B2 (en) | 2010-10-25 | 2017-03-21 | Vjs Investments Limited | Superabsorbent polymer seed coatings and associated methods |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2649438A (en) * | 1950-10-28 | 1953-08-18 | Ind Rayon Corp | Copolymers of acrylonitrile and basic acrylamides |
| US2980657A (en) * | 1954-07-06 | 1961-04-18 | Rohm & Haas | Quaternary ammonium compounds of polymers of acrylamido type and methods for making them |
| US3043822A (en) * | 1957-08-01 | 1962-07-10 | Ciba Ltd | New polymerization process |
| US3188228A (en) * | 1958-05-14 | 1965-06-08 | Du Pont | Method of graft polymerizing an organic compound to a solid shaped condensation polymer structure |
| US3170901A (en) * | 1960-12-27 | 1965-02-23 | Rohm & Hans Company | Novel quaternary ammonium compounds and polymers thereof |
| US3424820A (en) * | 1966-12-21 | 1969-01-28 | Du Pont | Graft copolymers of amine compounds on polyamide and polyester substrates |
| US3666810A (en) * | 1969-06-11 | 1972-05-30 | Lubrizol Corp | Novel n-3-aminoalkyl amides, polymers thereof, and method for their preparation |
| US3856689A (en) * | 1969-06-11 | 1974-12-24 | Lubrizol Corp | Oil-soluble polymers of n-3-aminoalkyl acrylamides, and lubricants containing them |
| DE2233337A1 (de) * | 1969-06-11 | 1974-01-10 | Lubrizol Corp | Polymerisate von amiden und ihre verwendung als flockungsmittel |
| US3883491A (en) * | 1969-06-11 | 1975-05-13 | Lubrizol Corp | Novel N-3-aminoalkyl amides, polymers thereof, and method for their preparation |
| US3661868A (en) * | 1970-05-01 | 1972-05-09 | Dow Chemical Co | Flocculant |
| NL7308872A (ro) * | 1972-07-12 | 1974-01-15 | ||
| NL7309742A (ro) * | 1972-07-24 | 1974-01-28 | ||
| US3914303A (en) * | 1972-09-01 | 1975-10-21 | Cpc International Inc | Preparation of N,N-dialkylacylamides |
| GB1510689A (en) * | 1974-12-19 | 1978-05-10 | Sumitomo Chemical Co | Preparation of water-soluble cationic high polymer |
| US4031138A (en) * | 1976-03-18 | 1977-06-21 | Texaco Development Corporation | Stable substituted acrylamides or methacrylamides |
| DE2623838A1 (de) * | 1976-05-28 | 1977-12-15 | Basf Ag | Verfahren zur herstellung von n-substituierten acrylamiden |
| IN151693B (ro) * | 1978-05-05 | 1983-07-02 | Stockhausen & Cie Chem Fab | |
| DE2819735C2 (de) * | 1978-05-05 | 1982-09-16 | Chemische Fabrik Stockhausen GmbH, 4150 Krefeld | Verfahren zur Herstellung von α,β-ungesättigten N-substituierten Säureamiden |
-
1979
- 1979-12-21 DD DD79218050A patent/DD148213A5/de unknown
- 1979-12-21 DE DE8181103346T patent/DE2967510D1/de not_active Expired
- 1979-12-21 EP EP79105340A patent/EP0013416B1/de not_active Expired
- 1979-12-21 DE DE7979105340T patent/DE2967515D1/de not_active Expired
- 1979-12-21 AT AT81103346T patent/ATE15377T1/de active
- 1979-12-21 DD DD79228049A patent/DD158244A5/de unknown
- 1979-12-21 EP EP81103346A patent/EP0038573B1/de not_active Expired
- 1979-12-24 PL PL1979220782A patent/PL130693B1/pl unknown
- 1979-12-26 RO RO7999706A patent/RO79816A/ro unknown
- 1979-12-26 US US06/107,245 patent/US4408073A/en not_active Expired - Lifetime
- 1979-12-27 CA CA342,641A patent/CA1129883A/en not_active Expired
- 1979-12-27 BR BR7908569A patent/BR7908569A/pt unknown
-
1983
- 1983-07-11 US US06/512,496 patent/US4528350A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0038573A1 (de) | 1981-10-28 |
| PL130693B1 (en) | 1984-08-31 |
| DD158244A5 (de) | 1983-01-05 |
| US4408073A (en) | 1983-10-04 |
| DE2967510D1 (en) | 1985-10-10 |
| EP0013416A1 (de) | 1980-07-23 |
| RO79816A (ro) | 1983-02-01 |
| EP0013416B1 (de) | 1985-09-18 |
| CA1129883A (en) | 1982-08-17 |
| US4528350A (en) | 1985-07-09 |
| BR7908569A (pt) | 1980-09-16 |
| DE2967515D1 (en) | 1985-10-24 |
| PL220782A1 (en) | 1983-01-03 |
| EP0038573B1 (de) | 1985-09-04 |
| ATE15377T1 (de) | 1985-09-15 |
| DD148213A5 (de) | 1981-05-13 |
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