PT78057B - Process for bunding high efficiency chromium electrodeposits - Google Patents
Process for bunding high efficiency chromium electrodeposits Download PDFInfo
- Publication number
- PT78057B PT78057B PT78057A PT7805784A PT78057B PT 78057 B PT78057 B PT 78057B PT 78057 A PT78057 A PT 78057A PT 7805784 A PT7805784 A PT 7805784A PT 78057 B PT78057 B PT 78057B
- Authority
- PT
- Portugal
- Prior art keywords
- iron
- bath
- acid
- substrate
- coating
- Prior art date
Links
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 229910052804 chromium Inorganic materials 0.000 title claims abstract description 45
- 239000011651 chromium Substances 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 40
- 230000008569 process Effects 0.000 title abstract description 11
- 239000002659 electrodeposit Substances 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 134
- 229910052742 iron Inorganic materials 0.000 claims abstract description 67
- 239000000758 substrate Substances 0.000 claims abstract description 44
- 239000002253 acid Substances 0.000 claims abstract description 14
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 229910000640 Fe alloy Inorganic materials 0.000 claims abstract description 7
- 230000001464 adherent effect Effects 0.000 claims abstract description 7
- 238000000151 deposition Methods 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 150000002505 iron Chemical class 0.000 claims abstract description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 3
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 3
- 150000002367 halogens Chemical class 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims description 72
- 239000011248 coating agent Substances 0.000 claims description 70
- 238000011282 treatment Methods 0.000 claims description 47
- 229910052751 metal Inorganic materials 0.000 claims description 28
- 239000002184 metal Substances 0.000 claims description 28
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 23
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims description 23
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- 230000004913 activation Effects 0.000 claims description 4
- 230000008021 deposition Effects 0.000 claims description 4
- 150000004820 halides Chemical class 0.000 claims description 4
- 238000007654 immersion Methods 0.000 claims description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 2
- 238000007747 plating Methods 0.000 abstract description 8
- 239000003054 catalyst Substances 0.000 abstract description 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 abstract description 2
- 230000003213 activating effect Effects 0.000 abstract description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 abstract description 2
- 150000007942 carboxylates Chemical class 0.000 abstract description 2
- 150000001805 chlorine compounds Chemical class 0.000 abstract description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 abstract description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- 150000004673 fluoride salts Chemical class 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- 230000000153 supplemental effect Effects 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 11
- 239000010959 steel Substances 0.000 description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 3
- 229910000358 iron sulfate Inorganic materials 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000010953 base metal Substances 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000004070 electrodeposition Methods 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical group [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910004809 Na2 SO4 Inorganic materials 0.000 description 1
- 229910000978 Pb alloy Inorganic materials 0.000 description 1
- 229910018503 SF6 Inorganic materials 0.000 description 1
- FXXACINHVKSMDR-UHFFFAOYSA-N acetyl bromide Chemical compound CC(Br)=O FXXACINHVKSMDR-UHFFFAOYSA-N 0.000 description 1
- 230000003444 anaesthetic effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005363 electrowinning Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- -1 halide ion Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- IQUGDGIIAQZHGL-UHFFFAOYSA-L iron(2+);dichloride;hydrochloride Chemical compound Cl.[Cl-].[Cl-].[Fe+2] IQUGDGIIAQZHGL-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 229910001256 stainless steel alloy Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- OBTWBSRJZRCYQV-UHFFFAOYSA-N sulfuryl difluoride Chemical compound FS(F)(=O)=O OBTWBSRJZRCYQV-UHFFFAOYSA-N 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/04—Electroplating: Baths therefor from solutions of chromium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/627—Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
- Nonmetallic Welding Materials (AREA)
- Polymerisation Methods In General (AREA)
- Electrolytic Production Of Metals (AREA)
- Chemically Coating (AREA)
- Chemical Treatment Of Metals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/463,465 US4450050A (en) | 1983-02-03 | 1983-02-03 | Process for bonding high efficiency chromium electrodeposits |
Publications (2)
Publication Number | Publication Date |
---|---|
PT78057A PT78057A (en) | 1984-03-01 |
PT78057B true PT78057B (en) | 1986-03-20 |
Family
ID=23840183
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PT78057A PT78057B (en) | 1983-02-03 | 1984-02-02 | Process for bunding high efficiency chromium electrodeposits |
Country Status (15)
Country | Link |
---|---|
US (1) | US4450050A (OSRAM) |
EP (1) | EP0137817B1 (OSRAM) |
JP (1) | JPS60500873A (OSRAM) |
DE (1) | DE3468442D1 (OSRAM) |
EG (1) | EG16172A (OSRAM) |
ES (1) | ES529411A0 (OSRAM) |
GR (1) | GR81725B (OSRAM) |
IN (1) | IN160454B (OSRAM) |
IT (2) | IT8409333A1 (OSRAM) |
NO (2) | NO843974L (OSRAM) |
NZ (1) | NZ207033A (OSRAM) |
PH (1) | PH20218A (OSRAM) |
PT (1) | PT78057B (OSRAM) |
WO (1) | WO1984003109A1 (OSRAM) |
ZA (1) | ZA84794B (OSRAM) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8411063D0 (en) * | 1984-05-01 | 1984-06-06 | Mccormick M | Chromium electroplating |
US4668348A (en) * | 1985-09-26 | 1987-05-26 | M&T Chemicals Inc. | Method for forming adherent, bright, smooth and hard chromium electrodeposits on ferrous metal substrates from high energy efficient chromium baths |
US4664759A (en) * | 1985-10-15 | 1987-05-12 | M&T Chemicals Inc. | Method for forming adherent, bright, smooth and hard chromium electrodeposits on stainless steel substrates from high energy efficient chromium baths |
EP0235173A1 (en) * | 1985-08-09 | 1987-09-09 | M & T Chemicals, Inc. | Process for forming adherent chromium electrodeposits from a high energy efficient bath |
US4585530A (en) * | 1985-08-09 | 1986-04-29 | M&T Chemicals Inc. | Process for forming adherent chromium electrodeposits from high energy efficient bath on ferrous metal substrates |
US5243320A (en) * | 1988-02-26 | 1993-09-07 | Gould Inc. | Resistive metal layers and method for making same |
DE4422877A1 (de) | 1994-06-30 | 1996-01-04 | Gesipa Blindniettechnik | Blindbefestigersetzgerät |
CN103255454A (zh) * | 2013-06-08 | 2013-08-21 | 河北瑞兆激光再制造技术有限公司 | 报废活塞杆的修复工艺 |
CN104227316B (zh) * | 2014-09-30 | 2016-05-25 | 任晓东 | 一种修复井下千斤顶的方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3806429A (en) * | 1972-07-03 | 1974-04-23 | Oxy Metal Finishing Corp | Electrodeposition of bright nickel-iron deposits,electrolytes therefor and coating an article with a composite nickel-iron,chromium coating |
DE2500730C3 (de) * | 1975-01-10 | 1980-04-24 | Bergische Metallwarenfabrik Dillenberg & Co Kg, 5601 Gruiten | Galvanisches Chrombad |
JPS5464034A (en) * | 1977-10-31 | 1979-05-23 | Toyo Kohan Co Ltd | Pretreatment of steel plate treated with electrolytic chromic acid |
DE2908846A1 (de) * | 1978-03-08 | 1979-09-13 | Yissum Res Dev Co | Galvanisches chrombad |
US4188459A (en) * | 1978-09-27 | 1980-02-12 | Whyco Chromium Company, Inc. | Corrosion resistant plating and method utilizing alloys having micro-throwing power |
US4366034A (en) * | 1981-06-04 | 1982-12-28 | Westinghouse Electric Corp. | Hard chromium plating process for cobalt-chromium-tungsten alloys |
-
1983
- 1983-02-03 US US06/463,465 patent/US4450050A/en not_active Expired - Fee Related
-
1984
- 1984-02-01 JP JP59501013A patent/JPS60500873A/ja active Granted
- 1984-02-01 IN IN96/DEL/84A patent/IN160454B/en unknown
- 1984-02-01 WO PCT/US1984/000158 patent/WO1984003109A1/en active IP Right Grant
- 1984-02-01 EP EP84901037A patent/EP0137817B1/en not_active Expired
- 1984-02-01 DE DE8484901037T patent/DE3468442D1/de not_active Expired
- 1984-02-02 ZA ZA84794A patent/ZA84794B/xx unknown
- 1984-02-02 ES ES529411A patent/ES529411A0/es active Granted
- 1984-02-02 PT PT78057A patent/PT78057B/pt unknown
- 1984-02-02 GR GR73687A patent/GR81725B/el unknown
- 1984-02-03 IT IT1984A09333A patent/IT8409333A1/it unknown
- 1984-02-03 NZ NZ207033A patent/NZ207033A/en unknown
- 1984-02-03 IT IT09333/84A patent/IT1198780B/it active
- 1984-02-03 PH PH30200A patent/PH20218A/en unknown
- 1984-02-04 EG EG79/84A patent/EG16172A/xx active
- 1984-10-02 NO NO843974A patent/NO843974L/no unknown
- 1984-10-02 NO NO843973A patent/NO843973L/no unknown
Also Published As
Publication number | Publication date |
---|---|
IT1198780B (it) | 1988-12-21 |
GR81725B (OSRAM) | 1984-12-12 |
EG16172A (en) | 1987-05-30 |
JPS648718B2 (OSRAM) | 1989-02-15 |
PT78057A (en) | 1984-03-01 |
JPS60500873A (ja) | 1985-06-06 |
IT8409333A0 (it) | 1984-02-03 |
DE3468442D1 (en) | 1988-02-11 |
EP0137817A1 (en) | 1985-04-24 |
IT8409333A1 (it) | 1985-08-03 |
ES8502485A1 (es) | 1985-01-01 |
NO843974L (no) | 1984-10-02 |
ZA84794B (en) | 1985-03-27 |
EP0137817A4 (en) | 1985-09-26 |
WO1984003109A1 (en) | 1984-08-16 |
NZ207033A (en) | 1987-05-29 |
ES529411A0 (es) | 1985-01-01 |
NO843973L (no) | 1984-10-02 |
US4450050A (en) | 1984-05-22 |
IN160454B (OSRAM) | 1987-07-11 |
EP0137817B1 (en) | 1988-01-07 |
PH20218A (en) | 1986-10-21 |
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