PT1970214E - Pigmentação parcial de uma camada de cobertura destinada a evitar interferências em peças de alumínio ou peças que compreendem alumínio - Google Patents

Pigmentação parcial de uma camada de cobertura destinada a evitar interferências em peças de alumínio ou peças que compreendem alumínio Download PDF

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PT1970214E
PT1970214E PT08004259T PT08004259T PT1970214E PT 1970214 E PT1970214 E PT 1970214E PT 08004259 T PT08004259 T PT 08004259T PT 08004259 T PT08004259 T PT 08004259T PT 1970214 E PT1970214 E PT 1970214E
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pigment
aluminum
sol
gel coating
components
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PT08004259T
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Sueddeutsche Aluminium Manufaktur Gmbh
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60RVEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/04External Ornamental or guard strips; Ornamental inscriptive devices thereon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/18Processes for applying liquids or other fluent materials performed by dipping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/005Processes, not specifically provided for elsewhere, for producing decorative surface effects by altering locally the surface material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • B44C5/04Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0415Ornamental plaques, e.g. decorative panels, decorative veneers containing metallic elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44DPAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
    • B44D5/00Surface treatment to obtain special artistic surface effects or finishes
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    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
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    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1204Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
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    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/125Process of deposition of the inorganic material
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    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/125Process of deposition of the inorganic material
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    • C23C30/00Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
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    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
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    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
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    • C25D11/18After-treatment, e.g. pore-sealing
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    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/18After-treatment, e.g. pore-sealing
    • C25D11/24Chemical after-treatment
    • CCHEMISTRY; METALLURGY
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    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/18After-treatment, e.g. pore-sealing
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    • C25D11/243Chemical after-treatment using organic dyestuffs
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    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
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    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/18After-treatment, e.g. pore-sealing
    • C25D11/24Chemical after-treatment
    • C25D11/246Chemical after-treatment for sealing layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2202/00Metallic substrate
    • B05D2202/20Metallic substrate based on light metals
    • B05D2202/25Metallic substrate based on light metals based on Al
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2601/00Inorganic fillers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2602/00Organic fillers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24926Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including ceramic, glass, porcelain or quartz layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264Up to 3 mils
    • Y10T428/2651 mil or less
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Description

DESCRIÇÃO "PIGMENTAÇÃO PARCIAL DE UMA CAMADA DE COBERTURA DESTINADA A EVITAR INTERFERÊNCIAS EM PEÇAS DE ALUMÍNIO OU PEÇAS QUE COMPREENDEM ALUMÍNIO" A invenção refere-se a uma peça em alumínio ou a uma peça que compreende alumínio, e cuja superfície é tratada, sendo dotada, em particular, de uma ou várias camadas de cobertura. 0 documento WO 2004/063427 divulga um processo para tratar a superfície de peças em alumínio com os passos de anodização ou oxidação anódica, pigmentação ou coloração, ou coloração por interferência, densificação a frio, por meio de uma solução com componentes silicatados e sais de níquel, e/ou densificação a quente, por hidratação. O documento US 3374155 divulga um processo para tratar a superfície de peças em alumínio com os passos: anodização ou oxidação anódica, pigmentação ou coloração, densificação por meio de uma solução silicatado, para formar uma camada cerâmica fina, sem pigmentos refringentes. O tratamento da superfície de peças deste género pode levar a efeitos de interferências ópticas, que geram, entre outros, a impressão de uma estrutura superficial irregular e, por conseguinte, opticamente inestética. 1 A invenção, por conseguinte, tem por base o objectivo de criar um processo para o tratamento da superfície de peças em alumínio, ou de peças que compreendem alumínio que, apesar do tratamento superficial por meio de uma e/ou várias camadas de cobertura, dão uma impressão opticamente irrepreensível, em particular isenta de interferências.
Este objectivo é solucionado, de acordo com a invenção, submetendo a superfície da peça em alumínio, ou da peça que compreende alumínio, em primeiro lugar, a uma oxidação anódica. Isto gera uma estrutura em forma de pente, ou porosa, sobre a superfície que apresenta depressões abertas para o exterior ou poros. Subsequentemente é introduzida, pelo menos, uma substância de pigmentação, em particular uma substância de pigmentação completa, nas depressões ou poros. Alternativamente, ou adicionalmente, introduzem-se substâncias, em particular substâncias metálicas, nas depressões ou poros, em particular, através de um processo de deposição num banho e uma subsequente oxidação das substâncias, em particular por aplicação de uma corrente eléctrica. Por este meio ajusta-se a cor das substâncias, em que também é possível um ajuste "incolor". Em seguida aplica-se, pelo menos, uma camada de cobertura na forma de um revestimento sol-gel silicatado sobre a superfície, em que a camada de cobertura apresenta um pigmento que serve, em particular, para fins de refractância. Utiliza-se portanto um tal revestimento, que esteja dotado de um pigmento deste género. Devido à pigmentação das depressões ou poros e/ou à sua coloração devida às substâncias oxidadas e à pigmentação do revestimento, não ocorrem quaisquer interferências ópticas, de modo que uma superfície assim tratada possui uma aparência completamente uniforme. 2
Segundo um aperfeiçoamento da invenção, está previsto que o revestimento sol-gel seja aplicado com uma espessura de camada de 0,5 μιη a 5 pm. Isto permite alcançar resultados particularmente bons.
Segundo um aperfeiçoamento da invenção, está previsto que o pigmento utilizado para estar presente no revestimento sol-gel seja um pigmento inorgânico. A substância de pigmentação destinada a ser introduzida nas depressões ou nos poros, pode apresentar um pigmento que é igualmente inorgânico. É ainda vantajoso que a estrutura porosa seja concebida na forma de estrutura de poros finos.
Segundo um aperfeiçoamento da invenção, está previsto que seja utilizada uma substância de pigmentação e/ou um pigmento com uma qualquer cor, ou respectivamente com uma qualquer cor, em particular uma cor transparente. Consequentemente podem ser utilizadas para a substância de pigmentação e/ou o pigmento quaisquer cores diferentes ou também iguais, em particular também pigmentos incolores. A invenção refere-se ainda a uma peça em alumínio ou que compreende alumínio, preparada segundo o processo de acordo com as realizações anteriores. A invenção refere-se a uma peça em alumínio ou a uma peça que compreende alumínio. A superfície da peça é submetida a uma oxidação anódica ou anodização, isto é, forma-se uma camada oxidada sobre a superfície. Este processo realiza-se, em particular, o tempo necessário para que se forme uma estrutura em forma de pente, ou porosa, sobre a superfície da peça (quando 3 observada microscopicamente) . A estrutura em forma de pente ou porosa, não é fechada, sendo, pelo contrário, uma construção aberta para o lado superior. Para efeitos de configuração de cor pode-se introduzir, pelo menos, uma substância pigmentada nas depressões desta estrutura em forma de pente ou porosa, em particular uma estrutura de poros finos. A cor de pigmento considerada pode ser qualquer cor, contudo também uma cor transparente. Alternativamente ou adicionalmente, para efeitos de configuração de cor das depressões desta estrutura em forma de pente ou porosa, em particular da estrutura de poros finos, pode-se ajustar uma cor ou um espectro de cores à superfície, por meio de processos de deposição e processos de oxidação, em particular por acção de uma corrente eléctrica, em função do produto de deposição empregue, em particular das substâncias metálicas. Alternativamente ou adicionalmente, a uma configuração colorida, é também concebível uma cor transparente. Subsequentemente aplica-se um revestimento sol-gel silicatado sobre a superfície oxidada anodicamente, em que o revestimento sol-gel é dotado, antes ou durante o processo de revestimento, de um pigmento, de um modo preferido inorgânico, numa fracção volumétrica reduzida de 0,1 a 0,01. Através da adição deste pigmento, que pode ser igualmente configurado em qualquer cor, ou também transparente, evita-se a formação de uma interferência, isto é, as diversas camadas sobre a peça não conduzem a efeitos ópticos de interferência. O revestimento sol-gel é endurecido por aplicação de calor. A espessura de camada do revestimento sol-gel silicatado perfaz, de um modo preferido, 0,5 pm a 5 pm.
Antes da aplicação do revestimento sol-gel e/ou antes ou depois da introdução, nos poros, da substância pigmentada e/ou 4 das substâncias oxidáveis para efeitos de coloração, pode-se efectuar opcionalmente uma densificação, de modo que os poros na região superior se comprimam, sem contudo fechar. A densificação pode ser efectuada, em particular, por hidratação.
Lisboa, 6 de Agosto de 2012 5

Claims (4)

  1. REIVINDICAÇÕES 1. Processo para o tratamento da superfície de peças em alumínio ou de peças que compreendem alumínio, com os seguintes passos: -Oxidação anódica da superfície, - introdução de, pelo menos, uma substância de pigmentação, em particular uma substância de pigmentação completa, em depressões abertas na direcção da superfície ou poros, de uma estrutura em forma de pente ou porosa, gerada pela oxidação anódica da superfície, e/ou - introdução de substâncias oxidáveis em depressões abertas na direcção da superfície ou poros, de uma estrutura em forma de pente ou porosa, gerada pela oxidação anódica da superfície e oxidação destas substâncias, - Aplicação de um revestimento de sol-gel silicatado sobre a superfície, em que o revestimento sol-gel apresenta um pigmento, que serve, em particular, para fins de refractância.
  2. 2. Processo de acordo com a reivindicação 1, caracterizado por o revestimento sol-gel ser aplicado com uma espessura de camada de 0,5 pm a 5 pm. 1 Processo de acordo com qualquer uma das reivindicações anteriores, caracterizado por o pigmento utilizado para estar presente no revestimento sol-gel ser um pigmento inorgânico. Processo de acordo com qualquer uma das reivindicações anteriores, caracterizado por a estrutura porosa ser realizada na forma de uma estrutura de poros finos. Processo de acordo com qualquer uma das reivindicações anteriores, caracterizado por ser utilizada uma substância de pigmentação e/ou um pigmento com uma qualquer cor, ou respectivamente com uma qualquer cor, em particular uma cor transparente.
  3. 6. Processo de acordo com qualquer uma das reivindicações anteriores, caracterizado por ser efectuada uma densificação, em particular por hidratação, da estrutura em forma de pente ou porosa, antes da aplicação do revestimento sol-gel.
  4. 7. Peça em alumínio ou que compreende alumínio, preparada segundo o processo de acordo com uma ou várias das reivindicações anteriores. Lisboa, 6 de Agosto de 2012 2
PT08004259T 2007-03-16 2008-03-07 Pigmentação parcial de uma camada de cobertura destinada a evitar interferências em peças de alumínio ou peças que compreendem alumínio PT1970214E (pt)

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PT08004258T PT1970256E (pt) 2007-03-16 2008-03-07 Peça para veículos automóveis com revestimento sol-gel

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ES2454176T3 (es) 2014-04-09
CN101307478A (zh) 2008-11-19
CA2625779A1 (en) 2008-09-16
US8377561B2 (en) 2013-02-19
DE102008011298A1 (de) 2008-09-18
CN101270477A (zh) 2008-09-24
DK1970214T3 (da) 2012-08-20
EP1970256A3 (de) 2011-01-26
PT1970256E (pt) 2014-04-11
EP1970256B1 (de) 2014-01-15
CA2625751A1 (en) 2008-09-16
SI1970256T1 (sl) 2014-05-30
US20080311362A1 (en) 2008-12-18
US20080261033A1 (en) 2008-10-23
EP1970214A2 (de) 2008-09-17
HRP20120623T1 (hr) 2012-08-31
ES2387510T3 (es) 2012-09-25
CA2625751C (en) 2015-02-24
PL1970214T3 (pl) 2012-10-31
SI1970214T1 (sl) 2012-08-31
CA2625779C (en) 2015-10-06
EP1970214A3 (de) 2011-03-02
EP1970256A2 (de) 2008-09-17
DE102008011296A1 (de) 2008-09-18
HRP20140329T1 (hr) 2014-05-09
US8747641B2 (en) 2014-06-10
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