PL441986A1 - Sposób wytwarzania alkilowych estrów kwasów fosfonooctowych - Google Patents
Sposób wytwarzania alkilowych estrów kwasów fosfonooctowychInfo
- Publication number
- PL441986A1 PL441986A1 PL441986A PL44198622A PL441986A1 PL 441986 A1 PL441986 A1 PL 441986A1 PL 441986 A PL441986 A PL 441986A PL 44198622 A PL44198622 A PL 44198622A PL 441986 A1 PL441986 A1 PL 441986A1
- Authority
- PL
- Poland
- Prior art keywords
- alkyl esters
- phosphonoacetic acids
- phosphonoacetic
- acids
- reaction
- Prior art date
Links
- XUYJLQHKOGNDPB-UHFFFAOYSA-N phosphonoacetic acid Chemical class OC(=O)CP(O)(O)=O XUYJLQHKOGNDPB-UHFFFAOYSA-N 0.000 title abstract 3
- 125000005907 alkyl ester group Chemical group 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 238000003786 synthesis reaction Methods 0.000 abstract 2
- 150000001298 alcohols Chemical group 0.000 abstract 1
- -1 aliphatic alcohols Chemical group 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4075—Esters with hydroxyalkyl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4078—Esters with unsaturated acyclic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4081—Esters with cycloaliphatic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4087—Esters with arylalkanols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Abstract
Przedmiotem zgłoszenia jest sposób wytwarzania alkilowych estrów kwasów fosfonooctowych, przedstawionych wzorem ogólnym 1, znajdujących zastosowanie jako substraty do produkcji alkenów w reakcji Homera-Wadswortha-Emmonsa lub półprodukty w syntezie organicznej do otrzymywania związków o działaniu biologicznie czynnym, w tym farmaceutyków i herbicydów oraz jako prekursory w syntezie materiałów optycznych i polimerów. Sposób polegający na reakcji kwasów fosfonooctowych, z alkoholami alifatycznymi pierwszorzędowymi albo drugorzędowymi, względnie alkoholami zawierającymi wiązania nienasycone, przebiega w obniżonej temperaturze, pod ciśnieniem atmosferycznym i stosunkowo krótkim czasie, z użyciem nietoksycznego katalizatora, bez dodatkowych rozpuszczalników, z bardzo dobrą wydajnością i czystością chemiczną 98 - 99%.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL441986A PL441986A1 (pl) | 2022-08-09 | 2022-08-09 | Sposób wytwarzania alkilowych estrów kwasów fosfonooctowych |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL441986A PL441986A1 (pl) | 2022-08-09 | 2022-08-09 | Sposób wytwarzania alkilowych estrów kwasów fosfonooctowych |
Publications (1)
Publication Number | Publication Date |
---|---|
PL441986A1 true PL441986A1 (pl) | 2024-02-12 |
Family
ID=89855734
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PL441986A PL441986A1 (pl) | 2022-08-09 | 2022-08-09 | Sposób wytwarzania alkilowych estrów kwasów fosfonooctowych |
Country Status (1)
Country | Link |
---|---|
PL (1) | PL441986A1 (pl) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63243092A (ja) * | 1987-03-31 | 1988-10-07 | Hodogaya Chem Co Ltd | ホスホノアセテ−ト誘導体及びその製造法 |
RU2527977C1 (ru) * | 2013-05-27 | 2014-09-10 | Министерство Образования И Науки Российской Федерации, Федеральное Государственное Унитарное Предприятие "Государственный Ордена Трудового Красного Знамени Научно-Исследовательский Институт Химических Реактивов И Особо Чистых Химических Веществ" | Способ получения триметилового эфира фосфонуксусной кислоты |
-
2022
- 2022-08-09 PL PL441986A patent/PL441986A1/pl unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63243092A (ja) * | 1987-03-31 | 1988-10-07 | Hodogaya Chem Co Ltd | ホスホノアセテ−ト誘導体及びその製造法 |
RU2527977C1 (ru) * | 2013-05-27 | 2014-09-10 | Министерство Образования И Науки Российской Федерации, Федеральное Государственное Унитарное Предприятие "Государственный Ордена Трудового Красного Знамени Научно-Исследовательский Институт Химических Реактивов И Особо Чистых Химических Веществ" | Способ получения триметилового эфира фосфонуксусной кислоты |
Non-Patent Citations (1)
Title |
---|
MATTHEW G. LLOYD I IN.: "2014, 16, 2772-2775; oraz materiały dodatkowe", „A ONE-POT C-H INSERTION/OLEFINATION SEQUENCE FOR THE FORMATION OF Α-ALKYLIDENE-Γ-BUTYROLACTONES" * |
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