PL407586A1 - Nanokompozytowy mikroporowaty elastomer poliuretanowy i sposób jego wytwarzania - Google Patents

Nanokompozytowy mikroporowaty elastomer poliuretanowy i sposób jego wytwarzania

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Publication number
PL407586A1
PL407586A1 PL407586A PL40758614A PL407586A1 PL 407586 A1 PL407586 A1 PL 407586A1 PL 407586 A PL407586 A PL 407586A PL 40758614 A PL40758614 A PL 40758614A PL 407586 A1 PL407586 A1 PL 407586A1
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Poland
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weight
parts
amount
graphene oxide
groups
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PL407586A
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English (en)
Inventor
Łukasz Piszczyk
Józef Haponiuk
Michał Strankowski
Magdalena Danowska
Anna Będlin
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Politechnika Gdańska
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Application filed by Politechnika Gdańska filed Critical Politechnika Gdańska
Priority to PL407586A priority Critical patent/PL407586A1/pl
Priority to EP14460073.1A priority patent/EP2921068A1/en
Publication of PL407586A1 publication Critical patent/PL407586A1/pl

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066—Use of inorganic compounding ingredients
    • C08J9/0071—Nanosized fillers, i.e. having at least one dimension below 100 nanometers
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B1/00—Footwear characterised by the material
    • A43B1/14—Footwear characterised by the material made of plastics
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/02—Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04—Plastics, rubber or vulcanised fibre
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2081—Heterocyclic amines; Salts thereof containing at least two non-condensed heterocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6603—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6607—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/042—Graphene or derivatives, e.g. graphene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0066—≥ 150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2350/00—Acoustic or vibration damping material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2410/00—Soles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/022—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments premixing or pre-blending a part of the components of a foamable composition, e.g. premixing the polyol with the blowing agent, surfactant and catalyst and only adding the isocyanate at the time of foaming
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/044—Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Przedmiotem wynalazku jest nanokompozytowy mikroporowaty elastomer poliuretanowy, będący produktem reakcji przedmieszki poliolowej zawierającej od 1 do 90 części wagowych polieteroli i/lub poliestroli o masie cząsteczkowej od 150 do 150000 g/mol, liczbie hydroksylowej od 10 do 700 mg KOH/g i funkcyjności od 1,5 do 6, środka powierzchniowo czynnego w ilości od 0,01 do 15 części wagowych, katalizatorów aminowych i metaloorganicznych w ilości od 0,01 do 15 części wagowych, ekologicznego czynnika porotwórczego w ilości od 0,01 do 20 części wagowych, z czynnikiem izocyjanianowym zawierającym od 1 do 90 części wagowych prepolimeru zawierającego niezwiązane grupy izocyjanianowe w ilości od 1 do 32%, powstałego z oligoeteroli i/lub oligoestroli o masie cząsteczkowej od 400 do 15000 g/mol, liczbie hydroksylowej od 10 do 700 mg KOH/g i funkcyjności od 1 do 4 oraz diizocyjaniany, w których stosunek grup -NCO do grup -OH wynosi od 0,5 do 4 na jeden mol grup -OH, który zawiera nanonapełniacz w ilości 0,01 do 30 części wagowych. Korzystnie nanonapełniaczem jest homogenizowana dyspersja tlenku grafenu lub zredukowanego tlenku grafenu w rozpuszczalnikach polarnych lub niepolarnych, korzystnie z grupy woda, tetrahydrofuran, dimetyloformamid, aceton, albo dyspersja tlenku grafenu lub zredukowanego tlenku grafenu w składniku oligomerowym lub mieszaninie składników opartych o przedmieszkę poliolową lub w składniku izocyjanianowy. Czynnik izocyjanianowy dodany jest w ilości odpowiadającej indeksowi IC od 0,5 do 4. Przedmiotem wynalazku jest także sposób otrzymywania nanokompozytowego mikroporowatego elastomera poliuretanowego.
PL407586A 2014-03-19 2014-03-19 Nanokompozytowy mikroporowaty elastomer poliuretanowy i sposób jego wytwarzania PL407586A1 (pl)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PL407586A PL407586A1 (pl) 2014-03-19 2014-03-19 Nanokompozytowy mikroporowaty elastomer poliuretanowy i sposób jego wytwarzania
EP14460073.1A EP2921068A1 (en) 2014-03-19 2014-10-20 Microporous polyurethane elastomer-based nanocomposite and a method of its manufacturing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL407586A PL407586A1 (pl) 2014-03-19 2014-03-19 Nanokompozytowy mikroporowaty elastomer poliuretanowy i sposób jego wytwarzania

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PL407586A1 true PL407586A1 (pl) 2015-09-28

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KR101960619B1 (ko) * 2015-10-27 2019-07-15 지난 셩취엔 그룹 쉐어 홀딩 코., 엘티디. 그래핀을 포함하는 복합 폴리우레탄 폼, 그 제조방법 및 용도
CN105504199B (zh) * 2015-11-27 2019-01-08 济南圣泉集团股份有限公司 一种含有石墨烯的复合聚氨酯泡沫、制备方法和用途
US10689501B2 (en) 2015-10-27 2020-06-23 Jinan Shengquan Group Share Holding Co., Ltd. Composite polyester material, composite polyester fiber, processes for preparing the same and uses thereof
US9868835B1 (en) * 2016-08-11 2018-01-16 Ford Global Technologies, Llc Bio-based polyurethane foam materials including graphite materials
CN107266914A (zh) * 2017-07-27 2017-10-20 合肥远科服装设计有限公司 一种防脚气中药透气保健鞋垫及其制备方法
GB2568723A (en) * 2017-11-24 2019-05-29 Inoveight Ltd A shoe sole with enhanced performance characteristics
CN108285517B (zh) * 2018-02-12 2021-08-20 化州市联合民生轮业有限公司 一种石墨烯/酯醚共聚型热固性聚氨酯复合材料及其制备方法
CN108659199B (zh) * 2018-04-13 2021-08-20 中国皮革和制鞋工业研究院（晋江）有限公司 改性水性聚氨酯分散体及其制备方法和鞋面整理剂
CN109401276A (zh) * 2018-09-15 2019-03-01 台州学院 一种石墨烯增强聚氨酯复合材料及其制备方法
CN109749406A (zh) * 2019-01-07 2019-05-14 北京慕成防火绝热特种材料有限公司 一种氧化石墨烯泡沫封堵材料、制备方法及应用
CN109810485B (zh) * 2019-01-29 2022-04-15 天津佐源新材料科技有限公司 石墨/弹性树脂复粒、其制法及在制作抛光轮中的应用
CN109880050B (zh) * 2019-03-11 2022-02-01 浙江圆融科技有限公司 一种石墨烯类物质改性的弹性体材料及其制备方法
TW202144285A (zh) * 2020-05-26 2021-12-01 遠東新世紀股份有限公司 石墨烯分散液及其製法、供製備聚氨酯複合材的組成物及聚氨酯複合材
CN113801465B (zh) * 2020-06-12 2023-04-07 中国科学院福建物质结构研究所 聚氨酯微孔发泡弹性体及其制备方法和用途
CN111808263B (zh) * 2020-07-21 2022-07-01 浙江华峰新材料有限公司 一种鞋用聚氨酯组合物的制备方法及其成型体
CN112745476B (zh) * 2020-12-30 2022-09-02 浙江领拓科技股份有限公司 一种高热稳定性的石墨烯改性聚氨酯树脂材料及制法
WO2023092288A1 (zh) * 2021-11-23 2023-06-01 广州市白云化工实业有限公司 石墨炔分散液、双组分聚氨酯胶及其制备方法
CN113980356B (zh) * 2021-11-24 2023-07-14 浙江工业大学 一种含氧叠氮基团功能化改性氧化石墨烯纳米材料
CN114276515B (zh) * 2021-12-08 2023-04-21 山东奥卓新材料有限公司 一种超高强度低动静刚度比聚氨酯微孔弹性垫板及其制备方法

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KR20100096609A (ko) * 2009-02-25 2010-09-02 김영식 흑연산화물을 함유한 난연 폴리우레탄 발포체의 제조방법

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