PL3310846T3 - Ciągły sposób wytwarzania polioli polieterowych o wysokiej zawartości spolimeryzowanego tlenku etylenu z wykorzystaniem kompleksu katalizatora dimetylocyjankowego i związku magnezu, metalu z grupy od 3 do 15 lub metalu z grupy lantanowców - Google Patents

Ciągły sposób wytwarzania polioli polieterowych o wysokiej zawartości spolimeryzowanego tlenku etylenu z wykorzystaniem kompleksu katalizatora dimetylocyjankowego i związku magnezu, metalu z grupy od 3 do 15 lub metalu z grupy lantanowców

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Publication number
PL3310846T3
PL3310846T3 PL16732849.1T PL16732849T PL3310846T3 PL 3310846 T3 PL3310846 T3 PL 3310846T3 PL 16732849 T PL16732849 T PL 16732849T PL 3310846 T3 PL3310846 T3 PL 3310846T3
Authority
PL
Poland
Prior art keywords
group
metal
magnesium
ethylene oxide
continuous process
Prior art date
Application number
PL16732849.1T
Other languages
English (en)
Polish (pl)
Inventor
David A. Babb
Jean-Paul Masy
Mattias SCHAEFER
William A. Koonce
Donald Cameron
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of PL3310846T3 publication Critical patent/PL3310846T3/pl

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C08G65/2606Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
    • C08G65/2609Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645Metals or compounds thereof, e.g. salts
    • C08G65/2651Alkaline earth metals or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645Metals or compounds thereof, e.g. salts
    • C08G65/2654Aluminium or boron; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645Metals or compounds thereof, e.g. salts
    • C08G65/266Metallic elements not covered by group C08G65/2648 - C08G65/2645, or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645Metals or compounds thereof, e.g. salts
    • C08G65/2663Metal cyanide catalysts, i.e. DMC's
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2696Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/22Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the initiator used in polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/28Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
    • C08G2650/58Ethylene oxide or propylene oxide copolymers, e.g. pluronics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Polyethers (AREA)
PL16732849.1T 2015-06-20 2016-06-15 Ciągły sposób wytwarzania polioli polieterowych o wysokiej zawartości spolimeryzowanego tlenku etylenu z wykorzystaniem kompleksu katalizatora dimetylocyjankowego i związku magnezu, metalu z grupy od 3 do 15 lub metalu z grupy lantanowców PL3310846T3 (pl)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562182462P 2015-06-20 2015-06-20
PCT/US2016/037526 WO2016209677A1 (en) 2015-06-20 2016-06-15 Continuous process for making polyether polyols having high polymerized ethylene oxide content using a double metal cyanide catalyst complex and a magnesium, group 3 - group 15 metal or lanthanide series metal compound

Publications (1)

Publication Number Publication Date
PL3310846T3 true PL3310846T3 (pl) 2022-10-10

Family

ID=56264077

Family Applications (1)

Application Number Title Priority Date Filing Date
PL16732849.1T PL3310846T3 (pl) 2015-06-20 2016-06-15 Ciągły sposób wytwarzania polioli polieterowych o wysokiej zawartości spolimeryzowanego tlenku etylenu z wykorzystaniem kompleksu katalizatora dimetylocyjankowego i związku magnezu, metalu z grupy od 3 do 15 lub metalu z grupy lantanowców

Country Status (11)

Country Link
US (1) US10160830B2 (enExample)
EP (1) EP3310846B1 (enExample)
JP (1) JP6785800B2 (enExample)
KR (1) KR102575873B1 (enExample)
CN (1) CN107750262B (enExample)
AR (1) AR104981A1 (enExample)
BR (1) BR112017026729B1 (enExample)
ES (1) ES2927335T3 (enExample)
HU (1) HUE059586T2 (enExample)
PL (1) PL3310846T3 (enExample)
WO (1) WO2016209677A1 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112019023463B1 (pt) * 2017-05-10 2023-10-24 Dow Global Technologies Llc Método para produzir um complexo catalisador, complexo catalisador, complexo catalisador insolúvel em água, complexo catalisador insolúvel em água particulado e método para a produção de um policarbonato
US12024587B2 (en) 2017-09-15 2024-07-02 Dow Global Technologies Llc Continuous process for making polyether polyols
EP3707192B1 (en) * 2017-11-06 2023-06-07 Shell Internationale Research Maatschappij B.V. Process for preparing a polyether polyol with a high ethylene oxide content
US11820861B2 (en) * 2018-12-21 2023-11-21 Dow Global Technologies Llc Polyether polymerization process
WO2020176278A1 (en) * 2019-02-28 2020-09-03 Dow Global Technologies Llc Polyether polymerization process
ES2964144T3 (es) 2019-07-16 2024-04-04 Thyssenkrupp Uhde Gmbh Procedimiento para la producción de alcoxilatos
US20250115711A1 (en) * 2021-10-25 2025-04-10 Dow Global Technologies Llc Polyether polymerization process
CN113831528A (zh) * 2021-11-08 2021-12-24 浙江劲光实业股份有限公司 一种聚亚烷基二醇聚醚的制备方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3278459A (en) 1963-02-14 1966-10-11 Gen Tire & Rubber Co Method of making a polyether using a double metal cyanide complex compound
US3278457A (en) 1963-02-14 1966-10-11 Gen Tire & Rubber Co Method of making a polyether using a double metal cyanide complex compound
US3427335A (en) 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanides complexed with an acyclic aliphatic saturated monoether,an ester and a cyclic ether and methods for making the same
GB1063525A (en) 1963-02-14 1967-03-30 Gen Tire & Rubber Co Organic cyclic oxide polymers, their preparation and tires prepared therefrom
US3427334A (en) 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanides complexed with an alcohol aldehyde or ketone to increase catalytic activity
US3278458A (en) 1963-02-14 1966-10-11 Gen Tire & Rubber Co Method of making a polyether using a double metal cyanide complex compound
US3427256A (en) 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanide complex compounds
US4792620A (en) * 1983-10-14 1988-12-20 Bp Chemicals Limited Carbonylation catalysts
US5470813A (en) 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
US6077978A (en) 1997-09-17 2000-06-20 Arco Chemical Technology L.P. Direct polyoxyalkylation of glycerine with double metal cyanide catalysis
DE19918727A1 (de) * 1999-04-24 2000-10-26 Bayer Ag Langkettige Polyetherpolyole mit hohem Anteil primärer OH-Gruppen
US6884826B2 (en) 2003-06-09 2005-04-26 Bayer Antwerp, N.V. Process for preparing double metal cyanide catalyzed polyols
US20050209438A1 (en) 2004-03-19 2005-09-22 Browne Edward P Starter feed stream acidification in DMC-catalyzed process
DE102010008410A1 (de) * 2010-02-18 2011-08-18 Bayer MaterialScience AG, 51373 Verfahren zur Herstellung von Polyethercarbonatpolyolen
ES2525591T3 (es) * 2010-08-24 2014-12-26 Dow Global Technologies Llc Poliéter-polioles de óxido de etileno/óxido de propileno y poliuretanos preparados a partir de los mismos
CN103403061B (zh) 2010-12-27 2016-06-01 陶氏环球技术有限责任公司 使用双金属氰化物催化剂络合物和镁、第3族-第15族金属或镧系金属化合物的环氧烷烃聚合反应
BR112014014850B1 (pt) * 2011-12-18 2020-09-24 Dow Global Technologies Llc Método para produzir um poliéster-poliéter híbrido
US9708448B2 (en) * 2013-09-27 2017-07-18 Dow Global Technologies Llc Method for making poly(butylene oxide) polyols

Also Published As

Publication number Publication date
US20180162995A1 (en) 2018-06-14
JP6785800B2 (ja) 2020-11-18
BR112017026729A2 (enExample) 2018-08-21
ES2927335T3 (es) 2022-11-04
EP3310846B1 (en) 2022-08-17
HUE059586T2 (hu) 2022-12-28
CN107750262B (zh) 2023-09-08
KR20180022780A (ko) 2018-03-06
JP2018517821A (ja) 2018-07-05
KR102575873B1 (ko) 2023-09-11
BR112017026729B1 (pt) 2022-05-31
US10160830B2 (en) 2018-12-25
WO2016209677A1 (en) 2016-12-29
AR104981A1 (es) 2017-08-30
EP3310846A1 (en) 2018-04-25
CN107750262A (zh) 2018-03-02

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