PL2970553T3 - Nowe polimerowe poliole na bazie polioli z olejów naturalnych - Google Patents
Nowe polimerowe poliole na bazie polioli z olejów naturalnychInfo
- Publication number
- PL2970553T3 PL2970553T3 PL14776520T PL14776520T PL2970553T3 PL 2970553 T3 PL2970553 T3 PL 2970553T3 PL 14776520 T PL14776520 T PL 14776520T PL 14776520 T PL14776520 T PL 14776520T PL 2970553 T3 PL2970553 T3 PL 2970553T3
- Authority
- PL
- Poland
- Prior art keywords
- polyols
- natural oils
- novel polymer
- polymer polyols
- polyols based
- Prior art date
Links
- 229920005862 polyol Polymers 0.000 title 2
- 150000003077 polyols Chemical class 0.000 title 2
- 239000003921 oil Substances 0.000 title 1
- 229920000642 polymer Polymers 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4829—Polyethers containing at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
- C08G71/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
- C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4891—Polyethers modified with higher fatty oils or their acids or by resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
- C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
- C08G18/636—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers characterised by the presence of a dispersion-stabiliser
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/81—Unsaturated isocyanates or isothiocyanates
- C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0016—Foam properties semi-rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2350/00—Acoustic or vibration damping material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/10—Rigid foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Lubricants (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/826,911 US20140275310A1 (en) | 2013-03-14 | 2013-03-14 | Novel polymer polyols based on natural oils polyols |
| PCT/US2014/021704 WO2014159048A1 (en) | 2013-03-14 | 2014-03-07 | Novel polymer polyols based on natural oils polyols |
| EP14776520.0A EP2970553B1 (en) | 2013-03-14 | 2014-03-07 | Novel polymer polyols based on natural oils polyols |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL2970553T3 true PL2970553T3 (pl) | 2019-07-31 |
Family
ID=51530048
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL14776520T PL2970553T3 (pl) | 2013-03-14 | 2014-03-07 | Nowe polimerowe poliole na bazie polioli z olejów naturalnych |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20140275310A1 (enExample) |
| EP (1) | EP2970553B1 (enExample) |
| JP (1) | JP2016512280A (enExample) |
| KR (1) | KR20150128978A (enExample) |
| CN (1) | CN105452317B (enExample) |
| BR (1) | BR112015021958A2 (enExample) |
| CA (1) | CA2903015A1 (enExample) |
| ES (1) | ES2717755T3 (enExample) |
| MX (1) | MX2015012027A (enExample) |
| PL (1) | PL2970553T3 (enExample) |
| SG (2) | SG11201506884QA (enExample) |
| WO (1) | WO2014159048A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3250619B1 (en) * | 2015-01-26 | 2024-04-24 | Henkel AG & Co. KGaA | Functionalized polyurethanes prepared from renewable materials |
| WO2017020124A1 (en) | 2015-07-31 | 2017-02-09 | The Governors Of The University Of Alberta | Synthesis of polyols suitable for castor oil replacement |
| CN109642046B (zh) * | 2016-06-28 | 2022-01-25 | Ptt全球化学公众有限公司 | 基于天然油多元醇的杂化多元醇 |
| US10975190B2 (en) * | 2016-07-21 | 2021-04-13 | Bionanofoam Llc | Bio-based and hydrophilic polyurethane prepolymer and foam made therefrom |
| US10479862B2 (en) * | 2017-12-07 | 2019-11-19 | Covestro Llc | Amine based polymer polyol stabilizers |
| SG11202004869PA (en) | 2017-12-08 | 2020-06-29 | Shell Int Research | Antioxidant for low-density polyurethane foam |
| US10851239B2 (en) * | 2018-11-07 | 2020-12-01 | Covestro Llc | Ethylenically unsaturated macromers produced from a residue of isocyanate manufacturing, related preformed stabilizers, polymer polyols, foam-forming compositions and foams |
| US11407874B2 (en) | 2019-10-07 | 2022-08-09 | Covestro Llc | Polyol premixes, thermally insulating rigid polyurethane foams and methods for their production |
| WO2021145869A1 (en) * | 2020-01-15 | 2021-07-22 | Covestro Llc | Methods of manufacturing short chain polyether polyols |
| US11993733B2 (en) * | 2020-03-18 | 2024-05-28 | Iowa State University Research Foundation, Inc. | Bio-based coatings and adhesives using oils of Physaria fendleri and Euphorbia lagascae |
| CN111440180B (zh) * | 2020-04-07 | 2021-04-20 | 万华化学集团股份有限公司 | 阻燃聚合物多元醇及其制备方法和用途 |
| KR20230029846A (ko) * | 2020-06-25 | 2023-03-03 | 바스프 에스이 | 높은 압축 강도, 낮은 열 전도도, 및 높은 표면 품질을 갖는 폴리이소시아누레이트 수지 발포체 |
| KR20230056674A (ko) | 2020-08-24 | 2023-04-27 | 에보닉 오퍼레이션스 게엠베하 | 온화한 조건하에서 폴리우레탄의 탈중합 |
| CN115989257B (zh) | 2020-08-24 | 2026-03-03 | 赢创运营有限公司 | 聚氨酯解聚方法 |
| CN115160555A (zh) * | 2021-04-02 | 2022-10-11 | 常州强力先端电子材料有限公司 | 一种氧杂环丁烷类聚合物及其制备方法 |
| US12428523B2 (en) | 2021-05-05 | 2025-09-30 | H.B. Fuller Company | Polyurethanes and moisture curable compositions including the same |
| WO2023275031A1 (de) * | 2021-07-02 | 2023-01-05 | Evonik Operations Gmbh | Herstellung von pu-schaumstoffen unter einsatz von recycling-polyolen |
| US12006413B2 (en) | 2022-01-12 | 2024-06-11 | Covestro Llc | Polymer polyols, processes for their preparation, and the use thereof to produce foams exhibiting resistance to combustion |
| CN116178634B (zh) * | 2023-02-01 | 2024-08-20 | 中国林业科学研究院林产化学工业研究所 | 一种桐油基聚合物及其制备方法和应用 |
| US12679922B2 (en) | 2023-06-15 | 2026-07-14 | Covestro Llc | Isocyanate-reactive compositions, rigid polyurethane foams and methods for their production |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7179882B2 (en) * | 2004-08-02 | 2007-02-20 | Bayer Materialscience Llc | Low viscosity polymer polyols |
| US20070060690A1 (en) * | 2005-09-09 | 2007-03-15 | Bayer Materialscience Llc | Low viscosity polymer polyols characterized by a high hydroxyl number |
| EP2001921A2 (en) * | 2006-03-23 | 2008-12-17 | Dow Global Technologies Inc. | Natural oil based polyols with intrinsic surpactancy for polyurethane foaming |
| US7456229B2 (en) * | 2006-05-31 | 2008-11-25 | Bayer Materialscience Llc | Process for the production of rigid and semi-rigid foams with low amounts of diisocyanate using polymer polyols characterized by high solids and a high hydroxyl number and the resultant foams |
| ZA200709673B (en) * | 2006-11-13 | 2009-09-30 | Bayer Materialscience Ag | Process for the preparation of polyether-ester polyols |
| US9284401B2 (en) * | 2006-11-13 | 2016-03-15 | Bayer Materialscience Llc | Process for the preparation of polyether-ester polyols |
| US8097739B2 (en) * | 2007-04-18 | 2012-01-17 | BioBases Technologies, LLC | Process for the manufacture of natural oil hydroxylates |
| EP2225194A4 (en) * | 2007-11-29 | 2012-07-11 | Univ Saskatchewan | METHOD FOR PRODUCING POLYOL BASED CATALYSTS |
| DE102008051882A1 (de) * | 2008-10-16 | 2010-04-29 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyetheresterpolyolen |
| US10239985B2 (en) * | 2008-12-23 | 2019-03-26 | Covestro Llc | Polymer polyols comprising a natural oil base polyol, polyurethane foams comprising these polymer polyols and processes for their preparation |
-
2013
- 2013-03-14 US US13/826,911 patent/US20140275310A1/en not_active Abandoned
-
2014
- 2014-03-07 PL PL14776520T patent/PL2970553T3/pl unknown
- 2014-03-07 CN CN201480015442.1A patent/CN105452317B/zh not_active Expired - Fee Related
- 2014-03-07 EP EP14776520.0A patent/EP2970553B1/en not_active Not-in-force
- 2014-03-07 WO PCT/US2014/021704 patent/WO2014159048A1/en not_active Ceased
- 2014-03-07 MX MX2015012027A patent/MX2015012027A/es unknown
- 2014-03-07 KR KR1020157028864A patent/KR20150128978A/ko not_active Withdrawn
- 2014-03-07 ES ES14776520T patent/ES2717755T3/es active Active
- 2014-03-07 SG SG11201506884QA patent/SG11201506884QA/en unknown
- 2014-03-07 BR BR112015021958A patent/BR112015021958A2/pt not_active IP Right Cessation
- 2014-03-07 SG SG10201707482QA patent/SG10201707482QA/en unknown
- 2014-03-07 CA CA2903015A patent/CA2903015A1/en not_active Abandoned
- 2014-03-07 JP JP2016500813A patent/JP2016512280A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| KR20150128978A (ko) | 2015-11-18 |
| BR112015021958A2 (pt) | 2017-07-18 |
| JP2016512280A (ja) | 2016-04-25 |
| US20140275310A1 (en) | 2014-09-18 |
| SG11201506884QA (en) | 2015-09-29 |
| CN105452317A (zh) | 2016-03-30 |
| CA2903015A1 (en) | 2014-10-02 |
| EP2970553A4 (en) | 2016-10-26 |
| EP2970553B1 (en) | 2019-03-06 |
| EP2970553A1 (en) | 2016-01-20 |
| CN105452317B (zh) | 2018-02-16 |
| MX2015012027A (es) | 2015-11-18 |
| WO2014159048A8 (en) | 2015-12-23 |
| WO2014159048A1 (en) | 2014-10-02 |
| ES2717755T3 (es) | 2019-06-25 |
| SG10201707482QA (en) | 2017-10-30 |
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