CN105452317B - 基于天然油多元醇的新的聚合物多元醇 - Google Patents

基于天然油多元醇的新的聚合物多元醇 Download PDF

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Publication number
CN105452317B
CN105452317B CN201480015442.1A CN201480015442A CN105452317B CN 105452317 B CN105452317 B CN 105452317B CN 201480015442 A CN201480015442 A CN 201480015442A CN 105452317 B CN105452317 B CN 105452317B
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polyol
polyols
mixture
initiator
low viscosity
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Chinese (zh)
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CN105452317A (zh
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R·L·阿德金斯
J·英格兰德
D·S·瓦尔迪乌斯
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Covestro LLC
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Covestro LLC
Bayer MaterialScience LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4829—Polyethers containing at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
    • C08G71/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
    • C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4891—Polyethers modified with higher fatty oils or their acids or by resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/636—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers characterised by the presence of a dispersion-stabiliser
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0016—Foam properties semi-rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2350/00—Acoustic or vibration damping material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/10—Rigid foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
CN201480015442.1A 2013-03-14 2014-03-07 基于天然油多元醇的新的聚合物多元醇 Expired - Fee Related CN105452317B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/826,911 US20140275310A1 (en) 2013-03-14 2013-03-14 Novel polymer polyols based on natural oils polyols
US13/826,911 2013-03-14
PCT/US2014/021704 WO2014159048A1 (en) 2013-03-14 2014-03-07 Novel polymer polyols based on natural oils polyols

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CN105452317A CN105452317A (zh) 2016-03-30
CN105452317B true CN105452317B (zh) 2018-02-16

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US (1) US20140275310A1 (enExample)
EP (1) EP2970553B1 (enExample)
JP (1) JP2016512280A (enExample)
KR (1) KR20150128978A (enExample)
CN (1) CN105452317B (enExample)
BR (1) BR112015021958A2 (enExample)
CA (1) CA2903015A1 (enExample)
ES (1) ES2717755T3 (enExample)
MX (1) MX2015012027A (enExample)
PL (1) PL2970553T3 (enExample)
SG (2) SG11201506884QA (enExample)
WO (1) WO2014159048A1 (enExample)

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EP3250619B1 (en) * 2015-01-26 2024-04-24 Henkel AG & Co. KGaA Functionalized polyurethanes prepared from renewable materials
WO2017020124A1 (en) 2015-07-31 2017-02-09 The Governors Of The University Of Alberta Synthesis of polyols suitable for castor oil replacement
WO2018005538A2 (en) * 2016-06-28 2018-01-04 Myriant Corporation Hybrid polyols based on natural oil polyols
US10975190B2 (en) * 2016-07-21 2021-04-13 Bionanofoam Llc Bio-based and hydrophilic polyurethane prepolymer and foam made therefrom
US10479862B2 (en) * 2017-12-07 2019-11-19 Covestro Llc Amine based polymer polyol stabilizers
LT3720893T (lt) 2017-12-08 2021-08-25 Shell Internationale Research Maatschappij B.V. Antioksidantas mažo tankio poliuretano putplasčiui
US10851239B2 (en) * 2018-11-07 2020-12-01 Covestro Llc Ethylenically unsaturated macromers produced from a residue of isocyanate manufacturing, related preformed stabilizers, polymer polyols, foam-forming compositions and foams
US11407874B2 (en) * 2019-10-07 2022-08-09 Covestro Llc Polyol premixes, thermally insulating rigid polyurethane foams and methods for their production
CN114945617A (zh) * 2020-01-15 2022-08-26 科思创有限公司 生产短链聚醚多元醇的方法
US11993733B2 (en) * 2020-03-18 2024-05-28 Iowa State University Research Foundation, Inc. Bio-based coatings and adhesives using oils of Physaria fendleri and Euphorbia lagascae
CN111440180B (zh) * 2020-04-07 2021-04-20 万华化学集团股份有限公司 阻燃聚合物多元醇及其制备方法和用途
CA3188780A1 (en) * 2020-06-25 2021-12-30 Basf Se Polyisocyanurate resin foam having high compressive strength, low thermal conductivity, and high surface quality
US12291599B2 (en) 2021-05-05 2025-05-06 H.B. Fuller Company Semi-crystalline polyester polyol and method of making the same
WO2023275031A1 (de) * 2021-07-02 2023-01-05 Evonik Operations Gmbh Herstellung von pu-schaumstoffen unter einsatz von recycling-polyolen
US12006413B2 (en) 2022-01-12 2024-06-11 Covestro Llc Polymer polyols, processes for their preparation, and the use thereof to produce foams exhibiting resistance to combustion
CN116178634B (zh) * 2023-02-01 2024-08-20 中国林业科学研究院林产化学工业研究所 一种桐油基聚合物及其制备方法和应用

Citations (3)

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CN101250260A (zh) * 2006-11-13 2008-08-27 拜尔材料科学股份公司 聚醚酯多元醇的制备方法
CN101792512A (zh) * 2008-12-23 2010-08-04 拜尔材料科学有限公司 包含天然油基多元醇的聚合物多元醇,包含这些聚合物多元醇的聚氨酯泡沫材料以及它们的制备方法
US20100305344A1 (en) * 2007-11-29 2010-12-02 University Of Saskatchewan Process for the production of polyol base catalysts

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US7179882B2 (en) * 2004-08-02 2007-02-20 Bayer Materialscience Llc Low viscosity polymer polyols
US20070060690A1 (en) * 2005-09-09 2007-03-15 Bayer Materialscience Llc Low viscosity polymer polyols characterized by a high hydroxyl number
CN101448866A (zh) * 2006-03-23 2009-06-03 陶氏环球技术公司 用于聚氨酯发泡的具有内在表面活性的天然油基多元醇
US7456229B2 (en) * 2006-05-31 2008-11-25 Bayer Materialscience Llc Process for the production of rigid and semi-rigid foams with low amounts of diisocyanate using polymer polyols characterized by high solids and a high hydroxyl number and the resultant foams
US9284401B2 (en) * 2006-11-13 2016-03-15 Bayer Materialscience Llc Process for the preparation of polyether-ester polyols
US8097739B2 (en) * 2007-04-18 2012-01-17 BioBases Technologies, LLC Process for the manufacture of natural oil hydroxylates
DE102008051882A1 (de) * 2008-10-16 2010-04-29 Bayer Materialscience Ag Verfahren zur Herstellung von Polyetheresterpolyolen

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN101250260A (zh) * 2006-11-13 2008-08-27 拜尔材料科学股份公司 聚醚酯多元醇的制备方法
US20100305344A1 (en) * 2007-11-29 2010-12-02 University Of Saskatchewan Process for the production of polyol base catalysts
CN101792512A (zh) * 2008-12-23 2010-08-04 拜尔材料科学有限公司 包含天然油基多元醇的聚合物多元醇,包含这些聚合物多元醇的聚氨酯泡沫材料以及它们的制备方法

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EP2970553A4 (en) 2016-10-26
US20140275310A1 (en) 2014-09-18
EP2970553B1 (en) 2019-03-06
WO2014159048A8 (en) 2015-12-23
BR112015021958A2 (pt) 2017-07-18
CN105452317A (zh) 2016-03-30
KR20150128978A (ko) 2015-11-18
PL2970553T3 (pl) 2019-07-31
MX2015012027A (es) 2015-11-18
SG10201707482QA (en) 2017-10-30
ES2717755T3 (es) 2019-06-25
SG11201506884QA (en) 2015-09-29
WO2014159048A1 (en) 2014-10-02
JP2016512280A (ja) 2016-04-25
EP2970553A1 (en) 2016-01-20
CA2903015A1 (en) 2014-10-02

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