PL2526045T3 - Proces oraz urządzenie do reformowania węglowodorów - Google Patents
Proces oraz urządzenie do reformowania węglowodorówInfo
- Publication number
- PL2526045T3 PL2526045T3 PL11704919T PL11704919T PL2526045T3 PL 2526045 T3 PL2526045 T3 PL 2526045T3 PL 11704919 T PL11704919 T PL 11704919T PL 11704919 T PL11704919 T PL 11704919T PL 2526045 T3 PL2526045 T3 PL 2526045T3
- Authority
- PL
- Poland
- Prior art keywords
- reforming hydrocarbons
- reforming
- hydrocarbons
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
- B01J2208/00221—Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00327—Controlling the temperature by direct heat exchange
- B01J2208/00336—Controlling the temperature by direct heat exchange adding a temperature modifying medium to the reactants
- B01J2208/00353—Non-cryogenic fluids
- B01J2208/00371—Non-cryogenic fluids gaseous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0872—Methods of cooling
- C01B2203/0877—Methods of cooling by direct injection of fluid
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA201000038 | 2010-01-19 | ||
| DKPA201000377 | 2010-04-27 | ||
| EP11704919.7A EP2526045B1 (en) | 2010-01-19 | 2011-01-18 | Process and apparatus for reforming hydrocarbons |
| PCT/EP2011/000179 WO2011088982A1 (en) | 2010-01-19 | 2011-01-18 | Process and apparatus for reforming hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL2526045T3 true PL2526045T3 (pl) | 2018-10-31 |
Family
ID=43858372
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL11704919T PL2526045T3 (pl) | 2010-01-19 | 2011-01-18 | Proces oraz urządzenie do reformowania węglowodorów |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9227844B2 (pl) |
| EP (1) | EP2526045B1 (pl) |
| JP (1) | JP5757581B2 (pl) |
| KR (1) | KR101826064B1 (pl) |
| CN (1) | CN102811944B (pl) |
| BR (1) | BR112012017774B1 (pl) |
| CA (1) | CA2786448C (pl) |
| PL (1) | PL2526045T3 (pl) |
| RU (1) | RU2552460C2 (pl) |
| WO (1) | WO2011088982A1 (pl) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103111239B (zh) * | 2011-11-16 | 2015-09-30 | 西安核设备有限公司 | 一种气冷甲醇反应器 |
| US20140241949A1 (en) * | 2012-03-26 | 2014-08-28 | Sundrop Fuels, Inc. | Radiant heat tube chemical reactor |
| CN106907235B (zh) | 2012-03-30 | 2020-06-02 | 孟山都技术公司 | 用于内燃机的醇重整系统 |
| CN104321272B (zh) * | 2012-03-30 | 2018-01-30 | 孟山都技术公司 | 用于将醇重整成包括氢的气体的混合物的醇重整器 |
| US9358526B2 (en) | 2013-11-19 | 2016-06-07 | Emerging Fuels Technology, Inc. | Optimized fischer-tropsch catalyst |
| US9180436B1 (en) | 2013-11-19 | 2015-11-10 | Emerging Fuels Technology, Inc. | Optimized fischer-tropsch catalyst |
| RU2554008C1 (ru) * | 2014-01-13 | 2015-06-20 | Общество с ограниченной ответственностью "Газохим Техно" | Реактор для парциального окисления углеводородных газов |
| US10525428B2 (en) * | 2015-03-20 | 2020-01-07 | Haldor Topsoe A/S | Boiling water reactor |
| CN105347301B (zh) * | 2015-12-10 | 2018-01-05 | 刘建安 | 一种可燃气体发生装置 |
| EP3397733B1 (en) * | 2015-12-30 | 2022-08-24 | Forestgas Oy | Arrangement and method for preparing a gas |
| US11052364B2 (en) * | 2016-02-08 | 2021-07-06 | Kt Kinetics Technology Spa | Enhanced efficiency endothermic reactor for syngas production with flexible heat recovery to meet low export steam generation |
| US10472236B2 (en) | 2016-10-25 | 2019-11-12 | Technip France | Catalyst tube for reforming |
| CA3042969A1 (en) | 2016-11-09 | 2018-05-17 | 8 Rivers Capital, Llc | Systems and methods for power production with integrated production of hydrogen |
| KR102079036B1 (ko) * | 2016-12-28 | 2020-02-20 | 한국화학연구원 | 발열반응과 흡열반응의 결합에 의한 메탄의 고효율 전환 방법 |
| CN106987284B (zh) * | 2017-04-17 | 2019-08-02 | 东南大学 | 一种生物质合成气中焦油脱除转化的装置及转化方法 |
| EP3406970A1 (en) | 2017-05-26 | 2018-11-28 | ALFA LAVAL OLMI S.p.A. | Vapour and liquid drum for a shell-and-tube heat exchanger |
| DK3406999T3 (da) | 2017-05-26 | 2021-02-01 | Alfa Laval Olmi S P A | Rørkedelvarmeveksler |
| JP7297775B2 (ja) | 2017-11-09 | 2023-06-26 | ８ リバーズ キャピタル，エルエルシー | 水素および二酸化炭素の生成および分離のためのシステムおよび方法 |
| KR20220020842A (ko) | 2019-06-13 | 2022-02-21 | 8 리버스 캐피탈, 엘엘씨 | 추가 생성물들의 공동 발생을 구비하는 동력 생산 |
| KR20220052909A (ko) | 2019-06-28 | 2022-04-28 | 테크니프 에너지스 프랑스 | 튜브형 반응기에 촉매 튜브 조립체를 로딩하는 방법 및 튜브형 반응기를 위한 촉매 튜브 조립체 |
| BR112022003964A2 (pt) * | 2019-09-03 | 2022-05-24 | Haldor Topsoe As | Forno reformador com tubos reformadores suportados |
| JP7544499B2 (ja) * | 2020-03-31 | 2024-09-03 | Ｅｎｅｏｓ株式会社 | 水素供給システム、及び水素製造方法 |
| KR102725906B1 (ko) * | 2021-10-06 | 2024-11-06 | 두산에너빌리티 주식회사 | 복합 개질기 |
| KR102602141B1 (ko) * | 2021-10-06 | 2023-11-14 | 두산에너빌리티 주식회사 | 복합 개질기 |
| CA3238658A1 (en) | 2021-11-15 | 2023-05-19 | Topsoe A/S | Blue hydrogen process and plant |
| AU2022394811A1 (en) | 2021-11-18 | 2024-06-27 | 8 Rivers Capital, Llc | Apparatus for hydrogen production |
| EP4519206B1 (en) | 2022-11-16 | 2025-05-14 | Topsoe A/S | Plant and process for producing hydrogen with improved operation of a low temperature co2 removal unit |
| WO2024149734A1 (en) | 2023-01-10 | 2024-07-18 | Topsoe A/S | Blue hydrogen process and plant |
| CN117181128A (zh) * | 2023-08-16 | 2023-12-08 | 浙江美阳国际工程设计有限公司 | 饱和水移热全自卸套管列管式等温加氢反应器 |
| WO2025078974A2 (en) | 2023-10-09 | 2025-04-17 | 8 Rivers Capital, Llc | Systems and methods for producing hydrogen with integrated capture of carbon dioxide |
| WO2025085678A1 (en) * | 2023-10-17 | 2025-04-24 | Vladimir Mancevski | Indirect thermal decomposition with joule heating of powder |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3334971A (en) * | 1964-08-18 | 1967-08-08 | Chemical Construction Corp | Catalytically reforming hydrocarbon and steam mixtures |
| US3515520A (en) * | 1967-02-13 | 1970-06-02 | Universal Oil Prod Co | Reactor with internal protective sleeve for corrosive systems |
| JPS5382690A (en) | 1976-12-29 | 1978-07-21 | Chiyoda Chem Eng & Constr Co Ltd | Improved preparation of synthetic gas for ammonia |
| US4337170A (en) | 1980-01-23 | 1982-06-29 | Union Carbide Corporation | Catalytic steam reforming of hydrocarbons |
| IT1141031B (it) | 1980-08-29 | 1986-10-01 | Snam Progetti | Procedimento per la preparazione di gas contenenti idrogeno ed azoto |
| JPS59217605A (ja) | 1983-05-26 | 1984-12-07 | Babcock Hitachi Kk | 水素発生装置 |
| DE3430792C1 (de) * | 1984-08-22 | 1986-04-30 | Ed. Züblin AG, 7000 Stuttgart | Verfahren zum Absenken von Membranabschnitten in suspensionsgestuetzte senkrechte Schlitze und Vorrichtung zur Durchfuehrung des Verfahrens |
| DE3663652D1 (en) | 1985-03-05 | 1989-07-06 | Ici Plc | Steam reforming hydrocarbons |
| DE3540782A1 (de) | 1985-11-16 | 1987-05-21 | Uhde Gmbh | Vorrichtung zur endothermen katalytischen spaltung von kohlenwasserstoffen |
| DE68909979D1 (de) | 1988-03-24 | 1993-11-25 | Ici Plc | Zweistufiges Dampfreformierungsverfahren. |
| DK167864B1 (da) * | 1990-02-02 | 1993-12-27 | Topsoe Haldor As | Fremgangsmaade og reaktorsystem til reforming af carbonhydrider under varmeveksling |
| US5106590A (en) * | 1990-05-11 | 1992-04-21 | Davy Mckee (London) Limited | Gas mixer and distributor with heat exchange between incoming gases |
| US5429809A (en) * | 1991-09-23 | 1995-07-04 | Haldor Topsoe A/S | Process and reactor for carrying out non-adiabatic catalytic reactions |
| DK162891A (da) | 1991-09-23 | 1993-03-24 | Haldor Topsoe As | Fremgangsmaade og reaktor til gennemfoerelse af ikke-adiabatiske reaktioner. |
| EP0687648B1 (de) * | 1994-06-15 | 1998-09-16 | dbb fuel cell engines GmbH | Zweistufige Methanol-Reformierung |
| US6296814B1 (en) * | 1998-11-10 | 2001-10-02 | International Fuel Cells, L.L.C. | Hydrocarbon fuel gas reformer assembly for a fuel cell power plant |
| US6497856B1 (en) * | 2000-08-21 | 2002-12-24 | H2Gen Innovations, Inc. | System for hydrogen generation through steam reforming of hydrocarbons and integrated chemical reactor for hydrogen production from hydrocarbons |
| DE10142999B4 (de) * | 2001-09-03 | 2006-07-06 | Zentrum für Brennstoffzellen Technik ZBT Duisburg GmbH | Hocheffiziente, kompakte Reformereinheit zur Wasserstofferzeugung aus gasförmigen Kohlenwasserstoffen im kleinen Leistungsbereich |
| CA2415536A1 (en) * | 2002-12-31 | 2004-06-30 | Long Manufacturing Ltd. | Reformer for converting fuel to hydrogen |
| WO2004092062A1 (en) * | 2003-04-15 | 2004-10-28 | Shell Internationale Research Maatschappij B.V. | Process to prepare synthesis gas |
| JP4048277B2 (ja) | 2003-08-06 | 2008-02-20 | 国立大学法人東北大学 | バイオマスのガス化方法及びガス化装置 |
| JP4477432B2 (ja) * | 2004-06-29 | 2010-06-09 | 東洋エンジニアリング株式会社 | 改質器 |
| JP2007229548A (ja) | 2006-02-27 | 2007-09-13 | Nippon Steel Engineering Co Ltd | バイオマス熱分解ガス化過程で使用する改質用触媒とその製造方法、及びその改質用触媒を用いた改質方法とバイオマス熱分解ガス化装置、並びに触媒再生方法 |
| GR1006128B (el) * | 2007-05-25 | 2008-11-03 | . | Υψηλα θερμικα ολοκληρωμενος αναμορφωτης για παραγωγη υδρογονου |
| US8178062B2 (en) * | 2007-09-27 | 2012-05-15 | Sanyo Electric Co., Ltd. | Reforming apparatus for fuel cell |
| US20090184293A1 (en) * | 2008-01-18 | 2009-07-23 | Han Pat A | Process for reforming hydrocarbons |
-
2011
- 2011-01-18 KR KR1020127021397A patent/KR101826064B1/ko active Active
- 2011-01-18 WO PCT/EP2011/000179 patent/WO2011088982A1/en not_active Ceased
- 2011-01-18 JP JP2012549284A patent/JP5757581B2/ja active Active
- 2011-01-18 EP EP11704919.7A patent/EP2526045B1/en active Active
- 2011-01-18 BR BR112012017774-5A patent/BR112012017774B1/pt active IP Right Grant
- 2011-01-18 CN CN201180006565.5A patent/CN102811944B/zh active Active
- 2011-01-18 US US13/522,341 patent/US9227844B2/en active Active
- 2011-01-18 CA CA2786448A patent/CA2786448C/en active Active
- 2011-01-18 RU RU2012135374/05A patent/RU2552460C2/ru active
- 2011-01-18 PL PL11704919T patent/PL2526045T3/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2012135374A (ru) | 2014-02-27 |
| US20120277327A1 (en) | 2012-11-01 |
| KR101826064B1 (ko) | 2018-02-07 |
| CN102811944A (zh) | 2012-12-05 |
| BR112012017774B1 (pt) | 2021-09-21 |
| BR112012017774A2 (pt) | 2017-10-03 |
| CN102811944B (zh) | 2015-05-20 |
| JP2013517213A (ja) | 2013-05-16 |
| WO2011088982A1 (en) | 2011-07-28 |
| RU2552460C2 (ru) | 2015-06-10 |
| EP2526045B1 (en) | 2018-03-07 |
| US9227844B2 (en) | 2016-01-05 |
| KR20120127453A (ko) | 2012-11-21 |
| WO2011088982A8 (en) | 2012-08-16 |
| JP5757581B2 (ja) | 2015-07-29 |
| CA2786448C (en) | 2018-09-25 |
| EP2526045A1 (en) | 2012-11-28 |
| CA2786448A1 (en) | 2011-07-28 |
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