PL16626B1 - Method of obtaining catalysts containing chromium and iron. - Google Patents
Method of obtaining catalysts containing chromium and iron. Download PDFInfo
- Publication number
- PL16626B1 PL16626B1 PL16626A PL1662630A PL16626B1 PL 16626 B1 PL16626 B1 PL 16626B1 PL 16626 A PL16626 A PL 16626A PL 1662630 A PL1662630 A PL 1662630A PL 16626 B1 PL16626 B1 PL 16626B1
- Authority
- PL
- Poland
- Prior art keywords
- iron
- chromium
- catalysts containing
- containing chromium
- obtaining catalysts
- Prior art date
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 14
- 229910052804 chromium Inorganic materials 0.000 title claims description 7
- 239000011651 chromium Substances 0.000 title claims description 7
- 229910052742 iron Inorganic materials 0.000 title claims description 7
- 239000003054 catalyst Substances 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title description 6
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 5
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims description 5
- 150000002506 iron compounds Chemical class 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims 1
- 150000001845 chromium compounds Chemical class 0.000 claims 1
- 229910017464 nitrogen compound Inorganic materials 0.000 claims 1
- 150000002830 nitrogen compounds Chemical class 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- QLOKJRIVRGCVIM-UHFFFAOYSA-N 1-[(4-methylsulfanylphenyl)methyl]piperazine Chemical compound C1=CC(SC)=CC=C1CN1CCNCC1 QLOKJRIVRGCVIM-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
Description
Dotychczasowe sposoby otrzymania ka¬ talizatorów zelaznych z chromem posluguja sie metoda stracania chromu ze soli chro¬ mu zapomoca alkaljów lub amonjaku lub tez dodaja do osadu tlenku lub wodorotlen¬ ku zelaza sole kwasu chromowego, np. chromian lub dwuchromian potasu. Przed¬ miotem niniejszego wynalazku jest otrzy¬ manie katalizatora, zawierajacego obok ze¬ laza chrom w specjalnie aktywnej postaci, znacznie przewyzszajacej aktywnoscia ka¬ talizatory znane o podobnym skladzie.Jako materjalu wyjsciowego uzywamy zwiazków zelaza dwuwartosciowego oraz kwasu chromowego; w wyniku reakcji tych cial nastepuje redukcja kwasu chromowe¬ go, przyczem zelazo dwuwartosciowe utle¬ nia isie na wyzszy stopien. Mozna otrzymy¬ wac na tej drodze katalizatory, zawieraja¬ ce obok zelaza i chromu tez inne skladniki, które mozna dodawac w róznych stadjach produkcji.Przyklad. 100 kg zelaza rozpuszcza sie w rozcienczonym kwasie azotowym, dodaje 10 kg kwasu chromowego lub 20 kg chro¬ mianu potasu i w temperaturze 60° sitra- ca sie amonjakiem. Cala ilosc chromu prze¬ chodzi do osadu.*) Wlascicielka patentu oswiadczyla, ze wynalazca jest p. Godlewicz w Królewskiej Hucie. PLHitherto methods of obtaining iron catalysts with chromium use the method of removing chromium from the chromium salt by means of alkali or ammonia, or by adding to the precipitate iron oxide or hydroxide salts of chromic acid, for example potassium chromate or dichromate. The object of the present invention is to obtain a catalyst containing, in addition to iron, chromium in a specially active form, significantly exceeding the activity of known catalysts of similar composition. We use divalent iron compounds and chromic acid as a starting material; as a result of the reaction of these bodies, the chromic acid is reduced, with the oxidation of divalent iron and the increase to a higher degree. In this way, it is possible to obtain catalysts containing, in addition to iron and chromium, also other ingredients, which can be added at various stages of production. 100 kg of iron are dissolved in dilute nitric acid, 10 kg of chromic acid or 20 kg of potassium chloride are added and the temperature is 60 ° filtered with ammonia. All the chromium goes to the sediment. *) The owner of the patent stated that the inventor was Mr. Godlewicz in Królewska Huta. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL16626B1 true PL16626B1 (en) | 1932-08-31 |
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