PE20150282A1 - Nuevos compuestos bifuncionales utiles como ligando de uranios (vi), metodos de sintesis de los mismos y usos de los mismos - Google Patents

Nuevos compuestos bifuncionales utiles como ligando de uranios (vi), metodos de sintesis de los mismos y usos de los mismos

Info

Publication number
PE20150282A1
PE20150282A1 PE2014001977A PE2014001977A PE20150282A1 PE 20150282 A1 PE20150282 A1 PE 20150282A1 PE 2014001977 A PE2014001977 A PE 2014001977A PE 2014001977 A PE2014001977 A PE 2014001977A PE 20150282 A1 PE20150282 A1 PE 20150282A1
Authority
PE
Peru
Prior art keywords
same
uranium
synthesis
carbon atoms
methods
Prior art date
Application number
PE2014001977A
Other languages
English (en)
Inventor
Guilhem Arrachart
Nicolas Aychet
Gilles Bernier
Fabien Burdet
Antoine Leydier
Manuel Miguirditchian
Stephane Pellet-Rostaing
Gabriel Plancque
Raphael Turgis
Elisabeth Zekri
Original Assignee
Areva Mines
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Areva Mines filed Critical Areva Mines
Publication of PE20150282A1 publication Critical patent/PE20150282A1/es

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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02—Obtaining thorium, uranium, or other actinides
    • C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/026—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries liquid-liquid extraction with or without dissolution in organic solvents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/572—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02—Obtaining thorium, uranium, or other actinides
    • C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0221—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching
    • C22B60/0226—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching using acidic solutions or liquors
    • C22B60/0243—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching using acidic solutions or liquors phosphorated ion as active agent
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/007—Recovery of isotopes from radioactive waste, e.g. fission products
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • G21F9/12—Processing by absorption; by adsorption; by ion-exchange
    • G21F9/125—Processing by absorption; by adsorption; by ion-exchange by solvent extraction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)

Abstract

Referida a un compuesto de formula general (I), donde: m es un entero de 0 a 2; R1 y R2 son un grupo hidrocarbonado con 6 a 12 atomos de carbono; R3 es H, un grupo hidrocarbonado con 1 a 12 atomos de carbono, un grupo hidrocarbonado monociclico con 3 a 8 atomos de carbono, entre otros; R4 es un grupo hidrocarbonado con 2 a 8 atomos de carbono; R5 es H o un grupo hidrocarbonado con 1 a 12 atomos de carbono, de cadena lineal o ramificada. Tambien esta referida a metodos para la sintesis de estos compuestos. Dichos compuestos actuan como ligandos del uranio (VI), y en particular extrayendo uranio (VI) a partir de una solucion acuosa de acido fosforico
PE2014001977A 2012-05-07 2013-05-06 Nuevos compuestos bifuncionales utiles como ligando de uranios (vi), metodos de sintesis de los mismos y usos de los mismos PE20150282A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1254176A FR2990206B1 (fr) 2012-05-07 2012-05-07 Nouveaux composes bifonctionnels utiles comme ligands de l'uranium(vi), leurs procedes de synthese et leurs utilisations
FR1262362A FR2990207B1 (fr) 2012-05-07 2012-12-19 Nouveaux composes bifonctionnels utiles comme ligands de l'uranium(vi), leurs procedes de synthese et leurs utilisations

Publications (1)

Publication Number Publication Date
PE20150282A1 true PE20150282A1 (es) 2015-03-08

Family

ID=47049228

Family Applications (1)

Application Number Title Priority Date Filing Date
PE2014001977A PE20150282A1 (es) 2012-05-07 2013-05-06 Nuevos compuestos bifuncionales utiles como ligando de uranios (vi), metodos de sintesis de los mismos y usos de los mismos

Country Status (11)

Country Link
US (1) US9441285B2 (es)
CN (1) CN104470936B (es)
AU (1) AU2013258153B2 (es)
BR (1) BR112014027732B1 (es)
CA (1) CA2872084C (es)
FR (2) FR2990206B1 (es)
IL (1) IL235520B (es)
PE (1) PE20150282A1 (es)
TN (1) TN2014000463A1 (es)
WO (1) WO2013167516A1 (es)
ZA (1) ZA201407955B (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2990206B1 (fr) 2012-05-07 2014-06-06 Commissariat Energie Atomique Nouveaux composes bifonctionnels utiles comme ligands de l'uranium(vi), leurs procedes de synthese et leurs utilisations
FR3002463B1 (fr) * 2013-02-25 2016-08-19 Commissariat Energie Atomique Materiau hybride organique-inorganique, utile pour extraire l'uranium(vi) de milieux aqueux contenant de l'acide phosphorique, ses procedes de preparation et ses utilisations
FR3002951B1 (fr) * 2013-03-11 2015-04-17 Areva Mines Utilisation de composes a fonctions amide et phosphonate pour extraire l'uranium(vi) de solutions aqueuses d'acide sulfurique, issues notamment de la lixiviation sulfurique de minerais uraniferes
FR3013059B1 (fr) * 2013-11-08 2016-01-01 Commissariat Energie Atomique Utilisation d'un materiau hybride organique-inorganique pour extraire l'uranium(vi) d'une solution aqueuse d'acide sulfurique, issue notamment de la lixiviation sulfurique d'un minerai uranifere
FR3034417B1 (fr) * 2015-04-03 2019-03-15 Commissariat A L'energie Atomique Et Aux Energies Alternatives Composes a fonctions oxyde de phosphine et amine, utiles comme ligands de l'uranium(vi), et leurs utilisations, notamment pour extraire l'uranium(vi) de solutions aqueuses d'acide sulfurique
FR3038326A1 (fr) 2015-06-30 2017-01-06 Areva Mines Procede de separation du fer d'une phase organique contenant de l'uranium et procede d'extraction de l'uranium d'une solution aqueuse d'acide mineral contenant de l'uranium et du fer
FR3044018B1 (fr) * 2015-11-19 2017-12-22 Areva Mines Procedes d'extraction et de recuperation de l'uranium present dans une solution aqueuse comprenant de l'acide phosphorique
FR3044006B1 (fr) 2015-11-19 2020-03-06 Orano Mining Nouveau materiau organique pour extraire l'uranium d'une solution aqueuse d'acide phosphorique, procedes d'extraction et de recuperation de l'uranium associes et precurseur d'un tel materiau organique
FR3055906B1 (fr) * 2016-09-15 2018-09-28 Commissariat A L'energie Atomique Et Aux Energies Alternatives Nouvel extractant, utile pour extraire des terres rares d'une solution aqueuse d'acide phosphorique, et ses applications
FR3060006B1 (fr) * 2016-12-13 2020-02-28 Orano Mining Materiau organique mesoporeux, utile notamment pour extraire l'uranium(vi) de milieux aqueux comprenant de l'acide phosphorique, et ses utilisations
CN106749407B (zh) * 2017-01-06 2019-06-18 中国工程物理研究院核物理与化学研究所 一种氨基磷酸基功能化离子液体及其制备方法和用途
FR3069539B1 (fr) 2017-07-31 2019-08-30 Areva Mines Composes bifonctionnels a fonction thiophosphine, utiles comme extractants de l'uranium(vi), leurs procedes de synthese et leurs utilisations
EP3441396A1 (en) * 2017-08-07 2019-02-13 Université de Montpellier Method for separating uranium and/or thorium
EP4199934A4 (en) * 2020-08-21 2024-09-04 Univ Texas FUNCTIONAL IONIZABLE PHOSPHOLIPIDS
FR3116834A1 (fr) 2020-12-02 2022-06-03 Commissariat A L'energie Atomique Et Aux Energies Alternatives Procédé de récupération sélective des terres rares et de l’uranium(VI) d’une solution aqueuse d’acide phosphorique
CN114797486B (zh) * 2022-04-13 2023-02-03 合肥凯华环保科技有限公司 废水脱氨用亲水后可重新疏水的疏水膜

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3711591A (en) 1970-07-08 1973-01-16 Atomic Energy Commission Reductive stripping process for the recovery of uranium from wet-process phosphoric acid
SU376387A1 (ru) * 1971-06-21 1973-04-05 Институт органической , физической химии А. Е. Арбузова Способ получения фосфорилированных дифениламинов
FR2396803A1 (fr) 1977-07-05 1979-02-02 Cogema Procede d'extraction d'uranium a partir d'acide phosphorique de voie humide
FR2460960A1 (fr) 1979-07-09 1981-01-30 Elf Aquitaine Nouveaux esthers triphosphoniques, utiles a l'extraction des metaux lourds
FR2460958A1 (fr) 1979-07-09 1981-01-30 Elf Aquitaine Nouveaux composes diphosphoniques, utiles a l'extraction des metaux lourds
US4316877A (en) * 1979-11-23 1982-02-23 Allied Corporation Extraction of uranium values from phosphoric acid
DE3235136A1 (de) * 1982-09-23 1984-03-29 Hoechst Ag, 6230 Frankfurt Verfahren zur abtrennung von gallium und indium aus waessrigen loesungen
FR2596383B1 (fr) 1986-03-28 1990-10-26 Cogema Procede de separation du fer a partir d'une solution organique contenant de l'uranium
IL79999A0 (en) 1986-09-10 1986-12-31 Yeda Res & Dev Bifunctional organophosphorus extractants and polymers for uranium recovery
FR2973377B1 (fr) 2011-04-01 2013-05-17 Commissariat Energie Atomique Derives de la 2,9-dipyridyl-1,10-phenanthroline utiles comme ligands des actinides, leur procede de synthese et leurs utilisations
FR2990206B1 (fr) 2012-05-07 2014-06-06 Commissariat Energie Atomique Nouveaux composes bifonctionnels utiles comme ligands de l'uranium(vi), leurs procedes de synthese et leurs utilisations

Also Published As

Publication number Publication date
AU2013258153A1 (en) 2014-11-20
US20150133688A1 (en) 2015-05-14
CA2872084C (fr) 2020-09-22
CN104470936B (zh) 2019-04-19
BR112014027732B1 (pt) 2022-01-18
IL235520B (en) 2018-01-31
FR2990206A1 (fr) 2013-11-08
IL235520A0 (en) 2015-02-01
FR2990207A1 (fr) 2013-11-08
US9441285B2 (en) 2016-09-13
CA2872084A1 (fr) 2013-11-14
WO2013167516A1 (fr) 2013-11-14
FR2990206B1 (fr) 2014-06-06
TN2014000463A1 (fr) 2016-03-30
FR2990207B1 (fr) 2015-08-21
CN104470936A (zh) 2015-03-25
ZA201407955B (en) 2015-10-28
BR112014027732A2 (pt) 2017-06-27
AU2013258153B2 (en) 2017-05-11

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