PE18897A1 - Articulos fotocromicos estables a la temperatura y protegidos de la luz solar - Google Patents

Articulos fotocromicos estables a la temperatura y protegidos de la luz solar

Info

Publication number
PE18897A1
PE18897A1 PE1995286827A PE28682795A PE18897A1 PE 18897 A1 PE18897 A1 PE 18897A1 PE 1995286827 A PE1995286827 A PE 1995286827A PE 28682795 A PE28682795 A PE 28682795A PE 18897 A1 PE18897 A1 PE 18897A1
Authority
PE
Peru
Prior art keywords
photochrome
mixture
coloring agent
polymeric matrix
procedure
Prior art date
Application number
PE1995286827A
Other languages
English (en)
Inventor
Frederic Henri Florent
David Henry
Andre Jean Vachet
Jacques Jean Vial
Original Assignee
Corning Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Corning Inc filed Critical Corning Inc
Publication of PE18897A1 publication Critical patent/PE18897A1/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432Six-membered rings
    • C08K5/3437Six-membered rings condensed with carbocyclic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/26Esters containing oxygen in addition to the carboxy oxygen
    • C08F20/30Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/10Esters
    • C08F22/1006Esters of polyhydric alcohols or polyhydric phenols, e.g. ethylene glycol dimethacrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/15Heterocyclic compounds having oxygen in the ring
    • C08K5/151Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1545Six-membered rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Eyeglasses (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)

Abstract

SE REFIERE A MATERIALES ORGANICOS TRANSPARENTES FOTOCROMICOS QUE CONSISTEN DE: 1) UNA MATRIZ POLIMERICA SELECCIONADA DEL GRUPO QUE CONSISTE DE A) HOMOPOLIMEROS DE DIMETACRILATO DE BISFENOL ETOXILADO DE FORMULA (I), EN LA QUE R ES H o CH3, Y m Y n SON INDEPENDIENTEMENTE 1 o 2, PREFERIBLEMENTE R ES H, Y m=n=2; Y B) COPOLIMEROS DE DIMETACRILATO DE BIFENOL ETOXILADO QUE CONTIENE A LO SUMO 30% EN PESO DE UN MONOMERO AROMATICO CON FUNCIONALIDAD VINILICA, ACRILICA O METOACRILICA; Y 2) POR LO MENOS UN AGENTE COLORANTE O UNA MEZCLA DE AGENTES COLORANTES SELECCIONADOS DEL GRUPO CONSISTENTE DE ESPIROOXACINAS, ESPIROPIRANOS Y CROMENOS, QUE OTORGA PROPIEDADES FOTOCROMICAS A DICHA MATRIZ, PREFERIBLEMENTE UNA MEZCLA DE AGENTES COLORANTES FOTOCROMICOS QUE OTORGUEN UN TINTE GRIS O MARRON AL VIDRIO EN ESTADO OSCURECIDO; SE REFIERE ADEMAS A UN PROCEDIMIENTO PARA PREPARAR EL MATERIAL ORGANICO FOTOCROMICO, QUE COMPRENDE LAS ETAPAS DE POLIMERIZAR LA MATRIZ POLIMERICA (1A o 1B) EN PRESENCIA DE UN INICIADOR DE UN RADICAL DIAZOICO Y EN AUSENCIA DE UN INICIADOR DE UN RADICAL PEROXIDO, SE INCORPORA ADEMAS UN AGENTE COLORANTE FOTOCROMICO (2) QUE PUEDE SER AGREGADO ANTES DE LA POLIMERIZACION O DESPUES DE LA POLIMERIZACION MEDIANTE UN PROCEDIMIENTO DE DIFUSION TERMICA. ES UTIL PARA LA PRODUCCION DE LENTES OFTALMICOS ORGANICOS FOTOCROMICOS
PE1995286827A 1994-12-12 1995-12-11 Articulos fotocromicos estables a la temperatura y protegidos de la luz solar PE18897A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9414933A FR2727971A1 (fr) 1994-12-12 1994-12-12 Nouveaux materiaux organiques photochromiques a indice de refraction eleve, leur preparation et articles formes de ces materiaux

Publications (1)

Publication Number Publication Date
PE18897A1 true PE18897A1 (es) 1997-07-04

Family

ID=9469712

Family Applications (1)

Application Number Title Priority Date Filing Date
PE1995286827A PE18897A1 (es) 1994-12-12 1995-12-11 Articulos fotocromicos estables a la temperatura y protegidos de la luz solar

Country Status (13)

Country Link
EP (1) EP0797785B1 (es)
JP (1) JPH11511765A (es)
CN (1) CN1169187A (es)
AR (1) AR000316A1 (es)
AU (1) AU692013B2 (es)
BR (1) BR9509982A (es)
CA (1) CA2203810A1 (es)
DE (1) DE69516900T2 (es)
ES (1) ES2148581T3 (es)
FR (1) FR2727971A1 (es)
MX (1) MX9704335A (es)
PE (1) PE18897A1 (es)
WO (1) WO1996018926A1 (es)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69624131T2 (de) 1995-12-05 2003-06-18 Corning Inc., Corning Neue organische photochrome materialien
FR2741959B1 (fr) * 1995-12-05 1998-02-13 Corning Inc Nouveaux verres organiques, photochromiques ou non, de qualite optique, leur preparation et articles formes a partir de ces verres
WO1997041468A1 (en) * 1996-04-30 1997-11-06 Corning Incorporated Organic photochromic contact lens compositions
BR9712251A (pt) * 1996-10-11 1999-08-24 Corning Inc Material org-nico fotocrom tico sua fabrica-Æo e artigos fotocrom ticos contendo os mesmos
FR2754534B1 (fr) * 1996-10-11 1998-12-31 Corning Inc Materiau organique photochromique, sa fabrication et les articles photochromiques en renfermant
US5973093A (en) * 1996-11-27 1999-10-26 Ppg Industries Ohio, Inc. Polymerizable polyol (allyl carbonate) composition
US5739243A (en) * 1996-11-27 1998-04-14 Ppg Industries, Inc. Polymerizable composition
US5965680A (en) * 1996-11-27 1999-10-12 Ppg Industries Ohio, Inc. Optical resin composition from polyol((meth)acryloyl carbonate) monomer
US5914174A (en) * 1996-12-05 1999-06-22 Innotech, Inc. Lens or semi-finished blank comprising photochromic resin compositions
WO2001002449A2 (en) 1999-07-02 2001-01-11 Ppg Industries Ohio, Inc. Poly(meth)acrylic photochromic coating
FR2811674B1 (fr) * 2000-07-17 2003-07-25 Corning Sa Resines et articles photochromiques; preparation; compositions precurseurs
US7342112B2 (en) * 2003-07-01 2008-03-11 Ppg Industries Ohio, Inc. Photochromic compounds
EP1740629B1 (en) * 2004-04-30 2011-03-30 Advanced Polymerik Pty Ltd Photochromic compositions and articles comprising siloxane, alkylene or substituted alkylene oligomers
US20090280709A1 (en) 2004-09-01 2009-11-12 Ppg Industries Ohio, Inc. Polyurethanes, Articles and Coatings Prepared Therefrom and Methods of Making the Same
US11248083B2 (en) 2004-09-01 2022-02-15 Ppg Industries Ohio, Inc. Aircraft windows
US9598527B2 (en) 2004-09-01 2017-03-21 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US11591436B2 (en) 2004-09-01 2023-02-28 Ppg Industries Ohio, Inc. Polyurethane article and methods of making the same
US20090280329A1 (en) 2004-09-01 2009-11-12 Ppg Industries Ohio, Inc. Polyurethanes, Articles and Coatings Prepared Therefrom and Methods of Making the Same
US11149107B2 (en) 2004-09-01 2021-10-19 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US9464169B2 (en) 2004-09-01 2016-10-11 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US11008418B2 (en) 2004-09-01 2021-05-18 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
CN101833175A (zh) * 2010-03-31 2010-09-15 江苏华天通科技有限公司 580nm防眩光纳米树脂镜片的制备方法
CN101831129A (zh) * 2010-03-31 2010-09-15 江苏华天通科技有限公司 含过渡金属氧化物纳米材料的电焊用透镜的制备方法
EP2698664B1 (en) 2011-04-13 2015-09-16 Hoya Corporation Photochromic lens for eye glasses
WO2014007154A1 (ja) 2012-07-06 2014-01-09 三井化学株式会社 重合体粒子およびその用途
EP3029124B1 (en) 2013-08-02 2018-10-10 Mitsui Chemicals, Inc. Polymerizable composition for photochromic optical material
JP6655395B2 (ja) * 2016-01-06 2020-02-26 株式会社Adeka 水系ポリウレタン樹脂組成物、及び該組成物を用いてなる光学フィルム
WO2018037621A1 (ja) * 2016-08-23 2018-03-01 伊藤光学工業株式会社 調光光学要素
JP7033605B2 (ja) * 2017-03-01 2022-03-10 ヤンガー・マニュファクチャリング・カンパニー・ドゥーイング/ビジネス/アズ・ヤンガー・オプティックス フォトクロミックアイウェアレンズの製造方法およびフォトクロミックアイウェア製品

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5817527B2 (ja) * 1978-07-17 1983-04-07 株式会社保谷レンズ 高屈折率レンズ用共重合体及びそれよりなるレンズ
JPS572312A (en) * 1980-06-05 1982-01-07 Tokuyama Soda Co Ltd Preparation of resin having high refractive index and improved moldability
IT1190382B (it) * 1985-07-26 1988-02-16 Montedison Spa Diesteri acrilici per bisfenolo alchil etere,relativi polimeri e compositi per uso dentale
GB2184734A (en) * 1985-12-19 1987-07-01 Pilkington Brothers Plc Process for manufacturing photochromic articles
US4931220A (en) * 1987-11-24 1990-06-05 Ppg Industries, Inc. Organic photochromic pigment particulates
AU638815B2 (en) * 1990-03-29 1993-07-08 Tokuyama Soda Kabushiki Kaisha Photochromic compound, composition and use thereof
JP2723340B2 (ja) * 1990-06-05 1998-03-09 株式会社トクヤマ フォトクロミック組成物
US5330686A (en) * 1992-08-19 1994-07-19 Ppg Industries, Inc. Temperature stable and sunlight protected photochromic articles
FR2699541B1 (fr) * 1992-12-22 1995-04-28 Essilor Int Compositions polymères à faible indice de jaune, compositions polymérisables et lentilles les mettant en Óoeuvre.
CA2124152A1 (en) * 1993-05-26 1994-11-27 Yoshihiro Miura Photochromic article
JP2822844B2 (ja) * 1993-05-26 1998-11-11 株式会社ニコン フォトクロミック成形体
DE4325154C1 (de) * 1993-07-27 1994-09-29 Rodenstock Optik G Verfahren zur Herstellung eines photochromen Gegenstandes
JPH07178831A (ja) * 1993-12-22 1995-07-18 Tokuyama Corp フォトクロミック成形体の製造方法
JP3471073B2 (ja) * 1994-04-27 2003-11-25 株式会社トクヤマ フォトクロミック組成物

Also Published As

Publication number Publication date
BR9509982A (pt) 1998-06-09
EP0797785A1 (en) 1997-10-01
ES2148581T3 (es) 2000-10-16
EP0797785B1 (en) 2000-05-10
CA2203810A1 (en) 1996-06-20
JPH11511765A (ja) 1999-10-12
DE69516900D1 (de) 2000-06-15
WO1996018926A1 (en) 1996-06-20
MX9704335A (es) 1997-09-30
FR2727971A1 (fr) 1996-06-14
EP0797785A4 (en) 1998-01-21
AU4106896A (en) 1996-07-03
FR2727971B1 (es) 1997-02-14
AR000316A1 (es) 1997-06-18
DE69516900T2 (de) 2000-12-07
CN1169187A (zh) 1997-12-31
AU692013B2 (en) 1998-05-28

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