OA10430A - Chloride assisted hydrometallurgical copper extraction - Google Patents
Chloride assisted hydrometallurgical copper extraction Download PDFInfo
- Publication number
- OA10430A OA10430A OA70031A OA70031A OA10430A OA 10430 A OA10430 A OA 10430A OA 70031 A OA70031 A OA 70031A OA 70031 A OA70031 A OA 70031A OA 10430 A OA10430 A OA 10430A
- Authority
- OA
- OAPI
- Prior art keywords
- copper
- solution
- process according
- raffinate
- zinc
- Prior art date
Links
- 239000010949 copper Substances 0.000 title claims abstract description 339
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 249
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 236
- 238000000605 extraction Methods 0.000 title claims abstract description 85
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title claims abstract description 32
- 230000003647 oxidation Effects 0.000 claims abstract description 187
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 187
- 238000000034 method Methods 0.000 claims abstract description 110
- 230000008569 process Effects 0.000 claims abstract description 106
- 239000011701 zinc Substances 0.000 claims abstract description 94
- 238000000638 solvent extraction Methods 0.000 claims abstract description 90
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 76
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 75
- 239000000706 filtrate Substances 0.000 claims abstract description 71
- 239000012141 concentrate Substances 0.000 claims abstract description 70
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 52
- 229910021653 sulphate ion Inorganic materials 0.000 claims abstract description 51
- 238000002386 leaching Methods 0.000 claims abstract description 47
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 43
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 42
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 30
- 235000011149 sulphuric acid Nutrition 0.000 claims abstract description 30
- 238000005363 electrowinning Methods 0.000 claims abstract description 26
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 26
- 230000002378 acidificating effect Effects 0.000 claims abstract description 18
- 239000001117 sulphuric acid Substances 0.000 claims abstract description 14
- -1 sulphate ions Chemical class 0.000 claims abstract description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000001301 oxygen Substances 0.000 claims abstract description 10
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 10
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 9
- QAOWNCQODCNURD-UHFFFAOYSA-M bisulphate group Chemical group S([O-])(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims abstract description 8
- 238000011065 in-situ storage Methods 0.000 claims abstract description 4
- 230000003247 decreasing effect Effects 0.000 claims abstract description 3
- 239000002253 acid Substances 0.000 claims description 59
- 239000007787 solid Substances 0.000 claims description 45
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 37
- 239000005864 Sulphur Substances 0.000 claims description 37
- 238000006386 neutralization reaction Methods 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000002904 solvent Substances 0.000 claims description 20
- 239000003792 electrolyte Substances 0.000 claims description 15
- 238000004064 recycling Methods 0.000 claims description 15
- 238000005406 washing Methods 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 9
- 150000002500 ions Chemical class 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 5
- 229910052602 gypsum Inorganic materials 0.000 claims description 5
- 239000010440 gypsum Substances 0.000 claims description 5
- 238000011068 loading method Methods 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 5
- 235000009529 zinc sulphate Nutrition 0.000 claims description 5
- 239000011686 zinc sulphate Substances 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 2
- 150000003751 zinc Chemical class 0.000 claims description 2
- SGPGESCZOCHFCL-UHFFFAOYSA-N Tilisolol hydrochloride Chemical compound [Cl-].C1=CC=C2C(=O)N(C)C=C(OCC(O)C[NH2+]C(C)(C)C)C2=C1 SGPGESCZOCHFCL-UHFFFAOYSA-N 0.000 claims 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 150000001879 copper Chemical class 0.000 abstract description 4
- 239000000243 solution Substances 0.000 description 87
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 48
- 238000006243 chemical reaction Methods 0.000 description 30
- 239000012527 feed solution Substances 0.000 description 29
- 239000000047 product Substances 0.000 description 22
- 229910052742 iron Inorganic materials 0.000 description 15
- 238000012360 testing method Methods 0.000 description 15
- 238000011084 recovery Methods 0.000 description 11
- 239000002002 slurry Substances 0.000 description 11
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 10
- 238000007792 addition Methods 0.000 description 8
- HLQQMPGKASWZPH-UHFFFAOYSA-N diethyl hexyl phosphate Chemical compound CCCCCCOP(=O)(OCC)OCC HLQQMPGKASWZPH-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000012065 filter cake Substances 0.000 description 7
- 239000002562 thickening agent Substances 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 5
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 4
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 4
- 229910052951 chalcopyrite Inorganic materials 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000701 coagulant Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- 239000012633 leachable Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052683 pyrite Inorganic materials 0.000 description 2
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 229910017518 Cu Zn Inorganic materials 0.000 description 1
- 229910017752 Cu-Zn Inorganic materials 0.000 description 1
- 229910017943 Cu—Zn Inorganic materials 0.000 description 1
- 235000017343 Quebracho blanco Nutrition 0.000 description 1
- 241000065615 Schinopsis balansae Species 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 150000001649 bromium compounds Chemical group 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- BUGICWZUDIWQRQ-UHFFFAOYSA-N copper iron sulfane Chemical compound S.[Fe].[Cu] BUGICWZUDIWQRQ-UHFFFAOYSA-N 0.000 description 1
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000009854 hydrometallurgy Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical class [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052960 marcasite Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0069—Leaching or slurrying with acids or salts thereof containing halogen
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0071—Leaching or slurrying with acids or salts thereof containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/20—Obtaining zinc otherwise than by distilling
- C22B19/22—Obtaining zinc otherwise than by distilling with leaching with acids
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/20—Obtaining zinc otherwise than by distilling
- C22B19/26—Refining solutions containing zinc values, e.g. obtained by leaching zinc ores
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
- C22B23/0423—Halogenated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
- C22B23/043—Sulfurated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/10—Hydrochloric acid, other halogenated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CA1994/000696 WO1996019593A1 (en) | 1993-07-29 | 1994-12-20 | Chloride assisted hydrometallurgical copper extraction |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| OA10430A true OA10430A (en) | 2001-12-07 |
Family
ID=4160899
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| OA70031A OA10430A (en) | 1994-12-20 | 1997-06-20 | Chloride assisted hydrometallurgical copper extraction |
Country Status (27)
| Country | Link |
|---|---|
| US (3) | US5431788A (bg) |
| EP (1) | EP0804624B1 (bg) |
| JP (1) | JPH10510585A (bg) |
| KR (1) | KR100352496B1 (bg) |
| AR (1) | AR000381A1 (bg) |
| AU (1) | AU699194B2 (bg) |
| BA (1) | BA95051A (bg) |
| BG (1) | BG62179B1 (bg) |
| BR (1) | BR9408639A (bg) |
| CA (1) | CA2208026C (bg) |
| CO (1) | CO4440443A1 (bg) |
| CZ (1) | CZ184997A3 (bg) |
| DE (1) | DE69417455T2 (bg) |
| ES (1) | ES2132604T3 (bg) |
| FI (1) | FI115305B (bg) |
| HR (1) | HRP950601A2 (bg) |
| ID (1) | ID29555A (bg) |
| NO (1) | NO972836L (bg) |
| OA (1) | OA10430A (bg) |
| PE (2) | PE39695A1 (bg) |
| PL (1) | PL190429B1 (bg) |
| RU (1) | RU2137856C1 (bg) |
| TR (1) | TR199501621A2 (bg) |
| TW (2) | TW339362B (bg) |
| UY (1) | UY24125A1 (bg) |
| WO (1) | WO1996019593A1 (bg) |
| ZA (2) | ZA9410363B (bg) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5756402A (en) * | 1992-12-28 | 1998-05-26 | Kabushiki Kaisha Toshiba | Method of etching silicon nitride film |
| US5431788A (en) * | 1993-06-28 | 1995-07-11 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical copper extraction |
| US5869012A (en) * | 1993-07-29 | 1999-02-09 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical extraction of metal |
| US5902474A (en) * | 1993-07-29 | 1999-05-11 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical extraction of metal |
| USRE37251E1 (en) | 1993-07-29 | 2001-07-03 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical extraction of metal |
| US5874055A (en) * | 1993-07-29 | 1999-02-23 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical extraction of metal |
| US5650057A (en) * | 1993-07-29 | 1997-07-22 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical extraction of metal |
| US5807479A (en) * | 1994-07-15 | 1998-09-15 | Coproco Development Corporation | Process for recovering copper from copper-containing material |
| US5795465A (en) * | 1994-07-15 | 1998-08-18 | Coproco Development Corporation | Process for recovering copper from copper-containing material |
| US5814292A (en) * | 1996-12-19 | 1998-09-29 | Energy Research Group | Comprehensive energy producing methods for aqueous phase oxidation |
| US5849172A (en) * | 1997-06-25 | 1998-12-15 | Asarco Incorporated | Copper solvent extraction and electrowinning process |
| ZA987217B (en) * | 1997-08-15 | 2000-02-14 | Cominco Eng Services | Chloride assisted hydrometallurgical extraction of metal from sulphide or laterite ores. |
| AUPP484498A0 (en) | 1998-07-24 | 1998-08-20 | Aberfoyle Resources Limited | Processing minerals |
| AUPP543798A0 (en) * | 1998-08-24 | 1998-09-17 | Technological Resources Pty Limited | Hydrometallurgical extraction of copper and other valuable metals |
| US6315812B1 (en) | 1999-04-28 | 2001-11-13 | International Pgm Technologies Ltd | Oxidative pressure leach recovery using halide ions |
| AUPQ886300A0 (en) | 2000-07-19 | 2000-08-10 | Canopean Pty Ltd | Process for extraction of metals |
| ATE314494T1 (de) * | 2000-07-25 | 2006-01-15 | Phelps Dodge Corp | Verfahren zur gewinnung von kupfer aus sulfiderzen unter verwendung einer feinstzermahlung und einer auslaugung unter druck bei mittelhohen temperaturen |
| US6428604B1 (en) | 2000-09-18 | 2002-08-06 | Inco Limited | Hydrometallurgical process for the recovery of nickel and cobalt values from a sulfidic flotation concentrate |
| US7116722B2 (en) * | 2001-02-09 | 2006-10-03 | Lucent Technologies Inc. | Wireless communication system using multi-element antenna having a space-time architecture |
| US7476308B2 (en) * | 2001-07-25 | 2009-01-13 | Phelps Dodge Corporation | Process for multiple stage direct electrowinning of copper |
| US20050126923A1 (en) * | 2001-07-25 | 2005-06-16 | Phelps Dodge Corporation | Process for recovery of copper from copper-bearing material using medium temperature pressure leaching, direct electrowinning and solvent/solution extraction |
| US20040200730A1 (en) * | 2003-04-14 | 2004-10-14 | Kyo Jibiki | Hydrometallurgical copper recovery process |
| CA2478516C (en) * | 2003-09-30 | 2007-12-11 | Jaguar Nickel Inc. | A process for the recovery of value metals from base metal sulfide ores |
| AP1842A (en) * | 2003-11-03 | 2008-04-30 | Oxiana Ltd | Leach extraction method |
| CA2472495A1 (en) * | 2004-02-18 | 2005-08-18 | Sgs Lakefield Research Limited | Process to recover base metals |
| WO2005113845A1 (en) * | 2004-05-21 | 2005-12-01 | Wmc Resources Ltd | Recovery of nickel |
| DE102004038693B4 (de) * | 2004-08-10 | 2010-02-25 | Blasberg Werra Chemie Gmbh | Vorrichtung und Verfahren zur Entfernung von Fremdstoffen aus Prozesslösungen und Verfahren zur Regenerierung eines Kationenaustauschers |
| BRPI0516774A (pt) * | 2004-10-21 | 2008-09-23 | Anglo Operations Ltd | processo de lixiviação na presença de ácido clorìdrico para a recuperação de um metal valioso de minério |
| CA2588257C (en) * | 2004-10-29 | 2010-03-09 | Phelps Dodge Corporation | Process for multiple stage direct electrowinning of copper |
| US7736487B2 (en) | 2004-10-29 | 2010-06-15 | Freeport-Mcmoran Corporation | Process for recovery of copper from copper-bearing material using pressure leaching, direct electrowinning and solution extraction |
| BRPI0419191B1 (pt) * | 2004-10-29 | 2013-05-14 | mÉtodo de recuperaÇço de cobre a partir de um material metalÍfero. | |
| WO2006104816A1 (en) | 2005-03-29 | 2006-10-05 | Cytec Technology Corp. | Modification of copper/iron selectivity in oxime-based copper solvent extraction systems |
| JP5052834B2 (ja) * | 2006-07-27 | 2012-10-17 | Ｊｘ日鉱日石金属株式会社 | 黄銅鉱を含有する硫化銅鉱の浸出方法 |
| US8025859B2 (en) | 2007-05-18 | 2011-09-27 | Cesl Limited | Process for gold and silver recovery from a sulphide concentrate |
| US8003064B2 (en) | 2007-09-17 | 2011-08-23 | Freeport-Mcmoran Corporation | Controlled copper leach recovery circuit |
| WO2009037596A2 (en) * | 2007-09-17 | 2009-03-26 | Barrick Gold Corporation | Method to improve recovery of gold from double refractory gold ores |
| JP5069173B2 (ja) * | 2008-03-27 | 2012-11-07 | Ｊｘ日鉱日石金属株式会社 | 鉱物からの銅の回収方法 |
| JP4468999B2 (ja) * | 2008-03-27 | 2010-05-26 | 日鉱金属株式会社 | 鉱物からの金属の回収方法 |
| CN101328542B (zh) * | 2008-07-25 | 2010-06-02 | 紫金矿业集团股份有限公司 | 一种用铜精矿直接制取硫酸铜和阴极铜的方法 |
| JP4717908B2 (ja) * | 2008-08-11 | 2011-07-06 | Ｊｘ日鉱日石金属株式会社 | 銅を含有する塩化物浴からの銅の回収方法 |
| US8168847B2 (en) * | 2009-04-01 | 2012-05-01 | Earth Renewal Group, Llc | Aqueous phase oxidation process |
| US8481800B2 (en) * | 2009-04-01 | 2013-07-09 | Earth Renewal Group, Llc | Aqueous phase oxidation process |
| US7951988B2 (en) * | 2009-04-01 | 2011-05-31 | Earth Renewal Group, Llc | Aqueous phase oxidation process |
| US9272936B2 (en) | 2009-04-01 | 2016-03-01 | Earth Renewal Group, Llc | Waste treatment process |
| US7915474B2 (en) * | 2009-04-01 | 2011-03-29 | Earth Renewal Group, Llc | Aqueous phase oxidation process |
| US8115047B2 (en) * | 2009-04-01 | 2012-02-14 | Earth Renewal Group, Llc | Aqueous phase oxidation process |
| US8936770B2 (en) * | 2010-01-22 | 2015-01-20 | Molycorp Minerals, Llc | Hydrometallurgical process and method for recovering metals |
| US9695070B2 (en) | 2011-10-27 | 2017-07-04 | Pentair Residential Filtration, Llc | Regeneration of a capacitive deionization system |
| US8961770B2 (en) | 2011-10-27 | 2015-02-24 | Pentair Residential Filtration, Llc | Controller and method of operation of a capacitive deionization system |
| US9010361B2 (en) | 2011-10-27 | 2015-04-21 | Pentair Residential Filtration, Llc | Control valve assembly |
| US9637397B2 (en) | 2011-10-27 | 2017-05-02 | Pentair Residential Filtration, Llc | Ion removal using a capacitive deionization system |
| US8671985B2 (en) | 2011-10-27 | 2014-03-18 | Pentair Residential Filtration, Llc | Control valve assembly |
| US9169533B2 (en) | 2011-12-20 | 2015-10-27 | Freeport Minerals Corporation | System and method including multi-circuit solution extraction for recovery of metal values from metal-bearing materials |
| US8420048B1 (en) | 2011-12-20 | 2013-04-16 | Freeport-Mcmoran Corporation | System and method for parallel solution extraction of one or more metal values from metal-bearing materials |
| KR101449185B1 (ko) * | 2012-12-21 | 2014-10-13 | 주식회사 포스코 | 광석으로부터 유가금속 및 부산물 회수장치 |
| US9410225B2 (en) | 2014-05-13 | 2016-08-09 | Teck Resources Limited | Process for recovery of copper from arsenic-bearing and/or antimony-bearing copper sulphide concentrates |
| KR102201781B1 (ko) * | 2019-01-23 | 2021-01-12 | 한국지질자원연구원 | 황동광으로부터 선택적 구리 침출 방법 |
| US11359260B2 (en) * | 2019-09-04 | 2022-06-14 | Korea Resources Corporation | Method of inhibiting degradation of extractant by anhydrous environment avoiding and metal stripping |
| US20220267877A1 (en) * | 2021-02-24 | 2022-08-25 | Sherritt International Corporation | Co-Processing of Copper Sulphide Concentrate with Nickel Laterite Ore |
| WO2023049383A1 (en) * | 2021-09-24 | 2023-03-30 | American Battery Technology Company | Systems and methods for lithium extraction from sedimentary deposits |
| CN114058844A (zh) * | 2021-10-26 | 2022-02-18 | 广东佳纳能源科技有限公司 | 中间品除铁的方法 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB190219035A (en) * | 1902-08-29 | 1903-03-05 | William Payne | Improvements in the Treatment of Ores Containing Copper. |
| US2377832A (en) * | 1941-11-28 | 1945-06-05 | Int Nickel Co | Precipitation of cobaltic hydroxide |
| US2488561A (en) * | 1943-09-30 | 1949-11-22 | Ferro Enamel Corp | Method for the separation of cobalt and nickel from solutions |
| BE539910A (bg) * | 1954-07-19 | 1900-01-01 | ||
| CA938794A (en) * | 1968-12-13 | 1973-12-25 | Weston David | Hydrometallurgical treatment of nickel group ores |
| US3728105A (en) * | 1970-11-16 | 1973-04-17 | Kennecott Copper Corp | Extraction of metal values from manganese deep sea nodules |
| US3642440A (en) * | 1971-01-11 | 1972-02-15 | Tunis L Holmes | Process for nickel-cobalt separation |
| US3788959A (en) * | 1972-05-05 | 1974-01-29 | Sybron Corp | Electrodialytic recovery of acid and insoluble products from spent liquors |
| FI51110C (fi) * | 1973-05-22 | 1976-10-11 | Outokumpu Oy | Tapa erottaa kobolttia(II) ja nikkeliä(II) neste-nesteuuttauksella |
| US4039406A (en) * | 1973-08-10 | 1977-08-02 | Noranda Mines Limited | Recovering copper from concentrates with insoluble sulfate forming leach |
| US3923616A (en) * | 1973-10-01 | 1975-12-02 | Du Pont | Recovery of metal values from ores |
| US3933975A (en) * | 1974-02-08 | 1976-01-20 | Amax Inc. | Nickel-cobalt separation |
| US3917519A (en) * | 1974-02-27 | 1975-11-04 | Freeport Minerals Co | Process for the manufacture of electrolytic copper |
| DE2501284C3 (de) * | 1975-01-15 | 1980-06-12 | Duisburger Kupferhuette, 4100 Duisburg | Verfahren zur Aufarbeitung von Manganknollen und Gewinnung der in ihnen enthaltenen Wertstoffe |
| AT341234B (de) * | 1975-07-10 | 1978-01-25 | Pawlek Dr Ing Franz | Verfahren zur hydrometallurgischen gewinnung von kupfer aus sulfidischen kupferkonzentraten |
| DE2621144C3 (de) * | 1976-05-13 | 1978-11-02 | Th. Goldschmidt Ag, 4300 Essen | Verfahren zur Aufarbeitung von Buntmetallhydroxidschlamm-Abfällen |
| US4159232A (en) * | 1977-09-23 | 1979-06-26 | Bacon William G | Electro-hydrometallurgical process for the extraction of base metals and iron |
| DE2840424A1 (de) * | 1978-09-16 | 1980-04-24 | Duisburger Kupferhuette | Verfahren zur herstellung von sulfidischen kupferkonzentraten |
| CA1150062A (en) * | 1980-06-10 | 1983-07-19 | Robert W. Stanley | Hydrometallurgical treatment of copper-bearing hematite residue |
| US4378275A (en) * | 1981-12-03 | 1983-03-29 | Saudi-Sudanese Red Sea Joint Commission | Metal sulphide extraction |
| CA1212242A (en) * | 1982-07-27 | 1986-10-07 | Donald R. Weir | Recovery of zinc from zinc-containing sulphidic material |
| ZA835167B (en) * | 1982-08-10 | 1984-05-30 | Broken Hill Ass Smelters | Hydrometallurgical recovery of metal values from copper containing sulphide materials |
| US4632738A (en) * | 1982-09-03 | 1986-12-30 | Great Central Mines Ltd. | Hydrometallurgical copper process |
| US4541868A (en) * | 1983-07-22 | 1985-09-17 | California Nickel Corporation | Recovery of nickel and cobalt by controlled sulfuric acid leaching |
| EP0214324B1 (en) * | 1985-09-05 | 1990-03-07 | Cheminvest A/S | Method for separation and leaching of the valuable metals in metal sulphide materials |
| US4594132A (en) * | 1984-06-27 | 1986-06-10 | Phelps Dodge Corporation | Chloride hydrometallurgical process for production of copper |
| US4900522A (en) * | 1986-07-22 | 1990-02-13 | Amax Inc. | Separation of nickel and cobalt from sulfate solutions by solvent extraction |
| CA1338345C (en) * | 1988-06-14 | 1996-05-28 | Gary A. Kordosky | Nickel extraction with oxime extractants |
| US5779997A (en) * | 1992-06-08 | 1998-07-14 | Outokumpu Harjavalta Metals Oy | Method for preventing the formation of jarosite and ammonium and alkali based double salts in solvent extraction circuits connected to acidic leaching processes |
| US5431788A (en) * | 1993-06-28 | 1995-07-11 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical copper extraction |
-
1993
- 1993-07-29 US US08/098,874 patent/US5431788A/en not_active Expired - Lifetime
-
1994
- 1994-12-20 CZ CZ971849A patent/CZ184997A3/cs unknown
- 1994-12-20 DE DE69417455T patent/DE69417455T2/de not_active Expired - Lifetime
- 1994-12-20 CA CA 2208026 patent/CA2208026C/en not_active Expired - Lifetime
- 1994-12-20 WO PCT/CA1994/000696 patent/WO1996019593A1/en active IP Right Grant
- 1994-12-20 BR BR9408639A patent/BR9408639A/pt not_active IP Right Cessation
- 1994-12-20 AU AU12701/95A patent/AU699194B2/en not_active Expired
- 1994-12-20 ES ES95903735T patent/ES2132604T3/es not_active Expired - Lifetime
- 1994-12-20 PL PL94320939A patent/PL190429B1/pl not_active IP Right Cessation
- 1994-12-20 KR KR1019970704167A patent/KR100352496B1/ko not_active IP Right Cessation
- 1994-12-20 RU RU97112397A patent/RU2137856C1/ru not_active IP Right Cessation
- 1994-12-20 EP EP19950903735 patent/EP0804624B1/en not_active Expired - Lifetime
- 1994-12-20 JP JP52485295A patent/JPH10510585A/ja active Pending
- 1994-12-28 ZA ZA9410363A patent/ZA9410363B/xx unknown
-
1995
- 1995-01-06 PE PE1995258759A patent/PE39695A1/es not_active IP Right Cessation
- 1995-01-14 TW TW084100351A patent/TW339362B/zh not_active IP Right Cessation
- 1995-03-30 CO CO95012974A patent/CO4440443A1/es unknown
- 1995-04-21 US US08/425,117 patent/US5645708A/en not_active Expired - Lifetime
- 1995-12-14 TW TW84113341A patent/TW408185B/zh active
- 1995-12-15 ZA ZA9510710A patent/ZA9510710B/xx unknown
- 1995-12-15 PE PE28735095A patent/PE37396A1/es not_active Application Discontinuation
- 1995-12-19 HR HRCA94/000696A patent/HRP950601A2/hr not_active Application Discontinuation
- 1995-12-19 AR AR33468895A patent/AR000381A1/es unknown
- 1995-12-20 TR TR95/01621A patent/TR199501621A2/xx unknown
- 1995-12-20 UY UY24125A patent/UY24125A1/es unknown
- 1995-12-21 ID ID20010299D patent/ID29555A/id unknown
- 1995-12-29 BA BA950051A patent/BA95051A/bs unknown
-
1997
- 1997-06-19 NO NO972836A patent/NO972836L/no unknown
- 1997-06-19 FI FI972663A patent/FI115305B/fi not_active IP Right Cessation
- 1997-06-20 OA OA70031A patent/OA10430A/en unknown
- 1997-07-02 BG BG101726A patent/BG62179B1/bg unknown
-
1998
- 1998-11-27 US US09/200,712 patent/US6054105A/en not_active Expired - Lifetime
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| OA10430A (en) | Chloride assisted hydrometallurgical copper extraction | |
| US5902474A (en) | Chloride assisted hydrometallurgical extraction of metal | |
| AU709602B2 (en) | Chloride assisted hydrometallurgical extraction of metal | |
| US5874055A (en) | Chloride assisted hydrometallurgical extraction of metal | |
| US5869012A (en) | Chloride assisted hydrometallurgical extraction of metal | |
| CA1119817A (en) | Method for the recovery of metallic copper | |
| USRE37251E1 (en) | Chloride assisted hydrometallurgical extraction of metal | |
| US3687828A (en) | Recovery of metal values | |
| EP1507878B1 (en) | Chloride assisted hydrometallurgical extraction of metals | |
| EP0214324B1 (en) | Method for separation and leaching of the valuable metals in metal sulphide materials | |
| US4671945A (en) | Method for separation and leaching of the valuable metals in sulphide materials | |
| AU731780B2 (en) | Chloride assisted hydrometallurgical extraction of metal | |
| CA2099333A1 (en) | Chloride assisted hydrometallurgical copper extraction | |
| MXPA97009727A (en) | Hydrometalurgical extraction of metal assisted porclor |