NZ274610A - Hollow borosilicate microspheres and method of making - Google Patents
Hollow borosilicate microspheres and method of makingInfo
- Publication number
- NZ274610A NZ274610A NZ274610A NZ27461094A NZ274610A NZ 274610 A NZ274610 A NZ 274610A NZ 274610 A NZ274610 A NZ 274610A NZ 27461094 A NZ27461094 A NZ 27461094A NZ 274610 A NZ274610 A NZ 274610A
- Authority
- NZ
- New Zealand
- Prior art keywords
- microspheres
- microns
- hollow
- precursor
- borosilicate
- Prior art date
Links
- 239000004005 microsphere Substances 0.000 title claims abstract description 98
- 238000004519 manufacturing process Methods 0.000 title description 13
- 239000002243 precursor Substances 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 21
- 239000007921 spray Substances 0.000 claims abstract description 8
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 229910021538 borax Inorganic materials 0.000 claims abstract description 4
- 238000003801 milling Methods 0.000 claims abstract description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 4
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000001694 spray drying Methods 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract description 35
- 239000000463 material Substances 0.000 description 26
- 239000011521 glass Substances 0.000 description 10
- 239000000945 filler Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 239000005388 borosilicate glass Substances 0.000 description 4
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 description 4
- 230000004927 fusion Effects 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000002928 artificial marble Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011796 hollow space material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002991 molded plastic Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
- C03C11/002—Hollow glass particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/04—Making microcapsules or microballoons by physical processes, e.g. drying, spraying
- B01J13/043—Drying and spraying
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
- C03B19/107—Forming hollow beads
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/021—Agglomerated materials, e.g. artificial aggregates agglomerated by a mineral binder, e.g. cement
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
- Y10T428/2996—Glass particles or spheres
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Glass Compositions (AREA)
- Silicon Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Medicinal Preparation (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11842193A | 1993-09-08 | 1993-09-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NZ274610A true NZ274610A (en) | 1996-10-28 |
Family
ID=22378487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NZ274610A NZ274610A (en) | 1993-09-08 | 1994-09-07 | Hollow borosilicate microspheres and method of making |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5534348A (OSRAM) |
| EP (1) | EP0717675B1 (OSRAM) |
| JP (1) | JP2996354B2 (OSRAM) |
| AT (1) | ATE186037T1 (OSRAM) |
| AU (1) | AU695077B2 (OSRAM) |
| DE (1) | DE69421402T2 (OSRAM) |
| ES (1) | ES2137380T3 (OSRAM) |
| NZ (1) | NZ274610A (OSRAM) |
| WO (1) | WO1995007177A1 (OSRAM) |
Families Citing this family (78)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4400024A1 (de) * | 1994-01-03 | 1995-07-06 | Henkel Kgaa | Silikatische Builder und ihre Verwendung in Wasch- und Reinigungsmitteln sowie Mehrstoffgemische für den Einsatz auf diesem Sachgebiet |
| AU701603B2 (en) * | 1994-04-25 | 1999-02-04 | Minnesota Mining And Manufacturing Company | Compositions comprising fused particulates and methods of making them |
| US6045913A (en) * | 1995-11-01 | 2000-04-04 | Minnesota Mining And Manufacturing Company | At least partly fused particulates and methods of making them by flame fusion |
| US6254981B1 (en) | 1995-11-02 | 2001-07-03 | Minnesota Mining & Manufacturing Company | Fused glassy particulates obtained by flame fusion |
| JP3633091B2 (ja) * | 1996-04-09 | 2005-03-30 | 旭硝子株式会社 | 微小無機質球状中実体の製造方法 |
| US6020387A (en) * | 1997-09-22 | 2000-02-01 | Caschem, Inc. | Low density polymers and methods of making and using same |
| US7456571B1 (en) | 2002-05-21 | 2008-11-25 | Imaging Systems Technology | Microsphere plasma display |
| US6245733B1 (en) | 1999-04-30 | 2001-06-12 | James Mosbaugh | Porous agglomerations of fused microspheres |
| EP1172341A4 (en) * | 1999-06-30 | 2003-06-04 | Asahi Glass Co Ltd | FINE, HOLLOW AND SPHERICAL GLASS PARTICLES AND METHOD FOR THEIR PRODUCTION |
| ATE368017T1 (de) | 2000-03-14 | 2007-08-15 | James Hardie Int Finance Bv | Faserzementbaumaterialien mit zusatzstoffen niedriger dichte |
| EP1156021A1 (en) * | 2000-05-19 | 2001-11-21 | Asahi Glass Co., Ltd. | Hollow aluminosilicate glass microspheres and process for their production |
| EP1360228A1 (fr) * | 2001-01-02 | 2003-11-12 | Société de Technologie Michelin | Composition de caoutchouc utilisable comme appui de securite pour pneu et cet appui |
| US8138673B1 (en) | 2002-05-21 | 2012-03-20 | Imaging Systems Technology | Radiation shielding |
| US7638943B1 (en) | 2002-05-21 | 2009-12-29 | Imaging Systems Technology | Plasma-disc article of manufacture |
| US7727040B1 (en) | 2002-05-21 | 2010-06-01 | Imaging Systems Technology | Process for manufacturing plasma-disc PDP |
| US7628666B1 (en) | 2002-05-21 | 2009-12-08 | Imaging Systems Technology | Process for manufacturing plasma-dome PDP |
| US7405516B1 (en) | 2004-04-26 | 2008-07-29 | Imaging Systems Technology | Plasma-shell PDP with organic luminescent substance |
| US8198812B1 (en) | 2002-05-21 | 2012-06-12 | Imaging Systems Technology | Gas filled detector shell with dipole antenna |
| US7932674B1 (en) | 2002-05-21 | 2011-04-26 | Imaging Systems Technology | Plasma-dome article of manufacture |
| US8513887B1 (en) | 2002-05-21 | 2013-08-20 | Imaging Systems Technology, Inc. | Plasma-dome article of manufacture |
| JP4490816B2 (ja) | 2002-08-23 | 2010-06-30 | ジェームズ ハーディー インターナショナル ファイナンス ベスローテン フェンノートシャップ | 合成中空小球体 |
| US7455798B2 (en) * | 2002-08-23 | 2008-11-25 | James Hardie International Finance B.V. | Methods for producing low density products |
| MXPA05003691A (es) | 2002-10-07 | 2005-11-17 | James Hardie Int Finance Bv | Material mixto de fibrocemento de densidad media durable. |
| US20050065240A1 (en) * | 2003-09-24 | 2005-03-24 | Kyte William J, | Grout composition, dispenser therefor, and method of use |
| US20090156385A1 (en) | 2003-10-29 | 2009-06-18 | Giang Biscan | Manufacture and use of engineered carbide and nitride composites |
| US7772773B1 (en) | 2003-11-13 | 2010-08-10 | Imaging Systems Technology | Electrode configurations for plasma-dome PDP |
| EP1541535B1 (de) | 2003-12-12 | 2011-12-07 | bene_fit GmbH | Herstellungsverfahren für Mikrohohlkugeln, Lösung dafür und Mikrohohlkugeln |
| US8129906B1 (en) | 2004-04-26 | 2012-03-06 | Imaging Systems Technology, Inc. | Lumino-shells |
| US8113898B1 (en) | 2004-06-21 | 2012-02-14 | Imaging Systems Technology, Inc. | Gas discharge device with electrical conductive bonding material |
| US8368303B1 (en) | 2004-06-21 | 2013-02-05 | Imaging Systems Technology, Inc. | Gas discharge device with electrical conductive bonding material |
| US7998571B2 (en) | 2004-07-09 | 2011-08-16 | James Hardie Technology Limited | Composite cement article incorporating a powder coating and methods of making same |
| US20060026900A1 (en) * | 2004-08-09 | 2006-02-09 | Jang Bor Z | Method for storing and delivering hydrogen to fuel cells |
| US20060063003A1 (en) * | 2004-09-20 | 2006-03-23 | Laixia Yang | Infrared-absorbing glass micro-spheres for storing and delivering hydrogen to fuel cells |
| US20060060820A1 (en) * | 2004-09-21 | 2006-03-23 | Schumacher Ray F | Hollow porous-wall glass microspheres for hydrogen storage |
| US7666807B2 (en) * | 2004-09-21 | 2010-02-23 | Savannah River Nuclear Solutions, Llc | Hollow porous-wall glass microspheres for hydrogen storage |
| US8951608B1 (en) | 2004-10-22 | 2015-02-10 | Imaging Systems Technology, Inc. | Aqueous manufacturing process and article |
| EP2292894A1 (en) | 2005-02-04 | 2011-03-09 | Oxane Materials, Inc. | A composition and method for making a proppant |
| US8012533B2 (en) * | 2005-02-04 | 2011-09-06 | Oxane Materials, Inc. | Composition and method for making a proppant |
| US7491444B2 (en) | 2005-02-04 | 2009-02-17 | Oxane Materials, Inc. | Composition and method for making a proppant |
| US7867613B2 (en) | 2005-02-04 | 2011-01-11 | Oxane Materials, Inc. | Composition and method for making a proppant |
| US7622866B1 (en) | 2005-02-22 | 2009-11-24 | Imaging Systems Technology | Plasma-dome PDP |
| US8299696B1 (en) | 2005-02-22 | 2012-10-30 | Imaging Systems Technology | Plasma-shell gas discharge device |
| CA2598708A1 (en) | 2005-02-24 | 2006-08-31 | James Hardie International Finance B.V. | Alkali resistant glass compositions |
| US7730746B1 (en) | 2005-07-14 | 2010-06-08 | Imaging Systems Technology | Apparatus to prepare discrete hollow microsphere droplets |
| US8609244B2 (en) | 2005-12-08 | 2013-12-17 | James Hardie Technology Limited | Engineered low-density heterogeneous microparticles and methods and formulations for producing the microparticles |
| US7863815B1 (en) | 2006-01-26 | 2011-01-04 | Imaging Systems Technology | Electrode configurations for plasma-disc PDP |
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| US20080107744A1 (en) * | 2006-11-06 | 2008-05-08 | Jack Fa-De Chu | Injectable hollow tissue filler |
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| US20080196627A1 (en) * | 2007-02-16 | 2008-08-21 | Core Technologies, Inc. | Vitreous enamel coating powder |
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| US8209927B2 (en) | 2007-12-20 | 2012-07-03 | James Hardie Technology Limited | Structural fiber cement building materials |
| US9376766B2 (en) | 2008-09-02 | 2016-06-28 | Interface, Inc. | Low weight-hardback carpet tile |
| JP2012501235A (ja) | 2008-09-02 | 2012-01-19 | インターフェイス，インコーポレイテッド | 低重量カーペットおよびカーペットタイル、並びに、製造、サイジング、および設置方法 |
| FR2942470A1 (fr) | 2009-02-26 | 2010-08-27 | Weber & Broutin Sa | Mortier isolant pulverulent, mortier isolant en couche |
| US9013102B1 (en) | 2009-05-23 | 2015-04-21 | Imaging Systems Technology, Inc. | Radiation detector with tiled substrates |
| BR112012015322A2 (pt) * | 2009-12-22 | 2019-09-24 | Oxane Mat Inc | propante e método para formar o propante |
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| EP2649147B1 (en) | 2010-12-08 | 2016-06-08 | Joseph Buford Parse | Single component neutrally buoyant proppant |
| EP2649148B1 (en) | 2010-12-08 | 2016-05-25 | Joseph Buford Parse | Multiple component neutrally buoyant proppant |
| RU2586128C2 (ru) * | 2011-03-07 | 2016-06-10 | 3М Инновейтив Пропертиз Компани | Полые микросферы |
| CN103073176B (zh) * | 2013-02-05 | 2015-01-21 | 山西海诺科技有限公司 | 一种空心玻璃微珠的制备方法 |
| KR102060088B1 (ko) * | 2013-07-23 | 2019-12-27 | 로저스코포레이션 | 회로 물질, 회로 라미네이트, 및 이의 제조방법 |
| US20170283306A1 (en) | 2014-05-12 | 2017-10-05 | Prince Minerals Llc | Glass composite suitable for providing a protective coating on untreated substrates |
| CN107106432B (zh) | 2015-01-09 | 2021-06-08 | 生活实验公司 | 头发组合物及其使用方法 |
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| NO3184494T3 (OSRAM) * | 2015-12-21 | 2018-07-07 | ||
| EP3426706A1 (en) | 2016-03-08 | 2019-01-16 | Living Proof, Inc. | Long lasting cosmetic compositions |
| GB2559805A (en) * | 2017-02-21 | 2018-08-22 | The Millboard Company Ltd | Improvements to a board |
| US10987300B2 (en) | 2017-09-13 | 2021-04-27 | Living Proof, Inc. | Long lasting cosmetic compositions |
| CA3074845A1 (en) | 2017-09-13 | 2019-03-21 | Living Proof, Inc. | Color protectant compositions |
| US12029805B2 (en) | 2017-11-20 | 2024-07-09 | Living Proof, Inc. | Properties for achieving long-lasting cosmetic performance |
| US12048760B2 (en) | 2018-04-27 | 2024-07-30 | Living Proof, Inc. | Long lasting cosmetic compositions |
| US12102247B2 (en) | 2021-05-03 | 2024-10-01 | Interface, Inc. | Non-square rectangular flooring tiles and methods for cutting same |
| WO2023060347A1 (en) * | 2021-10-13 | 2023-04-20 | Nanoxplore Inc. | Sheet molding compound reinforced with graphene flakes, and methods of producing the same |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2797201A (en) * | 1953-05-11 | 1957-06-25 | Standard Oil Co | Process of producing hollow particles and resulting product |
| NL232500A (OSRAM) * | 1957-10-22 | |||
| US3365315A (en) * | 1963-08-23 | 1968-01-23 | Minnesota Mining & Mfg | Glass bubbles prepared by reheating solid glass partiles |
| US3699050A (en) * | 1967-08-02 | 1972-10-17 | Emerson & Cuming Inc | Spray dried product for feed in the manufacture of hollow glass spheres and process for forming said spray dried product |
| US4119422A (en) * | 1977-08-18 | 1978-10-10 | Pittsburgh Corning Corporation | Pulverulent borosilicate composition and a method of making a cellular borosilicate body therefrom |
| ZA831343B (en) * | 1982-04-08 | 1983-11-30 | Pq Corp | Hollow microspheres with organosilicon-silicate surfaces |
| US4778502A (en) * | 1984-06-21 | 1988-10-18 | Saint-Gobain Vitrage | Production of glass microspheres |
| US5069702A (en) * | 1990-12-20 | 1991-12-03 | W. R. Grace & Co.-Conn. | Method of making small hollow glass spheres |
-
1994
- 1994-09-07 AU AU78711/94A patent/AU695077B2/en not_active Ceased
- 1994-09-07 AT AT94929767T patent/ATE186037T1/de not_active IP Right Cessation
- 1994-09-07 EP EP94929767A patent/EP0717675B1/en not_active Expired - Lifetime
- 1994-09-07 ES ES94929767T patent/ES2137380T3/es not_active Expired - Lifetime
- 1994-09-07 DE DE69421402T patent/DE69421402T2/de not_active Expired - Fee Related
- 1994-09-07 JP JP7508783A patent/JP2996354B2/ja not_active Expired - Fee Related
- 1994-09-07 NZ NZ274610A patent/NZ274610A/en not_active IP Right Cessation
- 1994-09-07 WO PCT/US1994/010110 patent/WO1995007177A1/en not_active Ceased
-
1995
- 1995-03-28 US US08/411,394 patent/US5534348A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU7871194A (en) | 1995-03-27 |
| WO1995007177A1 (en) | 1995-03-16 |
| EP0717675A4 (OSRAM) | 1996-07-31 |
| JP2996354B2 (ja) | 1999-12-27 |
| EP0717675B1 (en) | 1999-10-27 |
| DE69421402T2 (de) | 2000-02-10 |
| AU695077B2 (en) | 1998-08-06 |
| DE69421402D1 (de) | 1999-12-02 |
| US5534348A (en) | 1996-07-09 |
| JPH09502417A (ja) | 1997-03-11 |
| ATE186037T1 (de) | 1999-11-15 |
| EP0717675A1 (en) | 1996-06-26 |
| ES2137380T3 (es) | 1999-12-16 |
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| RENW | Renewal (renewal fees accepted) | ||
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| EXPY | Patent expired |