NZ202971A

NZ202971A - Foodstuff in gelled slurry shaped and cooked

Info

Publication number: NZ202971A
Application number: NZ202971A
Authority: NZ
Inventors: Y Smadar; D M Trilling
Original assignee: Y Smadar
Priority date: 1982-01-08
Filing date: 1983-01-07
Publication date: 1986-03-14
Also published as: ES8401832A1; CH657251A5; IL64728A0; ZA829584B; GR77872B; IL64728A; KR860000371B1; DE3248692A1; AU1000783A; SE8207407L; EG16240A; GB2114417A; JPS58165746A; GB2114417B; PH19279A; SE8207407D0; IT1159821B; BE895554A; KR840003007A; NL8300059A

Description

<div class="application article clearfix" id="description"> New Zealand Paient Spedficaiion for Paient Number £02971 2 029 7 t Priority Date(s): Complete Specification Filed: i.. Class: .j&jj.. ft |CP. Publication Date: .... It P.O. Journal, No: . N0 DRAWINGS Patents form Ho. 5 NEK ZEALAND PATENTS ACT 1953 COMPLETE SPECIFICATION "PRODUCTION OF SHAPED FOOD PRODUCTS" / 7 E O I,-WE- YECHIEL SMADAR, a citizen of Israel, of 27 Sokolov Street, Ramat-Hasharon, Israel, hereby declare the invention, for which I/ve- pray that a patent may be granted to me/ueT and the method by which it is to be performed, to be particularly described in and by the following statement:- 20297 BACKGROUND ART Production of food products by reconstitution of comminuted materials by shaping the comminuted materials with the aid of gums and gel-forming materials, by 5 mechanical methods such as extruding and molding, as well as by thermal . treatment such as heating or cooling, are common ■' practices in the food industry. Various processes are known for the production of such shaped food products. Many of these processes are based on the use of a gel forming system 10 comprising an alginate and a bivalent cation such as the calcium ion. One type of process employing these materials produces a shaped product encased in a skin, such as a sausage. For example, U.S. Patent Nos. 3,650,765 and 3,650,766 dis-15 close food products which are manufactured in any shape or size by a process including the steps of forming an extrudable slurry of a food material, extruding the slurry and forming a gel-like skin around the extruded product. The skin is formed by subjecting gelable materials such as alginates to 20 the action of gelation agents such as alkaline earth ions, at the surface of the extrusion product. U.S. Patent Nos. 3,891,776; 3,922,360; 4,117,172 and 3,676,158 also disclose similar processes whereby a shaped food product encased in a skin is formed. Some of these processes produce 25 a peelable, self-supporting skin. When the skin is peeled off and the resulting product is again subjected to a bivalent cation solution, a skin is again formed. Other processes based on the use of alginates and calcium ions produce a stabilized food product where the 30 alginate contained in the slurry used for production is converted throughout into a complete advanced gel. For example, U.S. Patent No. 2,791,508 discloses a process for producing reconstituted food products comprising initially forming a thixotropic semi-gel like substance by dispersing a comminuted/ powdered, granulated or shredded foodstuff in a water solution of an edible hydrophilic colloid in which the dispersed foodstuff is present as discreet particles more or less completely enclosed in a matrix of the colloid gel. Alginates are disclosed as useful hydrophilic colloids. In addition, a gelation agent such as calcium carbonate must be added to the dispersed foodstuff and hydrophilic colloid to institute gelation. The time at which the gelation agent is added to the dispersion of foodstuff and hydrophilic colloid is critical since when the gelation agent is added, it liberates calcium ions which rapidly react with the colloid thereby forming a gel. Since this gelation occurs rapidly, it is necessary to quickly transfer the substance to an extruding feed pipe wherein the final advanced gel structure is formed. The feed pipe must be of such a length that the ensuing mixture becomes an advance gel substantially simultaneous with its exit. This is a major disadvantage since if the gelation agent is added too soon, the mixture will become an advanced gel before it exits the extruder thereby creating a blockage in the extruder mechanism. If, on the other hand, the gelation agent is added too late, the mixture will not become an advanced gel when it exits the extruder, thereby preventing the formation of a shaped food product. Thus, the above prior art processes may result in both production and product difficulties, such as undesired skin formation, undesired finished product texture, and difficulties during extrusion. Accordingly, it is among the objects of the present invention to provide an improved process for producing shaped food products which will insure both a smooth production run and a control of the desired characteristics of the finished product. "■079 71 DISCLOSURE OF THE INVENTION It has been found in accordance with the present invention that prepared food products having any desired size or shape may be formed from a slurry 5 of comminuted food particles and additives including a binder and a time reaction system comprising a gelling agent such as an alginate and a bivalent ion releasing material. The slurry employed in the process according to the invention has the required rheological properties 10 for shaping and shape retention making possible a continuous production process based on either extrusion, molding or the like. The consistency of the slurry is such that the shaped product is easily released from the shaping or forming device. 15 The method of the present invention may be applied to a wide variety of foodstuffs including vegetables, fruits, proteinaceous substances such as meats and fish products, shrimp products and the like and is not dependent upon the acidity of the foods or upon temperature. According to the present invention, the slurry may be formed from one or more of the comminuted foodstuffs referred to above, a binder comprising, for example, a cellulose ether alone or together with a gum such as guar gum, an alginate, a bivalent ion ^ releasing material such as calcium carbonate, which reacts with the alginate to form a gel, an extender such as flour and/or starch, and optionally a pH control agent such as citric acid or any other weak physiologically acceptable acid, a suitable sequestring agent, such 30 as a metaphosphate, and other additives, such as salt, sweetners and colorants. I 2 02971 The binder used in the slurry maintains a certain degree of rigidity and shape of the product, and the gradual gelling of the alginate results in a certain setting of the product. 5 The pH control agent in combination with the sequestring agent results in a predetermined rate of release of the calcium ions, which results in the controlled gelling of the alginate. In certain cases the pH of the comminuted food product is such that 10 either the acid or the acid and sequestring agent need not be added. For example, in the case of comminuted food products which release acid such as onions the pH control agent and sequestring agent need not be added to the slurry. 15 In each case the slurry must be adjusted in such a manner that the gelling takes place at a predetermined time interval. In general, the slurry is left standing for a predetermined period of time of from about 5 to about 3 0 minutes before the actual 20 shaping and further processing is commenced. This allows sufficient time for the gelling to take place. The ratio of, and quantity of the various ingredients in the slurry determines the consistency and characteristics of the final product. 25 The actual shaping is carried out with an extruder, cutter or molding device. As mentioned above, the easy and fast release of the shaped food product from the extruder, cutter or molding device is important for an efficient continuous production process. Such -5- ?029 71 release may be facilitated by a continuous rinsing of the extrusion head, cutter or mold with a liquid sud, water or with an aqueous solution of bivalent ions such as calcium ions which prevents the shaped j product from sticking to the shaping device. When j I 5 a solution such as calcium chloride solution is used j for the rinsing, there results a smooth slippery surface j which has a very low friction coefficient and which will * be easily released from the shaping device. This rinsing ! s solution is used in a small quantity and concentration, j 10 and is intended only to facilitate the easy release of the | [ / I product, and does not result in the formation of a j I shape-retaining or self-supporting film or skin. The shaped product may be further processed by contacting it with either a floury material or a normal : 15 batter and breading. If added adhesion of the batter coating to the product is desired, a small quantity of gelling agent can be added to the batter which will interact with alginate in the upper layer of the product. The shaped food products may also be coated, i 20 cooked, fried, frozen and packed. When such frozen products | are heated, they retain their shape, texture, eating qualities. j The components used for the process of the I t instant invention are reasonable in price, and thus 25 the product can be produced on an economical basis. ? 029 71 DETAILED DESCRIPTION OF THE INVENTION As indicated hereinabove, the shaped foods of this invention are produced by first forming a slurry of a comminuted food product and other additives, thereafter shaping the slurry by means of extrusion, molding or the like, followed by final processing which may include batter application, breading, cooking, such as frying, freezing and packaging. According to the present invention, the slurry contains one or more comminuted food products, a binder, a gelling agent, a compound releasing bivalent 10 ions for reacting with the gelling agent, extenders, and optionally a pH control agent, a sequestring agent and additives such as salt, spices, sweetening agents, and coloring materials. Suitable binders for use in the present invention 15 include edible cellulose ethers which are non-toxic and water soluble. Examples of suitable cellulose ethers are alkyl, hydroxyalkyl and carboxyalkyl ethers, wherein the alkyl group contains 1-3 carbon atoms. Specific examples of the cellulose ethers are sodium carboxymethyl cellulose, 20 methyl cellulose, ethyl cellulose, hydroxy methyl cellulose, hydroxy ethyl cellulose, hydroxypropyl cellulose, hydroxy-propyl methyl cellulose and combinations thereof. These cellulose ethers may be employed in combination with gums such as a guar gum, gum tragacanth, gum karaya, xanthan gum, 25 carageenan gum, furcellaran gum, locust bean gum, gum arabic or combinations thereof. While any suitable binder may be employed, it is presently preferred to employ hydroxypropyl methyl cellulose together with guar gum as the binder. A particularly preferred hydroxyxnethyl propyl cellulose is 30 100,000 CPS viscosity grade hydroxypropyl methocel K100M manufactured by Dow Chemical. -7- \ 10 15 20 25 30 ~0^9 7 1 In general, the binder is employed in an amount of from about 0.10% to about 6.0% by weight based on the weight of the comminuted food product. When the binder is composed of both a cellulose ether and a gum, the cellulose ether is present, for example, in an amount of from about 20% to about 30% by weight of the binder, and the gum is present, for example, in an amount of from about 70% to about 80% by weight of the binder. While any suitable gelling agent may be employed, it is presently preferred to employ an alginate such as sodium alginate or potassium alginate. A particularly preferred alginate is a sodium alginate having the trade name Protanal SF-120 distributed by Multi-Kem Corp. and produced by Protan and Fagertun of Norway. The alginate is generally present in the slurry in an amount of from about 0.1% to about 1.0% by weight based on the weight of the comminuted food product. Compounds which release bivalent ions for reacting with the alginate to produce a gel include calcium carbonate, calcium phosphate and the like. Calcium carbonate is, however, presently preferred. The calcium ion releasing compounds react with the alginate to produce a calcium alginate gel. The ion releasing compound is generally present in an amount of from about 0.001% to about 0.0 04% by weight based on the weight of the comminuted food product. Suitable pH control agents include weak organic acids such as citric acid, maleic acid and tartaric acid. The pH control agent may be omitted from the slurry when the comminuted food product that is being used releases a weak acid. Onions are an example of such a food product. When the pH control agent is employed, it is generally present in an amount of from about 0.001% to about 0.05% by -8- 2 02971 weight based on the weight of comminuted food product. While any suitable sequestering agent may be employed together with the pH control agent, according to the present invention it is presently preferred to use a metaphosphate such as sodium hexametaphosphate. The sequestering agent is usually employed only when a pH control agent is employed. In general, when the sequestering agent is employed, it is present in an amount of from about 0.001% to about 0.05% by weight based on the weight of the comminuted food product. Suitable extenders which may be employed in the slurry according to the present invention include starch and flour which are usually used together. In general, the starch is present in an amount of from about 3% to about 12% by weight based on the weight of the comminuted food product. It is, however, presently preferred to use starch in an amount of from about 5.5% to about 6.5% by weight. The flour is generally present in an amount of from about 3% to about 12% by weight based on the weight of comminuted food product. A preferred amount is of from about 7.5 to about 8.5 by weight. The slurry may also contain one or more optional additives such as salt, spices, sweetening agents, and coloring materials. In general, when such materials are present in the slurry they are present in an amount of from about 0.01% to about 1.0% by weight based on the weight of the comminuted food particles. As stated above, the food products which are suitable for use in the present invention include vegetables, fruits, proteinaceous substances, such as meat and fish products, shrimp product and the like. The process according to the present invention is parti- cularly suitable for use with comminuted or 'shre food products such as fresh onions, rehydrated onions, cauliflower, mushrooms, peppers, apples, poultry meats, meat, fish, shrimps and calamari. A preferred product is onion rings, which require a very well defined consistency in order to an acceptable and saleable product. The food products are shredded, diced or comminuted by conventional means known in the art. of the materials which make up the slurry excepting the comminuted or shredded food product. When the dry blend of these materials is mixed together, they are then added and mixed with the comminuted or shredded food product for 2 to 5 minutes at room temperature so as to form a slurry. The resultant slurry which has a very high viscosity is allowed to stand for a period of from about 5 to about 30 minutes so as to allow the release of ions such as calcium ions from calcium carbonate which forms a calcium alginate gel. The slurry is then fed into a shaping apparatus such as an extruder or molding device. While any such suitable device may be employed, it is presently preferred to pump the slurry through an extruder with cutting heads. When making onion rings, one can employ an Autoprod/Food extruder manufactured by Autoprod, Inc. with cutting heads which generate a ring-shaped product of approximately 10 to 12 grams. The same extruder can be used with different cutting heads to extrude other shapes such as balls, crescent, rods, etc. solution is used to wash the extruder cutters or molding plate to facilitate the easy release of the shaped product The slurry is prepared by mixing together all Desirably a bivalent ion containing rinse -10- 10 15 > f from the cutters or molding plate. It is presently preferred to employ an aqueous calcium chloride solution (0.2% to 5.0%) . The extruder shaped products then fall individually on a mesh conveyor belt that carries the products ^ to a batter unit wherein batter is applied. If more adhesion of the batter to the product is desired, a small quantity of a suitable alginate, e.g., sodium alginate, can be added to the batter which will then interact with the calcium ions on the surface of the product. This process step is normally followed by a breading unit wherein the products are breaded. The breaded product is then usually cooked, and in the case of onion rings, deep fried for a short period of time for example about 30 seconds at 400°F, and then individually quick frozen and packaged. The final shaped product before batter and breading is applied according to the present invention comprises, for example, a cellulose ether in an amount of from about 0.10% to about 2.5% by weight, a gum in an amount of from about 0% to about 2.5% by weight, alginate salt in an amount of from about 0.05 to about 0.80% by weight, an extender in an amount of from about 6.0% to about 15.0% by weight and a foodstuff in an amount of from about 80% to about 90% by,weight. A preferred example is 0.2% cellulose ether, 0.9% guar gum, 0.36% alginate salt, 12.0% extender, and 86.0% foodstuff (onion). As stated above, ingredients in the dry blend prior to the addition of the comminuted or shredded food product comprise the following materials, the weight percent, (based on the weight of materials in the slurry before the addition of the foodstuff) indicated for each material representing the broad range which could be used and preferred amounts. -11- 20 25 30 IV z 1 Materials Preferred Range Corn Starch 37% 30-60% Wheat Flour 49 30-60 Hydroxypropyl methyl cellulose 1.5 1-15 Guar Gum 6.0 0-15 5 Sodium Alginate 2.5 0.5-5 Calcium Carbonate .012 .006-.02 Sugar (optional) 4.4 0.-10 Salt (optional) 0.9 0-5 Citric Acid (as required) 0 0-.02 10 Sodium Hexametaphosphate 0 0-.02 (as required) The ratio of the diced fresh and/or rehydrated onion to the dry blend mix system is preferably 6.0 to 1, but can range from about 5:1.to about 10:1. Specific examples of some preferred formulations are illustrated in the following examples. These examples are by way of illustration only and are not to be construed in a non-limitative manner. Example 1: Production of Onion Rings A dry blend of the following was prepared (parts by weight) : 16 Parts corn starch 25 Parts wheat flour 0.8 Parts sodium alginate (KELTONE, Kelco Co.). 0.003 Parts calcium carbonate 3.2 Parts hydroxypropyl methyl cellulose, 100,000 CPS viscosity grade (hydroxypropyl methocel K-1000M, Dow Chemical). This mix was added to 250 parts of 1/4"-diced, fresh onions in a ribbon mixer and mixed for three minutes at room temperature so as to form a slurry. 15 20 25 A. ^ ij y 9 7 1 The resultant slurry had avery high paste-like viscosity. The mixture was allowed to stand for 5-15 min~ utes so as to allow the release of calcium ions from the calcium carbonate due to the acid pH created by the onion exudate and for the consequent reaction of the calcium 5 ions with the algin molecules to form a calcium alginate gel. The slurry was then, pumped by a creamery pump through an Autoprod Food type extruder with cutting heads generating a ring-shaped product of approximately 10-12 grams, •10 .The cutters were washed with an aqueous solution of calcium chloride of five parts to one hundred parts of water by weight. This wash solution facilitated the release of the formed ring-shaped product from the cutters. The extruded onion rings fell individually on a mesh conveyor belt that' carries the product to a batter unit which is followed by a breading unit. The breaded product was deep fried at 4 00°F for 30 seconds, and then individually quick frozen and packaged. The finished product, when heat reconstituted 20 for serving, had the desired juiciness and mouth feel. Example 2: Production of Onion-Rings Extruded onion rings were prepared according to Example 1, with the substitution of water-rehydrated dried onion pieces which, when reconstituted with water, were 25 approximately 1/4" in size. The interior texture of the finished cooked product resembled that of Example 1. Example 3: Production of Onion Rings Dry blend of the following was prepared (parts by weight): 30 15.2 parts corn starch 20.0 parts wheat flour 1.0 parts sodium alginate -13- / 02971 0-004 parts calcium carbonate 0.6 parts hydroxypropyl methyl cellulose 2.5 parts guar gum 0.4 parts salt 1.8 parts sugar 5 This mix was added to 250 parts of 1/4" diced fresh onions, The procedure for preparing the onion rings was as set forth in Example 1. Example 4: Production of Apple Rings Dry blend of the following is prepared (parts by weight): 10 25 parts corn starch 16 parts white flour 0.6 parts sodium alginate 0.003 parts calcium carbonate 2.3 parts of hydroxypropyl methyl cellulose 15 1.1 parts of guar gum 5 parts of sugar 1 part of salt This mix is added to 250 parts of 1/4" diced fresh apples. The remainder of the process is as in Example 1. 20 Having thus discussed the present invention, what is desired to be secured by Letters Patent and hereby claimed is: Example 5: Production of Shrimp Product A blend was prepared comprising parts by weight: Shredded shrimp 85 Salt 1.0 HVP 1.5 Garlic Powder 0.02 Onion Powder 0.3 Corn Starch 1.2 Mater up to 100 100 -14- 2 029 7 1 250 Parts by weight of the above mixture were mixed with the dry blend of Example 1 and processed as set out in Example 1, giving it a crescent or a shrimp shape. Example 6: Zucchini Rings or Nuggets A blenc was prepared comprising, parts by weight: 1/4" diced zucchini 56 Tomato puree 42 Onion Powder 0.15 Garlic Powder 0.15 Oregano 0.4 Salt 1.3 100 250 Parts by weight of this mixture were mixed with the dry mix of Example 1 and processed as set out in Example 1, in ring or nugget shape. Example 7: Chicken Rings or Crescents A blend was prepared comprising, parts by weight: 1/4" diced chicken roll 76.6 Chicken flavor 3.0 Parsley 0.1 Water 17.7 100 250 Parts by weight of this blenc were mixed with the dry mix defined in claim 1 and processed to produce rings or oreacantaJftese were processed further as set out in Example 1 - 15 - V </div>

Claims

<div class="application article clearfix printTableText" id="claims"> 2 02971 The above examples were repeated with various binders and gums as well as with different proportions of extenders, and with the addition of further gums. Various proportions of alginates and other low-solubility calcium compounds were tried. In all cases satisfactory products were obtained by suitable adjustments of the ingredients. - 16 - WHAT I CLAIM IS: 202971

1. A process for the production of shaped food products from comminuted, granulated or chopped foodstuffs comprising (1) preparing a slurry of one or more comminuted foodstuffs, a binder, a gelling agent,a bivalent ion releasing material and an extender, the amounts of binder, gelling agent and bivalent ion releasing material being sufficient to permit a degree of interaction between the gelling agent and the bivalent ion releasing material after a predetermined period of time after the slurry is prepared; (2) preparing a shaped food product by shaping the slurry by means of a shaping and forming device; and (3) contacting the shaped food product with either a floury material or a batter and thereafter breading it.

2. A process according to claim 1, wherein the binder is a cellulose ether.

3. A process according to claim 2, wherein the cellulose ■o-i-fchor is carboxy methyl cellulose, carboxy ethyl cellulose, carboxy-propyl cellulose, methyl cellulose, ethyl cellulose, hydroxy methyl cellulose, hydroxy ethyl cellulose, hydroxypropyl methyl cellulose or a mixture thereof-

4. A process according to claim 1, 2 or 3, wherein the binder comprises a cellulose ether and a gum.

5. A process according to claim 4, wherein the gum is guar gum, gum tragacanth, gum karaya, xanthan gum, carageenan, furcellaran gum, locust bean gum, gum arabic or a mixture thereof.

6. A process according to any of claims 1 to 5, wherein the gelling agent is an alkali metal alginate and the bivalent ion releasing compound is a calcium ion contain' of low solubility.

7. A process according to claim 6, wherein the alkali netal alginate 1s sodium alginate and the calcium compound Is calcium carbonate.

8. A process according to any of claims 1 to 9, wherein the slurry additionally contains a pH control agent.

9. A process according to claim 8, wherein the pH control agent 1s a weak organic acid selected from citric acid, tartaric acid and aelelc acid.

10. A process according to any of claims 1 to 9, wherein the slurry additionally contains a sequestring agent.

11. A process according to claim 10, wherein the sequestring agent Is a metaphosphate.

12. A process according to claim 11, wherein the metaphosphate 1s sodium hexametaphosphate.

13. A process according to any of claims 1 to 12, wherein the shaped food product is rinsed with an aqueous calcium containing compound solution while being released from the shaping and forming device.

14. A process according to claim 13, wherein the calcium compound solution 1s an aqueous calcium chloride solution.

15. A process according to any one of claims 1 to 14, wherein the extender is starch, flour or a mixture thereof. - 18 •-t ■a %

16. A process according to any of claims 6 to 15, wherein the components are used in such proportions so that the slurry is left to stand for a period of time of from 5 to 30 minutes, allowing for the interaction of the alginate with the calcium ion releasing compound, thereby increasing the viscosity of the slurry prior to the shaping step.

17. A process according to any of claims 1 to 16, wherein the binder is present in an amount of from 0.10 to 6.0% by weight based on the weight of the comminuted food product.

18. A process according to any of claims 1 to 17, wherein the alginate is present in an amount of from 0.10 to 1.0% by weight based on the weight of the comminuted food product.

19. A process according to any of claims 1 to 18, wherein the bivalent ion releasing compound is present in an amount of from 0.001 to 0.02% by weight based on the weight of the comminuted food.

20. A shaped food product obtained by a process according to claim 1, which food product is in the form of a gel and -omprises a cellulose ether selected from the group consisting hydroxy alkyl and carboxy alkyl cellulose ethers the alkyl oups of which contain from 1 to 3 carbon atoms, said cellulose ether being present in an amount of from 0.1 to 2.5% by weight; alginate salt in an amount of from 0.05 to 0.80% by weight; a comminuted, granulated oi chopped foodstuff selected from vegetables, fruits, meat, fish and seafood, and mixtures thereof, in an amount of from 80 to 90% by weight and an extender in an amount of from 6 to 15% by weight.

21. A shaped food product according to clairt 20 containing another gum in an amount of from 0.1 to 2.5% by weight.

22. A food product according to claim 20, wherein onions are employed as said foodstuff.

23. A food product according to claim 20 wherein apples are employed as said foodstuff. - 19 - 202971

24. The product according to claim 22, in the shape of a ring.

25. The product according to claim 23, in the shape of a ring.

26. A process for the production of shaped food products from comminuted, granulated or chopped foodstuffs substantially as herein particularly described with reference to any one of the examples.

27. A shaped food product substantially as herein particularly described with reference to any one of the examples. </div>