NO973031L - Fremgangsmåte ved fjerning av praktisk talt alle svovelforbindelser H2S, SO2, COS og/eller CS2 fra svovelanleggsavgasser og gjenvinning av slike forbindelser i form av svovel - Google Patents

Fremgangsmåte ved fjerning av praktisk talt alle svovelforbindelser H2S, SO2, COS og/eller CS2 fra svovelanleggsavgasser og gjenvinning av slike forbindelser i form av svovel

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Publication number
NO973031L
NO973031L NO973031A NO973031A NO973031L NO 973031 L NO973031 L NO 973031L NO 973031 A NO973031 A NO 973031A NO 973031 A NO973031 A NO 973031A NO 973031 L NO973031 L NO 973031L
Authority
NO
Norway
Prior art keywords
sulfur
compounds
gas stream
cos
sulphur
Prior art date
Application number
NO973031A
Other languages
English (en)
Other versions
NO973031D0 (no
Inventor
Jean Nougayrede
Andre Philippe
Sabine Savin-Poncet
Original Assignee
Elf Aquitaine
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9512988A external-priority patent/FR2740703B1/fr
Application filed by Elf Aquitaine filed Critical Elf Aquitaine
Publication of NO973031D0 publication Critical patent/NO973031D0/no
Publication of NO973031L publication Critical patent/NO973031L/no

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0456—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process the hydrogen sulfide-containing gas being a Claus process tail gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8606—Removing sulfur compounds only one sulfur compound other than sulfur oxides or hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8612—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8612—Hydrogen sulfide
    • B01D53/8615—Mixtures of hydrogen sulfide and sulfur oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/046—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide
    • C01B17/0469—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide at least one catalyst bed operating below the dew-point of sulfur

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Treating Waste Gases (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Industrial Gases (AREA)

Abstract

En avløpsgass bringes i kontakt med en hydrolyseringskatalysator for omdannelse av COS og CStil HS i en enhet (1) og alternativt, i nærvær av en luftstrøm, med en HS-oksidasjonskatalysator for å gi en hydrolysert gass (17) inneholdende HS og S0, men intet COS eller CS, mens volumkonsentrasjonene av (HS) og (S0) i gassen (17) kontrolleres på en slik måte at (HS)-2(S0) er større enn 0,2%, men ikke over-skrider 0,5 %. Gassen (17) fares inn i en Claus-enhet (3a) hvori HS og S0reagerer for å gi svovel og pro-duserer en i det vesentlige renset gass (25a) inneholdende HS som den eneste svovelforbindelse. Gassen (25a) injiseres ved 80-100°C med overskuddsluft inn i den katalytiske enhet (4a) hvori HS totalt oksideres til svovel. Svovelforbindelsene i avløpsgassen gjenvin-nes praktisk talt alle i form av svovel.
NO973031A 1995-11-03 1997-06-27 Fremgangsmåte ved fjerning av praktisk talt alle svovelforbindelser H2S, SO2, COS og/eller CS2 fra svovelanleggsavgasser og gjenvinning av slike forbindelser i form av svovel NO973031L (no)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9512988A FR2740703B1 (fr) 1995-11-03 1995-11-03 Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre
FR9613051A FR2740704B1 (fr) 1995-11-03 1996-10-25 Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre
PCT/FR1996/001698 WO1997017283A1 (fr) 1995-11-03 1996-10-30 Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre

Publications (2)

Publication Number Publication Date
NO973031D0 NO973031D0 (no) 1997-06-27
NO973031L true NO973031L (no) 1997-09-01

Family

ID=26232306

Family Applications (1)

Application Number Title Priority Date Filing Date
NO973031A NO973031L (no) 1995-11-03 1997-06-27 Fremgangsmåte ved fjerning av praktisk talt alle svovelforbindelser H2S, SO2, COS og/eller CS2 fra svovelanleggsavgasser og gjenvinning av slike forbindelser i form av svovel

Country Status (15)

Country Link
US (1) US6444185B1 (no)
EP (1) EP0801632B1 (no)
JP (1) JP3889051B2 (no)
CN (1) CN1080701C (no)
AT (1) ATE206685T1 (no)
CA (1) CA2209332C (no)
DE (1) DE69615816T2 (no)
ES (1) ES2166006T3 (no)
FR (1) FR2740704B1 (no)
NO (1) NO973031L (no)
PT (1) PT801632E (no)
RU (1) RU2142404C1 (no)
TW (1) TW358753B (no)
UA (1) UA48162C2 (no)
WO (1) WO1997017283A1 (no)

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FR2740704B1 (fr) * 1995-11-03 1997-12-26 Elf Aquitaine Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre
RU2232128C2 (ru) 1998-08-25 2004-07-10 Гастек Н.В. Способ извлечения серы из газа, содержащего сероводород
FR2840295B1 (fr) * 2002-06-03 2005-02-04 Inst Francais Du Petrole Prodede d'elimination du soufre d'une charge contenant de l'hydrogene sulfure et du benzene, toluene et/ou xylenes
CA2561455C (en) * 2004-04-22 2009-08-11 Fluor Technologies Corporation Improved configurations and methods for effluent gas treatment
CA2562845C (en) * 2004-04-22 2009-09-29 Fluor Technologies Corporation Cos-claus configurations and methods
CA2567790C (en) * 2004-07-12 2013-01-08 Exxonmobil Upstream Research Company Methods for removing sulfur-containing compounds
MY140997A (en) * 2004-07-22 2010-02-12 Shell Int Research Process for the removal of cos from a synthesis gas stream comprising h2s and cos
EA200801713A1 (ru) * 2006-01-18 2008-12-30 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ удаления карбонилсульфида и сероводорода из потока синтез-газа
CN101835537B (zh) * 2007-09-17 2013-05-22 国际壳牌研究有限公司 用于使气体物流中含有的硫化合物催化还原的催化剂组合物及其制备方法和用途
CN102380311B (zh) * 2010-09-01 2013-12-25 中国石油化工股份有限公司 汽油吸附脱硫再生烟气处理方法及其尾气加氢催化剂制法
CA2782944C (en) * 2012-02-17 2014-11-04 Archon Technologies Ltd. Process for the removal of sulfur compounds from gas streams
GB201303737D0 (en) * 2013-03-01 2013-04-17 Cross Peter F Catalytic treatment
US9370745B2 (en) 2013-04-24 2016-06-21 Jiangsu New Century Jiangnan Environmental Protection Co., Ltd Flue gas-treating method and apparatus for treating acidic tail gas by using ammonia process
CN106621796B (zh) * 2016-10-31 2023-06-13 昆明理工大学 一种同时脱除羰基硫、二硫化碳的方法及装置
CN108144428A (zh) 2017-03-15 2018-06-12 江苏新世纪江南环保股份有限公司 一种氨法高效脱除气体中硫氧化物和尘的方法及装置
CN107213785B (zh) 2017-05-25 2020-08-07 江苏新世纪江南环保股份有限公司 一种fcc尾气氨法脱硝脱硫除尘的方法及装置
CN107213769B (zh) 2017-05-25 2019-09-20 江苏新世纪江南环保股份有限公司 一种分室加氨的氨法脱硫方法及装置
EP3415222A1 (en) 2017-06-14 2018-12-19 Jiangnan Environmental Protection Group Inc. Automatic ammonia-adding system and method for ammonia-based desulfurization device
CN107213770B (zh) 2017-07-03 2023-03-17 江苏新世纪江南环保股份有限公司 氨法脱硫吸收塔及其建立方法和运行方法
CN107497449B (zh) * 2017-09-06 2020-09-01 淄博天净环保技术有限公司 催化氧化元素硫及硫化物的催化剂及其制备方法和应用
CN108722163B (zh) 2017-09-07 2019-06-07 江苏新世纪江南环保股份有限公司 一种氨法脱硫控制吸收过程气溶胶产生的方法
EP3752457A1 (en) 2018-02-13 2020-12-23 Haldor Topsøe A/S Production of fertilizers from landfill gas or digester gas
CN116510513A (zh) 2018-04-13 2023-08-01 江苏新世纪江南环保股份有限公司 氨法脱硫溶液的氧化方法及装置
CN110732227B (zh) 2018-07-20 2023-02-21 江南环保集团股份有限公司 一种酸性气处理的方法和装置
US11731080B2 (en) 2018-12-21 2023-08-22 King Fahd University Of Petroleum And Minerals Method of sweetening hydrocarbon gas from hydrogen sulfide
CN111957183A (zh) 2019-12-26 2020-11-20 江苏新世纪江南环保股份有限公司 一种改进的氨法脱硫控制吸收过程气溶胶产生的方法
CN115945203A (zh) * 2022-12-23 2023-04-11 华烁科技股份有限公司 一种高抗酸性气体的高炉煤气有机硫水解催化剂的制备方法及其应用

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FR2740704B1 (fr) * 1995-11-03 1997-12-26 Elf Aquitaine Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre

Also Published As

Publication number Publication date
DE69615816D1 (de) 2001-11-15
UA48162C2 (uk) 2002-08-15
NO973031D0 (no) 1997-06-27
JPH11501280A (ja) 1999-02-02
EP0801632B1 (fr) 2001-10-10
RU2142404C1 (ru) 1999-12-10
FR2740704B1 (fr) 1997-12-26
ATE206685T1 (de) 2001-10-15
PT801632E (pt) 2002-04-29
CA2209332A1 (fr) 1997-05-15
WO1997017283A1 (fr) 1997-05-15
CN1080701C (zh) 2002-03-13
ES2166006T3 (es) 2002-04-01
EP0801632A1 (fr) 1997-10-22
JP3889051B2 (ja) 2007-03-07
DE69615816T2 (de) 2002-06-13
CA2209332C (fr) 2001-05-08
US6444185B1 (en) 2002-09-03
TW358753B (en) 1999-05-21
CN1173854A (zh) 1998-02-18
FR2740704A1 (fr) 1997-05-09

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