DE69615816T2 - Verfahren zur quasitotaler entfernung der schwefelverbindungen h2s, so2, cos und/oder cs2 aus denselben enthaltenden restlichen rauchgasen einer schwefelanlage mit rückgewinnung dieser verbindungen als schwefel - Google Patents

Verfahren zur quasitotaler entfernung der schwefelverbindungen h2s, so2, cos und/oder cs2 aus denselben enthaltenden restlichen rauchgasen einer schwefelanlage mit rückgewinnung dieser verbindungen als schwefel

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Publication number
DE69615816T2
DE69615816T2 DE69615816T DE69615816T DE69615816T2 DE 69615816 T2 DE69615816 T2 DE 69615816T2 DE 69615816 T DE69615816 T DE 69615816T DE 69615816 T DE69615816 T DE 69615816T DE 69615816 T2 DE69615816 T2 DE 69615816T2
Authority
DE
Germany
Prior art keywords
compounds
sulfur
gas stream
cos
sulphur
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69615816T
Other languages
English (en)
Other versions
DE69615816D1 (de
Inventor
Jean Nougayrede
Andre Philippe
Sabine Savin-Poncet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe National Elf Aquitaine
Societe Nationale Elf Aquitaine Production SA
Original Assignee
Societe National Elf Aquitaine
Societe Nationale Elf Aquitaine Production SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9512988A external-priority patent/FR2740703B1/fr
Application filed by Societe National Elf Aquitaine, Societe Nationale Elf Aquitaine Production SA filed Critical Societe National Elf Aquitaine
Publication of DE69615816D1 publication Critical patent/DE69615816D1/de
Application granted granted Critical
Publication of DE69615816T2 publication Critical patent/DE69615816T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/02Preparation of sulfur; Purification
    • C01B17/04Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0456Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process the hydrogen sulfide-containing gas being a Claus process tail gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8603Removing sulfur compounds
    • B01D53/8606Removing sulfur compounds only one sulfur compound other than sulfur oxides or hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8603Removing sulfur compounds
    • B01D53/8612Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8603Removing sulfur compounds
    • B01D53/8612Hydrogen sulfide
    • B01D53/8615Mixtures of hydrogen sulfide and sulfur oxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/02Preparation of sulfur; Purification
    • C01B17/04Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/046Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide
    • C01B17/0469Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide at least one catalyst bed operating below the dew-point of sulfur

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Treating Waste Gases (AREA)
  • Catalysts (AREA)
  • Industrial Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE69615816T 1995-11-03 1996-10-30 Verfahren zur quasitotaler entfernung der schwefelverbindungen h2s, so2, cos und/oder cs2 aus denselben enthaltenden restlichen rauchgasen einer schwefelanlage mit rückgewinnung dieser verbindungen als schwefel Expired - Lifetime DE69615816T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9512988A FR2740703B1 (fr) 1995-11-03 1995-11-03 Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre
FR9613051A FR2740704B1 (fr) 1995-11-03 1996-10-25 Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre
PCT/FR1996/001698 WO1997017283A1 (fr) 1995-11-03 1996-10-30 Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre

Publications (2)

Publication Number Publication Date
DE69615816D1 DE69615816D1 (de) 2001-11-15
DE69615816T2 true DE69615816T2 (de) 2002-06-13

Family

ID=26232306

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69615816T Expired - Lifetime DE69615816T2 (de) 1995-11-03 1996-10-30 Verfahren zur quasitotaler entfernung der schwefelverbindungen h2s, so2, cos und/oder cs2 aus denselben enthaltenden restlichen rauchgasen einer schwefelanlage mit rückgewinnung dieser verbindungen als schwefel

Country Status (15)

Country Link
US (1) US6444185B1 (de)
EP (1) EP0801632B1 (de)
JP (1) JP3889051B2 (de)
CN (1) CN1080701C (de)
AT (1) ATE206685T1 (de)
CA (1) CA2209332C (de)
DE (1) DE69615816T2 (de)
ES (1) ES2166006T3 (de)
FR (1) FR2740704B1 (de)
NO (1) NO973031L (de)
PT (1) PT801632E (de)
RU (1) RU2142404C1 (de)
TW (1) TW358753B (de)
UA (1) UA48162C2 (de)
WO (1) WO1997017283A1 (de)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2740704B1 (fr) * 1995-11-03 1997-12-26 Elf Aquitaine Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre
DE69910049T2 (de) * 1998-08-25 2004-04-22 Gastec N.V. Verfahren zur rückgewinung von schwefel aus schwefelwasserstoff enthaltenden gasen
FR2840295B1 (fr) * 2002-06-03 2005-02-04 Inst Francais Du Petrole Prodede d'elimination du soufre d'une charge contenant de l'hydrogene sulfure et du benzene, toluene et/ou xylenes
MXPA06011997A (es) * 2004-04-22 2007-01-25 Fluor Tech Corp Configuraciones y metodos mejorados para el tratamiento de gas efluente.
EA010173B1 (ru) * 2004-04-22 2008-06-30 Флуор Текнолоджиз Корпорейшн Установки и способы для переработки cos по реакции клауса
DE112005001658T5 (de) * 2004-07-12 2007-06-06 Exxonmobil Upstream Research Co., Houston Verfahren zum Entfernen schwefel-haltiger Verbindungen
MY140997A (en) * 2004-07-22 2010-02-12 Shell Int Research Process for the removal of cos from a synthesis gas stream comprising h2s and cos
EP1973841A1 (de) * 2006-01-18 2008-10-01 Shell Internationale Research Maatschappij B.V. Verfahren zur entfernung von carbonylsulfid und schwefelwasserstoff aus einem synthesegasstrom
US8142748B2 (en) 2007-09-17 2012-03-27 Shell Oil Company Catalyst composition useful in the catalytic reduction of sulfur compound contained in a gas stream and a method of making and using such composition
CN102380311B (zh) * 2010-09-01 2013-12-25 中国石油化工股份有限公司 汽油吸附脱硫再生烟气处理方法及其尾气加氢催化剂制法
CA2782944C (en) * 2012-02-17 2014-11-04 Archon Technologies Ltd. Process for the removal of sulfur compounds from gas streams
GB201303737D0 (en) * 2013-03-01 2013-04-17 Cross Peter F Catalytic treatment
US9370745B2 (en) 2013-04-24 2016-06-21 Jiangsu New Century Jiangnan Environmental Protection Co., Ltd Flue gas-treating method and apparatus for treating acidic tail gas by using ammonia process
CN106621796B (zh) * 2016-10-31 2023-06-13 昆明理工大学 一种同时脱除羰基硫、二硫化碳的方法及装置
CN108144428A (zh) 2017-03-15 2018-06-12 江苏新世纪江南环保股份有限公司 一种氨法高效脱除气体中硫氧化物和尘的方法及装置
CN107213769B (zh) 2017-05-25 2019-09-20 江苏新世纪江南环保股份有限公司 一种分室加氨的氨法脱硫方法及装置
CN107213785B (zh) 2017-05-25 2020-08-07 江苏新世纪江南环保股份有限公司 一种fcc尾气氨法脱硝脱硫除尘的方法及装置
MX2017008528A (es) 2017-06-14 2019-02-08 Jiangnan Environmental Prot Group Inc Sistema y método de adición automatica de amoniaco para dispositivo de desulfuración basado en amoniaco.
CN107213770B (zh) 2017-07-03 2023-03-17 江苏新世纪江南环保股份有限公司 氨法脱硫吸收塔及其建立方法和运行方法
CN107497449B (zh) * 2017-09-06 2020-09-01 淄博天净环保技术有限公司 催化氧化元素硫及硫化物的催化剂及其制备方法和应用
CN108722163B (zh) 2017-09-07 2019-06-07 江苏新世纪江南环保股份有限公司 一种氨法脱硫控制吸收过程气溶胶产生的方法
EP3752457A1 (de) 2018-02-13 2020-12-23 Haldor Topsøe A/S Herstellung von düngemitteln aus deponiegas oder faulgas
CN110368816A (zh) 2018-04-13 2019-10-25 江苏新世纪江南环保股份有限公司 一种氨法脱硫溶液的氧化方法及装置
CN110732227B (zh) 2018-07-20 2023-02-21 江南环保集团股份有限公司 一种酸性气处理的方法和装置
US11731080B2 (en) 2018-12-21 2023-08-22 King Fahd University Of Petroleum And Minerals Method of sweetening hydrocarbon gas from hydrogen sulfide
CN111957183A (zh) 2019-12-26 2020-11-20 江苏新世纪江南环保股份有限公司 一种改进的氨法脱硫控制吸收过程气溶胶产生的方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4311683A (en) * 1976-06-28 1982-01-19 Union Oil Company Of California Process for removal of hydrogen sulfide from gas streams
DE3535815A1 (de) * 1985-10-08 1987-04-09 Metallgesellschaft Ag Verfahren zum reinigen von schwefelwasserstoff und schwefeldioxid enthaltendem abgas
FR2589141B1 (fr) * 1985-10-25 1987-12-11 Elf Aquitaine Procede d'elimination des composes soufres contenus dans un gaz residuaire, notamment issu d'une usine a soufre claus, avec recuperation desdits composes sous la forme de soufre
US5185140A (en) * 1985-10-25 1993-02-09 Elf Aquitaine Production Process for removing sulphur compounds from a residual gas
NL8600960A (nl) * 1986-04-16 1987-11-16 Veg Gasinstituut Nv Werkwijze voor het winnen van zwavel uit zwavelhoudende gassen.
FR2632626B1 (fr) * 1988-06-08 1990-08-31 Elf Aquitaine Procede pour ameliorer le rendement en soufre d'un ensemble de production de soufre a partir d'un gaz acide renfermant h2s, ledit ensemble comportant une usine a soufre suivie d'une unite d'epuration
US5202107A (en) * 1988-06-08 1993-04-13 Societe National Elf Aquitaine (Prod.) Process for improving the sulphur yield of a complex for the production of sulphur followed by a purification unit
US5494650A (en) * 1989-01-19 1996-02-27 Societe Nationale Elf Aquitaine (Production) Process for improving the sulphur yield of a complex for producing sulphur from a sour gas containing H2 S, the said complex comprising a sulphur plant and then an oxidation and hydrolysis unit followed by a purification unit
FR2653422B1 (fr) * 1989-10-19 1992-01-03 Elf Aquitaine Procede pour ameliorer le rendement en soufre d'un ensemble de production de soufre a partir d'un gaz acide renfermant h2s, ledit ensemble comportant une usine a soufre, puis une unite d'oxydation et d'hydrolyse suivie d'une unite d'epuration.
FR2702674B1 (fr) * 1993-03-16 1995-04-28 Elf Aquitaine Procédé d'élimination des composés soufrés contenus dans un gaz résiduaire du type gaz résiduaire d'usine à soufre Claus, avec récupération desdits composés sous la forme de soufre.
FR2740704B1 (fr) * 1995-11-03 1997-12-26 Elf Aquitaine Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre

Also Published As

Publication number Publication date
NO973031L (no) 1997-09-01
CN1080701C (zh) 2002-03-13
UA48162C2 (uk) 2002-08-15
EP0801632B1 (de) 2001-10-10
JP3889051B2 (ja) 2007-03-07
WO1997017283A1 (fr) 1997-05-15
DE69615816D1 (de) 2001-11-15
NO973031D0 (no) 1997-06-27
ATE206685T1 (de) 2001-10-15
TW358753B (en) 1999-05-21
CA2209332A1 (fr) 1997-05-15
FR2740704A1 (fr) 1997-05-09
CN1173854A (zh) 1998-02-18
JPH11501280A (ja) 1999-02-02
ES2166006T3 (es) 2002-04-01
PT801632E (pt) 2002-04-29
CA2209332C (fr) 2001-05-08
FR2740704B1 (fr) 1997-12-26
RU2142404C1 (ru) 1999-12-10
US6444185B1 (en) 2002-09-03
EP0801632A1 (de) 1997-10-22

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