EA200801713A1 - Способ удаления карбонилсульфида и сероводорода из потока синтез-газа - Google Patents

Способ удаления карбонилсульфида и сероводорода из потока синтез-газа

Info

Publication number
EA200801713A1
EA200801713A1 EA200801713A EA200801713A EA200801713A1 EA 200801713 A1 EA200801713 A1 EA 200801713A1 EA 200801713 A EA200801713 A EA 200801713A EA 200801713 A EA200801713 A EA 200801713A EA 200801713 A1 EA200801713 A1 EA 200801713A1
Authority
EA
Eurasian Patent Office
Prior art keywords
synthesis gas
hydrogen
carbonesulfide
gas flow
metals
Prior art date
Application number
EA200801713A
Other languages
English (en)
Inventor
Рудольф Хенри Макс Херольд
Тейме Ласт
Бернардус Йозефус Мария Мансханде
Корнелис Якобус Смит
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Publication of EA200801713A1 publication Critical patent/EA200801713A1/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/308—Carbonoxysulfide COS
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/406—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/408—Cyanides, e.g. hydrogen cyanide (HCH)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process

Abstract

В настоящем изобретении предложен способ удаления COS и HS из сырьевого потока синтез-газа, содержащего COS и HS, причем способ включает введение в контакт сырьевого потока синтез-газа с твердым адсорбентом при температуре в диапазоне от 100 до 240°С с целью удаления карбонилсульфида и сероводорода, тем самым получают очищенный поток синтез-газа, в котором твердый адсорбент содержит один или несколько металлов или оксидов металлов или их сочетаний, и эти металлы выбирают из группы Ag, Sn, Mo, Fe и Zn.
EA200801713A 2006-01-18 2007-01-17 Способ удаления карбонилсульфида и сероводорода из потока синтез-газа EA200801713A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP06100495 2006-01-18
PCT/EP2007/050439 WO2007082896A1 (en) 2006-01-18 2007-01-17 Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream

Publications (1)

Publication Number Publication Date
EA200801713A1 true EA200801713A1 (ru) 2008-12-30

Family

ID=36528833

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200801713A EA200801713A1 (ru) 2006-01-18 2007-01-17 Способ удаления карбонилсульфида и сероводорода из потока синтез-газа

Country Status (8)

Country Link
US (1) US8043589B2 (ru)
EP (1) EP1973841A1 (ru)
CN (1) CN101374759A (ru)
AU (1) AU2007206964A1 (ru)
EA (1) EA200801713A1 (ru)
MY (1) MY149541A (ru)
WO (1) WO2007082896A1 (ru)
ZA (1) ZA200805501B (ru)

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EP2158155A1 (en) 2007-06-18 2010-03-03 Shell Internationale Research Maatschappij B.V. Process for removal of hydrogen cyanide and ammonia from synthesis gas
UA100395C2 (en) 2007-10-26 2012-12-25 Haldor Topsoe As Process for a reduction in the amount of sulphur compounds, hydrogen cyanide and formic acid in synthesis gas
DK200801093A (en) * 2008-08-13 2010-02-14 Topsoe Haldor As Process and system for removing impurities from a gas stream
US8282707B2 (en) 2010-06-30 2012-10-09 Uop Llc Natural gas purification system
CN102259835B (zh) * 2011-06-20 2013-03-27 中国科学院广州能源研究所 一种基于熔融盐特性的粗合成气净化提质方法
CA2776369C (en) * 2012-05-09 2014-01-21 Steve Kresnyak Enhancement of fischer-tropsch process for hydrocarbon fuel formulation in a gtl environment
US9394490B2 (en) 2014-02-11 2016-07-19 Uop Llc Process for removing carbonyl sulfide from a hydrocarbon stream
DE102014205955A1 (de) * 2014-03-31 2015-10-01 Siemens Aktiengesellschaft Verfahren und Vorrichtung zur Reinigung eines Synthesegasstroms eines Rohbrennstoffvergasers
AU2015336109B2 (en) * 2014-10-24 2020-11-19 Research Triangle Institute Integrated system and method for removing acid gas from a gas stream
US20170290358A1 (en) * 2016-04-08 2017-10-12 John Bean Technologies Corporation System and method for automated, continuous high temperature sterilization and filling of food products
JP6789777B2 (ja) * 2016-11-22 2020-11-25 三菱重工エンジニアリング株式会社 ガス精製装置及びガス精製方法
US20210300766A1 (en) * 2018-07-17 2021-09-30 Sabic Global Technologies B.V. Process for removal of sulfides from carbon monoxide rich gas stream at ambient temperatures
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Also Published As

Publication number Publication date
CN101374759A (zh) 2009-02-25
AU2007206964A1 (en) 2007-07-26
EP1973841A1 (en) 2008-10-01
US20100197984A1 (en) 2010-08-05
ZA200805501B (en) 2009-02-25
WO2007082896A1 (en) 2007-07-26
MY149541A (en) 2013-09-13
US8043589B2 (en) 2011-10-25

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