ZA200805501B - Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream - Google Patents

Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream

Info

Publication number
ZA200805501B
ZA200805501B ZA200805501A ZA200805501A ZA200805501B ZA 200805501 B ZA200805501 B ZA 200805501B ZA 200805501 A ZA200805501 A ZA 200805501A ZA 200805501 A ZA200805501 A ZA 200805501A ZA 200805501 B ZA200805501 B ZA 200805501B
Authority
ZA
South Africa
Prior art keywords
sulphide
gas stream
synthesis gas
removing carbonyl
hydrogen
Prior art date
Application number
ZA200805501A
Other languages
English (en)
Inventor
Herold Rudolf Henri Max
Last Thijme
Manshande Bernardus Josephus Maria
Smit Cornelis Jacobus
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of ZA200805501B publication Critical patent/ZA200805501B/xx

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/104Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/112Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/304Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/308Carbonoxysulfide COS
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/406Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/408Cyanides, e.g. hydrogen cyanide (HCH)
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415Purification by absorption in liquids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042Purification by adsorption on solids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0485Composition of the impurity the impurity being a sulfur compound
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/062Hydrocarbon production, e.g. Fischer-Tropsch process

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Industrial Gases (AREA)
  • Separation Of Gases By Adsorption (AREA)
ZA200805501A 2006-01-18 2008-06-24 Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream ZA200805501B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP06100495 2006-01-18

Publications (1)

Publication Number Publication Date
ZA200805501B true ZA200805501B (en) 2009-02-25

Family

ID=36528833

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA200805501A ZA200805501B (en) 2006-01-18 2008-06-24 Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream

Country Status (8)

Country Link
US (1) US8043589B2 (xx)
EP (1) EP1973841A1 (xx)
CN (1) CN101374759A (xx)
AU (1) AU2007206964A1 (xx)
EA (1) EA200801713A1 (xx)
MY (1) MY149541A (xx)
WO (1) WO2007082896A1 (xx)
ZA (1) ZA200805501B (xx)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101553303B (zh) 2006-12-08 2011-12-28 国际壳牌研究有限公司 用于生产纯化的合成气物流的方法
MY149141A (en) 2007-06-18 2013-07-15 Shell Int Research Process for removal of hydrogen cyanide and ammonia from synthesis gas
CN101918111B (zh) 2007-10-26 2014-10-08 赫多特普索化工设备公司 用于降低合成气中含硫化合物、氰化氢和甲酸的量的方法
DK200801093A (en) * 2008-08-13 2010-02-14 Topsoe Haldor As Process and system for removing impurities from a gas stream
US8282707B2 (en) 2010-06-30 2012-10-09 Uop Llc Natural gas purification system
CN102259835B (zh) 2011-06-20 2013-03-27 中国科学院广州能源研究所 一种基于熔融盐特性的粗合成气净化提质方法
CA2776369C (en) * 2012-05-09 2014-01-21 Steve Kresnyak Enhancement of fischer-tropsch process for hydrocarbon fuel formulation in a gtl environment
US9394490B2 (en) 2014-02-11 2016-07-19 Uop Llc Process for removing carbonyl sulfide from a hydrocarbon stream
DE102014205955A1 (de) * 2014-03-31 2015-10-01 Siemens Aktiengesellschaft Verfahren und Vorrichtung zur Reinigung eines Synthesegasstroms eines Rohbrennstoffvergasers
KR102472112B1 (ko) * 2014-10-24 2022-11-28 리써치 트라이앵글 인스티튜트 가스 스트림으로부터 산 가스를 제거하기 위한 통합 시스템 및 방법
US20170290358A1 (en) * 2016-04-08 2017-10-12 John Bean Technologies Corporation System and method for automated, continuous high temperature sterilization and filling of food products
JP6789777B2 (ja) * 2016-11-22 2020-11-25 三菱重工エンジニアリング株式会社 ガス精製装置及びガス精製方法
US20210300766A1 (en) * 2018-07-17 2021-09-30 Sabic Global Technologies B.V. Process for removal of sulfides from carbon monoxide rich gas stream at ambient temperatures
CN111337425B (zh) * 2018-12-18 2022-07-12 山东华光光电子股份有限公司 一种半导体激光器cos合金强度检测装置及检测方法

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3441370A (en) * 1966-04-25 1969-04-29 Catalysts & Chem Inc Method of removing sulfur compounds from gases
US3974256A (en) * 1974-05-07 1976-08-10 Exxon Research And Engineering Company Sulfide removal process
FR2295782A1 (fr) * 1974-12-27 1976-07-23 Inst Francais Du Petrole Procede d'epuration d'un gaz contenant du sulfure d'hydrogene et masses de contact utilisables a cet effet
US4254094A (en) * 1979-03-19 1981-03-03 Air Products And Chemicals, Inc. Process for producing hydrogen from synthesis gas containing COS
US4271133A (en) * 1980-03-31 1981-06-02 Union Carbide Corporation Process for removing hydrogen cyanide from gaseous streams
US4299802A (en) * 1980-03-31 1981-11-10 Union Carbide Corporation Process for removing carbonyl sulfide from gaseous streams
DE3131257C2 (de) * 1981-08-07 1986-10-30 VEG-Gasinstituut N.V., Apeldoorn Verfahren zum Entfernen von Schwefelwasserstoff aus Gasen
DE3713844C2 (de) * 1986-04-24 1997-04-17 Mitsubishi Heavy Ind Ltd Verfahren zum Reinigen eines Hochtemperatur-Reduktionsgases
GB8610196D0 (en) * 1986-04-25 1986-05-29 Ici Plc Sulphur compounds removal
US4888131A (en) * 1988-03-28 1989-12-19 Exxon Research And Engineering Company Synthesis gas preparation and catalyst therefor
DK165969C (da) * 1989-05-29 1993-11-08 Haldor Topsoe As Fremgangsmaade til fjernelse af sulfider fra gasstroemme
US5104630A (en) * 1990-11-13 1992-04-14 Uop Processes for removing carbonyl sulfide from hydrocarbon feedstreams
NL9002661A (nl) 1990-12-04 1992-07-01 Pacques Bv Werkwijze voor de verwijdering van h2s uit gas.
ZA935964B (en) 1992-08-18 1994-03-15 Shell Res Ltd Process for the preparation of hydrocarbon fuels
DE4321542C1 (de) 1993-06-29 1994-09-01 Bfi Entsorgungstech Verfahren zur getrennten Entfernung von Schwefelverbindungen und CO¶2¶ aus Gas
GB9404191D0 (en) 1994-03-04 1994-04-20 Imperial College Preparations and uses of polyferric sulphate
US5463168A (en) * 1994-08-17 1995-10-31 Mobil Oil Corporation Process for the removal of hydrogen cyanide from FCC hydrocarbon product gas streams
DE4431788A1 (de) 1994-09-07 1996-03-14 Huels Chemische Werke Ag Katalysator und Verfahren zur Zersetzung von HCN in Gasen
DE69607423T2 (de) 1995-08-08 2000-08-03 Exxon Research Engineering Co Verfahren zur Beseitigung von Cyanwasserstoff aus Synthesegas
FR2740704B1 (fr) * 1995-11-03 1997-12-26 Elf Aquitaine Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre
WO1999034917A1 (en) 1997-12-30 1999-07-15 Shell Internationale Research Maatschappij B.V. Cobalt based fisher-tropsch catalyst
US6168768B1 (en) * 1998-01-23 2001-01-02 Exxon Research And Engineering Company Production of low sulfer syngas from natural gas with C4+/C5+ hydrocarbon recovery
US5882614A (en) * 1998-01-23 1999-03-16 Exxon Research And Engineering Company Very low sulfur gas feeds for sulfur sensitive syngas and hydrocarbon synthesis processes
US6322763B1 (en) * 1998-12-15 2001-11-27 Teco, Inc. Method and apparatus for removing carbonyl sulfide from a gas stream via wet scrubbing
US6551566B1 (en) * 2000-10-12 2003-04-22 Air Liquide Process And Construction, Inc. Hydrodehalogenation process using a catalyst containing nickel
GB0118416D0 (en) * 2001-07-30 2001-09-19 Ici Plc Desulphurisation
DE10141193B4 (de) * 2001-08-22 2006-07-13 Daimlerchrysler Ag Vorrichtung zur Entschwefelung von Gasströmen
CN100418614C (zh) * 2003-04-17 2008-09-17 国际壳牌研究有限公司 从气流中脱除h2s和硫醇的方法
EP1628744B1 (en) * 2003-05-29 2008-07-09 Shell Internationale Researchmaatschappij B.V. A process for the removal of so2, hcn and h2s and optionally cos, cs2 and nh3 from a gas stream
US7056487B2 (en) * 2003-06-06 2006-06-06 Siemens Power Generation, Inc. Gas cleaning system and method
MY140997A (en) * 2004-07-22 2010-02-12 Shell Int Research Process for the removal of cos from a synthesis gas stream comprising h2s and cos
CN101175547B (zh) * 2005-05-23 2011-12-28 国际壳牌研究有限公司 去除污染物的方法

Also Published As

Publication number Publication date
CN101374759A (zh) 2009-02-25
EP1973841A1 (en) 2008-10-01
AU2007206964A1 (en) 2007-07-26
US8043589B2 (en) 2011-10-25
WO2007082896A1 (en) 2007-07-26
US20100197984A1 (en) 2010-08-05
EA200801713A1 (ru) 2008-12-30
MY149541A (en) 2013-09-13

Similar Documents

Publication Publication Date Title
ZA200805501B (en) Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream
EP2097156A4 (en) METHOD FOR RECOVERING CARBON DIOXIDE FROM A GAS STREAM
PL2164608T3 (pl) Sposób odzyskiwania składnika gazowego ze strumienia gazu
MY147349A (en) Method and system for removing h2s from a natural gas stream
EP1931755A4 (en) METHOD AND APPARATUS FOR REMOVAL OF ACIDIC SPECIES FROM A NATURAL GAS FLOW
EP2007674A4 (en) METHODS AND SYSTEMS FOR GASIFICATION OF A FLOW TO BE PROCESSED
ZA200708732B (en) Removal of carbon dioxide from a gas stream
EP2109491A4 (en) METHOD AND DEVICE FOR REMOVING ACID GAS FROM A NATURAL GAS STREAM
ZA201001545B (en) Process for removal of hydrogen sulphide and carbon dioxide from an acid gas stream
PL2032236T3 (pl) Sposób obróbki strumienia gazu
PT2142470T (pt) Processo de condensação-adsorção para a remoção de componentes orgânicos de um fluxo de gás que contém cloreto de hidrogénio
PL1950176T3 (pl) Sposób usuwania zanieczyszczeń ze strumieni gazu
ZA201005438B (en) Contaminant removal from a gas stream
ZA201106810B (en) Process for producing a purified synthesis gas stream
PL2265357T3 (pl) Systemy i sposoby usuwania zanieczyszczeń gazowych ze strumienia gazu
GB0505852D0 (en) Method of treating a gas stream
ZA200804371B (en) Process for the removal of sulphur compounds and carbon dioxide from a gas stream
PL2092044T3 (pl) Sposób i urządzenie do wytwarzania gazu syntezowego z biomasy
GB0610978D0 (en) Method of treating a gas stream
EP1968728A4 (en) METHOD FOR REMOVING CONTAMINATION FROM A GAS
GB2428598B (en) Process for removing mercury from gaseous streams
EP2217351A4 (en) METHOD AND DEVICE FOR REMOVING CARBON DIOXIDE FROM A GAS STREAM
ZA201101230B (en) Method for removing sulfur from a gas stream
GB0907884D0 (en) Removal of hydrogen cyanide from synthesis gas
ZA200904863B (en) Method of treating a gas stream