NO860440L - Fremgangsmaate ved fremstilling av pulverformige belegningsmaterialer paa basis av en epoxyharpiks og en carboxylert polyester. - Google Patents
Fremgangsmaate ved fremstilling av pulverformige belegningsmaterialer paa basis av en epoxyharpiks og en carboxylert polyester.Info
- Publication number
- NO860440L NO860440L NO860440A NO860440A NO860440L NO 860440 L NO860440 L NO 860440L NO 860440 A NO860440 A NO 860440A NO 860440 A NO860440 A NO 860440A NO 860440 L NO860440 L NO 860440L
- Authority
- NO
- Norway
- Prior art keywords
- polyester resin
- carboxylated
- mixture
- parts
- weight
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 17
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 17
- 238000000576 coating method Methods 0.000 title claims description 24
- 239000011248 coating agent Substances 0.000 title claims description 21
- 239000000463 material Substances 0.000 title claims description 21
- 229920000728 polyester Polymers 0.000 title description 9
- 238000002360 preparation method Methods 0.000 title 1
- 229920001225 polyester resin Polymers 0.000 claims abstract description 46
- 239000004645 polyester resin Substances 0.000 claims abstract description 46
- 239000003054 catalyst Substances 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 20
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 claims abstract description 9
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 claims abstract description 8
- 239000004593 Epoxy Substances 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 6
- MCTWTZJPVLRJOU-UHFFFAOYSA-N 1-methyl-1H-imidazole Chemical compound CN1C=CN=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-N 0.000 claims abstract description 5
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000011654 magnesium acetate Substances 0.000 claims abstract description 5
- 229940069446 magnesium acetate Drugs 0.000 claims abstract description 5
- 235000011285 magnesium acetate Nutrition 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 5
- ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 2-phenyl-1h-imidazole Chemical compound C1=CNC(C=2C=CC=CC=2)=N1 ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- FUOZJYASZOSONT-UHFFFAOYSA-N 2-propan-2-yl-1h-imidazole Chemical compound CC(C)C1=NC=CN1 FUOZJYASZOSONT-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims abstract description 4
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 claims abstract description 4
- 239000004246 zinc acetate Substances 0.000 claims abstract description 4
- 239000008199 coating composition Substances 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 235000011037 adipic acid Nutrition 0.000 description 4
- 239000001361 adipic acid Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical group CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 1
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- DOKHEARVIDLSFF-UHFFFAOYSA-N prop-1-en-1-ol Chemical group CC=CO DOKHEARVIDLSFF-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical class O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 description 1
- YMBCJWGVCUEGHA-UHFFFAOYSA-M tetraethylammonium chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC YMBCJWGVCUEGHA-UHFFFAOYSA-M 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Epoxy Resins (AREA)
- Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8501771A FR2577231B1 (fr) | 1985-02-08 | 1985-02-08 | Procede de preparation des compositions de revetement en poudre a base d'une resine epoxy et d'un polyester carboxyle |
Publications (1)
Publication Number | Publication Date |
---|---|
NO860440L true NO860440L (no) | 1986-08-11 |
Family
ID=9316060
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO860440A NO860440L (no) | 1985-02-08 | 1986-02-07 | Fremgangsmaate ved fremstilling av pulverformige belegningsmaterialer paa basis av en epoxyharpiks og en carboxylert polyester. |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0194904B1 (de) |
JP (1) | JPS61183367A (de) |
CN (1) | CN1003646B (de) |
AT (1) | ATE42315T1 (de) |
CA (1) | CA1264882A (de) |
DE (1) | DE3662902D1 (de) |
DK (1) | DK61586A (de) |
FI (1) | FI860565A (de) |
FR (1) | FR2577231B1 (de) |
NO (1) | NO860440L (de) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4920182A (en) * | 1987-12-18 | 1990-04-24 | Ciba-Geigy Corporation | Epoxy resin compositions containing polyester flexibilizer and metallocene complex initiator |
DE4038681A1 (de) * | 1990-12-05 | 1992-06-11 | Basf Lacke & Farben | Pulverlack und dessen verwendung zur innenbeschichtung von verpackungsbehaeltern und zur schweissnahtabdeckung |
DE4141776A1 (de) * | 1991-12-18 | 1993-06-24 | Hoechst Ag | Haertbares bindemittel und verfahren zu dessen herstellung |
NL9400182A (nl) * | 1994-02-04 | 1995-09-01 | Dsm Nv | Poederverf. |
GB9901485D0 (en) | 1999-01-22 | 1999-03-17 | Swan Thomas & Co Ltd | Improvements in or relating to powdered coating compositions |
US6576718B1 (en) * | 1999-10-05 | 2003-06-10 | General Electric Company | Powder coating of thermosetting resin(s) and poly(phenylene ethers(s)) |
JP2002020683A (ja) * | 2000-07-05 | 2002-01-23 | Sumitomo Bakelite Co Ltd | エポキシ樹脂粉体塗料 |
CN100384955C (zh) * | 2004-09-06 | 2008-04-30 | 上海盛伦化工有限公司 | 低温快速固化抗菌型环氧聚酯粉体涂料及其制备方法 |
DE102005042822A1 (de) * | 2005-09-09 | 2007-03-22 | Degussa Ag | Hybrid-Pulverlackzusammensetzung mit niedriger Einbrenntemperatur für halbglänzende bis matte Überzüge |
CN100347250C (zh) * | 2005-10-10 | 2007-11-07 | 湘潭市至诚涂料有限公司 | 热敏基材专用超低温固化粉末涂料 |
FR3000075B1 (fr) * | 2012-12-21 | 2015-11-13 | Arkema France | Systemes catalytiques pour resines thermodurcissables deformables |
CN103601872B (zh) * | 2013-11-21 | 2015-07-29 | 天津翔盛粉末涂料有限公司 | 一种可降低端基为羧基的饱和聚酯树脂固化温度的催化剂 |
CN109627427A (zh) * | 2018-11-19 | 2019-04-16 | 天津翔盛新材料有限公司 | 一种低粘度环氧树脂的制备方法及超流平粉末涂料 |
CN112409882A (zh) * | 2020-11-13 | 2021-02-26 | 湖南太子化工涂料有限公司 | 一种环氧树脂和羧基聚酯粉末涂料和制备方法 |
CN115093776A (zh) * | 2022-07-08 | 2022-09-23 | 广东睿智环保科技有限责任公司 | 一种mdf热转印用抗菌粉末涂料及其应用方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1391527A (fr) * | 1963-05-02 | 1965-03-05 | Shell Int Research | Procédé de durcissement de polyépoxydes et produits résultants |
US3689444A (en) * | 1971-04-23 | 1972-09-05 | Celanese Coatings Co | Latent catalysts for one-component epoxy resin/anhydride compositions |
JPS5949260B2 (ja) * | 1975-08-27 | 1984-12-01 | 日本エステル (株) | 粉体塗料用ポリエステル樹脂組成物 |
DE2641108C2 (de) * | 1976-09-13 | 1978-05-18 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Beschleunigerkombination für die Vernetzung von Pulverlackbindemitteln |
IT1076226B (it) * | 1977-01-17 | 1985-04-27 | Sir Soc Italiana Resine Spa | Composizioni solide reticolabili comprendenti una resina poliestere ed una resina epossidica |
US4370452A (en) * | 1981-01-12 | 1983-01-25 | The Goodyear Tire & Rubber Company | Process to induce rapid curing of a copolyester resin with epoxide compounds and a composition formed for that process |
-
1985
- 1985-02-08 FR FR8501771A patent/FR2577231B1/fr not_active Expired
-
1986
- 1986-01-29 EP EP86400190A patent/EP0194904B1/de not_active Expired
- 1986-01-29 AT AT86400190T patent/ATE42315T1/de not_active IP Right Cessation
- 1986-01-29 DE DE8686400190T patent/DE3662902D1/de not_active Expired
- 1986-02-07 DK DK61586A patent/DK61586A/da not_active Application Discontinuation
- 1986-02-07 JP JP61025639A patent/JPS61183367A/ja active Pending
- 1986-02-07 FI FI860565A patent/FI860565A/fi not_active Application Discontinuation
- 1986-02-07 NO NO860440A patent/NO860440L/no unknown
- 1986-02-07 CA CA000501387A patent/CA1264882A/fr not_active Expired - Fee Related
- 1986-02-07 CN CN86100991.6A patent/CN1003646B/zh not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FI860565A (fi) | 1986-08-09 |
FI860565A0 (fi) | 1986-02-07 |
CN1003646B (zh) | 1989-03-22 |
ATE42315T1 (de) | 1989-05-15 |
DK61586D0 (da) | 1986-02-07 |
EP0194904A1 (de) | 1986-09-17 |
FR2577231B1 (fr) | 1987-09-11 |
CA1264882A (fr) | 1990-01-23 |
DK61586A (da) | 1986-08-09 |
CN86100991A (zh) | 1986-08-20 |
EP0194904B1 (de) | 1989-04-19 |
DE3662902D1 (en) | 1989-05-24 |
JPS61183367A (ja) | 1986-08-16 |
FR2577231A1 (fr) | 1986-08-14 |
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