NO852451L - Fremgangmaate for polymerisering av olefiner. - Google Patents
Fremgangmaate for polymerisering av olefiner.Info
- Publication number
- NO852451L NO852451L NO852451A NO852451A NO852451L NO 852451 L NO852451 L NO 852451L NO 852451 A NO852451 A NO 852451A NO 852451 A NO852451 A NO 852451A NO 852451 L NO852451 L NO 852451L
- Authority
- NO
- Norway
- Prior art keywords
- titanium
- stated
- compound
- zirconium
- hafnium
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 24
- 238000006116 polymerization reaction Methods 0.000 title description 15
- 239000010936 titanium Substances 0.000 claims abstract description 31
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 29
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 26
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000005977 Ethylene Substances 0.000 claims abstract description 20
- 239000003054 catalyst Substances 0.000 claims abstract description 19
- 239000011777 magnesium Substances 0.000 claims abstract description 15
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 13
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 229910052735 hafnium Inorganic materials 0.000 claims abstract description 6
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims description 13
- 229910052736 halogen Inorganic materials 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- -1 aluminum compound Chemical class 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 230000003197 catalytic effect Effects 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 150000002430 hydrocarbons Chemical group 0.000 claims description 6
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 238000007334 copolymerization reaction Methods 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 5
- 150000002363 hafnium compounds Chemical class 0.000 claims description 5
- 150000004820 halides Chemical class 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000003609 titanium compounds Chemical class 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 2
- 150000004703 alkoxides Chemical class 0.000 claims description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 2
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 2
- PDPJQWYGJJBYLF-UHFFFAOYSA-J hafnium tetrachloride Chemical compound Cl[Hf](Cl)(Cl)Cl PDPJQWYGJJBYLF-UHFFFAOYSA-J 0.000 claims description 2
- 229910001502 inorganic halide Inorganic materials 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 abstract description 6
- 150000001336 alkenes Chemical class 0.000 abstract 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 14
- 239000000725 suspension Substances 0.000 description 10
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 8
- 238000009826 distribution Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 101000798109 Homo sapiens Melanotransferrin Proteins 0.000 description 4
- 102100032239 Melanotransferrin Human genes 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 229910003074 TiCl4 Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 229910007932 ZrCl4 Inorganic materials 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- ABNGESMFWMTZHX-UHFFFAOYSA-N 1-chlorohexane Chemical compound [CH2]CCCCCCl ABNGESMFWMTZHX-UHFFFAOYSA-N 0.000 description 1
- 241000974482 Aricia saepiolus Species 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000001641 gel filtration chromatography Methods 0.000 description 1
- 125000006277 halobenzyl group Chemical group 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000000075 primary alcohol group Chemical group 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 150000003509 tertiary alcohols Chemical class 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT21559/84A IT1176299B (it) | 1984-06-22 | 1984-06-22 | Metodo per la preparazione di un catalizzatore a base di zirconio o afnio e processo di polimerizzazione o copolimerizzazione di composti insaturi impiegante lo stesso |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO852451L true NO852451L (no) | 1985-12-23 |
Family
ID=11183595
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO852451A NO852451L (no) | 1984-06-22 | 1985-06-18 | Fremgangmaate for polymerisering av olefiner. |
Country Status (18)
| Country | Link |
|---|---|
| JP (1) | JPS6114202A (ru) |
| BE (1) | BE902730A (ru) |
| DE (1) | DE3522295A1 (ru) |
| DK (1) | DK279185A (ru) |
| ES (1) | ES8609372A1 (ru) |
| FR (1) | FR2566412A1 (ru) |
| GB (1) | GB2160535A (ru) |
| GR (1) | GR851522B (ru) |
| IL (1) | IL75590A0 (ru) |
| IT (1) | IT1176299B (ru) |
| LU (1) | LU85968A1 (ru) |
| NL (1) | NL8501815A (ru) |
| NO (1) | NO852451L (ru) |
| PL (1) | PL254120A1 (ru) |
| PT (1) | PT80685B (ru) |
| RO (1) | RO92339B (ru) |
| SE (1) | SE8503033L (ru) |
| ZA (1) | ZA854595B (ru) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5015511A (en) * | 1988-05-12 | 1991-05-14 | The Dow Chemical Company | Linear low density ethylene interpolymers for injection molding |
| JP2740922B2 (ja) * | 1989-11-21 | 1998-04-15 | 石原産業株式会社 | 磁気記録材料用金属磁性粉末の製造方法 |
| IT1311978B1 (it) * | 1999-03-25 | 2002-03-22 | Polimeri Europa Srl | Catalizzatore bimetallico per la (co) polimerizzazione dellealfa-olefine. |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1464451A (en) * | 1973-09-08 | 1977-02-16 | Chubu Chem Inc | Solid catalytic complexes and their use in olefin polymerization |
| JPS5146387A (en) * | 1974-10-18 | 1976-04-20 | Yozo Kondo | Horiorefuinno seizohoho |
| GB1578745A (en) * | 1976-05-24 | 1980-11-12 | Bp Chem Int Ltd | Polymerisation catalyst component |
| IT1130243B (it) * | 1980-02-01 | 1986-06-11 | Anic Spa | Composizione chimica a base di titanio trialogenuro,metodo per la sua preparazione e processo di polimerizzazione o copolimerizzazione di composti insaturi impiegante la stessa |
| US4396747A (en) * | 1981-05-22 | 1983-08-02 | Phillips Petroleum Company | Zirconium-titanium catalyzed olefin polymerization |
| IT1137631B (it) * | 1981-07-29 | 1986-09-10 | Anic Spa | Procedimento per la polimerizzazione e copolimerizzazione in alta resa di composti olefinicamente insaturi e mezzi adatti allo socpo |
| IT1210855B (it) * | 1982-02-12 | 1989-09-29 | Assoreni Ora Enichem Polimeri | Polimeri dell'etilene a struttura lineare e processi per la loro preparazione. |
-
1984
- 1984-06-22 IT IT21559/84A patent/IT1176299B/it active
-
1985
- 1985-06-18 NO NO852451A patent/NO852451L/no unknown
- 1985-06-18 ZA ZA854595A patent/ZA854595B/xx unknown
- 1985-06-18 SE SE8503033A patent/SE8503033L/xx not_active Application Discontinuation
- 1985-06-19 GB GB08515470A patent/GB2160535A/en not_active Withdrawn
- 1985-06-20 IL IL75590A patent/IL75590A0/xx unknown
- 1985-06-20 LU LU85968A patent/LU85968A1/fr unknown
- 1985-06-20 DK DK279185A patent/DK279185A/da not_active Application Discontinuation
- 1985-06-21 JP JP60134440A patent/JPS6114202A/ja active Pending
- 1985-06-21 PL PL25412085A patent/PL254120A1/xx unknown
- 1985-06-21 GR GR851522A patent/GR851522B/el unknown
- 1985-06-21 DE DE19853522295 patent/DE3522295A1/de not_active Ceased
- 1985-06-21 RO RO119262A patent/RO92339B/ro unknown
- 1985-06-21 FR FR8509510A patent/FR2566412A1/fr not_active Withdrawn
- 1985-06-21 BE BE0/215248A patent/BE902730A/fr not_active IP Right Cessation
- 1985-06-21 PT PT80685A patent/PT80685B/pt unknown
- 1985-06-21 ES ES544981A patent/ES8609372A1/es not_active Expired
- 1985-06-24 NL NL8501815A patent/NL8501815A/nl not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| SE8503033L (sv) | 1985-12-23 |
| GR851522B (ru) | 1985-11-25 |
| DK279185D0 (da) | 1985-06-20 |
| DK279185A (da) | 1985-12-23 |
| GB2160535A (en) | 1985-12-24 |
| JPS6114202A (ja) | 1986-01-22 |
| ZA854595B (en) | 1986-02-26 |
| IT8421559A0 (it) | 1984-06-22 |
| DE3522295A1 (de) | 1985-12-19 |
| IT8421559A1 (it) | 1985-12-22 |
| IT1176299B (it) | 1987-08-18 |
| ES544981A0 (es) | 1986-07-16 |
| ES8609372A1 (es) | 1986-07-16 |
| GB8515470D0 (en) | 1985-07-24 |
| BE902730A (fr) | 1985-12-23 |
| PL254120A1 (en) | 1986-05-20 |
| PT80685A (en) | 1985-07-01 |
| FR2566412A1 (fr) | 1985-12-27 |
| IL75590A0 (en) | 1985-10-31 |
| SE8503033D0 (sv) | 1985-06-18 |
| RO92339A (ro) | 1987-08-31 |
| LU85968A1 (fr) | 1986-01-24 |
| NL8501815A (nl) | 1986-01-16 |
| PT80685B (en) | 1987-03-31 |
| RO92339B (ro) | 1987-09-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2678688B2 (ja) | オレフィン重合用の第▲ｉｖ▼ｂ、▲ｖ▼ｂ及び▲ｖｉ▼ｂ族金属ヒドロカルビルオキシドとアルモキサン | |
| EP0497531B1 (en) | Process for producing ethylene polymers | |
| AU773920B2 (en) | Method for polymerising olefins | |
| CA1204725A (en) | Polyolefin polymerization process and catalyst | |
| NO180340B (no) | Fremgangsmåte for fremstilling av etylen--olefinkopolymerer | |
| US3210332A (en) | Production of solid olefin polymers | |
| US3981849A (en) | Low pressure process for the production of low density co- and terpolymers of ethylene | |
| US4308357A (en) | Block copolymerization process and product | |
| NO852451L (no) | Fremgangmaate for polymerisering av olefiner. | |
| CA1160206A (en) | Process for the copolymerisation of ethylene with polyunsaturated hydrocarbons | |
| US4465781A (en) | Halogenated catalyst for ethylene polymerization containing a transition metal and magnesium and process for its preparation | |
| US5399540A (en) | ZR/V multi-site olefin polymerization catalyst | |
| US4379074A (en) | Chemical composition based on titanium trihalide, a method for its preparation, and a process for the polymerization or copolymerization of unsaturated compounds which uses this composition | |
| US3014018A (en) | Process for the polymerization of alpha-olefins | |
| US3969333A (en) | Manufacture of copolymers of 4-methylpentene-1 | |
| JPS5827706A (ja) | オレフイン類の重合用触媒およびその製法 | |
| US3732197A (en) | Production of alpha-olefin polymers | |
| US5258343A (en) | Metal halide catalyst, method of producing the catalyst, polymerization process employing the catalyst, and polymer produced by the polymerization process | |
| US5110884A (en) | Olefin polymerization | |
| EP0194457B1 (en) | Process for preparing polyolefins, polydienes and copolymers thereof | |
| US3424737A (en) | Process for the polymerization of olefins | |
| US5475068A (en) | Process to make homopolymers of 3-ethyl-1-hexene | |
| US3320224A (en) | Polymerization catalyst system and process | |
| GB2082603A (en) | Polymerisation catalyst | |
| US3330816A (en) | Method for the production of alpha-olefin polymers |