NO742745L - - Google Patents
Info
- Publication number
- NO742745L NO742745L NO74742745A NO742745A NO742745L NO 742745 L NO742745 L NO 742745L NO 74742745 A NO74742745 A NO 74742745A NO 742745 A NO742745 A NO 742745A NO 742745 L NO742745 L NO 742745L
- Authority
- NO
- Norway
- Prior art keywords
- triazine
- chloro
- substituted
- ethylamino
- benzothiadiazinone
- Prior art date
Links
- -1 methoxy, methyl Chemical group 0.000 claims description 49
- 239000000203 mixture Substances 0.000 claims description 27
- 150000003839 salts Chemical class 0.000 claims description 25
- 230000002363 herbicidal effect Effects 0.000 claims description 16
- 239000001257 hydrogen Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- 150000002431 hydrogen Chemical class 0.000 claims description 6
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 239000004009 herbicide Substances 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052794 bromium Inorganic materials 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 125000000392 cycloalkenyl group Chemical group 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 125000004001 thioalkyl group Chemical group 0.000 claims description 2
- 125000004014 thioethyl group Chemical group [H]SC([H])([H])C([H])([H])* 0.000 claims description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims 1
- 125000000852 azido group Chemical group *N=[N+]=[N-] 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 239000013543 active substance Substances 0.000 description 26
- 241000196324 Embryophyta Species 0.000 description 24
- 239000000126 substance Substances 0.000 description 19
- 150000002148 esters Chemical class 0.000 description 16
- 150000001408 amides Chemical class 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 13
- 239000003921 oil Substances 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 8
- WSLDBHOMADMWBN-UHFFFAOYSA-N 2-[[4-chloro-6-(methylamino)-1,3,5-triazin-2-yl]amino]-2-methylpropanenitrile Chemical compound CNC1=NC(Cl)=NC(NC(C)(C)C#N)=N1 WSLDBHOMADMWBN-UHFFFAOYSA-N 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- DDUIUBPJPOKOMV-UHFFFAOYSA-N Methoprotryne Chemical compound COCCCNC1=NC(NC(C)C)=NC(SC)=N1 DDUIUBPJPOKOMV-UHFFFAOYSA-N 0.000 description 7
- AAEVYOVXGOFMJO-UHFFFAOYSA-N prometryn Chemical compound CSC1=NC(NC(C)C)=NC(NC(C)C)=N1 AAEVYOVXGOFMJO-UHFFFAOYSA-N 0.000 description 7
- ODCWYMIRDDJXKW-UHFFFAOYSA-N simazine Chemical compound CCNC1=NC(Cl)=NC(NCC)=N1 ODCWYMIRDDJXKW-UHFFFAOYSA-N 0.000 description 7
- 159000000000 sodium salts Chemical class 0.000 description 7
- 239000002253 acid Substances 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 description 5
- 235000013877 carbamide Nutrition 0.000 description 5
- 230000012010 growth Effects 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000012876 carrier material Substances 0.000 description 4
- MZZBPDKVEFVLFF-UHFFFAOYSA-N cyanazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C#N)=N1 MZZBPDKVEFVLFF-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OOHIAOSLOGDBCE-UHFFFAOYSA-N 6-chloro-4-n-cyclopropyl-2-n-propan-2-yl-1,3,5-triazine-2,4-diamine Chemical compound CC(C)NC1=NC(Cl)=NC(NC2CC2)=N1 OOHIAOSLOGDBCE-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000002790 naphthalenes Chemical class 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 241000195952 Equisetaceae Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- MGJKQDOBUOMPEZ-UHFFFAOYSA-N N,N'-dimethylurea Chemical compound CNC(=O)NC MGJKQDOBUOMPEZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000000729 antidote Substances 0.000 description 2
- 229940075522 antidotes Drugs 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 239000003630 growth substance Substances 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
- 230000001069 nematicidal effect Effects 0.000 description 2
- 239000005645 nematicide Substances 0.000 description 2
- YDCVQGAUCOROHB-UHFFFAOYSA-N oxadiazolidine-4,5-dione Chemical class O=C1NNOC1=O YDCVQGAUCOROHB-UHFFFAOYSA-N 0.000 description 2
- 239000006072 paste Substances 0.000 description 2
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical class OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 150000003918 triazines Chemical class 0.000 description 2
- 150000003672 ureas Chemical class 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- FTDGDIFUDKDKAW-UHFFFAOYSA-N 1,1a,5,5a,6,6a-hexahydrocyclopropa[a]indene Chemical class C12C(CC3CC=CC=C13)C2 FTDGDIFUDKDKAW-UHFFFAOYSA-N 0.000 description 1
- FNQJDLTXOVEEFB-UHFFFAOYSA-N 1,2,3-benzothiadiazole Chemical class C1=CC=C2SN=NC2=C1 FNQJDLTXOVEEFB-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical class C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 description 1
- MFVFDTCSVFBOTL-UHFFFAOYSA-N 1,3-diazetidine Chemical class C1NCN1 MFVFDTCSVFBOTL-UHFFFAOYSA-N 0.000 description 1
- QPQPCSJXTCQSAT-UHFFFAOYSA-N 1-(4-chlorophenyl)-1-(cyclohexen-1-yl)-3-methylurea Chemical compound C=1C=C(Cl)C=CC=1N(C(=O)NC)C1=CCCCC1 QPQPCSJXTCQSAT-UHFFFAOYSA-N 0.000 description 1
- FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical class OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 description 1
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 1
- QZEDXQFZACVDJE-UHFFFAOYSA-N 2,3-dibutylnaphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(O)(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 QZEDXQFZACVDJE-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical class CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 1
- STMMVKNOSKBEEI-UHFFFAOYSA-N 2-n,2-n-diethyl-6-methoxy-4-n-propan-2-yl-1,3,5-triazine-2,4-diamine Chemical compound CCN(CC)C1=NC(NC(C)C)=NC(OC)=N1 STMMVKNOSKBEEI-UHFFFAOYSA-N 0.000 description 1
- BIDJPLCJFOGHTK-UHFFFAOYSA-N 2-n,4-n-diethyl-6-ethylsulfanyl-1,3,5-triazine-2,4-diamine Chemical compound CCNC1=NC(NCC)=NC(SCC)=N1 BIDJPLCJFOGHTK-UHFFFAOYSA-N 0.000 description 1
- REEXLQXWNOSJKO-UHFFFAOYSA-N 2h-1$l^{4},2,3-benzothiadiazine 1-oxide Chemical compound C1=CC=C2S(=O)NN=CC2=C1 REEXLQXWNOSJKO-UHFFFAOYSA-N 0.000 description 1
- UOCUSOBVEHOMMB-UHFFFAOYSA-N 2h-1$l^{6},2,3-benzothiadiazine 1,1-dioxide Chemical class C1=CC=C2S(=O)(=O)NN=CC2=C1 UOCUSOBVEHOMMB-UHFFFAOYSA-N 0.000 description 1
- WJTBWQIBKUMWOC-UHFFFAOYSA-N 4-n-ethyl-6-methylsulfanyl-2-n-propan-2-yl-1,3,5-triazine-2,4-diamine;4-n-methyl-6-methylsulfanyl-2-n-propan-2-yl-1,3,5-triazine-2,4-diamine Chemical compound CNC1=NC(NC(C)C)=NC(SC)=N1.CCNC1=NC(NC(C)C)=NC(SC)=N1 WJTBWQIBKUMWOC-UHFFFAOYSA-N 0.000 description 1
- QDFGDJMSSBURHH-UHFFFAOYSA-N 4-n-methyl-6-methylsulfanyl-2-n-propyl-1,3,5-triazine-2,4-diamine Chemical compound CCCNC1=NC(NC)=NC(SC)=N1 QDFGDJMSSBURHH-UHFFFAOYSA-N 0.000 description 1
- HQQTZCPKNZVLFF-UHFFFAOYSA-N 4h-1,2-benzoxazin-3-one Chemical class C1=CC=C2ONC(=O)CC2=C1 HQQTZCPKNZVLFF-UHFFFAOYSA-N 0.000 description 1
- ZVPGYHKLHJKWML-UHFFFAOYSA-N 6-chloro-2-n-propan-2-yl-4-n-propyl-1,3,5-triazine-2,4-diamine Chemical compound CCCNC1=NC(Cl)=NC(NC(C)C)=N1 ZVPGYHKLHJKWML-UHFFFAOYSA-N 0.000 description 1
- KLJYRZOFJHYOCO-UHFFFAOYSA-N 6-chloro-4-n-methyl-2-n-propan-2-yl-1,3,5-triazine-2,4-diamine Chemical compound CNC1=NC(Cl)=NC(NC(C)C)=N1 KLJYRZOFJHYOCO-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 244000000626 Daucus carota Species 0.000 description 1
- 235000002767 Daucus carota Nutrition 0.000 description 1
- 241000551547 Dione <red algae> Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical class C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- HFBWPRKWDIRYNX-UHFFFAOYSA-N Trietazine Chemical compound CCNC1=NC(Cl)=NC(N(CC)CC)=N1 HFBWPRKWDIRYNX-UHFFFAOYSA-N 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000009392 Vitis Nutrition 0.000 description 1
- 241000219095 Vitis Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000007244 Zea mays Nutrition 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 150000001448 anilines Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229940111121 antirheumatic drug quinolines Drugs 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- BUSBFZWLPXDYIC-UHFFFAOYSA-N arsonic acid Chemical class O[AsH](O)=O BUSBFZWLPXDYIC-UHFFFAOYSA-N 0.000 description 1
- GCKLGRUZDXSATG-UHFFFAOYSA-N atrazine-desethyl-2-hydroxy Chemical compound CC(C)NC1=NC(=O)N=C(N)N1 GCKLGRUZDXSATG-UHFFFAOYSA-N 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- 125000003785 benzimidazolyl group Chemical class N1=C(NC2=C1C=CC=C2)* 0.000 description 1
- 150000005130 benzoxazines Chemical class 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- QQSGDKKFXBGYON-UHFFFAOYSA-N ethoxy-methylperoxy-(6-methyl-2-propan-2-ylpyrimidin-4-yl)oxy-sulfanylidene-$l^{5}-phosphane Chemical class CCOP(=S)(OOC)OC1=CC(C)=NC(C(C)C)=N1 QQSGDKKFXBGYON-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Chemical class 0.000 description 1
- 229930195729 fatty acid Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical class CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical class CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 150000001469 hydantoins Chemical class 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- FWJLFUVWQAXWLE-UHFFFAOYSA-N methometon Chemical compound COCCCNC1=NC(NCCCOC)=NC(OC)=N1 FWJLFUVWQAXWLE-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- 239000004533 oil dispersion Substances 0.000 description 1
- SDRLFDJOSQLRPB-UHFFFAOYSA-N oxadiazine-4,5-dione Chemical class O=C1CON=NC1=O SDRLFDJOSQLRPB-UHFFFAOYSA-N 0.000 description 1
- 150000004866 oxadiazoles Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- REJGOFYVRVIODZ-UHFFFAOYSA-N phosphanium;chloride Chemical group P.Cl REJGOFYVRVIODZ-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- WJNRPILHGGKWCK-UHFFFAOYSA-N propazine Chemical compound CC(C)NC1=NC(Cl)=NC(NC(C)C)=N1 WJNRPILHGGKWCK-UHFFFAOYSA-N 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- 150000004892 pyridazines Chemical class 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000005299 pyridinones Chemical class 0.000 description 1
- 150000003230 pyrimidines Chemical class 0.000 description 1
- 150000008318 pyrimidones Chemical class 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- NYCVCXMSZNOGDH-UHFFFAOYSA-N pyrrolidine-1-carboxylic acid Chemical class OC(=O)N1CCCC1 NYCVCXMSZNOGDH-UHFFFAOYSA-N 0.000 description 1
- 150000003235 pyrrolidines Chemical class 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 150000003246 quinazolines Chemical class 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 125000005624 silicic acid group Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- OLPRIZQBWZMBAS-UHFFFAOYSA-N thiadiazolidine 1,1-dioxide Chemical class O=S1(=O)CCNN1 OLPRIZQBWZMBAS-UHFFFAOYSA-N 0.000 description 1
- 150000003566 thiocarboxylic acids Chemical class 0.000 description 1
- 150000003582 thiophosphoric acids Chemical class 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 244000045561 useful plants Species 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/32—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing >N—CO—N< or >N—CS—N< groups directly attached to a cycloaliphatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
- C07D285/01—Five-membered rings
- C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
- C07D285/14—Thiadiazoles; Hydrogenated thiadiazoles condensed with carbocyclic rings or ring systems
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Den foreliggende oppfinnelse angår et herbicid som inneholder en blanding av forskjellige virksomme stoffer.
Det ér kjent at urinstoffer, triaziner og benzotiadiazi-nondioksyder har en herbicid virkning. Deres herbicide virkning er imidlertid ikke alltid tilfredsstillende.
Det ble funnet at en blanding av
a) en forbindelse med formelen
hvor X betyr metoksy og Y betyr klor når R og R^betyr henholdsvis hydrogen og metoksy, og når R betyr en cykloalkenylrest,
" Herbicide midler"
■$
betyr hydrogen, metoksy, metyl og Y og X betyr halogen,
metyl, metoksy, trifluormetyl og hydrogen, og
b) en forbindelse med formelen
hvor X betyr klor, brom, cyan, hydroksy, metoksy, tiometyl, tioetyl, azider, R og R^ er like eller forskjellige og betyr hydrogen, en eventuelt med cyan, halogen, alkoksy, hydroksy substi-
tuert uforgrénet eller forgrenet alkyl-, alkenyl- eller alkinylrest med opp til 7 karbonatomer, cykloalkyl, acetyl, alkylacetyl, Y har samme betydning som R og R^og Y dessuten betyr tioalkyl
eller amino'.7log eventuelt
c) en forbindelse med formelen 0
^ "N 2
<*>1
hvor R betyr en lvere alkylrest, R^betyr hydrogen og salter derav,
har en bedre herbicid virkning enn de aktive enkeltstoffer.
Blandingene kan inneholde en eller flere forbindelser med
formelen a og b og eventuelt c.
Blandingsforholdene kan velges etater ønske. Blandingsfor-holdet mellom stoffene a og b og/eller c er 0,1-10 vektdeler a til 1 vektdel b og/eller c, fortrinnsvis 0,3-3 vektdeler a til 1 vektdel b og/eller c.
Den mengde som anvendes av middelet ifølge oppfinnelsen
kan variere. Den mengde som anvendes, avhenger hovedsakelig av arten av den ønskede effekt. Mengden ligger i alminnelighet mellom 0,1 og 30 eller mer, fortrinnsvis0,2-6 kgV^virksomt stoff pr. hektar.
Midlene ifølge oppfinnelsen kan blant annet anvendes ved metoder
hvor de tilføres før plantingen, etter plantingen, før såingen, før plantenes oppkomst, etter plantenes oppkomst eller mens kultur-
plantene eller de uønskede planter er i ferd med å komme opp av jorden, og midlene kan tilføres en eller flere ganger.
Blandingene er egnet til bekjempelse av uønskede planter i
i kulturer ,av nytteplanter, for eksempel Triticum spp.', Hordeum vulgare,
Se'ea!le cereale, Gossypum hirsutum, Zea mays, Solanum tuberosum,
Pisum sativum, Daucus carota, Phaseolus vulgaris, Nicotiana tabacum,
Soja max. ,• Vitis'vin-i-fera.
Dessuten kan blandingene anvendes som totalmiddel ved
graver, bekker eller elver, langs jernbaneskinner, på øde flater etc.
Anvendelsen skjer eksempelvis i fdrrn av direkte sprøytbare . løsninger, pulvere, suspensjoner eller dispersjoner, emulsjoner,
oljedispersjoner, pastaer, støvformige midler, strømidler eller granulater, ved utsprøyting, forstøvning, utstrøing eller uthelling.
Anvendelsesformene retter seg he.lt etter anvendelsesformålet; man tar
imidlertid alltid sikte på å oppnå en best mulig fordeling av de virksomme stoffer ifølge oppfinnelsen-.
For fremstilling av direkte sprøytbare løsninger, emulsjoner, pastaer og oljedispersjoner kan man bruke mineraloljefraksjoner med midlere til høyt kokepunkt, så som kerosin eller dieselolje, enn-.videre kulltjæreoljer etc, samt oljer av vegetabilsk eller animalsk opprinnelse, alifatiske, cykliske og aromatiske hydrokarboner, som for eksempel benzen, tolueh, xylen, paraffin, tetrahydronaftalin, alkylerte naftaliner eller deres derivater, for eksempel metanol, etanol, propanol, butanol, kloroform, karbontetraklorid, cykloheksa-noi, cykloheksanon, klorbenzen, isoforon etc, sterkt polare løs-ningsmidler som for eksempel dimetylformamid, dimetylsulfoksyd, N-metyl[py]rrolidon, vann etc.
Vandige bruksformer kan fremstilles av emulsjonskonsentrater, pastaer eller fuktbare pulvere (sprøytepulvere) og oljedispersjoner ved tilsetning av vann. Ved fremstilling av emulsjoner, pastaer eller ol jedispers joner kan stoffene som sådanne eller /løst i olje
eller løsningsmiddel homogeniseres i vann ved hjelp av fukte-, klebe-, dispergerings- eller emulgeringsmidler. Det kan imidlertid også
fremstilles konsentrater bestående av virksomt stoff, fukte-, klebe-, dispergerings- eller emulgeringsmiddel og eventuelt løsningsmiddel eller olje, hvilke konsentrater er egnet til å fortynnes med vann.
Blant overflateaktive stoffer kan nevnes: alkali-,.jord-alkali-, ammoniaumsalter av ligninsulfonsyre, naftalinsulfonsyrer, fenolsulfonsyrer, alkylarylsulfonater, alkylsulfater, alkylsulfonater, alkali- og jordalkalisalter av dibutylnaftalinsulfonsyre, lauryl-etersulfat, fettalkoholsulfater, fettsure alkali- og jordalkali^JJter, [salter av sulfaterte heksadekanoler, heptadekanoler, oktadekanoler, salter av sulfatert fettalkoholglykoleter, kondensasjonsprodukter av sulfonert naftalin og naftalinderivater med formaldehyd, konden-sas jonsprodukter av naftalin eller naftalinsulfonsyrer med fenol og formaldehyd, polyoksyetylen-oktylfenoleter, etoksylert isooktyl-
fenol, -okstylfenol, -nonylfenol, alkylfenolpolyglykoleter, tribu-tylfenylpolyglykoleter, alkylarylpolyeteralkoholer, isotridecylalko-hol, fettalkoholetylenoksyd-kondensater, etoksylert ricinusolje, polyoksyetylenalkyleter, etoksylert polyoksypropylen, laurylalkohol-polyglykoleteracetal, sorbitolester, lignin, sulfittavluter og metylcellulose.
Pulver, strø- og støvformige midler kan fremstilles ved blanding eller sammaling av de virksomme stoffer med et fast bære-materiale.
Granulater, for eksempel omhyllings-, impregnerings- og homogengranulater, kan fremstilles ved binding av de virksomme stoffer på faste bærematerialer. Faste bærematerialer er eksempelvis mineralmaterialer så som silicagel, kiselsyrer, kiselgeler, sili-kater, talkum, kaolin, attaclay, kalkstein, kalk, kritt, bolus,
løss, leire, dolomitt, diatoméjord, kalsium- og magnesiumsulfat, magnesiumoksyd, malte harpikser, gjødnirigsstoffer som for eksempel ammoniumsulfat, ammoniumfosfat, ammoniumnitrat, urinstoffer og vege-tabilske produkter så som mel av korn, bark, tre og nøtteskall, cellulosepulver og andre, faste bærematerialer.
Preparatene inneholder mellom 0,1 og 95 vekt% virksomt
stoff, fortrinnsvis mellom 0,5 og 90 vekt%.
Til blandingene eller de enkelte virksomme stoffer kan
man, eventuelt først umiddelbart før anvendelsen (tankblanding), til-sette oljer av forskjellige typer, herbicider, fungicider, nematocider, insekticider, baktericider, sporelementer, gjødningsstoffer, skumhindrende midler (eksempelvis silikoner), vekstregulatorer, motgiftmidler eller andre herbicid vi'rksomme forbindelser, som for eksempel
substituerte aniliner
substituerte aryloksykarboksylsyrer og deres salter, ester og amider, substituerte etere
substituerte arsonsyrer og deres salter, estere og amider substituerte benzimidazoler
substituerte benzisotiazoler
substituerte benztiadiazinondioksyder
substituerte benzoksaziner
substituerte benzoksazinoner
substituerte benztiadiazoler
substituerte biureter
substituerte kinoliner
substituerte karbamater
substituerte alifatiske karboksylsyrer og deres salter, estere og
amider,
substituerte aromatiske karboksylsyrer og deres salter, estere og
amider
substituerte karbamoylalkyl-tiol- eller ditiofosfater substituerte kinazoliner
substituerte cykloalkylamidokar&ontiolsyrer og deres salter, estere
og amider
substituerte cykloalkylkarbonamido-tiazoler
substituerte dikarboksylsyrer og deres, salter, estere og amider substituerte dihydrobenzofuranylsulfonater
substituerte disulfider
substituerte dipyridyliumsalter
substituerte ditiokarbamater
substituerte ditiofosforsyrer ,bgj&eres salter, festere og amider substituerte urinstoffer
substituerte heksahydro-lH-fkarbotiater
substituerte hydantoiner
'substituerte hydrazider
substituerte hydrazoniumsalter
substituerte isooksazolpyrimidoner v substituerte imidazoler
substituerte isotiazolpyrimidoner substituerte ketoner
substituerte.naftokinoner
substituerte alifatiske nitriler substituerte aromatiske nitriler
substituerte oksadiazoler
substituerte oksadiazinoner
substituerte oksadiazolidindioner
substituerte oksadiazindioner
substituerte fenoler og deres salter og estere
substituerte fosfonsyrer og deres salter, estere og amider substituerte fosfoniumklorider substituerte fosforialkylglyciner
substituerte fosfitter
substituerte fosforsyrer og deres salter, estere og amider substituerte piperidiner
substituerte pyrazoler
substituerte pyrazolalkylkarboksylsyrer og deres s'alteri, estere og
amider
substituerte pyrazoliumsalter
substituerte pyrazoliumalkylsulfater
substituerte pyridaziner
substituerte pyridazoner
substituerte pyridinkarboksylsyrer og deres salter, estere og amider substituerte pyridiner
substituerte pyridinkarboksylater
substituerte pyridinoner
substituerte pyrimidiner
substituerte pyrimidoner
substituerte pyrrolidinkarboksylsyrer og deres salter, estere og
amider
substituerte pyrrolidiner
substituerte pyrrolidoner
substituerte arylsulfonsyrer og deres salter, estere og amider substituerte styroler
substituerte tetrahydro-oksadiaziiVdionerj.
substituerte tetrahydro-oksadiazoldioner
substituerte tetrahydrometanoiindener
substituerte tetrahydro-diazol-tioner
substituerte tetrahydro-tiadiazin-tioner
substituerte tetrahydro-tiadiazoldioner
substituerte aromatiske tiokarboksylsyreamider
substituerte tiokarboksylsyrer og deres salter, estere og amider substituerte tiolkarbamater
substituerte tiourinstocfféV
substituerte tiofosforsyrer og deres salter, estere og amider substituerte triaziner
substituerte triazoler
substituerte uraciler
substituerte uretidindioner.
De sistnevnte herbicide forbindelser kan også bringes til anvendelse før eller etter de enkelte virksomme stoffer ifølge oppfinnelsen eller blandinger av disse.
Tilblandingen av disse midler til de herbicide stoffer ifølge oppfinnelsen kan skje i vektforholdet 1:10 til 10:1. Det samme gjelder oljer, fungicider, nematocider, insenticider, baktericider, motgiftmidler og vekstregulatorer.
Midlene oppviser en sterk herbicid virkning og kan derfor anvendes som ugrasdrepende midler eller til bekjempelse av uønskede plantevekster. Om midlene virker som totale eller selektive midler, vil hovedsakelig avhenge av den mengde virksomt stoff som anvendes pr. flateenhet.
Med ugras, henholdsvis uønskede plantevekster menes her alle enfrøbladede og tofrøbladede planter som vokser på steder hvor de ikke er ønsket.
Således kan eksempelvis følgende planter bekjempes med midlene ifølge oppfinnelsen:
Planter av grasfamilien, så som
Equisetaceae, så som
Equisetaceae spp. og andre
De følgende forbindelser ble [veTd forsøk i drivhus og på friland ut-prøvet i forskjellige blandinger overfor de nevnte planter: 2-klor-4-allylamino-6-(^-metoksypropyl)-amino-1,3,5-triazin 2-klor-4-allylamino-6-n-propylamino-l,3,4-triazin
2-klor-4-allylamino-6-isopropylamino-1,3,5-triazin
2-klor-4-allylamino-6-B-metoksyetylamino-l,3,5-triazin 2-klor-4-isopropylamExno-6-hydroksymetylamino-1, 3, 5-triazin 2-klor-4-cyklopropylamino-6-isopropylamino-1,3,5-triazin 2-klor-4,6-bis-(dietylamino)-1,3,5-triazin
2-klor-4-isopropylamino-6-n-propylamino-1,3,5-triazin 2-klor-4-et\ylamino-6-sek. -butylamino-1, 3, 5-triazin
2-klor-4-etylamino-6-butin-(l)-yl-(3)-amino-1,3,5-triazin 2-klor-4,6-dietylamino-1,3,5-triazin
2-klor-4-etylamino-6-isopropylamino-1,3,5-triazin
2-klor-4-etylamino-6-tert. -butylamino-1, 3 , 5-tria'zin
2-klor-4-etylamino-6-dietylamino-1,3,5-triazin
2-klor-4-dietylamino-6-isopropylamino-1,3,5-triazin
2-klor-4,6-diisopropylamino-1,3,5-triazin
2-klor-4-etylamino-6-7,-metoksypropylamino-1, 3 , 5-triazin 2-klor-4-isopropylamino-6-metylamino-l,3,5-triazin
2-klor-4-isopropylamino-6-^-metoksyvp^oj^Ia^ijno^l / J yf ^t^azlnj 2-klor-4-etylamino-6-B- (/[-metoksy) -propylamino-1, 3, 5-triazin 2-(2-klor-4-metylamino-1,3,5-triazin-6-yl-amino)-2-metyl-propionitril
2-(2-klor-4-etylamino-l,3,5-triazin-6-yl-amino)-2-metyl-propionitril 2-metoksy-4-metylamrino-6-isopropylamino-1, 3 , 5-triazin 2-metoksy-4-etylamino-6-tert.-butylamino-1,3,5-triazin 2-metoksy-4,6-di-(3-metoksypropylamino)-1,3,5-triazin 2-metoksy-4^,-bis-["(etylamino) -1,3, 5-triazin
2-metoksy-4-etylamino-6-sek7-butylamino-1,3,5-triazin 2-metoksy-4-B-metoksyetylamino-6-isopropylamino-1,3,5-triazin 2-metoksy-4-etylamino-6-isopropylamino-1,3,5-triazin 2-metoksy-4,6-diisopropylamino-1,3,5-triazin
2-metoksy-4-isopropylamino-6-dietylamino-1,3,5-triazin 2-metoksy-4-metylamino-6-sek.-butylamino-1,3,5-triazin
i
t 2-metoksy-4-isopropylamino-6-acetylamino-1,3,5-triazin 2-metoksy-4-isopropylamino-6-etylacetylamino-l,3,5-triazin 2-metoksy-4-(/-metoksypropy1)-amino-6-isoamylamino-1,3,5-triazin 2-metyltio-4-isopropylamino-6-sek.-butylamino-1,3,5-triazin 2-metyltio-4-isopropylamino-6-tert.-butylamino-1,3,5-triazin 2-metyltio-4-(3-metoksy-propyl-amino)-6-isopropylamino-1,3,5-triazin
2-metyltio-4i^6-di- (3-metoksy-propyl-amino) -1,3, 5-triazin 2-metyltio-4-metylamino-6-isopropylamino-1,3,5-triazin 2-metyltio-4-etylamino-6-isopropylamino-1,3,5-triazin 2-metyltio-4-etylamino-6-sék.-butylamino-1,3,5-triazin 2-metyltio-4-etylamino-6-tert.-butylamino-1,3,5-triazin 2-metyltio-4,6-diisopropylamino-1,3,5-triazin
2-metyltio-4-etylamino-6-a,S-dimetylpropylamino-1,3,5-triazin 2-metyltio-4-metylamino-6-n-propylamino-1,3,5-triazin 2-metyltio-4-metylamino-6-sek.-butylamino^l,3,5-triazin 2-metyltio-4,6-bis-(/-metoksypropylamino)-1,3,5-triazin 2-metyltio-4-allylamino-6-n-propylamino-1,3,5-triazin 2-metyltio-4-allylamino-6-isopropylamirio-l,3i,5-triazi<n>2-metyltio-4,6-bis-(allylamino)-1,3,5-triazin
2-metyltio-4-amino-6-isopropylamino-1,3,5-triazin 2-metyltio-4-amino-6-n-propylamino-1,3,5-triazin
2-metyltio-4-dietylamino-6-isopropylamino-1,3,5-triazin 2-metyltio-4-etylamino-6-metyltio-l,3,5-triazin
2-metyltio-4, 6-bis- (etylamino-1, 3;, 5-triazin
2-metyltio-4-etylamino-6-n-propyXamino-l,3,5-triazin 2-metyltio-4-etylamino-6-^-metoksypropylamino-1,3,5-triazin 2-(2-metyltio-4-isopropylamino-1,3,5-triazin-6-yl-amino)-2-metyl-propionitril 2-(2-metyltio-4-etylamino-1,3,5-triazin-6-yl-amino)-2-metyl-propionitril
2-(2-metyltio-4-metylamino-l,3,5-triazin-6-yl-amino)-2-metyl-propionitril
2-etyltio-4-etylamino-6-isopropylamino-1,3,5-triazin 2-etyltio-4,6-bis-(isopropylamino)-1,3,5-triazin
2-etyltio-4,6-bis-(etylamino)-1,3,5-triazin
2-azido-4-etylamino-6-sek.-butylamino-1,3,5-triazin 2-azido-4-sek.-butylamino-6-metyltio-l,3,5-triazin 2-azido-4-etylamino-6-tert.-butylamino-1,3,5-triazin 2-azido-4-isopropylamino-6-metyltio-l,3,5-triazin
■ i'
2-cyan-4~etylamino-6»isopropylamino-1,3,5-triazin
2-hydroksy~4~amino-6-etylamino-1,3,5-triazin
2-hydroksy-4-amino-6-isopropylamino-1,3,5-triazin
3- isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd
3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)- 2,2-dioksyd-dimety1-aminsalt
3 -i so pro py 1-2,1, 3-benzotiadiazinon-(4) - 2, 2-dioksyd-dietJanpl-aminsalt
3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-metylaminsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-trimetyl-aminsalt
3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-etylaminsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)- 2,2-dioksyd-dietylammsalt 3-isopropyl-2., 1, 3-benzotiadiazinon-(4) -2, 2-dioksyd-etanolaminsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-anilinsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-pyridinsalt 3-isopropyl-2,1, 3-benzotiadiazinon-(4)-2,2-dioksyd-fenylen-diaminsalt
3-isopropyl-2f1,3-benzotiadiazinon-(4)-2,2-dioksyd-cykloheksyl-aminsalt
3-isopropyl-2,1,3-benzotiadiazinon-(4)- 2, 2-dioksyd-dodecyl-heksametyleniminsalt
3-isopr6pyl-2,1,3-bénzotiadiazinon-(4)-2,2-dioksyd-hydrazinsalt
3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-magnesiumsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)- 2, 2-dioksyd-kalsiumsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2, 2-dioksyd-ammoniumsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-kalsiumsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)- 2,2-dioksyd-lithiumsalt 3-isobutyl-2,1,3-benzotiadiazinon-(4)- 2,2-dioksyd
3-isobutyl-2,1, 3-benzotiadiazinon-(4) -2, 2-dioksyd-natrium'salt 3-isobutyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylaminsalt 3-isobutyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanol-aminsalt
3-sek.-buty1-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd
3-sek.-buty 1-2,1,3-benzotiadiazinon-(4) - 2, 2-dioksyd -natriumsalt 3-sek.-buty1-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetyl-aminsalt
3-sek.-butyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanol-
'\ aminsalt
3-n-butyl-2,1, 3-benzotiadiazinon-(4) -2, 2-dioksyd
3-n-butyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt 3-n-butyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetyl- .
aminsalt
3-n-butyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanol-
aminsalt
3-n-propyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd
3-n-propyl-2,1,3-benzotiadiazinon-(4)- 2,2-dioksyd-natriumsalt 3-n-propyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetyl-
aminsalt
3-n-propyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanol-
aminsalt
3-etyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd
3-etyl-2,1,3-benzotiadiazinon-(4)- 2, 2-dioksyd-natriumsalt 3-etyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylaminsalt 3-etyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanol-
aminsalt
3-metyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd
3-metyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt 3-metyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetyl-
aminsalt
3-metyl-2,1,3-benzotiadiazinon-(4)- 2,2-dioksyd-dietanol-
aminsalt
3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-^-isopro-poksypropylaminsalt
3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-3-etyl-heksylaminsalt
3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-N,N-di-
metylpyridinsalt
3-isopropyl-2,1,3-benzotiadiazinon-(4)- 2, 2-dioksyd-N-metyl-N-butyl-piperodinsalt
3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-stearyl-
aminsalt
3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-heksylamin-
salt
3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-6-(butyl)-butoksyheksylaminsalt
3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-fenyl-
h<y>dr A gzi1nsalt
3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-etanolaminsalt
N-3-klorfenyl-N-cykloheksyl-l-enyl-N,f7IN!, -dimetylurinstof f N-fenyl-N-cykloheksyl-l-enyl-N',N•-dimetylurinstoff
N-3-klorfenyl-N-cykloheksyl-l-enyl-N-metylurinstoff
N-fenyl-N-cykloheks-l-enyl-N•-metylurinstoff
N-4-fluorfenyl-N-cykloheks-l-enyl-N *-metylurinstoff
N-3-klor-4-metoksyfenyi-N-cykloheks-l-enyl-N-metylurinstoff N-3-klor-4-metylfenyl-N-cykloheks-l-enyl-N',N'-dimetyl-
urinstoff
N-3-trif luormetylfenyl-N-cykloheks^ll-enyl-N' ,N'-dimetyl-
urinstoff
N-3-triflyormetylfenyl-N-cykloheks-l-enyl-N'-metylurinstoff N-3,4-diklorfenyl-N-cykloheks-l-enyl-N',N<1->dimetylurinstoff N-3-klor-4-metoksyfenyl-N-cykloheks-l-enyl-N<1>,N'-dimetyl-urinstoff
N-4-klorfenyl-N-cykloheks-1-enyl-N'-metylurinstoff
N-3-klor-4-metoksyfenyl-N'-metyl-N'-metoksyharnstoff.
De anførte midler har en tilsvarende biologisk virkning som de i
de følgende eksempler angitte blandinger.
Eksempel 1
På friland ble forskjellige planter ved en veksthøyde på 2-30 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som oljedispersjon:
I N-3-klor-4-metoksyfenyl-N'-metyl-N'-metoksyurinstoff
II 2-klor-4-etylamino-6-isopropylamino-1,3,5-tiriazin III 2-(2-klor-4-metylamino-l,3,5-triazin-6-yl-amino)-2-metylpropionitril
IV 2-klor-4,6-dietylamino-l,3,5-triazin
V 2-klor-4-etylamino-6-tert/butylamino-1, 3, 5-ttaazin
VI 2-(2-klor-4-etylamino-1,3,5-triazin-6-yl-amino)-2-metyl-propionitril
VII 2-metyltio-4-etylamino-6-tert.butylamino-l,3,5-
triazin
VIII 2-metyltio-4,6-diisopropylamino-1,3,5-triazin
IX 2-metylti6-4-(4-metoksypropylamino)-6-isopropyl-amino-1,3,5-triazin
X 2-azido-4-etylamino-6-tert.butylamino-1,3,5-triazin
XI 2-klor-4-isopropylamino-6-cyklopropylamino-1, 3,15-triazin XII 2-metyltio-4-etylamino-6-a,6-dimetylpropylamino-1,3,5-triazin
i hvert tilfelle 0,25 - 0,5 - 0,75 og 1 kg/ha aktivt stoff, i+ii, i+iii, i+iv, i+v7~n:+vi, i+vn, i+vin, i+ix, i+x, i+xi,
I+XII
i hvert tilfelle 0,25+0,75; 0,75+0,25 og 0,5+0,5 kg/ha aktivt stoff.
[._;_ Etter 8-12 dager ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn de virksomme enkeltstoffer.
Forsøksresultatet vil fremgå av den følgende tabell.
Eksempel 2
På friland ble forskjellige planter ved en veksthøyde på
(2-72 8 rem-behandlet med de følgende virksomme enkeltstoffer og deres blandinger i form av dispersjoner:
I N-3 -klor-4-metoksy-fenyl-ISM -mety I-N"* -metoksyurinstof f
rT"\
II 2-klor-4-etylamino-6-isporopylamino-1,3,5-triazin
III 2-(2-klor-4-metylamino-1,3,5-triazin-6-yl-amiho)-2-metyl-propionitril
IV 2-klor-4,6-dietyl'amino-l, 3-5-triazin
V2-klor-4-etylamino-6-tert.butylamino-l,3,5-triazin
VI 2-(2-klor-4-etylamino-1,3,5-triazin-6-yl-amino)-2-metylpropionitri1
VII 2-metyltio-4-etylamino-6-tert.butylamino-1, 3, 5-triazin
VIII 2-metyltio-4,6-diisopropylamino-l,3,5-triazin
IX 2-metyltio-4-(3-metoksypropylamino)-6-isopropylamino-1,3,5-triazin
X 2-azido-4-etylamino-6-tert.butylamino-1,3,5-triazin
XI 2-klor-4-isopropylamino-6-cyklopropylamino-l,3,5-triazin XII 2-metyltio-4-etylamino-6-a,B-dimetylpropylamino-1,3,5-triåzin
i hvert tilfelle 0,5 - 1 - 1,5 og 2 kg/ha aktivt stoff
I+II, I+III, I+IV, I+V, I+VI, I+VII, I+VIII, I+IX, I+X, I+XI
og I+XII
i hvert tilfelle 0,5+1,5; 1,5+0,5 og 1+1 kg/ha aktivt stoff.
Etter 8-10 dager ble det slått fast at blandingene viste en bedre forenlighet med kulturplantene og en bedre herbicid virkning enn enkeltstoffene ved bruk av 2 kg/ha aktivt stoff.
Forsøksresultatet vil fremgå av den følgende tabell.
Eksempel 3
På friland ble forskjellige p3a nter ved en veksthøyde på 2-18 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som diispSrsjon-emulsjon-tankblanding:
I N-3-klor-4-metoksy-fenyl-N<1->metyl-N'-metoksyurinstoff
II 2-klor-4-etylamino-6-isopropylamino-1,3,5-triazin
III 2-(2-klor-4-metylamino-l,3,5-triazin-6-yl-amino)-2-metylpropionitril
IV 2-klor-4,6-dietylamino-1,3,5-triazin
V 2-klor-4-etylamino-6-tert.butylamino-1,3,5-triazin
VI 2-.(2-klor-4-etylamino-1,3 , 5-triazin-6-yl-amino) -2-metylpropionitril
VII 2-metyltio-4-etylamino-6-tert.butylamino-1,3,5-triazin
VIII 2-metyltio-4,6-diisopropylamino-1,3,5-triazin
IX 2-metyltio-4-(3-metoksypropylamino)-6-isopropylamino-1,3,5-triazin
X 2-azido-4-etylamino-6-tert.butylamino-1,3,5-triazin
XI 2-klor-4-isopropylamino-6-cyklOipr'opylamino-1, 3, 5-triazin
XII 2-metyltio-4-etylamino-6-&7\B-dimetylpropylamino-1,3,5-triazin
XIII 3-isopropyl-2/1,3-benzotiadiazinon-(4)-2,2-dioksyd
XIV 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt
XV 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-"dilnefylalninsalt
XVI 3-isopropyl-2,1, 3-benzotiadiazinon-(4) -2, 2-dioksyd-dietJand,l-aminsalt
i hvert tilfelle 0,25 - 0,5 - 1 og 1,5 kg/ha aktivt stoff
I+II+XIII, I+III+XV, I+IV+XIV, I+V+XVI, I+VI+XIV, I+VII+XVI, I+VIII+XIII, I+IX+XV, I+X+XVI, I+XI+XIV, I+XII+XIV
i hvert tilfelle 0,25+0,25+0,5; 0,25+0,5+0,25; 0, 5+oi,.25+0, 25;
0,25+0,25+1?0,25+1+0,25; 1+0,25+0,25 kg/ha aktivt stoff.
Etter 8-14 dager ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene. Forsøksresultatet vil fremgå av den følgende tabell.
Eksempel 4
En jordbruksflate ble besådd med forskjellige frø. Umiddelbart deretter ble jorden behandlet med de følgende virksomme enkeltstoffer og deres blandinger i granulatform:
I N-3-klor-4-metoksy-fenyl-N<1->metyl-N'-metoksyurinstoff
II 2-klor-4-etylamino-6-isopropylamino-1,3,5-triazin
III 2-(2-klor-4-metylamino-l,3,5-triazin-6-yl-amino)-2-metylpropionitril
IV 2-klor-4,6-dietylamino-1,3,5-triazin
V 2-klor-4-etylamino-6-tert.butylamino-1,3,5-triazin
VI 2-(2-klor-4-etylamino-1,3,5-triazin-6-y1-amino)-2-metylpropionitril
VII 2-metyltio-4-etylamino-6-tert.butylamino-1,3,5-triazin VIII 2-metyltio-4,6-diisopropylamino-1,3,5-triazin
IX 2-metyltio-4-(3-metoksypropylamino)-6-isopropylamino-1,3,5-triazin
X 2-azido-4-etylamino-6-tert.butylamino-1,3,5-triazin
XI 2-klor-4-isorp ropylamino-6-cyklo!propy lamino-1, 3, 5-triazih
XII 2-metyltio-4-etylamino-6-a,6-dimétylpropylamino-1,3,5-triazin
i hvert tilfelle 0,25 - 0,5 - 0,75 - 1 - 1,5 og 2 kg/ha
aktivt stoff.
I+II, I+III, I+IV, I+V, I+VI, I+VII, I+VIII, I+IX, I+X, I+XI,
og I+XII
i hvert tilfelle 0,25+0,75; 0,75+0,25; 0,5+0,5; 0,5+1,5;
1,5+0,5 og 1+1 kg/ha aktivt stoff.
Forsøket ble utført under tørre betingelser.
Etter 4-5 uker ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene ved bruk av 1 kg/ha aktivt stoff og en bedre forenlighet med(kulturplantene og e(hTbedre herbicid virkning ved bruk av 2 kg/ha aktivt stoff enn enkeltstoffene I-XII.
Forsøksresultatet vil fremgå av den følgende tabell.
Eksempel 5
I et drivhus ble forskjellige planter ved en veksthøyde på 2-20 cm behandlet med de føigende virksomme enkeltstoffer og deres blandinger som emulsjon-dispersjon: XVII N-3-klor-4-metoksyfenyl-N-cykloheks-l-enyl-N », N' -
dimetylurinstoff
XVIII N-3-klor-4-metylfenyl-N-cykloheks-l-enyl-N',N'-dimetyl-urinstoff
II 2-klor-4-etylamiho-6-isopropylamino-1,3,5-triazin
III 2-(2-klor-4-metylamino-l,3,5-triazin-6-yl-amino)-2-metyl-propionitril
IV 2-klor-4,6-dietylamino-l,3,5-triazin
V 2-klor-4-ety lamino-6-tert.buty lamino-1, 3, 5-tr[iazin
VI 2-(2-klor-4-etyiamino-l,3,5-triazin-6-yl-amino)-2-metyl-propionitril
VII 2-metyltio-4-etylamino-6-tert.butylamino-1,3,5-triazin
VIII 2-metyltio-4,6-diisopropylamino-1,3,5-triazin IX 2-metyltio-4-(3-metoksypropylamino)-6-isopropylamino-1,3,5-triazin
X 2-azido-4-etylamino-6-tert.butylamino-1,3,5-triazin
XI 2-klor-4-isopropylamino~6-cyklopropylamino-l,3,5-triazin XII 2-metyltio-4-etylamino-6-a,8-dimetylpropylamino-1,3,5-triazin
i hvert tilfelle 0,5 - 1 - 1,5 og 2 kg/ha aktivt stoff
XVII+II, XVII+III, XVII+IV, XVII+XII, XVIII+XII, XVIII+XI, XVIII+X, XVIII+IX, XVIII+VIII, XVIII+VII, XVII+V, XVII+VI, XVII+VII, XVII+VIII, XVII+IX, XVII+X, XVII+XI, XVIII+VI, XVIII+V, XVIII+IV, XVIII+III, XVIII+II
i hvert.tilfelle 0,5 + 1,5; 1,5 + 0,5 og 1 + 1 kg/ha akitiyi: stoff.
Etter 12-15 dager ble det slått fast at blandingene viste en bedre herbicid virkning og en bedre forenlighet med kulturplantene enn enkeltstoffene.
Forsøksresultatet vil fremgå av den følgende tabell..
Eksempel 6
I et drivhus ble forskjellige planter ved en veksthøyde på 2-20 cm behandlet med de følgende enkeltstoffer og deres blandinger som dispersjon: XVIII N-3-klor-4-metyl-fenyl-N-cykloheks-l-enyl-N',N'-dimetyl-urinstoff
XVII N-3-klor-4-metoksy-fenyl-N-cykloheks-l-enyl-N', N'-dimetylurinstoff
XVI 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanolaminsalt
XV 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylaminsalt
XIV 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt
XIII 3-isopropyl-2,1,3-benzotiadiazihon-(4)-2,2-dioksyd
XII 2-metyltio-4-etylamino-6-a,6-dimetylpropylamino-1,3,5-triazin
XI 2-klor-4-isopropylamino-6-cyklopropylamino-1,3,5-triazin
X 2-azido-4-etylamino-6-tert.butylamino-1,3,5-triazin
IX 2-metyltio-4-(3-metoksy-propylamino)-6-isopropylamino-1,3,5-triazin
VIII 2-metyltio-4,6-diisopropylamino-l,3,5-triazin
VII 2-metyltio-4-etylamino-6-tert.butylamino-1,3,5-triazin
VI 2-(2-klor-4-etylamino-1,3,5-triazin-6-yl-amino)-2-metylpropionitril
V 2-klor-4-etylamino-6-tert.butylamino-1,3,5-triazin
IV 2-klor-4,6-dietylamino-l,3,5-triazin
III 2-(2-klor-4-metylamino-1,3,5-triazin-6-yl-amino)-2-metylpropionitril
II 2-klor-4-etylamino-6-isorpopylamino-1,3,5-triazin
i hvert; tilfelle 0,25 - 1 - 1,5 kg/ha aktivt stoff
XVIII+XIII+VI, XVIII+XIV+VII, XVIII+XV+VIII, XVIII+XVI+IX, XVIII+XIII+X, XVIII+XIV+XI, XVIII+XV+XII, XVII+XIII+XII, XVII+XIV+XI XVII+XV+X, XVII+XVI+IX, XVII+XIII+VIII, XVII+XIV+VIII, XVII+XIV+VII,
xvii+xv+vi, xvii+xvi+v, xvii+xv+iv, xvir+xiv+iii, xvii+xiii+n,
XVIII+II+XIII, XVIII+XIV+III, XVIII+XV+IV og XVIII+XVI+V
i hvert tilfelle 0,25 +0,25+1; 0,25 + 1 + 0,25 og 1 + 0,25 + 0,25 kg/ha aktivt stoff.
Etter 13-16 dager ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene.
Forsøksresultatet vil fremgå av den følgende tabell.
I et drivhus ble forsøkskasser fyllt med leirholdig sandjord, og forskjellige frø ble sådd. Deretter ble jorden behandlet med de følgende virksomme enkeltstoffer og deres blandinger: XVIII N-3-klor-4-metylfenyl-N-cykloheks-l-enyl-N',N'-dimetylurinstof f
XVII N-3-klor-4-metoksyfenyl-N-cykloheks-l-enyl-N*^'-dimetylurinstof f
XII 2-metyltio-4-etylamino-6-a, 6-dimetylpropylamino-1,3,5-triazin
XI 2-klor-4-isopfopylamino-6-cyklopropylamino-1,3,5-triazin
X 2-azido-4-etylamino-6-tert.butylamino-1,3,5-triazin
IX 2-metyltio-4-(3-metoksypropylamino)-6-isopropylamino-1,3,5-triazin
VIII 2-metyltio-4,6-diisopropylamino-1,3,5-triazin VII 2-metyltio-4-etylamino-6-tert.butylamino-1,3,5-triazin
VI 2-(2-klor-4-etylamino-1,3,5-triazin-6-yl-amino)-2-metylpropionitril
i—°v
V 2-klor-4-etylamino-6-tert.butylamino-1,3,5-triazin
IV 2-klor-4,6-dietylamino-l,3,5-triazin
III 2-(2-klor-4-metylamino-l,3,5-triazin-6-yl-amino)-2-metylpropionitril
II 2-klor-4-etylamino-6-isopropylamino-1,3,5-triazin
i hvert tilfelle 0,5 -1,5 -2 og 1 kg/ha aktivt stoff
XVIII+II, XVIII+III, XVIII+IV, XVIII+V, XVIII+VI, XVIII+VII, XVIII+VIII, XVIII+IX, XVIII+X, XVIII+XI, XVIII+XII, XVII+XII, XVIII+XI, XVII+X, XVII+IX, XVII+Vill, XVII+VII, XVII+VI, XVII+V, XVII+IV, XVII+III og XVII+II
i hvert tilfelle 0,5+1,5; 1,5+0,5 og 1+1 kg/ha aktivt stoff.
Etter 3-4 uker ble det slått fast at blandingene viste en bedre forenlighet med kulturplantene og en bedre herbicid virkning enn enkeltstoffene.
Forsøksresultatet vil fremgå av den følgende tabell.
Claims (2)
1. Herbicid middel, karakterisert ved at det inneholder en blanding ava) en forbindelse med formelen
hvor X betyr metoksy og Y betyr klor når R betyr hydrogen og R^ metoksy, og når R betyr en cykloalkenylrest, betyr R^ hydrogen, metoksy, metyl og Y og X betyr halogen, metyl, metoksy, trifluormetyl, hydrogen, og
b) en forbindelse med formelen
hvor X betyr klor, brom, cyan, hydroksy, metoksy, tiometyl, tioetyl, azido, R og R^ er like eller forskjellige og betyr hydrogen, en eventuelt med cyan, halogen, alkoksy, hydroksy substituert uforgrenet eller forgrenet alkyl-, alkenyl- eller alkinylrest med opp til 7 karbonatomer, cykloalkyl, acetyl, alkylacetyl, Y har samme betydning som R og R^ og Y dessuten kan bety tioalkyl eller amino, og eventuelt
on moH fnrmoTon
hvor R betyr en lavere alkylrest, R^ betyr hydrogen og salter derav.
2., Herbicid middel ifølge krav 1, kfa rakterisert ved at det inneholder blandingen a + b eller a + b + c.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19732341555 DE2341555A1 (de) | 1973-08-17 | 1973-08-17 | Herbizid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO742745L true NO742745L (no) | 1975-03-17 |
Family
ID=5889983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO74742745A NO742745L (no) | 1973-08-17 | 1974-07-29 |
Country Status (14)
| Country | Link |
|---|---|
| JP (1) | JPS5042048A (no) |
| BE (1) | BE818932A (no) |
| BR (1) | BR7406732D0 (no) |
| DD (1) | DD112341A5 (no) |
| DE (1) | DE2341555A1 (no) |
| DK (1) | DK435874A (no) |
| EG (1) | EG11774A (no) |
| FR (1) | FR2240687A1 (no) |
| IL (1) | IL45424A0 (no) |
| LU (1) | LU70746A1 (no) |
| NL (1) | NL7410015A (no) |
| NO (1) | NO742745L (no) |
| SE (1) | SE7410427L (no) |
| ZA (1) | ZA745268B (no) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EG11946A (en) * | 1974-09-12 | 1978-03-29 | Ciba Geigy Ag | New s-triazine derivatives uses in pest control agents |
-
1973
- 1973-08-17 DE DE19732341555 patent/DE2341555A1/de active Pending
-
1974
- 1974-07-24 NL NL7410015A patent/NL7410015A/xx unknown
- 1974-07-29 NO NO74742745A patent/NO742745L/no unknown
- 1974-08-07 IL IL45424A patent/IL45424A0/xx unknown
- 1974-08-09 FR FR7427724A patent/FR2240687A1/fr active Granted
- 1974-08-15 SE SE7410427A patent/SE7410427L/xx unknown
- 1974-08-15 DK DK435874A patent/DK435874A/da unknown
- 1974-08-15 JP JP49092866A patent/JPS5042048A/ja active Pending
- 1974-08-15 DD DD180518A patent/DD112341A5/xx unknown
- 1974-08-15 BR BR6732/74A patent/BR7406732D0/pt unknown
- 1974-08-16 LU LU70746A patent/LU70746A1/de unknown
- 1974-08-16 ZA ZA00745268A patent/ZA745268B/xx unknown
- 1974-08-16 BE BE147681A patent/BE818932A/xx unknown
- 1974-08-17 EG EG339/74A patent/EG11774A/xx active
Also Published As
| Publication number | Publication date |
|---|---|
| FR2240687A1 (en) | 1975-03-14 |
| DD112341A5 (no) | 1975-04-12 |
| NL7410015A (nl) | 1975-02-19 |
| ZA745268B (en) | 1975-09-24 |
| LU70746A1 (de) | 1975-01-02 |
| EG11774A (en) | 1978-06-30 |
| SE7410427L (no) | 1975-02-18 |
| IL45424A0 (en) | 1974-11-29 |
| DK435874A (no) | 1975-04-14 |
| FR2240687B3 (no) | 1977-06-10 |
| BR7406732D0 (pt) | 1975-06-03 |
| BE818932A (fr) | 1975-02-17 |
| JPS5042048A (no) | 1975-04-16 |
| DE2341555A1 (de) | 1975-02-27 |
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