NO327405B1 - Fremgangsmate for a danne en katalysatorforloper - Google Patents
Fremgangsmate for a danne en katalysatorforloper Download PDFInfo
- Publication number
- NO327405B1 NO327405B1 NO20030346A NO20030346A NO327405B1 NO 327405 B1 NO327405 B1 NO 327405B1 NO 20030346 A NO20030346 A NO 20030346A NO 20030346 A NO20030346 A NO 20030346A NO 327405 B1 NO327405 B1 NO 327405B1
- Authority
- NO
- Norway
- Prior art keywords
- catalyst
- precursor
- support
- impregnation
- untreated
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 38
- 239000012018 catalyst precursor Substances 0.000 title claims description 14
- 230000008569 process Effects 0.000 title claims description 9
- 239000003054 catalyst Substances 0.000 claims abstract description 139
- 239000002243 precursor Substances 0.000 claims abstract description 31
- 239000007864 aqueous solution Substances 0.000 claims abstract description 13
- 238000001354 calcination Methods 0.000 claims abstract description 13
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 11
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 11
- 230000007935 neutral effect Effects 0.000 claims abstract description 10
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 9
- 229910052776 Thorium Inorganic materials 0.000 claims abstract description 3
- 229910052770 Uranium Inorganic materials 0.000 claims abstract description 3
- 125000002252 acyl group Chemical group 0.000 claims abstract description 3
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 3
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 3
- 229910052788 barium Inorganic materials 0.000 claims abstract description 3
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 3
- 229910052802 copper Inorganic materials 0.000 claims abstract description 3
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 3
- 229910052735 hafnium Inorganic materials 0.000 claims abstract description 3
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 3
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 3
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 3
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 3
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 3
- 229910052715 tantalum Inorganic materials 0.000 claims abstract description 3
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 3
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 3
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 58
- 238000005470 impregnation Methods 0.000 claims description 37
- 238000001035 drying Methods 0.000 claims description 35
- 230000015572 biosynthetic process Effects 0.000 claims description 29
- 239000002002 slurry Substances 0.000 claims description 28
- 238000003786 synthesis reaction Methods 0.000 claims description 25
- 229920001296 polysiloxane Polymers 0.000 claims description 24
- 239000000243 solution Substances 0.000 claims description 23
- 239000002904 solvent Substances 0.000 claims description 15
- 125000004429 atom Chemical group 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 11
- 238000009835 boiling Methods 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 10
- -1 zirconium alkoxide Chemical class 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 7
- 239000003929 acidic solution Substances 0.000 claims description 7
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 239000002019 doping agent Substances 0.000 claims description 4
- 230000009467 reduction Effects 0.000 claims description 4
- 230000004913 activation Effects 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 229910052716 thallium Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 239000011260 aqueous acid Substances 0.000 abstract description 3
- 239000010941 cobalt Substances 0.000 description 26
- 229910017052 cobalt Inorganic materials 0.000 description 26
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical group [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 26
- 239000000047 product Substances 0.000 description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 17
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 13
- 238000004090 dissolution Methods 0.000 description 11
- 239000010936 titanium Substances 0.000 description 8
- 238000012986 modification Methods 0.000 description 7
- 230000004048 modification Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 238000011068 loading method Methods 0.000 description 6
- 239000000395 magnesium oxide Substances 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 4
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 229910001593 boehmite Inorganic materials 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical group [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000011066 ex-situ storage Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- ZGSOBQAJAUGRBK-UHFFFAOYSA-N propan-2-olate;zirconium(4+) Chemical compound [Zr+4].CC(C)[O-].CC(C)[O-].CC(C)[O-].CC(C)[O-] ZGSOBQAJAUGRBK-UHFFFAOYSA-N 0.000 description 2
- 239000013557 residual solvent Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 description 2
- 239000011882 ultra-fine particle Substances 0.000 description 2
- 229910002706 AlOOH Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical group [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8913—Cobalt and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0209—Impregnation involving a reaction between the support and a fluid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
- B01J37/033—Using Hydrolysis
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/648—Fischer-Tropsch-type reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/703—Activation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US22076900P | 2000-07-24 | 2000-07-24 | |
PCT/IB2001/001310 WO2002007883A2 (en) | 2000-07-24 | 2001-07-23 | Production of hydrocarbons from a synthesis gas |
Publications (3)
Publication Number | Publication Date |
---|---|
NO20030346D0 NO20030346D0 (no) | 2003-01-23 |
NO20030346L NO20030346L (no) | 2003-03-24 |
NO327405B1 true NO327405B1 (no) | 2009-06-22 |
Family
ID=22824889
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO20030346A NO327405B1 (no) | 2000-07-24 | 2003-01-23 | Fremgangsmate for a danne en katalysatorforloper |
Country Status (17)
Country | Link |
---|---|
US (1) | US6875720B2 (xx) |
EP (1) | EP1303350B2 (xx) |
JP (1) | JP4949594B2 (xx) |
KR (1) | KR20030040374A (xx) |
CN (1) | CN1444507A (xx) |
AT (1) | ATE341396T1 (xx) |
AU (2) | AU7657801A (xx) |
BR (1) | BRPI0112706B1 (xx) |
DE (1) | DE60123621T3 (xx) |
EG (1) | EG22794A (xx) |
ES (1) | ES2271051T5 (xx) |
MY (1) | MY136085A (xx) |
NO (1) | NO327405B1 (xx) |
PE (1) | PE20020250A1 (xx) |
RU (1) | RU2299763C2 (xx) |
WO (1) | WO2002007883A2 (xx) |
ZA (1) | ZA200300567B (xx) |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR0210649B1 (pt) | 2001-07-27 | 2015-03-10 | Sasol Tech Pty Ltd | Processo para preparar e usar um catalisador de cobalto de síntese de fischer-tropsch em fase de suspensão |
AU2002363102B2 (en) * | 2001-10-25 | 2006-11-23 | Basf Nederland B.V. | Process for activating cobalt catalysts |
AU2003277409C1 (en) | 2002-10-16 | 2009-06-25 | Conocophillips Company | Fischer-Tropsch processes and catalysts using stabilized supports |
RU2005115062A (ru) * | 2002-10-16 | 2005-10-10 | КонокоФиллипс Кампэни (US) | Способ получения носителя для катализатора (варианты), катализатор (варианты) и способ проведения гидротермального процесса |
WO2004035193A2 (en) | 2002-10-16 | 2004-04-29 | Conocophillips Company | Fischer-tropsch processes and catalysts made from a material comprising boehmite |
US7176160B2 (en) | 2002-10-16 | 2007-02-13 | Conocophillips Company | Method for forming a Fischer-Tropsch catalyst using a boehmite support |
WO2004035196A2 (en) | 2002-10-16 | 2004-04-29 | Conocophillips Company | A stabilized transition alumina catalyst support from boehmite and catalysts made therefrom |
US7341976B2 (en) | 2002-10-16 | 2008-03-11 | Conocophillips Company | Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using |
US7276540B2 (en) | 2002-11-11 | 2007-10-02 | Conocophillips Company | Supports for high surface area catalysts |
US8022108B2 (en) | 2003-07-02 | 2011-09-20 | Chevron U.S.A. Inc. | Acid treatment of a fischer-tropsch derived hydrocarbon stream |
US7150823B2 (en) | 2003-07-02 | 2006-12-19 | Chevron U.S.A. Inc. | Catalytic filtering of a Fischer-Tropsch derived hydrocarbon stream |
US7163963B2 (en) | 2003-09-08 | 2007-01-16 | Conocophillips Company | Chemically and thermally stabilized alumina for Fischer-Tropsch catalysts |
WO2005037745A1 (en) | 2003-10-16 | 2005-04-28 | Conocophillips Company | Silica-alumina catalyst support with bimodal pore distribution, catalysts, methods of making and using same |
WO2005046855A2 (en) | 2003-10-16 | 2005-05-26 | Conocophillips Company | Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same |
US7348293B2 (en) | 2003-12-05 | 2008-03-25 | Chevron U.S.A. Inc. | Homogeneous modified-alumina Fischer-Tropsch catalyst supports |
US7332073B2 (en) | 2004-03-31 | 2008-02-19 | Chevron U.S.A. Inc. | Process for removing contaminants from Fischer-Tropsch feed streams |
DE102005019103B4 (de) | 2004-04-26 | 2023-09-21 | Sasol Technology (Proprietary) Ltd. | Verfahren zur Herstellung eines auf Cobalt basierenden Katalysators für die Fischer-Tropsch-Synthese und Verfahren zur Herstellung eines Fischer-Tropsch-Kohlenwasserstoffproduktes |
RU2383581C2 (ru) * | 2004-07-06 | 2010-03-10 | Сэйзол Текнолоджи (Пти) Лтд | Способ обработки углеводородов, полученных методом фишера-тропша |
RU2364615C2 (ru) * | 2004-07-06 | 2009-08-20 | Сэйзол Текнолоджи (Пти) Лтд | Способ обработки углеводородов, полученных методом фишера-тропша |
BRPI0516430A (pt) * | 2004-11-10 | 2008-09-02 | Sasol Tech Pty Ltd | tratamento de correntes de hidrocarboneto de alta massa molar |
CN101522296A (zh) * | 2006-10-06 | 2009-09-02 | 格雷斯公司 | 耐硫的氧化铝催化剂载体 |
EP2081681B1 (en) * | 2006-10-06 | 2016-02-17 | W. R. Grace & Co.-Conn | Process for preparing a sulfur tolerant alumina catalyst support |
US8337621B2 (en) * | 2006-11-29 | 2012-12-25 | Tokyo Electron Limited | Substrate processing apparatus |
US8809215B2 (en) | 2007-05-11 | 2014-08-19 | Sasol Technology (Proprietary) Limited | Catalysts |
US20090098032A1 (en) * | 2007-10-11 | 2009-04-16 | Basf Catalysts Llc | Methods of making aluminosilicate coated alumina |
US8252393B2 (en) | 2007-12-28 | 2012-08-28 | Canon Kabushiki Kaisha | Surface-modified inorganic pigment, colored surface-modified inorganic pigment, recording medium and production processes thereof, and image forming method and recorded image |
WO2011043995A1 (en) | 2009-10-08 | 2011-04-14 | W. R. Grace & Co.-Conn. | Sulfur tolerant alumina catalyst support |
JP5952293B2 (ja) * | 2010-11-16 | 2016-07-13 | ロディア オペレーションズRhodia Operations | 硫黄耐性アルミナ触媒担体 |
CA2826520C (en) | 2011-02-09 | 2019-02-12 | Sasol Technology (Proprietary) Limited | A method of preparing a catalyst precursor |
FR2978682B1 (fr) | 2011-06-01 | 2016-01-01 | Sicat Llc | Procede catalytique pour la conversion d'un gaz de synthese en hydrocarbures |
EP2790831B1 (en) * | 2011-12-14 | 2020-10-28 | Sasol Technology (Proprietary) Limited | Catalysts |
WO2014001697A1 (fr) | 2012-06-26 | 2014-01-03 | Sicat Llc | Supports de catalyseur à base de carbure de silicium recouvert de TiO2 pour la synthèse de Fischer-Tropsch |
US9527782B2 (en) * | 2012-08-02 | 2016-12-27 | Sasol Technology (Propietary) Limited | Method of preparing a modified support, a catalyst precursor and a catalyst, and a hydrocarbon synthesis process using the catalyst |
US9289750B2 (en) | 2013-03-09 | 2016-03-22 | Brigham Young University | Method of making highly porous, stable aluminum oxides doped with silicon |
WO2015104056A1 (en) | 2014-01-09 | 2015-07-16 | Statoil Petroleum As | Catalyst support and catalyst for fischer-tropsch synthesis |
US9233358B1 (en) | 2014-09-10 | 2016-01-12 | Chevron U.S.A. Inc. | Stable support for Fischer-Tropsch catalyst |
US9168512B1 (en) | 2014-09-10 | 2015-10-27 | Chevron U.S.A. Inc. | Stable support for Fischer-Tropsch catalyst |
US9233360B1 (en) | 2014-09-10 | 2016-01-12 | Chevron U.S.A. Inc. | Stable support for Fischer-Tropsch catalyst |
WO2016039896A1 (en) | 2014-09-10 | 2016-03-17 | Chevron U.S.A. Inc. | Stable support for fischer-tropsch catalyst |
US9192921B1 (en) | 2014-09-10 | 2015-11-24 | Chevron U.S.A. Inc. | Support for Fischer-Tropsch catalyst having improved activity |
US9687826B2 (en) | 2014-09-10 | 2017-06-27 | Chevron U.S.A. Inc. | Support for fischer-tropsch catalyst having improved activity |
CN104607223A (zh) * | 2015-02-04 | 2015-05-13 | 厦门大学 | 一种含钌钴基费托合成催化剂及其制备方法 |
CN106140226B (zh) * | 2015-03-27 | 2018-06-19 | 中国石油化工股份有限公司 | 一种制烯烃的催化剂及其制备方法与应用 |
US9725381B2 (en) * | 2015-07-07 | 2017-08-08 | King Fahd University Of Petroleum And Minerals | Fluidizable catalysts for oxidative dehydrogenation of hydrocarbons |
US10744486B2 (en) | 2015-09-04 | 2020-08-18 | Clariant Corporation | Catalyst support materials and catalyst materials useful for Fischer-Tropsch processes |
CN106588526B (zh) * | 2015-10-20 | 2019-07-23 | 中国石油化工股份有限公司 | 一种以煤和炼厂干气为原料制烯烃的系统以及制烯烃的方法 |
CN109304174B (zh) * | 2017-07-26 | 2021-08-10 | 国家能源投资集团有限责任公司 | 制备费托合成钴基催化剂的方法 |
CN109289865A (zh) * | 2018-09-30 | 2019-02-01 | 中国科学院山西煤炭化学研究所 | 一种合成气制低碳混合醇的含硅催化剂及制法和应用 |
CN112391191B (zh) * | 2020-10-30 | 2022-09-02 | 山西潞安煤基清洁能源有限责任公司 | 一种防止费托合成工艺中催化剂凝结结垢的方法以及催化剂和应用 |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2722504A (en) † | 1950-12-04 | 1955-11-01 | Union Oil Co | Silicone coated catalyst and use thereof |
US3274120A (en) * | 1964-02-20 | 1966-09-20 | Cabot Corp | Catalyst composition having increased hydroxyl groups bound thereto and method for producing same |
US4032550A (en) † | 1975-11-26 | 1977-06-28 | Emery Industries, Inc. | Process for the production of esters |
US4086261A (en) † | 1975-12-08 | 1978-04-25 | Mobil Oil Corporation | Methanation over synthetic amorphous silicas |
EP0110449B1 (en) * | 1982-11-22 | 1986-08-13 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of a fischer-tropsch catalyst, a catalyst so prepared and use of this catalyst in the preparation of hydrocarbons |
FR2553430B1 (fr) * | 1983-10-14 | 1986-02-21 | Shell Int Research | Procede pour l'hydro-isomerisation de cires de petrole |
US4748145A (en) * | 1983-12-30 | 1988-05-31 | The Dow Chemical Company | Catalysts having alkoxide-modified supports and method of increasing the catalytic activity of a catalytic metal |
EP0180269B1 (en) * | 1984-11-02 | 1990-06-27 | Shell Internationale Researchmaatschappij B.V. | Catalyst preparation |
US4670472A (en) * | 1985-06-05 | 1987-06-02 | Air Products And Chemicals, Inc. | Fischer-Tropsch process |
EP0206172B1 (en) † | 1985-06-17 | 1991-07-24 | Idemitsu Petrochemical Co. Ltd. | Method for producing polyolefins |
CA1270002C (en) † | 1986-01-27 | 1990-06-05 | DIMERIZATION AND POLYMERIZATION OF ETHYLENE | |
US5169821A (en) † | 1991-11-14 | 1992-12-08 | Exxon Research And Engineering Company | Method for stabilizing titania supported cobalt catalyst and the catalyst for use in Fischer-Tropsch process |
FR2688149B1 (fr) † | 1992-03-06 | 1994-04-29 | Total Raffinage Distribution | Nouvelle solution aqueuse pour l'impregnation de supports de catalyseur, catalyseurs prepares a partir de cette solution et applications de ces catalyseurs. |
BE1007148A3 (fr) * | 1993-05-17 | 1995-04-11 | Solvay | Support pour catalyseurs, procede pour la fabrication d'un gel precurseur d'un support pour catalyseurs, procede de preparation d'un support pour catalyseurs, catalyseur pour la polymerisation d'olefines et procede pour la polymerisation d'olefines au moyen de ce catalyseur. |
DE19506843A1 (de) † | 1995-02-28 | 1996-08-29 | Studiengesellschaft Kohle Mbh | Mikroporöse amorphe Mischmetalloxide für formselektive Katalyse |
DZ2013A1 (fr) | 1995-04-07 | 2002-10-23 | Sastech Ltd | Catalyseurs. |
DE19545042A1 (de) † | 1995-12-02 | 1997-06-05 | Studiengesellschaft Kohle Mbh | Amorphe mikroporöse Mischoxidkatalysatoren mit kontrollierter Oberflächenpolarität für die selektive heterogene Katalyse Adsorption und Stofftrennung |
JP2000506438A (ja) * | 1996-03-14 | 2000-05-30 | セラニーズ・インターナショナル・コーポレーション | 酢酸ビニル製造用のコロイド状パラジウム―金合金触媒 |
FR2746672B1 (fr) * | 1996-04-02 | 1998-04-24 | Atochem Elf Sa | Composante catalytique et son utilisation en polymerisation des olefines |
US6207128B1 (en) * | 1997-05-05 | 2001-03-27 | Akzo Nobel N.V. | Method of producing a catalyst |
KR100590415B1 (ko) * | 1997-12-30 | 2006-06-19 | 쉘 인터내셔날 리서치 마챠피즈 비.브이. | 코발트 기재의 피셔-트롭쉬 촉매 |
DZ2724A1 (fr) * | 1998-02-20 | 2003-09-01 | Sasol Tech Pty Ltd | Procédé pour la production d'hydrocarbures à partir d'un gaz de synthèse et leurs catalyseurs. |
DE19828364A1 (de) † | 1998-06-25 | 1999-12-30 | Degussa | Hydrophobe Fällungskieselsäure |
DE19831804A1 (de) † | 1998-07-15 | 2000-01-27 | Univ Bayreuth | Heterogene Katalysatorsysteme mit Kaolin als Träger für die Olefinpolymerisation |
PL347129A1 (en) * | 1998-10-05 | 2002-03-25 | Sasol Tech Pty Ltd | Impregnation process for catalysts |
EG22489A (en) * | 1999-02-05 | 2003-02-26 | Sasol Technology | Process for producing liquid and optionally gaseous products from gaseous reactants |
US6313062B1 (en) * | 1999-10-29 | 2001-11-06 | Exxon Reserach And Engineering Company | Process for the preparation of high activity carbon monoxide hydrogenation catalysts; the catalyst composition, use of the catalysts for conducting such reactions, and the products of such reactions |
FR2804689B1 (fr) * | 2000-02-08 | 2002-03-15 | Inst Francais Du Petrole | Procede de synthese d'hydrocarbures en presence d'un catalyseur comprenant un metal du groupe viii supporte sur silice-alumine |
-
2001
- 2001-07-23 JP JP2002513610A patent/JP4949594B2/ja not_active Expired - Fee Related
- 2001-07-23 WO PCT/IB2001/001310 patent/WO2002007883A2/en active IP Right Grant
- 2001-07-23 DE DE60123621T patent/DE60123621T3/de not_active Expired - Lifetime
- 2001-07-23 ES ES01954235T patent/ES2271051T5/es not_active Expired - Lifetime
- 2001-07-23 KR KR10-2003-7001020A patent/KR20030040374A/ko not_active Application Discontinuation
- 2001-07-23 CN CN01813314A patent/CN1444507A/zh active Pending
- 2001-07-23 AT AT01954235T patent/ATE341396T1/de not_active IP Right Cessation
- 2001-07-23 PE PE2001000741A patent/PE20020250A1/es not_active Application Discontinuation
- 2001-07-23 AU AU7657801A patent/AU7657801A/xx active Pending
- 2001-07-23 BR BRPI0112706A patent/BRPI0112706B1/pt not_active IP Right Cessation
- 2001-07-23 EP EP01954235A patent/EP1303350B2/en not_active Expired - Lifetime
- 2001-07-23 RU RU2003104989/04A patent/RU2299763C2/ru active
- 2001-07-23 AU AU2001276578A patent/AU2001276578B2/en not_active Expired
- 2001-07-24 MY MYPI20013506A patent/MY136085A/en unknown
- 2001-07-24 EG EG20010805A patent/EG22794A/xx active
-
2003
- 2003-01-21 ZA ZA200300567A patent/ZA200300567B/en unknown
- 2003-01-22 US US10/349,330 patent/US6875720B2/en not_active Expired - Lifetime
- 2003-01-23 NO NO20030346A patent/NO327405B1/no not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
AU7657801A (en) | 2002-02-05 |
EG22794A (en) | 2003-08-31 |
JP4949594B2 (ja) | 2012-06-13 |
ES2271051T3 (es) | 2007-04-16 |
EP1303350B1 (en) | 2006-10-04 |
BRPI0112706B1 (pt) | 2016-01-19 |
DE60123621T3 (de) | 2010-07-01 |
AU2001276578B2 (en) | 2005-11-03 |
EP1303350B2 (en) | 2010-01-27 |
KR20030040374A (ko) | 2003-05-22 |
DE60123621D1 (de) | 2006-11-16 |
RU2299763C2 (ru) | 2007-05-27 |
JP2004504136A (ja) | 2004-02-12 |
EP1303350B9 (en) | 2007-05-30 |
ES2271051T5 (es) | 2010-05-07 |
US6875720B2 (en) | 2005-04-05 |
NO20030346D0 (no) | 2003-01-23 |
NO20030346L (no) | 2003-03-24 |
EP1303350A2 (en) | 2003-04-23 |
BR0112706A (pt) | 2003-07-01 |
ZA200300567B (en) | 2004-07-14 |
WO2002007883A3 (en) | 2002-10-31 |
MY136085A (en) | 2008-08-29 |
WO2002007883A2 (en) | 2002-01-31 |
US20030162849A1 (en) | 2003-08-28 |
ATE341396T1 (de) | 2006-10-15 |
DE60123621T2 (de) | 2007-01-11 |
PE20020250A1 (es) | 2002-04-24 |
CN1444507A (zh) | 2003-09-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
NO327405B1 (no) | Fremgangsmate for a danne en katalysatorforloper | |
EP1058580B1 (en) | Process for producing fischer-tropsch catalysts | |
AU2001276578A1 (en) | Catalyst Supports, Catalyst Precursors and Catalysts | |
NO335702B1 (no) | Produksjon av Fischer-Tropsch synteseprodusert voks | |
EP2879787B1 (en) | Method of preparing a modified catalyst support, method of preparing a catalyst, and hydrocarbon synthesis process employing the catalyst support | |
US9327273B2 (en) | Catalysts | |
CZ20002971A3 (cs) | Způsob zpracování nosiče katalyzátoru, nosič katalyzátoru, způsob výroby katalyzátoru, katalyzátor a způsob výroby uhlovodíků | |
AU2012215108B2 (en) | Catalysts | |
NZ613645B2 (en) | Method of preparing a catalyst precursor |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK1K | Patent expired |