NO324457B1 - Baret koboltbasert katalysator, og Fischer-Tropsch prosess som utfores i naervaer av en slik katalysator. - Google Patents

Baret koboltbasert katalysator, og Fischer-Tropsch prosess som utfores i naervaer av en slik katalysator. Download PDF

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Publication number
NO324457B1
NO324457B1 NO20011008A NO20011008A NO324457B1 NO 324457 B1 NO324457 B1 NO 324457B1 NO 20011008 A NO20011008 A NO 20011008A NO 20011008 A NO20011008 A NO 20011008A NO 324457 B1 NO324457 B1 NO 324457B1
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NO
Norway
Prior art keywords
catalyst
fischer
carried out
cobalt
tropsch process
Prior art date
Application number
NO20011008A
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English (en)
Other versions
NO20011008D0 (no
NO20011008L (no
Inventor
Giuseppe Bellussi
Roberto Zennaro
Vincenzo Piccolo
Magalie Roy-Auberger
Enrico Radaelli
Original Assignee
Agip Petroli
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11444288&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=NO324457(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Agip Petroli filed Critical Agip Petroli
Publication of NO20011008D0 publication Critical patent/NO20011008D0/no
Publication of NO20011008L publication Critical patent/NO20011008L/no
Publication of NO324457B1 publication Critical patent/NO324457B1/no

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Claims (5)

1. Båret koboltbasert katalysator, karakterisert ved at bæreren har en gjennomsnittlig partikkeldiameter, målt ved hjelp av Coulter LS23 0, i området fra 120 til 180 fim, et overf lateareal i området fra 185 til 210 m<2>/g og et porevolum større enn 0,3 5 cm<3>/g, målt med B.E.T. metoden, idet den aktive fase hovedsakelig består av > 80% kobolt.
2. Katalysator som angitt i krav 1, hvori bæreren består av minst 80% aluminiumoksyd.
3. Katalysator som angitt i krav l, hvori bæreren har et porevolum større enn 0,40 cm<3>/g.
4. Fischer-Tropsch prosess i en gass-væske-faststoff fluidisert reaktor som omfatter reaksjonen av CO og H2, eventuelt fortynnet med C02 og/eller N2, til prevalent å gi C5+ hydrokarboner, karakterisert ved at den utføres i nærvær av katalysatoren i samsvar med ett eller flere av de foregående krav.
5. Fischer-Tropsch prosess som angitt i krav 4, hvori den utføres i en slurry-boblekolonnereaktor (SBCR).
NO20011008A 2000-03-02 2001-02-27 Baret koboltbasert katalysator, og Fischer-Tropsch prosess som utfores i naervaer av en slik katalysator. NO324457B1 (no)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT2000MI000409A IT1317868B1 (it) 2000-03-02 2000-03-02 Catalizzatore a base di cobalto supportato, particolarmente utilenella reazione di fischer-tropsch.

Publications (3)

Publication Number Publication Date
NO20011008D0 NO20011008D0 (no) 2001-02-27
NO20011008L NO20011008L (no) 2001-09-03
NO324457B1 true NO324457B1 (no) 2007-10-22

Family

ID=11444288

Family Applications (1)

Application Number Title Priority Date Filing Date
NO20011008A NO324457B1 (no) 2000-03-02 2001-02-27 Baret koboltbasert katalysator, og Fischer-Tropsch prosess som utfores i naervaer av en slik katalysator.

Country Status (14)

Country Link
US (2) US6596667B2 (no)
EP (1) EP1129776B2 (no)
CN (1) CN1193826C (no)
AT (1) ATE335543T1 (no)
CA (1) CA2337457C (no)
DE (1) DE60122039T3 (no)
DK (1) DK1129776T4 (no)
ES (1) ES2269293T5 (no)
ID (1) ID29553A (no)
IT (1) IT1317868B1 (no)
MY (1) MY127327A (no)
NO (1) NO324457B1 (no)
RU (1) RU2259876C2 (no)
ZA (1) ZA200101714B (no)

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CN102989459B (zh) * 2011-09-16 2014-10-29 中国科学院大连化学物理研究所 一种在醛助氧化作用下将环己酮/氧气氧化制备ε-己内脂的催化剂
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Also Published As

Publication number Publication date
CN1193826C (zh) 2005-03-23
CA2337457A1 (en) 2001-09-02
ATE335543T1 (de) 2006-09-15
NO20011008D0 (no) 2001-02-27
DE60122039T3 (de) 2014-12-11
ITMI20000409A0 (it) 2000-03-02
IT1317868B1 (it) 2003-07-15
DK1129776T3 (da) 2006-12-11
MY127327A (en) 2006-11-30
US20030203981A1 (en) 2003-10-30
ES2269293T5 (es) 2014-10-27
ITMI20000409A1 (it) 2001-09-02
CN1316298A (zh) 2001-10-10
RU2259876C2 (ru) 2005-09-10
CA2337457C (en) 2009-12-15
DE60122039T2 (de) 2007-03-15
NO20011008L (no) 2001-09-03
ZA200101714B (en) 2001-08-30
DK1129776T4 (da) 2014-10-20
EP1129776A1 (en) 2001-09-05
US6689819B2 (en) 2004-02-10
EP1129776B2 (en) 2014-07-16
EP1129776B1 (en) 2006-08-09
ES2269293T3 (es) 2007-04-01
DE60122039D1 (de) 2006-09-21
US20010041750A1 (en) 2001-11-15
ID29553A (id) 2001-09-06
US6596667B2 (en) 2003-07-22

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