NO324214B1 - Fremgangsmate for fremstilling av hydrokarboner fra syntesegass - Google Patents
Fremgangsmate for fremstilling av hydrokarboner fra syntesegass Download PDFInfo
- Publication number
- NO324214B1 NO324214B1 NO19993133A NO993133A NO324214B1 NO 324214 B1 NO324214 B1 NO 324214B1 NO 19993133 A NO19993133 A NO 19993133A NO 993133 A NO993133 A NO 993133A NO 324214 B1 NO324214 B1 NO 324214B1
- Authority
- NO
- Norway
- Prior art keywords
- reactor
- fischer
- catalyst
- stated
- tropsch
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 31
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 30
- 229930195733 hydrocarbon Natural products 0.000 title claims description 29
- 238000003786 synthesis reaction Methods 0.000 title claims description 28
- 230000015572 biosynthetic process Effects 0.000 title claims description 27
- 239000003054 catalyst Substances 0.000 claims description 38
- 238000006243 chemical reaction Methods 0.000 claims description 28
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 27
- 239000007789 gas Substances 0.000 claims description 26
- 239000000725 suspension Substances 0.000 claims description 17
- 239000000047 product Substances 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 239000012808 vapor phase Substances 0.000 claims description 10
- 239000007795 chemical reaction product Substances 0.000 claims description 9
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 239000007791 liquid phase Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 229910052715 tantalum Inorganic materials 0.000 claims description 4
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000007788 liquid Substances 0.000 description 17
- 239000012071 phase Substances 0.000 description 16
- 239000000203 mixture Substances 0.000 description 11
- 239000001993 wax Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000001354 calcination Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000002453 autothermal reforming Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- -1 methane) Chemical class 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003481 tantalum Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/24—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles
- C10G47/26—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles suspended in the oil, e.g. slurries
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1998MI001451A IT1301801B1 (it) | 1998-06-25 | 1998-06-25 | Procedimento per la preparazione di idrocarburi da gas di sintesi |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO993133D0 NO993133D0 (no) | 1999-06-23 |
| NO993133L NO993133L (no) | 1999-12-27 |
| NO324214B1 true NO324214B1 (no) | 2007-09-10 |
Family
ID=11380316
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19993133A NO324214B1 (no) | 1998-06-25 | 1999-06-23 | Fremgangsmate for fremstilling av hydrokarboner fra syntesegass |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6121333A (ja) |
| EP (1) | EP0967262B1 (ja) |
| JP (1) | JP4403204B2 (ja) |
| CN (1) | CN1183063C (ja) |
| CA (1) | CA2274990C (ja) |
| DE (1) | DE69906884T2 (ja) |
| ES (1) | ES2195507T3 (ja) |
| ID (1) | ID23272A (ja) |
| IT (1) | IT1301801B1 (ja) |
| MY (1) | MY117507A (ja) |
| NO (1) | NO324214B1 (ja) |
| ZA (1) | ZA994059B (ja) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6080301A (en) | 1998-09-04 | 2000-06-27 | Exxonmobil Research And Engineering Company | Premium synthetic lubricant base stock having at least 95% non-cyclic isoparaffins |
| US6475960B1 (en) | 1998-09-04 | 2002-11-05 | Exxonmobil Research And Engineering Co. | Premium synthetic lubricants |
| US6579443B1 (en) * | 1998-12-07 | 2003-06-17 | Exxonmobil Research And Engineering Company | Countercurrent hydroprocessing with treatment of feedstream to remove particulates and foulant precursors |
| US6262132B1 (en) * | 1999-05-21 | 2001-07-17 | Energy International Corporation | Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems |
| US6465529B1 (en) * | 2000-08-01 | 2002-10-15 | Exxonmobil Research And Engineering Company | Process for increasing cobalt catalyst hydrogenation activity via aqueous low temperature oxidation |
| US6642281B1 (en) * | 2000-09-01 | 2003-11-04 | Exxonmobil Research And Engineering Company | Fischer-tropsch process |
| US6359018B1 (en) * | 2000-10-27 | 2002-03-19 | Chevron U.S.A. Inc | Process for upflow fixed-bed hydroprocessing of fischer-tropsch wax |
| MY139353A (en) * | 2001-03-05 | 2009-09-30 | Shell Int Research | Process to prepare a lubricating base oil and a gas oil |
| ITMI20010478A1 (it) * | 2001-03-08 | 2002-09-08 | Inst Francais Du Petrole | Catalizzatore a base di cobalto e suo utilizzo nel processo di fischer-tropsch |
| US6812179B2 (en) * | 2001-04-25 | 2004-11-02 | Syntroleum Corporation | Process for regenerating a slurry fischer-tropsch catalyst |
| GB0112789D0 (en) * | 2001-05-25 | 2001-07-18 | Bp Exploration Operating | Process |
| NZ528955A (en) * | 2001-06-18 | 2005-02-25 | Japan Nat Oil Corp | Method for producing hydrocarbons by Fischer-Tropsch process |
| JP4660021B2 (ja) * | 2001-06-18 | 2011-03-30 | 独立行政法人石油天然ガス・金属鉱物資源機構 | フィッシャートロプシュ法による炭化水素類の製造方法 |
| JP4660039B2 (ja) * | 2001-09-28 | 2011-03-30 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 二酸化炭素の共存下のフィッシャートロプシュ法による炭化水素類の製造方法 |
| CN1223555C (zh) | 2001-07-13 | 2005-10-19 | 埃克森美孚研究工程公司 | 直接生产高纯度的费－托蜡 |
| US6649803B2 (en) * | 2001-11-06 | 2003-11-18 | Exxonmobil Research And Engineering Company | Slurry hydrocarbon synthesis with isomerization zone in external lift reactor loop |
| US6717024B2 (en) * | 2001-11-06 | 2004-04-06 | Exxonmobil Research And Engineering Company | Slurry hydrocarbon synthesis with liquid hydroisomerization in the synthesis reactor |
| US6555725B1 (en) * | 2001-11-06 | 2003-04-29 | Exxonmobil Research And Engineering Company | In-situ hydroisomerization of synthesized hydrocarbon liquid in a slurry fischer-tropsch reactor |
| FR2832416B1 (fr) * | 2001-11-20 | 2004-09-03 | Inst Francais Du Petrole | Procede de conversion de gaz de synthese dans des reacteurs en serie |
| US6800579B2 (en) * | 2002-01-29 | 2004-10-05 | Exxonmobil Research And Engineering Company | Catalyst regeneration |
| BR0317814A (pt) * | 2002-12-30 | 2005-11-29 | Shell Int Research | Processos para a preparação de detergentes, de combustìveis de hidrocarbonetos, e de hidrocarbonetos detergentes |
| AU2004218208A1 (en) * | 2003-03-05 | 2004-09-16 | Compactgtl Plc | Producing longer-chain hydrocarbons from natural gas |
| ITMI20031029A1 (it) * | 2003-05-22 | 2004-11-23 | Enitecnologie Spa | Procedimenti per la produzione in continuo di idrocarburi da gas di sintesi. |
| ATE498670T1 (de) * | 2003-07-04 | 2011-03-15 | Shell Int Research | Verfahren zur herstellung eines fischer-tropsch- produkts |
| GB2409825B (en) * | 2004-01-08 | 2007-06-13 | Statoil Asa | Heat exchange system for a slurry bubble column reactor |
| DE102005019103B4 (de) * | 2004-04-26 | 2023-09-21 | Sasol Technology (Proprietary) Ltd. | Verfahren zur Herstellung eines auf Cobalt basierenden Katalysators für die Fischer-Tropsch-Synthese und Verfahren zur Herstellung eines Fischer-Tropsch-Kohlenwasserstoffproduktes |
| GB0513484D0 (en) * | 2005-07-01 | 2005-08-10 | Accentus Plc | Producing liquid hydrocarbons |
| US8057744B2 (en) * | 2005-12-14 | 2011-11-15 | Nippon Steel Engineering Co., Ltd. | Bubble column-type Fischer-Tropsch synthesis slurry bed reaction system |
| JP2007307436A (ja) * | 2006-05-16 | 2007-11-29 | Ihi Corp | フィッシャー・トロプシュ合成触媒とその製造方法 |
| US7767278B2 (en) * | 2007-03-20 | 2010-08-03 | Chisso Corporation | Liquid crystal composition and liquid crystal display device |
| US20080260631A1 (en) | 2007-04-18 | 2008-10-23 | H2Gen Innovations, Inc. | Hydrogen production process |
| JP5367412B2 (ja) * | 2009-02-27 | 2013-12-11 | 独立行政法人石油天然ガス・金属鉱物資源機構 | Ｆｔ合成炭化水素の精製方法及びｆｔ合成炭化水素蒸留分離装置 |
| CN102041019B (zh) * | 2009-10-22 | 2013-06-26 | 中国石油化工股份有限公司 | 一种煤制油联产代用天然气的方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4097364A (en) * | 1975-06-13 | 1978-06-27 | Chevron Research Company | Hydrocracking in the presence of water and a low hydrogen partial pressure |
| IN161735B (ja) * | 1983-09-12 | 1988-01-30 | Shell Int Research | |
| US4684756A (en) * | 1986-05-01 | 1987-08-04 | Mobil Oil Corporation | Process for upgrading wax from Fischer-Tropsch synthesis |
| FR2694013B1 (fr) * | 1992-07-27 | 1994-09-30 | Inst Francais Du Petrole | Catalyseur à base de cobalt et procédé de conversion du gaz de synthèse en hydrocarbures. |
| MY108862A (en) * | 1992-08-18 | 1996-11-30 | Shell Int Research | Process for the preparation of hydrocarbon fuels |
| NZ250750A (en) * | 1993-01-27 | 1995-02-24 | Sasol Chem Ind Pty | Reacting gases in a slurry bed which contains a filtration zone to separate liquid product |
| NO313086B1 (no) * | 1995-08-04 | 2002-08-12 | Inst Francais Du Petrole | Fremgangsmåte for fremstilling av en katalysator, katalysator som kan oppnås derved, katalysatorblanding oppnådd derved samtfremgangsmåte for syntese av hydrokarboner |
-
1998
- 1998-06-25 IT IT1998MI001451A patent/IT1301801B1/it active IP Right Grant
-
1999
- 1999-06-14 EP EP99201883A patent/EP0967262B1/en not_active Expired - Lifetime
- 1999-06-14 ES ES99201883T patent/ES2195507T3/es not_active Expired - Lifetime
- 1999-06-14 DE DE69906884T patent/DE69906884T2/de not_active Expired - Lifetime
- 1999-06-15 CA CA002274990A patent/CA2274990C/en not_active Expired - Fee Related
- 1999-06-18 ZA ZA9904059A patent/ZA994059B/xx unknown
- 1999-06-18 US US09/335,484 patent/US6121333A/en not_active Expired - Fee Related
- 1999-06-23 ID IDP990605A patent/ID23272A/id unknown
- 1999-06-23 MY MYPI99002572A patent/MY117507A/en unknown
- 1999-06-23 NO NO19993133A patent/NO324214B1/no not_active IP Right Cessation
- 1999-06-24 JP JP17794799A patent/JP4403204B2/ja not_active Expired - Fee Related
- 1999-06-25 CN CNB991111222A patent/CN1183063C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0967262B1 (en) | 2003-04-16 |
| IT1301801B1 (it) | 2000-07-07 |
| CA2274990C (en) | 2007-08-21 |
| MY117507A (en) | 2004-07-31 |
| US6121333A (en) | 2000-09-19 |
| DE69906884D1 (de) | 2003-05-22 |
| ZA994059B (en) | 1999-12-20 |
| JP4403204B2 (ja) | 2010-01-27 |
| DE69906884T2 (de) | 2004-03-04 |
| EP0967262A1 (en) | 1999-12-29 |
| CA2274990A1 (en) | 1999-12-25 |
| ES2195507T3 (es) | 2003-12-01 |
| NO993133D0 (no) | 1999-06-23 |
| CN1243113A (zh) | 2000-02-02 |
| ITMI981451A1 (it) | 1999-12-25 |
| JP2000204050A (ja) | 2000-07-25 |
| NO993133L (no) | 1999-12-27 |
| ID23272A (id) | 2000-04-05 |
| CN1183063C (zh) | 2005-01-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM1K | Lapsed by not paying the annual fees |