NO318511B1 - Fremgangsmate for a generere kraft ved hjelp av en avansert, termokjemisk rekuperasjonssyklus - Google Patents
Fremgangsmate for a generere kraft ved hjelp av en avansert, termokjemisk rekuperasjonssyklus Download PDFInfo
- Publication number
- NO318511B1 NO318511B1 NO20005114A NO20005114A NO318511B1 NO 318511 B1 NO318511 B1 NO 318511B1 NO 20005114 A NO20005114 A NO 20005114A NO 20005114 A NO20005114 A NO 20005114A NO 318511 B1 NO318511 B1 NO 318511B1
- Authority
- NO
- Norway
- Prior art keywords
- exhaust gas
- fuel
- steam
- gas
- temperature
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 42
- 238000011084 recovery Methods 0.000 title abstract description 50
- 230000008569 process Effects 0.000 title description 26
- 239000000446 fuel Substances 0.000 claims abstract description 172
- 239000000203 mixture Substances 0.000 claims abstract description 47
- 239000007789 gas Substances 0.000 claims description 191
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 44
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 22
- 239000003054 catalyst Substances 0.000 claims description 12
- 239000003345 natural gas Substances 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 238000002407 reforming Methods 0.000 claims description 5
- 238000000629 steam reforming Methods 0.000 claims description 5
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 4
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 3
- 238000006555 catalytic reaction Methods 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 40
- 238000002485 combustion reaction Methods 0.000 abstract description 24
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- 239000003053 toxin Substances 0.000 abstract description 3
- 231100000765 toxin Toxicity 0.000 abstract description 3
- 108700012359 toxins Proteins 0.000 abstract description 3
- 238000012545 processing Methods 0.000 abstract description 2
- 238000010977 unit operation Methods 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 24
- 238000010248 power generation Methods 0.000 description 24
- 239000007788 liquid Substances 0.000 description 17
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 9
- 239000012530 fluid Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 8
- 239000001569 carbon dioxide Substances 0.000 description 7
- 229910002092 carbon dioxide Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 239000002737 fuel gas Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 230000003134 recirculating effect Effects 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- 239000013529 heat transfer fluid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000006057 reforming reaction Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000008400 supply water Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
- F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
- F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
- F01K23/10—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle with exhaust fluid of one cycle heating the fluid in another cycle
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
Landscapes
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Valve Device For Special Equipments (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Mechanical Treatment Of Semiconductor (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Plasma Technology (AREA)
- Dc-Dc Converters (AREA)
- General Induction Heating (AREA)
- Paper (AREA)
- Saccharide Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/248,437 US6223519B1 (en) | 1999-02-11 | 1999-02-11 | Method of generating power using an advanced thermal recuperation cycle |
| PCT/US2000/000253 WO2000047874A1 (en) | 1999-02-11 | 2000-01-06 | Method of generating power using an advanced thermochemical recuperation cycle |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20005114D0 NO20005114D0 (no) | 2000-10-11 |
| NO20005114L NO20005114L (no) | 2000-10-11 |
| NO318511B1 true NO318511B1 (no) | 2005-04-04 |
Family
ID=22939128
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20005114A NO318511B1 (no) | 1999-02-11 | 2000-10-11 | Fremgangsmate for a generere kraft ved hjelp av en avansert, termokjemisk rekuperasjonssyklus |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6223519B1 (ja) |
| EP (1) | EP1071867B1 (ja) |
| JP (1) | JP2002536587A (ja) |
| KR (1) | KR100656693B1 (ja) |
| CN (1) | CN1293735A (ja) |
| AT (1) | ATE356921T1 (ja) |
| AU (1) | AU754398B2 (ja) |
| DE (1) | DE60033889T2 (ja) |
| ID (1) | ID26952A (ja) |
| NO (1) | NO318511B1 (ja) |
| WO (1) | WO2000047874A1 (ja) |
| ZA (1) | ZA200005201B (ja) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0025552D0 (en) * | 2000-10-18 | 2000-11-29 | Air Prod & Chem | Process and apparatus for the generation of power |
| FR2819580B1 (fr) * | 2001-01-16 | 2003-04-04 | Ind Du Ponant L | Generateur de vapeur destine a humidifier l'air d'une enceinte ou l'air traite dans un systeme de conditionnement d'air |
| US20020108306A1 (en) * | 2001-02-12 | 2002-08-15 | Grieve Malcolm James | Reformer controls |
| US6467273B1 (en) * | 2001-03-01 | 2002-10-22 | Henry A. Lott | Method for producing electrical power |
| US6968700B2 (en) | 2001-03-01 | 2005-11-29 | Lott Henry A | Power systems |
| JP4585142B2 (ja) * | 2001-05-14 | 2010-11-24 | 株式会社東芝 | ガスタービンシステム |
| FR2825995B1 (fr) * | 2001-06-15 | 2004-07-09 | Inst Francais Du Petrole | Installation et procede de production de gaz de synthese comprenant un reacteur de vaporeformage et un reacteur de conversion du co2 chauffe par un gaz chaud |
| US6841683B2 (en) * | 2001-08-30 | 2005-01-11 | Teva Pharmaceutical Industries Ltd. | Sulfonation method for zonisamide intermediate in zonisamide synthesis and their novel crystal forms |
| ZA200304880B (en) * | 2003-02-24 | 2004-05-04 | Air Liquide | Integrated heat recovery systems and methods for increasing the efficiency of an oxygen-fired furnace. |
| US7210467B2 (en) * | 2004-06-22 | 2007-05-01 | Gas Technology Institute | Advanced high efficiency, ultra-low emission, thermochemically recuperated reciprocating internal combustion engine |
| WO2006029479A1 (en) * | 2004-09-17 | 2006-03-23 | John Burton | Biocidal treatment device |
| CN1869165B (zh) * | 2005-05-23 | 2010-04-28 | 中国科学院工程热物理研究所 | 双燃料重整多功能能源系统及方法 |
| US7293533B2 (en) * | 2005-08-08 | 2007-11-13 | Utilization Technology Development, Nfp | Recuperative reforming reactor |
| CN100386565C (zh) * | 2006-03-24 | 2008-05-07 | 清华大学 | 一种加氢贫燃预混燃烧装置 |
| US20080016768A1 (en) | 2006-07-18 | 2008-01-24 | Togna Keith A | Chemically-modified mixed fuels, methods of production and used thereof |
| US7870717B2 (en) * | 2006-09-14 | 2011-01-18 | Honeywell International Inc. | Advanced hydrogen auxiliary power unit |
| US20080155984A1 (en) * | 2007-01-03 | 2008-07-03 | Ke Liu | Reforming system for combined cycle plant with partial CO2 capture |
| CN102016411B (zh) * | 2007-03-22 | 2016-03-16 | 努特-艾瑞克森公司 | 高效给水加热器 |
| US20090011290A1 (en) * | 2007-07-05 | 2009-01-08 | Gas Technology Institute | Method and apparatus for thermochemical recuperation with partial heat recovery of the sensible heat present in products of combustion |
| US7861511B2 (en) * | 2007-10-30 | 2011-01-04 | General Electric Company | System for recirculating the exhaust of a turbomachine |
| US8056318B2 (en) * | 2007-11-08 | 2011-11-15 | General Electric Company | System for reducing the sulfur oxides emissions generated by a turbomachine |
| US7874141B2 (en) * | 2007-11-16 | 2011-01-25 | General Electric Company | Auxiliary fluid source for an EGR purge system |
| US8534073B2 (en) | 2008-10-27 | 2013-09-17 | General Electric Company | System and method for heating a fuel using an exhaust gas recirculation system |
| US7926256B2 (en) | 2008-10-27 | 2011-04-19 | General Electric Company | Inlet system for an EGR system |
| US20110146282A1 (en) * | 2009-12-18 | 2011-06-23 | General Electric Company | System and method for reducing sulfur compounds within fuel stream for turbomachine |
| JP5610950B2 (ja) * | 2010-09-22 | 2014-10-22 | 株式会社日本製鋼所 | 排熱エネルギー回収システム |
| US8755916B2 (en) * | 2010-12-07 | 2014-06-17 | Alstom Technology Ltd. | Optimized integrated controls for oxy-fuel combustion power plant |
| CN103765986B (zh) | 2011-08-04 | 2017-03-29 | S·L·坎宁安 | 等离子电弧炉和应用 |
| CN102562314B (zh) * | 2012-01-11 | 2013-12-18 | 哈尔滨工程大学 | 基于等离子催化的化学回热循环燃气轮机装置 |
| JP5998043B2 (ja) * | 2012-12-26 | 2016-09-28 | 株式会社日立製作所 | エンジンコンバインドシステム |
| US20140260203A1 (en) * | 2013-03-14 | 2014-09-18 | Cummins Ip, Inc. | Gaseous Fuel Spark-Ignited Internal Combustion Engine System |
| RU2524317C1 (ru) * | 2013-03-27 | 2014-07-27 | Геннадий Павлович Барчан | Способ преобразования энергии с регенерацией энергоносителей в циклическом процессе теплового двигателя |
| JP6183759B2 (ja) | 2013-04-22 | 2017-08-23 | パナソニックＩｐマネジメント株式会社 | 熱電併給システム |
| CA2947606A1 (en) | 2014-05-09 | 2015-11-12 | Stephen L. Cunningham | Arc furnace smeltering system & method |
| ES2763844T3 (es) * | 2015-02-19 | 2020-06-01 | Fpt Motorenforschung Ag | Motor de combustión provisto de un sistema de recuperación de calor residual |
| ES2802287T3 (es) * | 2015-02-19 | 2021-01-18 | Fpt Motorenforschung Ag | Motor de combustión dotado de un sistema de recuperación del calor residual |
| US10458712B2 (en) | 2015-08-28 | 2019-10-29 | Praxair Technology, Inc. | Thermochemical regeneration with oxidant preheating |
| KR101946491B1 (ko) * | 2016-12-23 | 2019-02-11 | 한국에너지기술연구원 | 리큐퍼레이터를 이용한 스팀 생산 히트펌프 시스템 |
| WO2018131051A1 (en) * | 2017-01-11 | 2018-07-19 | Mahesh Lakshminarayanan | Combined-cycle power generation thermodynamic system |
| US10584052B2 (en) | 2017-01-27 | 2020-03-10 | American Air Liquide, Inc. | Enhanced waste heat recovery using a pre-reformer combined with oxygen and fuel pre-heating for combustion |
| US11313252B2 (en) * | 2018-10-02 | 2022-04-26 | Nooter/Eriksen, Inc. | Enhanced HRSG for repowering a coal-fired electrical generating plant |
| US11679977B2 (en) * | 2021-09-22 | 2023-06-20 | Saudi Arabian Oil Company | Integration of power generation with methane reforming |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4185456A (en) | 1976-07-02 | 1980-01-29 | Cummings Donald Ray | Providing energy from the combustion of methanol |
| JP2511866B2 (ja) * | 1986-02-07 | 1996-07-03 | 株式会社日立製作所 | 燃料電池発電システム及びその起動方法 |
| US5048284A (en) * | 1986-05-27 | 1991-09-17 | Imperial Chemical Industries Plc | Method of operating gas turbines with reformed fuel |
| NL8602404A (nl) | 1986-09-23 | 1988-04-18 | Veg Gasinstituut Nv | Werkwijze voor het uitvoeren van een gasverbrandingsproces, onder terugwinning van een gedeelte van in de verbrandingsgassen aanwezige warmte. |
| JPS63280825A (ja) | 1987-05-12 | 1988-11-17 | Agency Of Ind Science & Technol | メタノ−ル改質型ガスタ−ビンの運転方法 |
| US5669216A (en) | 1990-02-01 | 1997-09-23 | Mannesmann Aktiengesellschaft | Process and device for generating mechanical energy |
| US5394685A (en) * | 1990-11-14 | 1995-03-07 | United Technologies Corporation | Method and apparatus to enhance combustion rates and extend extinction limits in high speed propulsion units |
| JP3029884B2 (ja) | 1991-05-23 | 2000-04-10 | 三菱重工業株式会社 | 廃熱回収装置 |
| WO1995011376A1 (en) * | 1993-10-19 | 1995-04-27 | State Of California Energy Resources Conservation And Development Commission | Performance enhanced gas turbine powerplants |
| US5431007A (en) * | 1994-03-04 | 1995-07-11 | Westinghouse Elec Corp | Thermochemically recuperated and steam cooled gas turbine system |
| JPH07317505A (ja) | 1994-05-24 | 1995-12-05 | Mitsubishi Heavy Ind Ltd | コンバインド発電システム |
| US5513488A (en) | 1994-12-19 | 1996-05-07 | Foster Wheeler Development Corporation | Power process utilizing humidified combusted air to gas turbine |
| US5595059A (en) | 1995-03-02 | 1997-01-21 | Westingthouse Electric Corporation | Combined cycle power plant with thermochemical recuperation and flue gas recirculation |
| DK94695A (da) | 1995-08-23 | 1997-02-24 | Haldor Topsoe As | Fremgangsmåde til generering af elektrisk energi |
| US5664414A (en) | 1995-08-31 | 1997-09-09 | Ormat Industries Ltd. | Method of and apparatus for generating power |
| DE19612921A1 (de) | 1996-04-01 | 1997-10-02 | Asea Brown Boveri | Kraftwerksanlage und Verfahren zum Betrieb einer Kraftwerksanlage |
| US5896738A (en) * | 1997-04-07 | 1999-04-27 | Siemens Westinghouse Power Corporation | Thermal chemical recuperation method and system for use with gas turbine systems |
| DE69925052T2 (de) * | 1998-01-21 | 2006-03-02 | Haldor Topsoe A/S | Verfahren zur Herstellung von wasserstoffreichem Gas |
-
1999
- 1999-02-11 US US09/248,437 patent/US6223519B1/en not_active Expired - Fee Related
-
2000
- 2000-01-06 AT AT00902335T patent/ATE356921T1/de not_active IP Right Cessation
- 2000-01-06 AU AU24070/00A patent/AU754398B2/en not_active Ceased
- 2000-01-06 DE DE60033889T patent/DE60033889T2/de not_active Expired - Fee Related
- 2000-01-06 ID IDW20002050A patent/ID26952A/id unknown
- 2000-01-06 CN CN00800039A patent/CN1293735A/zh active Pending
- 2000-01-06 WO PCT/US2000/000253 patent/WO2000047874A1/en active IP Right Grant
- 2000-01-06 JP JP2000598753A patent/JP2002536587A/ja not_active Withdrawn
- 2000-01-06 KR KR1020007011285A patent/KR100656693B1/ko not_active IP Right Cessation
- 2000-01-06 EP EP00902335A patent/EP1071867B1/en not_active Expired - Lifetime
- 2000-09-27 ZA ZA200005201A patent/ZA200005201B/xx unknown
- 2000-10-11 NO NO20005114A patent/NO318511B1/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US6223519B1 (en) | 2001-05-01 |
| KR100656693B1 (ko) | 2006-12-13 |
| AU754398B2 (en) | 2002-11-14 |
| EP1071867A1 (en) | 2001-01-31 |
| NO20005114D0 (no) | 2000-10-11 |
| AU2407000A (en) | 2000-08-29 |
| EP1071867B1 (en) | 2007-03-14 |
| ATE356921T1 (de) | 2007-04-15 |
| ID26952A (id) | 2001-02-22 |
| DE60033889D1 (de) | 2007-04-26 |
| NO20005114L (no) | 2000-10-11 |
| KR20010042609A (ko) | 2001-05-25 |
| DE60033889T2 (de) | 2007-11-29 |
| JP2002536587A (ja) | 2002-10-29 |
| WO2000047874A1 (en) | 2000-08-17 |
| CN1293735A (zh) | 2001-05-02 |
| ZA200005201B (en) | 2001-04-03 |
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