NO309728B1 - Fremgangsmåte for genering av kobberpyrition in-situ i maling - Google Patents
Fremgangsmåte for genering av kobberpyrition in-situ i maling Download PDFInfo
- Publication number
- NO309728B1 NO309728B1 NO950850A NO950850A NO309728B1 NO 309728 B1 NO309728 B1 NO 309728B1 NO 950850 A NO950850 A NO 950850A NO 950850 A NO950850 A NO 950850A NO 309728 B1 NO309728 B1 NO 309728B1
- Authority
- NO
- Norway
- Prior art keywords
- paint
- pyrithione
- copper
- oxide
- weight
- Prior art date
Links
- 239000003973 paint Substances 0.000 title claims description 97
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims description 48
- 229910052802 copper Inorganic materials 0.000 title claims description 28
- 239000010949 copper Substances 0.000 title claims description 28
- 238000000034 method Methods 0.000 title claims description 20
- 238000011065 in-situ storage Methods 0.000 title claims description 15
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 title 1
- 229910052683 pyrite Inorganic materials 0.000 title 1
- 239000011028 pyrite Substances 0.000 title 1
- QHNCWVQDOPICKC-UHFFFAOYSA-N copper;1-hydroxypyridine-2-thione Chemical compound [Cu].ON1C=CC=CC1=S.ON1C=CC=CC1=S QHNCWVQDOPICKC-UHFFFAOYSA-N 0.000 claims description 42
- 239000000203 mixture Substances 0.000 claims description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 39
- 229960002026 pyrithione Drugs 0.000 claims description 38
- FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical compound [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 claims description 34
- -1 pyrithione compound Chemical class 0.000 claims description 32
- 239000002904 solvent Substances 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 12
- 239000003139 biocide Substances 0.000 claims description 11
- 230000003115 biocidal effect Effects 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- ZHDBTKPXEJDTTQ-UHFFFAOYSA-N dipyrithione Chemical class [O-][N+]1=CC=CC=C1SSC1=CC=CC=[N+]1[O-] ZHDBTKPXEJDTTQ-UHFFFAOYSA-N 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 230000008961 swelling Effects 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- YBBJKCMMCRQZMA-UHFFFAOYSA-N pyrithione Chemical class ON1C=CC=CC1=S YBBJKCMMCRQZMA-UHFFFAOYSA-N 0.000 claims description 4
- 239000005749 Copper compound Substances 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 150000001880 copper compounds Chemical class 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 239000003125 aqueous solvent Substances 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 229910001919 chlorite Inorganic materials 0.000 claims description 2
- 229910052619 chlorite group Inorganic materials 0.000 claims description 2
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 2
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 159000000003 magnesium salts Chemical class 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 2
- 229910052627 muscovite Inorganic materials 0.000 claims description 2
- 229920005615 natural polymer Polymers 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920001225 polyester resin Polymers 0.000 claims description 2
- 239000004645 polyester resin Substances 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920005749 polyurethane resin Polymers 0.000 claims description 2
- 229920001059 synthetic polymer Polymers 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000005751 Copper oxide Substances 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 229910000431 copper oxide Inorganic materials 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 238000009472 formulation Methods 0.000 description 21
- 229940043810 zinc pyrithione Drugs 0.000 description 10
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 10
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 230000001105 regulatory effect Effects 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000003373 anti-fouling effect Effects 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 4
- 235000019341 magnesium sulphate Nutrition 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- XNRNJIIJLOFJEK-UHFFFAOYSA-N sodium;1-oxidopyridine-2-thione Chemical compound [Na+].[O-]N1C=CC=CC1=S XNRNJIIJLOFJEK-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920000180 alkyd Polymers 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000004067 bulking agent Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000002808 molecular sieve Substances 0.000 description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 238000004566 IR spectroscopy Methods 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000005102 attenuated total reflection Methods 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011877 solvent mixture Substances 0.000 description 2
- YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 150000000180 1,2-diols Chemical class 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical class COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- 241001082241 Lythrum hyssopifolia Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229960004643 cupric oxide Drugs 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- ILVXOBCQQYKLDS-UHFFFAOYSA-N pyridine N-oxide Chemical compound [O-][N+]1=CC=CC=C1 ILVXOBCQQYKLDS-UHFFFAOYSA-N 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Conductive Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/940,555 US5246489A (en) | 1992-09-04 | 1992-09-04 | Process for generating copper pyrithione in-situ in a paint formulation |
| US08/024,021 US5238490A (en) | 1992-09-04 | 1993-03-01 | Process for generating copper pyrithione in-situ in a paint formulation |
| PCT/US1993/007619 WO1994005734A1 (en) | 1992-09-04 | 1993-08-16 | Process for generating copper pyrithione in-situ in paint |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO950850D0 NO950850D0 (no) | 1995-03-03 |
| NO950850L NO950850L (no) | 1995-03-03 |
| NO309728B1 true NO309728B1 (no) | 2001-03-19 |
Family
ID=26697924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO950850A NO309728B1 (no) | 1992-09-04 | 1995-03-03 | Fremgangsmåte for genering av kobberpyrition in-situ i maling |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5238490A (de) |
| EP (1) | EP0658180B1 (de) |
| JP (1) | JP2873092B2 (de) |
| KR (1) | KR100273069B1 (de) |
| AU (1) | AU4807093A (de) |
| DE (1) | DE69321847T2 (de) |
| DK (1) | DK0658180T3 (de) |
| ES (1) | ES2124319T3 (de) |
| NO (1) | NO309728B1 (de) |
| SG (1) | SG73366A1 (de) |
| WO (1) | WO1994005734A1 (de) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK0677088T3 (da) * | 1993-01-04 | 2000-01-03 | Olin Corp | Gelfri maling indeholdende kuprooxid plus 2,2'-dithiobis(pyridin-1-oxid) forbindelse |
| US5342437A (en) * | 1993-10-15 | 1994-08-30 | Olin Corporation | Gel-free paint containing zinc pyrithione cuprous oxide and carboxylic acid |
| US5540860A (en) * | 1994-02-28 | 1996-07-30 | Olin Corporation | Process for preparing copper pyrithione |
| US5518774A (en) * | 1995-06-26 | 1996-05-21 | Olin Corporation | In-can and dry coating antimicrobial |
| US7942958B1 (en) * | 1998-07-22 | 2011-05-17 | Arch Chemicals, Inc. | Composite biocidal particles |
| KR100679497B1 (ko) * | 1999-03-17 | 2007-02-07 | 가부시키가이샤 에이피아이 코포레이션 | 코팅된 비스(2-피리딘티올-1-옥시드) 구리염 |
| US7455851B1 (en) * | 1999-06-25 | 2008-11-25 | Arch Chemicals, Inc. | Pyrithione biocides enhanced by silver, copper, or zinc ions |
| US6627665B2 (en) | 2001-09-28 | 2003-09-30 | Arch Chemicals, Inc. | Non-dusting copper pyrithione dispersion |
| US6821326B2 (en) | 2002-12-20 | 2004-11-23 | Arch Chemicals, Inc. | Small particle copper pyrithione |
| US7481873B2 (en) * | 2002-12-20 | 2009-01-27 | Arch Chemicals, Inc. | Small particle copper pyrithione |
| JP4629311B2 (ja) * | 2003-01-21 | 2011-02-09 | 株式会社エーピーアイ コーポレーション | 金属ピリチオンの油性分散組成物 |
| CN100372890C (zh) * | 2005-08-10 | 2008-03-05 | 北京玻钢院复合材料有限公司 | 不饱和聚酯/聚氨酯/有机蒙脱土复合材料及其制备方法 |
| CN1324084C (zh) * | 2005-10-09 | 2007-07-04 | 华东理工大学 | Pa/pet高分子合金材料 |
| US7893047B2 (en) * | 2006-03-03 | 2011-02-22 | Arch Chemicals, Inc. | Biocide composition comprising pyrithione and pyrrole derivatives |
| DE102009017677A1 (de) * | 2009-04-16 | 2010-10-21 | Sarastro Gmbh | Verfahren zum Herstellen eines Stoffs mit einstellbaren biologisch aktiven Gradienteneigenschaften und derartiger Stoff |
| EP2275466A1 (de) * | 2009-07-16 | 2011-01-19 | Bayer MaterialScience AG | Polyharnstoff-basierter Gewebekleber |
| US8541493B2 (en) * | 2010-02-19 | 2013-09-24 | Arch Chemicals, Inc. | Synthesis of zinc acrylate copolymer from acid functional copolymer, zinc pyrithione, and copper compound |
| CN103841831B (zh) * | 2011-08-17 | 2017-02-15 | 奥麒化工股份有限公司 | 由巯氧吡啶锌和铜化合物合成巯氧吡啶铜 |
| CN104114029A (zh) * | 2011-12-16 | 2014-10-22 | 泰克帝铜制品公司 | 包含至少一种铜盐和至少一种锌盐的活性粉末杀菌组合物和制备其的方法 |
| EP3910032B1 (de) | 2016-07-19 | 2023-07-12 | Behr Process Corporation | Antimikrobielle lackzusammensetzung und zugehörige verfahren |
| JP2017081956A (ja) * | 2016-12-20 | 2017-05-18 | テキスティル コッパー アンディノ エス．エー． | 少なくとも１種の銅塩及び少なくとも１種の亜鉛塩を含む活性パウダー体殺菌剤及びその製造方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NO128713B (de) * | 1967-07-03 | 1974-01-02 | Takeda Chemical Industries Ltd | |
| FR2190364B1 (de) * | 1972-07-04 | 1975-06-13 | Patru Marcel | |
| JPS59108066A (ja) * | 1982-11-08 | 1984-06-22 | インタ−ナシヨナル・ペイント・パブリツク・リミテイド・カンパニ− | 船舶用防汚塗料 |
| US4581351A (en) * | 1982-11-23 | 1986-04-08 | Sutton Laboratories, Inc. | Composition of matter containing imidazolidinyl urea and pyrithione and its derivatives |
| JPH0667975B2 (ja) * | 1986-11-17 | 1994-08-31 | 日本ペイント株式会社 | 金属含有塗料用樹脂の製造方法 |
| GB9006318D0 (en) * | 1990-03-21 | 1990-05-16 | Courtaulds Coatings Ltd | Coating compositions |
| US5057153A (en) * | 1990-05-03 | 1991-10-15 | Olin Corporation | Paint containing high levels of a pyrithione salt plus a copper salt |
| US5112397A (en) * | 1991-06-17 | 1992-05-12 | Olin Corporation | Process for stabilizing zinc pyrithione plus cuprous oxide in paint |
| US5098473A (en) * | 1991-03-04 | 1992-03-24 | Olin Corporation | Process for stabilizing zinc pyrithione plus cuprous oxide in paint |
| US5137569A (en) * | 1991-10-10 | 1992-08-11 | Olin Corporation | Process for stabilizing zinc pyrithione plus cuprous oxide in paint |
| US5185033A (en) * | 1992-09-01 | 1993-02-09 | Olin Corporation | Gel-free paint containing copper pyrithione or pyrithione disulfide plus cuprous oxide |
-
1993
- 1993-03-01 US US08/024,021 patent/US5238490A/en not_active Expired - Lifetime
- 1993-08-16 SG SG1996001738A patent/SG73366A1/en unknown
- 1993-08-16 KR KR1019950700846A patent/KR100273069B1/ko not_active IP Right Cessation
- 1993-08-16 ES ES93918730T patent/ES2124319T3/es not_active Expired - Lifetime
- 1993-08-16 DE DE69321847T patent/DE69321847T2/de not_active Expired - Lifetime
- 1993-08-16 DK DK93918730T patent/DK0658180T3/da active
- 1993-08-16 WO PCT/US1993/007619 patent/WO1994005734A1/en active IP Right Grant
- 1993-08-16 EP EP93918730A patent/EP0658180B1/de not_active Expired - Lifetime
- 1993-08-16 AU AU48070/93A patent/AU4807093A/en not_active Abandoned
- 1993-08-16 JP JP6507204A patent/JP2873092B2/ja not_active Expired - Fee Related
-
1995
- 1995-03-03 NO NO950850A patent/NO309728B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR100273069B1 (ko) | 2001-01-15 |
| JP2873092B2 (ja) | 1999-03-24 |
| ES2124319T3 (es) | 1999-02-01 |
| EP0658180A1 (de) | 1995-06-21 |
| NO950850D0 (no) | 1995-03-03 |
| SG73366A1 (en) | 2000-10-24 |
| JPH08501334A (ja) | 1996-02-13 |
| DE69321847D1 (de) | 1998-12-03 |
| EP0658180B1 (de) | 1998-10-28 |
| EP0658180A4 (de) | 1996-01-31 |
| KR950703033A (ko) | 1995-08-23 |
| US5238490A (en) | 1993-08-24 |
| NO950850L (no) | 1995-03-03 |
| DE69321847T2 (de) | 1999-06-10 |
| AU4807093A (en) | 1994-03-29 |
| WO1994005734A1 (en) | 1994-03-17 |
| DK0658180T3 (da) | 1999-07-12 |
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| MM1K | Lapsed by not paying the annual fees |