NL8020447A - ADDITIVES OR COMPOSITIONS FOR PETROL AND DIESEL FUELS TO INCREASE THE FLASH POINT. - Google Patents

ADDITIVES OR COMPOSITIONS FOR PETROL AND DIESEL FUELS TO INCREASE THE FLASH POINT. Download PDF

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NL8020447A
NL8020447A NL8020447A NL8020447A NL8020447A NL 8020447 A NL8020447 A NL 8020447A NL 8020447 A NL8020447 A NL 8020447A NL 8020447 A NL8020447 A NL 8020447A NL 8020447 A NL8020447 A NL 8020447A
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flash point
primene
nitrobenzene
kerosene
butanol
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NL8020447A
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Dutch (nl)
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Xrg Int Inc
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1208—Inorganic compounds elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1275—Inorganic compounds sulfur, tellurium, selenium containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1608—Well defined compounds, e.g. hexane, benzene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00—Engines characterised by air compression and subsequent fuel addition
    • F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition

Description

P & c S 5935-2 PCT/Ned elz/yh 80 2 04 4 7P & c S 5935-2 PCT / Ned elz / yh 80 2 04 4 7

Toevoegsels of samenstellingen voor benzine en dieselbrandstoffen ter verhoging van het ontvlammingspunt.Additives or compositions for petrol and diesel fuels to increase the flash point.

De onderhavige uitvinding heeft betrekking op twee samenstellingen, die geschikt zijn voor het verhogen van het ontvlammingspunt van (a) 5 dieselbrandstoffen en (b) benzine. In elk van deze gevallen verhoogt toepassing van een dosis hoeveelheid van het toevoegsel het ontvlammingspunt van het verkregen mengsel met ca. 6°C tot 29°C. Dit bevrijdt de gebruiker in feite van strikte wettelijke voorschriften en maakt het mogelijk de mengsels toe te passen bij locaal verkeer en verkeer tussen de staten.The present invention relates to two compositions suitable for increasing the flash point of (a) 5 diesel fuels and (b) gasoline. In either case, using a dose amount of the additive increases the flash point of the resulting mixture by about 6 ° C to 29 ° C. This basically frees the user from strict legal regulations and allows the mixtures to be applied to local and interstate traffic.

10 Een dosering van het toevoegsel voor brandstoffen ligt in het trajekt van 1:1000 tot 1:2000, waarbij een voorkeursdosis ca. 1:1600 volume dln. bedraagt.A dosage of the fuel additive ranges from 1: 1000 to 1: 2000, with a preferred dose of about 1: 1600 parts by volume. amounts.

Het ontvlammingspunt van een brandstof geeft de temperatuur aan, waar beneden hij zonder brandgevaar gehanteerd kan worden. Dit is de temperatuur, ; 15 waarop de brandstof verwarmd moet worden om voldoende brandstofdampen ;boven het oppervlak van de vloeibare brandstof te vormen om ontsteking te :doen plaatshebben bij aanwezigheid van een open vlam.The flash point of a fuel indicates the temperature below which it can be handled without risk of fire. This is the temperature,; 15 on which the fuel must be heated to form sufficient fuel vapors above the surface of the liquid fuel to ignite in the presence of an open flame.

; Bespreking van de stand der techniek.; Discussion of the prior art.

Van belang voor wat betreft gepubliceerde octrooischriften zijn drie 20 octrooischriften van Dr. Harry M. Webb, overgedragen aan XRG International,Regarding published patents, three patents of Dr. Harry M. Webb, transferred to XRG International,

Ine. Deze groep van octrooischriften, namelijk O.SY 4.099.930, U.S.Ine. This group of patents, namely O.SY 4,099,930, U.S. Pat.

4.129,421 en U.S. 4.145.190 past ferrosulfaat toe in kombinatie met I pricrinezuur en omvat ook water in het oplösmiddelmilieu. De onderhavige toevoegsels zijn gebaseerd op koper (II). carbonaat-hydroxide en elemen-25 tair ijzer, samen met pricrinezüur. Bovendien openbaart U.S. 1.669.181 , ikoper- en ijzerzouten in een brandstof voor een motor met inwendige verbranding. Verwant met deze aanvrage is een oudere aanvrage, ingediend onder het Octrooi-Samenwerkihgsverdrag, No. "U.S.'.'80/01509, ingediend , 12 november 1980.4,129,421 and U.S. Pat. 4,145,190 uses ferrous sulfate in combination with pricric acid and also includes water in the solvent medium. The present additives are based on copper (II). carbonate hydroxide and elemental iron, along with pricinic acid. In addition, U.S. 1,669,181, copper and iron salts in a fuel for an internal combustion engine. Related to this application is an older application filed under the Patent Cooperation Treaty, No. "U.S." 80/01509, filed Nov. 12, 1980.

i 30 In het geval van een mengsel voor verhoging van het ontvlammingspunt, ! 1 ; bestemd voor dieselbrandstof wordt het trajekt en een voorkeurssamenstelling hieronder gegeven.i 30 In the case of a mixture for raising the flash point,! 1; for diesel fuel, the range and a preferred composition is given below.

Trajekt.. Voorkeur i i ---· ΓΙ- - -n-n»Trajekt .. Preference i i --- · ΓΙ- - -n-n »

Elementair ijzer 0,01. - 0,03% 0,01% 35 Methyl-isobutylketon 3 - 7% 5,0%Elemental iron 0.01. - 0.03% 0.01% 35 Methyl isobutyl ketone 3 - 7% 5.0%

Picrinezuur 1 — 2% 1,5% j . ft',butanol 20 - 30% '20,0%Picric acid 1 - 2% 1.5% j. ft ', butanol 20 - 30%' 20, 0%

Keroseen 75 - 59% 73,0% | Nitrobenzeen '0,.05 - 0,1.1% - .0,08% ψ9 ^ Y- i40 i Primeen 8lR 0,1 - 0,2 % 0,05% j —.-.«xw· λ λ o λ / / Ί -9JUU982Kerosene 75 - 59% 73.0% | Nitrobenzene '0.05 - 0.1.1% - 0.08% ψ9 ^ Y- i40 i Primene 8lR 0.1 - 0.2% 0.05% j —.-. «Xw · λ λ o λ / / Ί -9JUU982

8020447 I8020447 I

0M0221.C0M0221.C

.-2-.-2-

Opgemerkt wordt, dat het van belang is bij het dieselpreparaat, dat de belangrijkste elementen elementair ijzer en picrinezuur zijn.It is noted that it is important in the diesel formulation that the major elements are elemental iron and picric acid.

De samenstelling voor het middel voor de verhoging van het ontvlammingspunt voor benzine wordt hieronder gegeven: 5 Traj ekt VoorkeurThe composition for the gasoline flash point enhancer is given below: 5 Range Preferred

Koper carbonaat-hydroxide 0,01-0,03% 0,02%Copper carbonate hydroxide 0.01-0.03% 0.02%

Methyl-isobutylketon 3 - 7% 5,0 % in.butanol 20 - 30% 20,0 %Methyl isobutyl ketone 3 - 7% 5.0% in. Butanol 20 - 30% 20.0%

Keroséen 75 - 59% 73,0 % ! 10 Picrinezuur 1-2% 1,5 %Kerosene 75 - 59% 73.0%! 10 Picric acid 1-2% 1.5%

Nitrobenzeen 0,05 - 0,11% 0,08%Nitrobenzene 0.05 - 0.11% 0.08%

Primeen 81R 0,1 - 0,2 % 0,05%Primene 81R 0.1 - 0.2% 0.05%

Opgemerkt wordt, dat in deze samenstelling voor benzine met een hoog ontvlammingspunt de belangrijkste bestanddelen kopercarbonaat-hydroxide 15 en picrinezuur zijn. Voor doeleinden van oplosbaarheid kan naast de bovenstaande komponenten koperacetaat worden toegepast in hoeveelheden van 0,01 - 0,05%.It should be noted that in this high flash point gasoline formulation, the major ingredients are copper carbonate hydroxide and picric acid. For solubility purposes, in addition to the above components, copper acetate may be used in amounts of 0.01-0.05%.

De bestanddelenThe ingredients

Picrinezuur. Dit trinitrofenol werkt synergistisch met het elementaire 20 ijzer of kopercarbonaat-hydroxide onder vorming van de aktieve komponent van de uitvinding.Picric acid. This trinitrophenol acts synergistically with the elemental iron or copper carbonate hydroxide to form the active component of the invention.

Keroseen. Dit is een mengsel van alifatische koolwaterstoffen met een kookpunt van 19° - 59°C (150° - 280°F).Kerosene. This is a mixture of aliphatic hydrocarbons with a boiling point of 150 ° - 280 ° F (19 ° - 59 ° C).

De alcoholische oplosmiddelen. Men gebruikt hier n.butanol in de 25 opgegeven samenstelling om een hoog ontvlammingspunt te verkrijgen.The alcoholic solvents. N-butanol in the specified composition is used here to obtain a high flash point.

Nitrobenzeen. Deze verbinding wordt toegepast als een verder oplosmiddel. Hij is mengbaar met alkanolen en is een bijzonder goed organisch oplosmiddel voor het picrinezuur.Nitrobenzene. This compound is used as a further solvent. It is miscible with alkanols and is a particularly good organic solvent for the picric acid.

Primeen. Primenen zijn tertiaire alkylaminen, die een kruising zijn 30 van primaire alifatische aminen met de algemene formule (R^)(R^)CNH^ waarbij de aminogroep gebonden is aan een tertiair koolstofatoom. De volgens de onderhavige uitvinding gebruikte aminen zijn Primeen 81R en Primeen JM-T, waarbij de 81R de voorkeur verdient. Deze aminen zijn anti-Oxidantia en stabiliseermiddelen voor brandstofoliën en straalbrandstoffen; 35 ; Koperacetaat. Dit bestanddeel is bekend als koper (II)acetaat en het ' jis geschikt als katalysator bij polymerisatieprocessen.Primene. Primenes are tertiary alkylamines, which are a cross of primary aliphatic amines of the general formula (R ^) (R ^) CNH ^ where the amino group is bonded to a tertiary carbon atom. The amines used in the present invention are Primene 81R and Primene JM-T, the 81R being preferred. These amines are anti-oxidants and stabilizers for fuel oils and jet fuels; 35; Copper acetate. This component is known as copper (II) acetate and is suitable as a catalyst in polymerization processes.

| Koper carbonaat-hydroxide. Dit is ook bekend als groen basisch koper- carbonaat, dat in de natuur voorkomt als het mineraal malachiet.| Copper carbonate hydroxide. This is also known as green basic copper carbonate, which occurs naturally as the mineral malachite.

Ketonen. Methyl-isobutylketon wordt gebruikt en het is een laag j ; | 8 02 0 447............ ..............................................................Ketones. Methyl isobutyl ketone is used and it is a layer j; | 8 02 0 447 ............ .................................. ............................

0I40?.?.LC0I40?.?. LC

- 3 - keton, dat geschikt is als oplosmiddel.- 3 - ketone, which is suitable as a solvent.

Ijzer. Bij voorkeur gebruikt men ijzerpoeder voor de dieselbrandstof met hoog ontvlammingspunt volgens de uitvinding.Iron. Iron powder for the high flashpoint diesel fuel according to the invention is preferably used.

VOORBEELD IEXAMPLE I

5 Bereiding van dieselsamenstelling met hoog ontvlammingspunt.5 Preparation of high flash point diesel fuel composition.

Methylisobutylketon 4,0%Methyl isobutyl ketone 4.0%

Picrinezuur 1,5% h.butanol 20,0% IJzer (elementair; poeder) 0,01% 10' Keroseen 73,36%Picric acid 1.5% h.butanol 20.0% Iron (elemental; powder) 0.01% 10 'Kerosene 73.36%

Nitrobenzeen 0,08%Nitrobenzene 0.08%

Primeen 81R 0,05%Primene 81R 0.05%

Men lost het picrinezuur op in het methyl-isobutylketon; men voegt ;de h.butanol aan het elementaire ijzer toe. De reaktietijd, waarbij geroerd 15 wordt, bedraagt 24 uren. Men voegt het keroseen, het nitrobenzeen en het primeen toe.The picric acid is dissolved in the methyl isobutyl ketone; the h-butanol is added to the elemental iron. The reaction time, with stirring, is 24 hours. Kerosene, nitrobenzene and primene are added.

VOORBEELD IIEXAMPLE II

Bereiding van toevoegsel voor benzine met hoog ontvlammingspunt.Preparation of High Flash Point Gasoline Additive.

Methyl-isobutylketon 5,0% 20 n.butanol 20,0%Methyl Isobutyl Ketone 5.0% 20 n.butanol 20.0%

Kopercarbonaat 0,02% ·Copper carbonate 0.02%

Picrinezuur 1,54%Picric acid 1.54%

Keroseen 73,0%Kerosene 73.0%

Primeen 81R 0,05% ; 25; Nitrobenzeen 0,08% iPrimene 81R 0.05%; 25; Nitrobenzene 0.08% i

De komponenten worden op overeenkomstige wijze gemengd als hier-| boven in voorbeeld I.The components are mixed in a similar manner as above above in example I.

VOORBEELD IIIEXAMPLE III

Men gebruikte een zelfde samenstelling ials in voorbeeld 2, maar 30 voegde ca. 0,01 - 0,05% koperacetaat toe.The same composition was used in Example 2, but 30 added about 0.01-0.05% copper acetate.

! ; ! i i ; i j i _ ! j 8020447 0140221.0! ; ! i i; i j i _! j 8020447 0140221.0

Claims (6)

1. Middel voor verhoging van het ontvlammingspunt van benzine, bevattende elementair ijzer, methyl-isobutylketon, picrinezuur, n.butanol, keroseen, nitrobenzeen en Primeen. 5 1 2. Dieseltoevoegsel voor verhoging van het ontvlammingspunt, bevattende het volgende: Elementair ijzer 0,01 - 0,03% Methyl-isobutylketon 3-7% Picrinezuur 1-2% 10. n.butanol 20 - 30% Keroseen 75 - 59% Nitrobenzeen 0,05 - 0,11% Primeen 81R 0,1 - 0,2 %1. Agent for increasing the flash point of gasoline, containing elemental iron, methyl isobutyl ketone, picric acid, n-butanol, kerosene, nitrobenzene and Primene. 5 1 2. Diesel additive for flash point elevation containing the following: Iron Elemental 0.01 - 0.03% Methyl Isobutyl Ketone 3-7% Picric Acid 1-2% 10. n.butanol 20 - 30% Kerosene 75 - 59 % Nitrobenzene 0.05 - 0.11% Primene 81R 0.1 - 0.2% 3. Toevoegsel volgens conclusie 2, waarbij de gebruikte samenstelling 15 als volgt is: Elementair ijzer 0,01% Methyl-isobutylketon 5,0 % Picrinezuur 1,5 % n.butanol 20,0 %Additive according to claim 2, wherein the composition used is as follows: Elemental iron 0.01% Methyl isobutyl ketone 5.0% Picric acid 1.5% n.butanol 20.0% 20 Keroseen 73,0 % Nitrobenzeen 0,)08% Primeen 81R 0,05%20 Kerosene 73.0% Nitrobenzene 0.008% Primene 81R 0.05% 4. Toevoegsel voor benzine met hoog ontvlammingspunt, bevattende: Koper carbonaat-hydroxide 0,01 - 0,03% ;25 ; Methyl-isobutylketon 3 - 7 % n.butanol 20 -30 % Keroseen 75 -59 % Picrinezuur 1 - 2 % ! Nitrobenzeen 0,05-0,11% |30 . Primeen 81R 0,1 - 0,2 %4. High flash point gasoline additive, containing: Copper carbonate hydroxide 0.01 - 0.03%; Methyl isobutyl ketone 3 - 7% n.butanol 20 -30% Kerosene 75 -59% Picric acid 1 - 2%! Nitrobenzene 0.05-0.11% | 30. Primene 81R 0.1 - 0.2% 5. Toevoegsel volgens conclusie 4, waarbij de gebruikte samenstelling als volgt is: ! Kopercarbonaat-hydroxide 0,02% ; Methyl-isobutylketon 5,0 % 35 n.butanol 20,0 % | Keroseen 73,0 % Picrinezuur 1,5% ; Nitrobenzeen 0,08% Primeen 81R 0,05% 8020447 01-!fr?2L C ** * 1 * - 5 -The additive of claim 4, wherein the composition used is as follows:! Copper carbonate hydroxide 0.02%; Methyl Isobutyl Ketone 5.0% 35 n.butanol 20.0% | Kerosene 73.0% Picric Acid 1.5%; Nitrobenzene 0.08% Primene 81R 0.05% 8020447 01-! Fr? 2L C ** * 1 * - 5 - 6. Toevoegsel volgens conclusie 4, waarbij voor oplosbaarheidsdoel-einden een hoeveelheid van 0,1 - 0,5% koperacetaat wordt toegevoegd. ! i i ! ! : . ; j ; 8020447 0U022LC i : |The additive of claim 4, wherein for solubility purposes, an amount of 0.1-0.5% copper acetate is added. ! i i! ! :. ; j; 8020447 0U022LC i: |
NL8020447A 1980-11-12 1980-11-17 ADDITIVES OR COMPOSITIONS FOR PETROL AND DIESEL FUELS TO INCREASE THE FLASH POINT. NL8020447A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US8001509 1980-11-12
PCT/US1980/001509 WO1982001717A1 (en) 1980-11-12 1980-11-12 Copper catalyst for fuels

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NL8020447A true NL8020447A (en) 1982-10-01

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NL8020472A NL8020472A (en) 1980-11-12 1980-11-12 COPPER FUEL CATALYST.
NL8020447A NL8020447A (en) 1980-11-12 1980-11-17 ADDITIVES OR COMPOSITIONS FOR PETROL AND DIESEL FUELS TO INCREASE THE FLASH POINT.

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GB2280200B (en) * 1993-06-28 1997-08-06 Exonflame Limited Fuel oil additives
GB2330149A (en) * 1997-10-10 1999-04-14 Sayed Ahmed Fuel additive for the reduction of post-combustion pollutants
CN1896197B (en) * 2006-06-26 2011-04-06 于涛 Methanol modified mixer
USD862834S1 (en) 2016-06-27 2019-10-15 Mondelez Europe Gmbh Cracker
USD879408S1 (en) 2016-06-06 2020-03-31 Mondelez Europe Gmbh Cracker
USD887666S1 (en) 2017-05-19 2020-06-23 Generale Biscuit Food bar

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EP0064494A4 (en) 1983-03-15
JPS57501854A (en) 1982-10-14
WO1982001717A1 (en) 1982-05-27
JPS57501853A (en) 1982-10-14
EP0064974A4 (en) 1983-03-15
GB2099774A (en) 1982-12-15
NL8020472A (en) 1982-10-01
EP0064974A1 (en) 1982-11-24
AU6645781A (en) 1982-06-07
WO1982001718A1 (en) 1982-05-27
EP0064494A1 (en) 1982-11-17
DE3050641A1 (en) 1982-12-30
GB2099850A (en) 1982-12-15
BR8009120A (en) 1982-10-13

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