US1820983A - Heavy oil fuel - Google Patents

Heavy oil fuel Download PDF

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Publication number
US1820983A
US1820983A US88482A US8848226A US1820983A US 1820983 A US1820983 A US 1820983A US 88482 A US88482 A US 88482A US 8848226 A US8848226 A US 8848226A US 1820983 A US1820983 A US 1820983A
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US
United States
Prior art keywords
fuel
heavy oil
oil fuel
oil
diesel
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US88482A
Inventor
Nathaniel E Loomis
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Standard Oil Development Co
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Standard Oil Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Development Co filed Critical Standard Oil Development Co
Priority to US88482A priority Critical patent/US1820983A/en
Application granted granted Critical
Publication of US1820983A publication Critical patent/US1820983A/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites

Definitions

  • I O Y TlllS lnventlon relatesto improvements 1n fuels for internal-combustion engines of the type in which a combustiblematerial is in-' 'troduced into a mass of highly compressed and heated air.
  • the invention has particular (reference to fuels for engines of the Diesel type, and will be described for illus-. tration in this connection.
  • acomponent adapted to secure substantially instantaneous and continuous ignition is added to Diesel fuel.
  • Such component is preferably an organic compound containing nitrogen and oxygen.
  • Nitro compounds such as the alkyl esters ofnitrous acid, are particularly suitable, for example isopropyl nitrite, butylnitri'te and ethyl nitrite.
  • the group of nitroparaflins, isomericwith the alkyl nitrites just mentioned, are also suitable.
  • nitroethane and nitropentane may be used with good results
  • Some aryl nitro compounds, especially dinitrobenzene and trinitrobenzene may be used.
  • Compounds of greater complexity-containing the N 0 group also will serve my purpose, for
  • a common property of allthesubstances mentioned'aboye is the tendency to produce knockingordetonation when used as a component'o'f a gasoline fuel for internal-combustion engines.
  • Diesel diesel
  • these compounds are not knock-producing but have predominantly rather'the opposite effect. Their function is to causeinstantaneous, or substantially instantaneous and continuous ignition of the fuel as it is injected, thus avoiding the accumulation of a large amount, of unburnt fuel in the cylinder and resultant generation of excessive pressuresat the time of ignition.
  • One ormore of the members of the classes of compounds mentioned may be added. to Diesel fuel, especially heavy hydrocarbon oil fuels. In, general, a small amount of ignition-facilitating compound is s'ufiicient.
  • Diesel engines may be operated with a varities, and it is therefore lmpractical to give precise directions for each case.
  • the addition of 0.10% of isopropyl nitrite toi fuel oil of 20 to 32 B. may be specified.
  • a fuel oil for Diesel engines and the like, zind comprising a heavy petroleum oil containing an alkyl nitrite in effective amount not greater than 5% by volume.

Description

Patented Sept. 193i I UNITED-sures PATENT QFFICE NATHANIEL E. LOOMIS, or? WESTFIELD, NEW JEIisEY, ASSIGNOR .'ro STANDARD on. n DEVELOPMENT COMPANY, 'A CORPORATION or DELAWARE HEAVY on. FUEL No Drawing.
I O Y TlllS lnventlonrelatesto improvements 1n fuels for internal-combustion engines of the type in which a combustiblematerial is in-' 'troduced into a mass of highly compressed and heated air. The invention has particular (reference to fuels for engines of the Diesel type, and will be described for illus-. tration in this connection.
In accordance with the present invention, 1 acomponent adapted to secure substantially instantaneous and continuous ignition is added to Diesel fuel. Such component is preferably an organic compound containing nitrogen and oxygen. Nitro compounds, such as the alkyl esters ofnitrous acid, are particularly suitable, for example isopropyl nitrite, butylnitri'te and ethyl nitrite. The group of nitroparaflins, isomericwith the alkyl nitrites just mentioned, are also suitable. Thus, nitroethane and nitropentane .may be used with good results, Some aryl nitro compounds, especially dinitrobenzene and trinitrobenzene, may be used. Compounds of greater complexity-containing the N 0 group also will serve my purpose, for
example nitroso-isopropyl-para-toluidine.
A common property of allthesubstances mentioned'aboyeis the tendency to produce knockingordetonation when used as a component'o'f a gasoline fuel for internal-combustion engines. When used in a Diesel ,fuel, however, these compounds are not knock-producing but have predominantly rather'the opposite effect. Their function is to causeinstantaneous, or substantially instantaneous and continuous ignition of the fuel as it is injected, thus avoiding the accumulation of a large amount, of unburnt fuel in the cylinder and resultant generation of excessive pressuresat the time of ignition. One ormore of the members of the classes of compounds mentioned may be added. to Diesel fuel, especially heavy hydrocarbon oil fuels. In, general, a small amount of ignition-facilitating compound is s'ufiicient. When a highly effective compound, such as isopropy nitrite, is. used, amounts approxi-- mating 0.10% by volume of the oil W1ll give good results. Compounds of a lower degree 50 of effectiveness, such as dinitrobenzene, re-
ety of oils having widely rapid, or even explosive.
lppl ication filed February 15-, 1926. Serial No. 88,482.
quire tobe used in amounts up to about 5% of the volume of the oil. As is well known,
Diesel engines may be operated with a varities, and it is therefore lmpractical to give precise directions for each case. As one example of the use of the invention, the addition of 0.10% of isopropyl nitrite toi fuel oil of 20 to 32 B. may be specified.
For the proper operation of Diesel engines the fuel should be injected at such a rate that combustion takes place without substantial increase in the cylinder pressure. In practice, however, this desirable condition is not always obtained, due to the failure of the heavy hydro-carbon oil, or other fuel, to ignite as rapidly as it is injected. A considerable charge of fuel may accumulate inthe cylinder before ignition. When com-' bustioirdoes take place it is likely to be very.
The resulting sudden increase of pressure produces shocks that may be destructive to the engine. Even' where the violence of the action is not sufiiclent' to cause mechanical in ury, inefficient utilization of the'fuel results from thelack dilferent propermissible with the fuels heretofore known.
In this way the speed of the engine may be increased and greater horse-power obtained.
I The foregoing examples are-merely illustrative of preferred embodiments of the invention. Various changes may be made within the scope of the appended claims, in,
which it is m intention to claim all novelty inherent in the invention as broadly as the prior art permits.
I claim:
1. A fuel oil-for Diesel engines and the,
2. A fuel oil for Diesel engines and the like, zind comprising a heavy petroleum oil containing an alkyl nitrite in effective amount not greater than 5% by volume.
3. A fuel oil for Diesel engines and the like and comprising a heavy petroleum-oil containing isopropyl nitrite in amount about 0.10% by volume. NATHANIEL E. LOOMIS.
US88482A 1926-02-15 1926-02-15 Heavy oil fuel Expired - Lifetime US1820983A (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2433943A (en) * 1944-03-11 1948-01-06 Aerojet Engineering Corp Operation of jet propulsion motors with nitroparaffin
US2560439A (en) * 1947-02-14 1951-07-10 Borg Warner Liquid explosive consisting of a nitroparaffin and n-dodecane
US2584803A (en) * 1946-08-07 1952-02-05 Borg Warner Mono-fuel
US2645079A (en) * 1944-06-06 1953-07-14 Union Oil Co Method of operating jet propulsion motors
US2698511A (en) * 1949-03-21 1955-01-04 Phillips Petroleum Co Method of operating turbojet engines
US2815270A (en) * 1945-07-11 1957-12-03 Aerojet General Co Fuel
US4073626A (en) * 1974-04-18 1978-02-14 Ferrous Corporation Hydrocarbon fuel additive and process of improving hydrocarbon fuel combustion
US4099930A (en) * 1977-04-01 1978-07-11 Natural Resources Guardianship International, Inc. Catalytic fuel additive for gasoline and diesel engines
US4145190A (en) * 1977-06-24 1979-03-20 Natural Resources Guardianship International, Inc. Catalytic fuel additive for jet, gasoline, diesel, and bunker fuels
DE2759055A1 (en) * 1977-12-30 1979-07-12 Ferrous Corp Hydrocarbon fuels esp. diesel fuel with improved combustion - contg. iron salt of aromatic nitro acid and nitro-aliphatic cpd.
WO1982001717A1 (en) * 1980-11-12 1982-05-27 Hart Rien T Copper catalyst for fuels
US4561862A (en) * 1985-04-08 1985-12-31 Olin Corporation Use of selected beta-nitroalkenes as cetane number boosters for diesel fuel

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2433943A (en) * 1944-03-11 1948-01-06 Aerojet Engineering Corp Operation of jet propulsion motors with nitroparaffin
US2645079A (en) * 1944-06-06 1953-07-14 Union Oil Co Method of operating jet propulsion motors
US2815270A (en) * 1945-07-11 1957-12-03 Aerojet General Co Fuel
US2584803A (en) * 1946-08-07 1952-02-05 Borg Warner Mono-fuel
US2560439A (en) * 1947-02-14 1951-07-10 Borg Warner Liquid explosive consisting of a nitroparaffin and n-dodecane
US2698511A (en) * 1949-03-21 1955-01-04 Phillips Petroleum Co Method of operating turbojet engines
US4073626A (en) * 1974-04-18 1978-02-14 Ferrous Corporation Hydrocarbon fuel additive and process of improving hydrocarbon fuel combustion
US4099930A (en) * 1977-04-01 1978-07-11 Natural Resources Guardianship International, Inc. Catalytic fuel additive for gasoline and diesel engines
US4129421A (en) * 1977-04-01 1978-12-12 Natural Resources Guardianship International, Inc. Catalytic fuel additive for jet, gasoline, diesel, and bunker fuels
US4145190A (en) * 1977-06-24 1979-03-20 Natural Resources Guardianship International, Inc. Catalytic fuel additive for jet, gasoline, diesel, and bunker fuels
DE2759055A1 (en) * 1977-12-30 1979-07-12 Ferrous Corp Hydrocarbon fuels esp. diesel fuel with improved combustion - contg. iron salt of aromatic nitro acid and nitro-aliphatic cpd.
WO1982001717A1 (en) * 1980-11-12 1982-05-27 Hart Rien T Copper catalyst for fuels
WO1982001718A1 (en) * 1980-11-12 1982-05-27 Hart Rien T High flash points additives or compositions for gasoline and diesel fuels
US4561862A (en) * 1985-04-08 1985-12-31 Olin Corporation Use of selected beta-nitroalkenes as cetane number boosters for diesel fuel

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