NL7908980A - Werkwijze voor het bereiden van aceetaldehyde. - Google Patents
Werkwijze voor het bereiden van aceetaldehyde. Download PDFInfo
- Publication number
- NL7908980A NL7908980A NL7908980A NL7908980A NL7908980A NL 7908980 A NL7908980 A NL 7908980A NL 7908980 A NL7908980 A NL 7908980A NL 7908980 A NL7908980 A NL 7908980A NL 7908980 A NL7908980 A NL 7908980A
- Authority
- NL
- Netherlands
- Prior art keywords
- carbon monoxide
- hydrogen
- reaction
- reaction zone
- acetaldehyde
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 238000006243 chemical reaction Methods 0.000 claims description 62
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 54
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 33
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 33
- 239000003054 catalyst Substances 0.000 claims description 33
- 239000001257 hydrogen Substances 0.000 claims description 33
- 229910052739 hydrogen Inorganic materials 0.000 claims description 33
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 32
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- 238000000034 method Methods 0.000 claims description 24
- 238000009835 boiling Methods 0.000 claims description 21
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- 229910052740 iodine Inorganic materials 0.000 claims description 9
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 claims description 9
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- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 50
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 18
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- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- HBEQXAKJSGXAIQ-UHFFFAOYSA-N oxopalladium Chemical compound [Pd]=O HBEQXAKJSGXAIQ-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 229960003540 oxyquinoline Drugs 0.000 description 1
- 150000002941 palladium compounds Chemical class 0.000 description 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- INIOZDBICVTGEO-UHFFFAOYSA-L palladium(ii) bromide Chemical compound Br[Pd]Br INIOZDBICVTGEO-UHFFFAOYSA-L 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 1
- AAQTWUVTGGSLJG-UHFFFAOYSA-N phenyl-di(propan-2-yl)arsane Chemical compound CC(C)[As](C(C)C)C1=CC=CC=C1 AAQTWUVTGGSLJG-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 229940081066 picolinic acid Drugs 0.000 description 1
- 229920000307 polymer substrate Polymers 0.000 description 1
- 229920003053 polystyrene-divinylbenzene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- LOAUVZALPPNFOQ-UHFFFAOYSA-N quinaldic acid Chemical compound C1=CC=CC2=NC(C(=O)O)=CC=C21 LOAUVZALPPNFOQ-UHFFFAOYSA-N 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- RBEXEKTWBGMBDZ-UHFFFAOYSA-N tri(propan-2-yl)stibane Chemical compound CC(C)[Sb](C(C)C)C(C)C RBEXEKTWBGMBDZ-UHFFFAOYSA-N 0.000 description 1
- TYLYVJBCMQFRCB-UHFFFAOYSA-K trichlororhodium;trihydrate Chemical compound O.O.O.[Cl-].[Cl-].[Cl-].[Rh+3] TYLYVJBCMQFRCB-UHFFFAOYSA-K 0.000 description 1
- PMZLFYBZWYRRAZ-UHFFFAOYSA-N tricyclohexylarsane Chemical compound C1CCCCC1[As](C1CCCCC1)C1CCCCC1 PMZLFYBZWYRRAZ-UHFFFAOYSA-N 0.000 description 1
- WLPUWLXVBWGYMZ-UHFFFAOYSA-N tricyclohexylphosphine Chemical compound C1CCCCC1P(C1CCCCC1)C1CCCCC1 WLPUWLXVBWGYMZ-UHFFFAOYSA-N 0.000 description 1
- WWVNWQJKWKSDQM-UHFFFAOYSA-N triethylarsane Chemical compound CC[As](CC)CC WWVNWQJKWKSDQM-UHFFFAOYSA-N 0.000 description 1
- HVYVMSPIJIWUNA-UHFFFAOYSA-N triphenylstibine Chemical compound C1=CC=CC=C1[Sb](C=1C=CC=CC=1)C1=CC=CC=C1 HVYVMSPIJIWUNA-UHFFFAOYSA-N 0.000 description 1
- LDXFCCZPPSEDCI-UHFFFAOYSA-N tris(2-methylphenyl)stibane Chemical compound CC1=CC=CC=C1[Sb](C=1C(=CC=CC=1)C)C1=CC=CC=C1C LDXFCCZPPSEDCI-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US97429078A | 1978-12-29 | 1978-12-29 | |
| US97429078 | 1978-12-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL7908980A true NL7908980A (nl) | 1980-07-01 |
Family
ID=25521856
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL7908980A NL7908980A (nl) | 1978-12-29 | 1979-12-13 | Werkwijze voor het bereiden van aceetaldehyde. |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS5592335A (pt) |
| BE (1) | BE880941A (pt) |
| BR (1) | BR7908592A (pt) |
| DE (1) | DE2952517C2 (pt) |
| FR (1) | FR2445307A1 (pt) |
| GB (1) | GB2038829B (pt) |
| IT (1) | IT1214390B (pt) |
| MX (1) | MX152526A (pt) |
| NL (1) | NL7908980A (pt) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4302611A (en) * | 1978-12-29 | 1981-11-24 | Halcon Research & Development Corp. | Preparation of acetaldehyde |
| US4511741A (en) * | 1983-12-02 | 1985-04-16 | Union Carbide Corporation | Production of aldehydes from organic acid esters |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE426583B (sv) * | 1975-03-10 | 1983-01-31 | Halcon Res & Dev | Sett att framstella etylidenacetat |
| US5138093A (en) * | 1975-03-10 | 1992-08-11 | Eastman Kodak Company | Process for preparing ethylidene diacetate |
| DE2941232A1 (de) * | 1979-10-11 | 1981-04-23 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von 1,1-diacetoxiethan |
| YU43520B (en) * | 1981-10-09 | 1989-08-31 | Monsanto Co | Preparation of ethylidene diacetates |
-
1979
- 1979-12-13 NL NL7908980A patent/NL7908980A/nl not_active Application Discontinuation
- 1979-12-28 BE BE0/198805A patent/BE880941A/fr not_active IP Right Cessation
- 1979-12-28 IT IT7951232A patent/IT1214390B/it active
- 1979-12-28 DE DE2952517A patent/DE2952517C2/de not_active Expired
- 1979-12-28 BR BR7908592A patent/BR7908592A/pt unknown
- 1979-12-28 FR FR7932031A patent/FR2445307A1/fr active Granted
- 1979-12-29 JP JP17402179A patent/JPS5592335A/ja active Granted
- 1979-12-31 GB GB7944596A patent/GB2038829B/en not_active Expired
-
1980
- 1980-01-02 MX MX180606A patent/MX152526A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR7908592A (pt) | 1980-07-29 |
| JPS5592335A (en) | 1980-07-12 |
| IT1214390B (it) | 1990-01-18 |
| GB2038829B (en) | 1983-02-09 |
| DE2952517A1 (de) | 1980-07-17 |
| MX152526A (es) | 1985-08-16 |
| BE880941A (fr) | 1980-06-30 |
| GB2038829A (en) | 1980-07-30 |
| FR2445307A1 (fr) | 1980-07-25 |
| FR2445307B1 (pt) | 1984-08-10 |
| JPH0112738B2 (pt) | 1989-03-02 |
| IT7951232A0 (it) | 1979-12-28 |
| DE2952517C2 (de) | 1982-06-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A85 | Still pending on 85-01-01 | ||
| BA | A request for search or an international-type search has been filed | ||
| BB | A search report has been drawn up | ||
| BC | A request for examination has been filed | ||
| BV | The patent application has lapsed |