NL1015035C2 - Flexibel proces voor de productie van basisoliÙn en destillatieproducten door een omzetting-hydroisomerisatie op een weinig gedispergeerde katalysator, gevolgd door een katalytische ontparaffinering. - Google Patents
Flexibel proces voor de productie van basisoliÙn en destillatieproducten door een omzetting-hydroisomerisatie op een weinig gedispergeerde katalysator, gevolgd door een katalytische ontparaffinering. Download PDFInfo
- Publication number
- NL1015035C2 NL1015035C2 NL1015035A NL1015035A NL1015035C2 NL 1015035 C2 NL1015035 C2 NL 1015035C2 NL 1015035 A NL1015035 A NL 1015035A NL 1015035 A NL1015035 A NL 1015035A NL 1015035 C2 NL1015035 C2 NL 1015035C2
- Authority
- NL
- Netherlands
- Prior art keywords
- catalyst
- hydrogen
- feed
- effluent
- metal
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 117
- 238000000034 method Methods 0.000 title claims description 66
- 238000004821 distillation Methods 0.000 title claims description 51
- 238000006243 chemical reaction Methods 0.000 title claims description 46
- 230000003197 catalytic effect Effects 0.000 title claims description 41
- 230000008569 process Effects 0.000 title claims description 31
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 239000002199 base oil Substances 0.000 title description 9
- 239000001257 hydrogen Substances 0.000 claims description 87
- 229910052739 hydrogen Inorganic materials 0.000 claims description 87
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 78
- 239000003921 oil Substances 0.000 claims description 53
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 51
- 239000000047 product Substances 0.000 claims description 46
- 229910052751 metal Inorganic materials 0.000 claims description 41
- 239000002184 metal Substances 0.000 claims description 41
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 29
- 238000011282 treatment Methods 0.000 claims description 28
- 238000009835 boiling Methods 0.000 claims description 24
- 229910052697 platinum Inorganic materials 0.000 claims description 23
- 239000007789 gas Substances 0.000 claims description 20
- 239000002808 molecular sieve Substances 0.000 claims description 19
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 19
- 229910000510 noble metal Inorganic materials 0.000 claims description 18
- 239000010970 precious metal Substances 0.000 claims description 18
- 238000000926 separation method Methods 0.000 claims description 16
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 15
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 14
- 150000002430 hydrocarbons Chemical class 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 125000004429 atom Chemical group 0.000 claims description 13
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 13
- 239000011148 porous material Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 238000012360 testing method Methods 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000010457 zeolite Substances 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 10
- 229910052698 phosphorus Inorganic materials 0.000 claims description 10
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 9
- 150000002431 hydrogen Chemical class 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- 229910021536 Zeolite Inorganic materials 0.000 claims description 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical class O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052796 boron Inorganic materials 0.000 claims description 7
- 229910052763 palladium Inorganic materials 0.000 claims description 7
- 239000011574 phosphorus Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 7
- 238000005292 vacuum distillation Methods 0.000 claims description 7
- SGVYKUFIHHTIFL-UHFFFAOYSA-N 2-methylnonane Chemical compound CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 claims description 6
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 229910001657 ferrierite group Inorganic materials 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000011593 sulfur Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000460 chlorine Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 5
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 5
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 5
- 229910001868 water Inorganic materials 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 150000001491 aromatic compounds Chemical class 0.000 claims description 4
- 238000000605 extraction Methods 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 239000011959 amorphous silica alumina Substances 0.000 claims description 3
- 229910052810 boron oxide Inorganic materials 0.000 claims description 3
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- PLZDDPSCZHRBOY-UHFFFAOYSA-N inaktives 3-Methyl-nonan Natural products CCCCCCC(C)CC PLZDDPSCZHRBOY-UHFFFAOYSA-N 0.000 claims description 3
- 239000010687 lubricating oil Substances 0.000 claims description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- TYSIILFJZXHVPU-UHFFFAOYSA-N 5-methylnonane Chemical compound CCCCC(C)CCCC TYSIILFJZXHVPU-UHFFFAOYSA-N 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 229910052570 clay Inorganic materials 0.000 claims description 2
- 239000012043 crude product Substances 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 238000006477 desulfuration reaction Methods 0.000 claims 1
- 230000023556 desulfurization Effects 0.000 claims 1
- 238000009826 distribution Methods 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 150000001335 aliphatic alkanes Chemical class 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000003350 kerosene Substances 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
- 238000005336 cracking Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000003502 gasoline Substances 0.000 description 5
- 238000005984 hydrogenation reaction Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 230000000737 periodic effect Effects 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 3
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- 229910003294 NiMo Inorganic materials 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000001588 bifunctional effect Effects 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000002923 metal particle Substances 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 238000004627 transmission electron microscopy Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- VIJYFGMFEVJQHU-UHFFFAOYSA-N aluminum oxosilicon(2+) oxygen(2-) Chemical class [O-2].[Al+3].[Si+2]=O VIJYFGMFEVJQHU-UHFFFAOYSA-N 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229910021472 group 8 element Inorganic materials 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 238000006317 isomerization reaction Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 description 2
- 229910003446 platinum oxide Inorganic materials 0.000 description 2
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- 102100027446 Acetylserotonin O-methyltransferase Human genes 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 206010053567 Coagulopathies Diseases 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 101000936718 Homo sapiens Acetylserotonin O-methyltransferase Proteins 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- -1 aromatic polycyclic hydrocarbons Chemical class 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000035602 clotting Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 239000008298 dragée Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- PQLXHQMOHUQAKB-UHFFFAOYSA-N miltefosine Chemical compound CCCCCCCCCCCCCCCCOP([O-])(=O)OCC[N+](C)(C)C PQLXHQMOHUQAKB-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 238000000302 molecular modelling Methods 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 1
- 150000003057 platinum Chemical class 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000002525 ultrasonication Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
- C10G49/08—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28004—Sorbent size or size distribution, e.g. particle size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
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- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
- C10G65/043—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
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- B01J21/12—Silica and alumina
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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- C10G2300/4006—Temperature
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- C—CHEMISTRY; METALLURGY
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4012—Pressure
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9905496 | 1999-04-29 | ||
| FR9905496A FR2792946B1 (fr) | 1999-04-29 | 1999-04-29 | Procede de production de bases huiles et de distillats moyens a partir de charges hydrocarbonees par une conversion-hydroisomerisation sur un catalyseur faiblement disperse suivie d'un deparaffinage catalytique |
| FR0002363A FR2805542B1 (fr) | 2000-02-24 | 2000-02-24 | Procede flexible de production de bases huiles et de distillats par une conversion-hydroisomerisation sur un catalyseur faiblement disperse suivie d'un deparaffinage catalytique |
| FR0002363 | 2000-02-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NL1015035A1 NL1015035A1 (nl) | 2000-10-31 |
| NL1015035C2 true NL1015035C2 (nl) | 2001-02-12 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL1015035A NL1015035C2 (nl) | 1999-04-29 | 2000-04-27 | Flexibel proces voor de productie van basisoliÙn en destillatieproducten door een omzetting-hydroisomerisatie op een weinig gedispergeerde katalysator, gevolgd door een katalytische ontparaffinering. |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6602402B1 (es) |
| JP (1) | JP2000345171A (es) |
| KR (1) | KR100695181B1 (es) |
| ES (1) | ES2190303B1 (es) |
| NL (1) | NL1015035C2 (es) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005000999A1 (en) * | 2003-06-27 | 2005-01-06 | Shell Internationale Research Maatschappij B.V. | Process to prepare a lubricating base oil |
| WO2006003119A1 (en) * | 2004-06-25 | 2006-01-12 | Shell Internationale Research Maatschappij B.V. | Process to prepare a lubricating base oil and its use |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2812301B1 (fr) * | 2000-07-26 | 2003-04-04 | Inst Francais Du Petrole | Procede flexible de production de bases huiles et de distillats moyens a partir de charge contenant des heteroatomes |
| FR2818285B1 (fr) * | 2000-12-15 | 2004-12-17 | Inst Francais Du Petrole | Procede flexible ameliore de production de bases huiles et de distillats par une conversion-hydroisomerisation sur un catalyseur faiblement disperse suivie d'un deparaffinage catalytique |
| FR2818284B1 (fr) * | 2000-12-15 | 2006-08-04 | Inst Francais Du Petrole | Procede flexible ameliore de production de bases huiles et distillats moyens avec une conversion-hydroisomerisation suivie d'un deparaffinage catalytique |
| AR032941A1 (es) * | 2001-03-05 | 2003-12-03 | Shell Int Research | Un procedimiento para preparar un aceite base lubricante y aceite base obtenido, con sus diversas utilizaciones |
| MY139353A (en) * | 2001-03-05 | 2009-09-30 | Shell Int Research | Process to prepare a lubricating base oil and a gas oil |
| US7344631B2 (en) * | 2002-10-08 | 2008-03-18 | Exxonmobil Research And Engineering Company | Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product |
| CN100378203C (zh) | 2003-06-23 | 2008-04-02 | 国际壳牌研究有限公司 | 制备润滑基础油的方法 |
| AU2005207842A1 (en) * | 2004-01-16 | 2005-08-11 | Syntroleum Corporation | Process to produce synthetic fuels and lubricants |
| US8158841B2 (en) | 2004-03-25 | 2012-04-17 | Japan Oil, Gas And Metals National Corporation | Hydrotreating method |
| US7214307B2 (en) * | 2004-07-22 | 2007-05-08 | Chevron U.S.A. Inc. | White oil from waxy feed using highly selective and active wax hydroisomerization catalyst |
| US7402236B2 (en) * | 2004-07-22 | 2008-07-22 | Chevron Usa | Process to make white oil from waxy feed using highly selective and active wax hydroisomerization catalyst |
| WO2007034556A1 (ja) * | 2005-09-22 | 2007-03-29 | Japan Oil, Gas And Metals National Corporation | 炭化水素燃料油の製造方法 |
| JP6190091B2 (ja) * | 2007-03-30 | 2017-08-30 | Ｊｘｔｇエネルギー株式会社 | 潤滑油基油及びその製造方法並びに潤滑油組成物 |
| WO2008123249A1 (ja) * | 2007-03-30 | 2008-10-16 | Nippon Oil Corporation | 緩衝器用作動油 |
| US20090065395A1 (en) * | 2007-09-07 | 2009-03-12 | Uop, Llc | Hydrotreating processes for fabricating petroleum distillates from light fischer-tropsch liquids |
| US8231776B2 (en) * | 2007-09-07 | 2012-07-31 | Uop Llc | Hydrotreating processes for fabricating petroleum distillates from light fischer-tropsch liquids |
| JP2009155639A (ja) * | 2007-12-05 | 2009-07-16 | Nippon Oil Corp | 潤滑油組成物 |
| CN106190503A (zh) * | 2007-12-05 | 2016-12-07 | 捷客斯能源株式会社 | 润滑油组合物 |
| JP5342138B2 (ja) * | 2007-12-28 | 2013-11-13 | Ｊｘ日鉱日石エネルギー株式会社 | 潤滑油組成物 |
| US8263519B2 (en) * | 2007-12-28 | 2012-09-11 | Exxonmobil Research And Engineering Company | Sour service dewaxing catalyst without separate hydrogenation function |
| US8030240B2 (en) * | 2007-12-28 | 2011-10-04 | Exxonmobil Research And Engineering Company | Multiple molecular sieve catalyst for sour service dewaxing |
| JP5483662B2 (ja) | 2008-01-15 | 2014-05-07 | Ｊｘ日鉱日石エネルギー株式会社 | 潤滑油組成物 |
| JP5806794B2 (ja) * | 2008-03-25 | 2015-11-10 | Ｊｘ日鉱日石エネルギー株式会社 | 内燃機関用潤滑油組成物 |
| JP2010090251A (ja) * | 2008-10-07 | 2010-04-22 | Nippon Oil Corp | 潤滑油基油及びその製造方法、潤滑油組成物 |
| EP2497820B1 (en) | 2008-10-07 | 2016-06-29 | JX Nippon Oil & Energy Corporation | Lubricant composition |
| EP2341122B2 (en) * | 2008-10-07 | 2019-04-03 | JX Nippon Oil & Energy Corporation | Lubricant base oil |
| JP2010090252A (ja) * | 2008-10-07 | 2010-04-22 | Nippon Oil Corp | 潤滑油組成物 |
| JP5806795B2 (ja) * | 2008-10-07 | 2015-11-10 | Ｊｘ日鉱日石エネルギー株式会社 | 潤滑油基油及びその製造方法、潤滑油組成物 |
| JP5806797B2 (ja) * | 2008-10-07 | 2015-11-10 | Ｊｘ日鉱日石エネルギー株式会社 | 潤滑油基油及びその製造方法、潤滑油組成物 |
| US8377286B2 (en) * | 2008-12-31 | 2013-02-19 | Exxonmobil Research And Engineering Company | Sour service hydroprocessing for diesel fuel production |
| CN103805319B (zh) | 2009-06-04 | 2016-01-06 | 吉坤日矿日石能源株式会社 | 润滑油组合物及其制造方法 |
| JP5829374B2 (ja) | 2009-06-04 | 2015-12-09 | Ｊｘ日鉱日石エネルギー株式会社 | 潤滑油組成物 |
| US9029303B2 (en) | 2009-06-04 | 2015-05-12 | Jx Nippon Oil & Energy Corporation | Lubricant oil composition |
| CN103275800B (zh) | 2009-06-04 | 2016-06-22 | 吉坤日矿日石能源株式会社 | 润滑油组合物 |
| JP5689592B2 (ja) | 2009-09-01 | 2015-03-25 | Ｊｘ日鉱日石エネルギー株式会社 | 潤滑油組成物 |
| US20120024843A1 (en) * | 2010-07-30 | 2012-02-02 | General Electric Company | Thermal treatment of carbonaceous materials |
| JP2014205860A (ja) * | 2014-08-04 | 2014-10-30 | Ｊｘ日鉱日石エネルギー株式会社 | 潤滑油基油及びその製造方法、潤滑油組成物 |
| JP2014205858A (ja) * | 2014-08-04 | 2014-10-30 | Ｊｘ日鉱日石エネルギー株式会社 | 潤滑油組成物 |
| JP2014205859A (ja) * | 2014-08-04 | 2014-10-30 | Ｊｘ日鉱日石エネルギー株式会社 | 潤滑油基油及びその製造方法、潤滑油組成物 |
| US10557092B2 (en) | 2016-08-03 | 2020-02-11 | Exxonmobil Research And Engineering Company | Raffinate hydroconversion for production of high performance base stocks |
| CN108579793B (zh) * | 2018-04-17 | 2020-10-20 | 连云港鹏辰特种新材料有限公司 | 一种基于纳米催化剂的高沸点芳烃溶剂的制备方法 |
| KR102533944B1 (ko) * | 2019-01-25 | 2023-05-17 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 저 금속 함량 촉매의 활성화 |
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| US5833839A (en) * | 1995-12-08 | 1998-11-10 | Exxon Research And Engineering Company | High purity paraffinic solvent compositions, and process for their manufacture |
| NL1015036C2 (nl) * | 1999-04-29 | 2001-02-12 | Inst Francais Du Petrole | Flexibel proces voor de productie van basisoliÙn en gemiddelde destillatieproducten met een omzetting-hydro-isomerisatie gevolgd door een katalytische ontparaffinering. |
| FR2797883B1 (fr) * | 1999-08-24 | 2004-12-17 | Inst Francais Du Petrole | Procede de production d'huiles ayant un indice de viscosite eleve |
-
2000
- 2000-04-27 NL NL1015035A patent/NL1015035C2/nl not_active IP Right Cessation
- 2000-04-27 ES ES200001085A patent/ES2190303B1/es not_active Expired - Fee Related
- 2000-04-29 KR KR1020000023056A patent/KR100695181B1/ko not_active IP Right Cessation
- 2000-05-01 JP JP2000132789A patent/JP2000345171A/ja active Pending
- 2000-05-01 US US09/562,286 patent/US6602402B1/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO1995027020A1 (fr) * | 1994-04-01 | 1995-10-12 | Institut Français Du Petrole | Procede de traitement avec hydroisomerisation de charges issues du procede fischer-tropsch |
| EP0776959A2 (en) * | 1995-11-28 | 1997-06-04 | Shell Internationale Researchmaatschappij B.V. | Process for producing lubricating base oils |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005000999A1 (en) * | 2003-06-27 | 2005-01-06 | Shell Internationale Research Maatschappij B.V. | Process to prepare a lubricating base oil |
| CN100358979C (zh) * | 2003-06-27 | 2008-01-02 | 国际壳牌研究有限公司 | 制备润滑基础油的方法 |
| WO2006003119A1 (en) * | 2004-06-25 | 2006-01-12 | Shell Internationale Research Maatschappij B.V. | Process to prepare a lubricating base oil and its use |
Also Published As
| Publication number | Publication date |
|---|---|
| KR100695181B1 (ko) | 2007-03-16 |
| ES2190303B1 (es) | 2005-02-16 |
| JP2000345171A (ja) | 2000-12-12 |
| KR20000071875A (ko) | 2000-11-25 |
| US6602402B1 (en) | 2003-08-05 |
| ES2190303A1 (es) | 2003-07-16 |
| NL1015035A1 (nl) | 2000-10-31 |
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