NL1003016C2 - Gesubstitueerde pentadieenverbinding. - Google Patents

Gesubstitueerde pentadieenverbinding. Download PDF

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Publication number
NL1003016C2
NL1003016C2 NL1003016A NL1003016A NL1003016C2 NL 1003016 C2 NL1003016 C2 NL 1003016C2 NL 1003016 A NL1003016 A NL 1003016A NL 1003016 A NL1003016 A NL 1003016A NL 1003016 C2 NL1003016 C2 NL 1003016C2
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Netherlands
Prior art keywords
group
compound
substituent
compound according
groups
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NL1003016A
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English (en)
Dutch (nl)
Inventor
Gerardus Johannes Maria Gruter
Henricus Johannes Arts
Gerardus Henricus Jo Doremaele
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Dsm Nv
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Priority to NL1003016A priority Critical patent/NL1003016C2/nl
Priority to PCT/NL1997/000237 priority patent/WO1997042163A1/fr
Priority to AU24113/97A priority patent/AU2411397A/en
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Publication of NL1003016C2 publication Critical patent/NL1003016C2/nl

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2291Olefins
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/25Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing rings other than six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54Metathesis reactions, e.g. olefin metathesis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48Zirconium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49Hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62Chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/824Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/845Cobalt
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/12Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
NL1003016A 1996-05-03 1996-05-03 Gesubstitueerde pentadieenverbinding. NL1003016C2 (nl)

Priority Applications (3)

Application Number Priority Date Filing Date Title
NL1003016A NL1003016C2 (nl) 1996-05-03 1996-05-03 Gesubstitueerde pentadieenverbinding.
PCT/NL1997/000237 WO1997042163A1 (fr) 1996-05-03 1997-04-29 Compose de pentadiene substitue
AU24113/97A AU2411397A (en) 1996-05-03 1997-04-29 Substituted pentadiene compound

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL1003016 1996-05-03
NL1003016A NL1003016C2 (nl) 1996-05-03 1996-05-03 Gesubstitueerde pentadieenverbinding.

Publications (1)

Publication Number Publication Date
NL1003016C2 true NL1003016C2 (nl) 1997-11-06

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Family Applications (1)

Application Number Title Priority Date Filing Date
NL1003016A NL1003016C2 (nl) 1996-05-03 1996-05-03 Gesubstitueerde pentadieenverbinding.

Country Status (3)

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AU (1) AU2411397A (fr)
NL (1) NL1003016C2 (fr)
WO (1) WO1997042163A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999057159A1 (fr) 1998-05-01 1999-11-11 Exxon Chemical Patents Inc. Complexes metalliques catalytiques contenant un ligand tridentate et destines a la polymerisation d'olefines

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3466162A (en) * 1966-02-25 1969-09-09 Hoffmann La Roche Process for control of algae growth using compositions containing diamines and/or derivatives thereof
EP0416815A2 (fr) * 1989-08-31 1991-03-13 The Dow Chemical Company Catalyseurs de polymérisation d'addition à géométrie restreinte, leur procédé de préparation, les précurseurs, procédés d'utilisation et polymères obtenus
DE4303647A1 (de) * 1993-02-09 1994-08-11 Basf Ag Cyclopentadiene mit funktionalisierter Kohlenwasserstoff-Seitenkette
JPH06279478A (ja) * 1993-03-24 1994-10-04 Mitsui Petrochem Ind Ltd シクロペンタジエニル基含有ケイ素化合物またはシクロペンタジエニル基含有ゲルマニウム化合物の製造方法
WO1996013529A1 (fr) * 1994-10-31 1996-05-09 Dsm N.V. Composition catalytique et procede de polymerisation d'une olefine
EP0728724A1 (fr) * 1995-02-21 1996-08-28 Montell North America Inc. Diéthers utilisables dans la préparation des catalyseurs Ziegler-Natta
EP0728769A1 (fr) * 1995-02-21 1996-08-28 Montell North America Inc. Composants et catalyseurs pour la polymérisation d'oléfines
EP0728770A1 (fr) * 1995-02-21 1996-08-28 Montell North America Inc. Procédé de préparation de composants solides de catalyseur pour la polymérisation d'oléfines

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3466162A (en) * 1966-02-25 1969-09-09 Hoffmann La Roche Process for control of algae growth using compositions containing diamines and/or derivatives thereof
EP0416815A2 (fr) * 1989-08-31 1991-03-13 The Dow Chemical Company Catalyseurs de polymérisation d'addition à géométrie restreinte, leur procédé de préparation, les précurseurs, procédés d'utilisation et polymères obtenus
DE4303647A1 (de) * 1993-02-09 1994-08-11 Basf Ag Cyclopentadiene mit funktionalisierter Kohlenwasserstoff-Seitenkette
JPH06279478A (ja) * 1993-03-24 1994-10-04 Mitsui Petrochem Ind Ltd シクロペンタジエニル基含有ケイ素化合物またはシクロペンタジエニル基含有ゲルマニウム化合物の製造方法
WO1996013529A1 (fr) * 1994-10-31 1996-05-09 Dsm N.V. Composition catalytique et procede de polymerisation d'une olefine
EP0728724A1 (fr) * 1995-02-21 1996-08-28 Montell North America Inc. Diéthers utilisables dans la préparation des catalyseurs Ziegler-Natta
EP0728769A1 (fr) * 1995-02-21 1996-08-28 Montell North America Inc. Composants et catalyseurs pour la polymérisation d'oléfines
EP0728770A1 (fr) * 1995-02-21 1996-08-28 Montell North America Inc. Procédé de préparation de composants solides de catalyseur pour la polymérisation d'oléfines

Non-Patent Citations (11)

* Cited by examiner, † Cited by third party
Title
B. HASIAK: "Évolution thermique de sels et hydroxydes de N-diméthyl pipéridinium alpha-substituées. III. Pyrolyse de sels et d'hydroxydes de diméthyl-1,1 alcényl-2 pipéridinium", BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, no. 9-10, 1976, PARIS FR, pages 1526 - 1530, XP002020387 *
BENSLEY, DENNIS M., JR. ET AL: "Synthesis of [C5(CH3)4H]CH2CH2CH2P(C6H5)2: a novel heterodifunctional ligand possessing both a tetramethylcyclopentadiene and a remote diphenylphosphine functionality", J. ORG. CHEM. (1988), 53(18), 4417-19 CODEN: JOCEAH;ISSN: 0022-3263, 1988, XP002020381 *
CHEMICAL ABSTRACTS, vol. 123, no. 13, 25 September 1995, Columbus, Ohio, US; abstract no. 169881, KISO, YOSHIHISA ET AL: "Preparation of cyclopentadienylsilicon or -germanium compounds" XP002020388 *
CHUNG, R. H. ET AL: "1-Isopropyl-4-methylenebicyclo[3.1.0]hex-2-ene. Synthesis and reactions", J. AMER. CHEM. SOC. (1972), 94(7), 2183-7 CODEN: JACSAT, 1972, XP002020385 *
G. KRESZE ET AL.: "Substitierte Cyclopentadiene und ihre Diels-Alder-Reaktionen", CHEMISCHE BERICHTE, vol. 666, 1963, WEINHEIM DE, pages 45 - 53, XP002020383 *
J. SZYMONIAK ET AL.: "New Heterodifunctional Ligands for Organotransiton-Metal Chemistry: Ph2P(CH2)nC5Me4H (n=0,2)", JOURNAL OF ORGANIC CHEMISTRY, vol. 55, 1990, EASTON US, pages 1429 - 1432, XP000601947 *
K. HAFNER ET AL.: "Synthesen und Reaktionen von Fulvenaldehyden", CHEMISCHE BERICHTE, vol. 661, 1963, WEINHEIM DE, pages 52 - 75, XP002020382 *
KRUT'KO, D. P. ET AL: "Tetramethyl(2-methylthioethyl)cyclopentadienyl complexes of zirconium(IV). Synthesis, crystal structure, and dynamic behavior in solutions", RUSSIAN CHEMICAL BULLETIN, vol. 45, no. 4, April 1996 (1996-04-01), pages 940 - 949, XP002020384 *
MU, YING ET AL: "Use of Alkane Elimination in the One-Step Synthesis of Organoscandium Complexes Containing a New Multidentate Cyclopentadienyl Ligand", ORGANOMETALLICS (1996), 15(14), 2720-2726 CODEN: ORGND7;ISSN: 0276-7333, 1996, XP000612366 *
P.V. BALAKRISHNAN ET AL.: "(Pentamethylcyclopentadiene)palladium complexes", J. CHEM. SOC. A (1971), (11), 1721-5 CODEN: JCSIAP, 1971, XP002020380 *
SIEMELING, ULRICH: "C5Me4(CH2)3(OCH2CH2)3OMe: a tentacle-bearing cyclopentadienyl ligand and its use in complex chemistry", J. CHEM. SOC., CHEM. COMMUN. (1992), (18), 1335-6 CODEN: JCCCAT;ISSN: 0022-4936, 1992, XP002020386 *

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AU2411397A (en) 1997-11-26
WO1997042163A1 (fr) 1997-11-13

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