MXPA05011392A - Ferrocenildifosfinas sustituidas, como ligaduras para catalizadores de hidrogenacion homogeneos. - Google Patents

Ferrocenildifosfinas sustituidas, como ligaduras para catalizadores de hidrogenacion homogeneos.

Info

Publication number
MXPA05011392A
MXPA05011392A MXPA05011392A MXPA05011392A MXPA05011392A MX PA05011392 A MXPA05011392 A MX PA05011392A MX PA05011392 A MXPA05011392 A MX PA05011392A MX PA05011392 A MXPA05011392 A MX PA05011392A MX PA05011392 A MXPA05011392 A MX PA05011392A
Authority
MX
Mexico
Prior art keywords
ligands
hydrogenation catalysts
ferrocenyldiphosphines
substituted
homogeneous hydrogenation
Prior art date
Application number
MXPA05011392A
Other languages
English (en)
Inventor
Thommen Marc
Original Assignee
Umicore Ag & Co Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Umicore Ag & Co Kg filed Critical Umicore Ag & Co Kg
Publication of MXPA05011392A publication Critical patent/MXPA05011392A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0286—Complexes comprising ligands or other components characterized by their function
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Compuestos de la formula (I), (ver formula (I)) en la cual: R1 es (C1-C4)alquilo, (C6-C10)arilo o (C7-C11)aralquilo; R2 es una cadena abierta o un grupo de amino secundario ciclico; y R es un radical de la formula: (ver formula) en la cual R3 es (C1-C4)alquilo o (C1-C4)alcoxi, y R4 es H, (C1-C4)alquilo o (C1-C4)alcoxi, son ligaduras para complejos de metales, como catalizadores de hidrogenacion homogeneos para compuestos organicos proquirales, que contienen enlaces dobles, por medio de los cuales se puede lograr muy alta actividad y productividad y tambien enantio-selectividad.
MXPA05011392A 2003-05-09 2004-05-07 Ferrocenildifosfinas sustituidas, como ligaduras para catalizadores de hidrogenacion homogeneos. MXPA05011392A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH8142003 2003-05-09
PCT/EP2004/050731 WO2004099226A1 (en) 2003-05-09 2004-05-07 Substituted ferrocenyldiphosphines as ligands for homogeneous hydrogenation catalysts

Publications (1)

Publication Number Publication Date
MXPA05011392A true MXPA05011392A (es) 2005-12-12

Family

ID=33426272

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA05011392A MXPA05011392A (es) 2003-05-09 2004-05-07 Ferrocenildifosfinas sustituidas, como ligaduras para catalizadores de hidrogenacion homogeneos.

Country Status (12)

Country Link
US (1) US7244860B2 (es)
EP (1) EP1622920B1 (es)
JP (1) JP4633047B2 (es)
CN (1) CN100410263C (es)
AT (1) ATE337327T1 (es)
CA (1) CA2524902C (es)
DE (1) DE602004002114T2 (es)
ES (1) ES2271886T3 (es)
IL (1) IL171765A (es)
MX (1) MXPA05011392A (es)
RU (1) RU2352577C2 (es)
WO (1) WO2004099226A1 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007513923A (ja) * 2003-12-12 2007-05-31 ソルヴィーアス　アクチェンゲゼルシャフト オルトメタレート及びオルト置換された芳香族化合物の製造方法
CA2653150C (en) * 2006-05-23 2014-05-13 Solvias Ag Chiral ligands used in transition metal catalysts for asymmetric addition reactions especially hydrogenation
CN100465181C (zh) * 2006-06-08 2009-03-04 上海交通大学 C2－对称的只具有面手性的二茂钌双膦配体的合成方法
US8507705B2 (en) * 2006-06-08 2013-08-13 Shanghai Jiaotong University C2-symmetrical ruthenocene diphosphine ligands only with surface chirality and their manufacture
JP5126626B2 (ja) 2007-02-01 2013-01-23 インターベツト・インターナシヨナル・ベー・ベー ６−アミノ−７−ヒドロキシ−４，５，６，７−テトラヒドロ−イミダゾ［４，５，１−ｊｋ］［１］−ベンゾアゼピン−２［１ｈ］−オンおよびジルパテロールのエナンチオ選択的合成
DE102007022389A1 (de) 2007-05-10 2008-11-13 Umicore Ag & Co. Kg Ruthenium-Komplexe mit (P-P)-koordinierten Ferrocenyl-diphosphinliganden, Verfahren zu ihrer Herstellung sowie ihre Anwendung in der homogenen Katalyse
EP2107065A1 (de) 2008-04-01 2009-10-07 Umicore AG & Co. KG Ruthenium-Komplexe mit (P-P)-koordinierten Di-Phosphor-Donorliganden sowie Verfahren zu ihrer Herstellung
US8450496B2 (en) * 2009-03-24 2013-05-28 Hoffman-La Roche Inc. Process for the preparation of propionic acid derivatives
CN106607092B (zh) * 2015-10-22 2019-10-08 中国石油化工股份有限公司 催化剂组合物及其应用
CN106046065B (zh) * 2016-05-26 2018-07-13 河南省科学院化学研究所有限公司 一种合成c2-对称性手性二茂铁膦化合物的方法
CN112047856B (zh) * 2019-06-06 2023-01-10 上海交通大学 手性α-酰胺基醛及其制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0262886A (ja) * 1988-08-29 1990-03-02 Sumitomo Chem Co Ltd 光学活性なフェロセニルホスフィンおよびその製法
EP0965574B1 (de) * 1998-06-19 2004-10-13 Degussa AG Verfahren zur enantioselektiven Hydrierung
EP0967015B1 (de) * 1998-06-19 2005-01-12 Degussa AG Verwendung von Ferrocenylliganden zur katalytischen enantioselektiven Hydrierung

Also Published As

Publication number Publication date
DE602004002114D1 (de) 2006-10-05
US20060241315A1 (en) 2006-10-26
EP1622920B1 (en) 2006-08-23
JP2006525978A (ja) 2006-11-16
RU2352577C2 (ru) 2009-04-20
US7244860B2 (en) 2007-07-17
CN1832953A (zh) 2006-09-13
EP1622920A1 (en) 2006-02-08
WO2004099226A1 (en) 2004-11-18
CA2524902A1 (en) 2004-11-18
CA2524902C (en) 2012-07-10
JP4633047B2 (ja) 2011-02-16
ATE337327T1 (de) 2006-09-15
CN100410263C (zh) 2008-08-13
RU2005138144A (ru) 2006-07-10
ES2271886T3 (es) 2007-04-16
IL171765A (en) 2010-04-15
DE602004002114T2 (de) 2007-03-29

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