MXPA05004167A - Empleo de compuestos de complejos metalicos como catalizadores para la oxidacion. - Google Patents
Empleo de compuestos de complejos metalicos como catalizadores para la oxidacion.Info
- Publication number
- MXPA05004167A MXPA05004167A MXPA05004167A MXPA05004167A MXPA05004167A MX PA05004167 A MXPA05004167 A MX PA05004167A MX PA05004167 A MXPA05004167 A MX PA05004167A MX PA05004167 A MXPA05004167 A MX PA05004167A MX PA05004167 A MXPA05004167 A MX PA05004167A
- Authority
- MX
- Mexico
- Prior art keywords
- substituted
- unsubstituted
- alkyl
- hydrogen
- phenyl
- Prior art date
Links
- -1 metal complex compounds Chemical class 0.000 title claims abstract description 263
- 239000003054 catalyst Substances 0.000 title claims abstract description 58
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 55
- 230000003647 oxidation Effects 0.000 title claims description 44
- 239000001257 hydrogen Substances 0.000 claims description 257
- 229910052739 hydrogen Inorganic materials 0.000 claims description 257
- 125000000217 alkyl group Chemical group 0.000 claims description 226
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 171
- RWRDLPDLKQPQOW-UHFFFAOYSA-N tetrahydropyrrole Natural products C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 141
- 150000001875 compounds Chemical class 0.000 claims description 127
- 150000002431 hydrogen Chemical class 0.000 claims description 126
- 229910052757 nitrogen Inorganic materials 0.000 claims description 125
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 115
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 111
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical class C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 102
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical class C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 96
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical class C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 93
- 125000003118 aryl group Chemical group 0.000 claims description 70
- 125000002947 alkylene group Chemical group 0.000 claims description 68
- 239000000203 mixture Substances 0.000 claims description 64
- 229910052736 halogen Inorganic materials 0.000 claims description 48
- 150000002367 halogens Chemical class 0.000 claims description 48
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 46
- 229910001868 water Inorganic materials 0.000 claims description 43
- 239000003599 detergent Substances 0.000 claims description 39
- 150000001768 cations Chemical class 0.000 claims description 37
- 125000001424 substituent group Chemical group 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- 238000004061 bleaching Methods 0.000 claims description 33
- 125000005842 heteroatom Chemical group 0.000 claims description 32
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 29
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 28
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 28
- 125000002785 azepinyl group Chemical group 0.000 claims description 27
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 27
- 125000003107 substituted aryl group Chemical group 0.000 claims description 26
- 125000005186 naphthyloxy group Chemical group C1(=CC=CC2=CC=CC=C12)O* 0.000 claims description 25
- 150000002978 peroxides Chemical class 0.000 claims description 24
- 125000003545 alkoxy group Chemical group 0.000 claims description 23
- 239000008187 granular material Substances 0.000 claims description 22
- 229910052742 iron Inorganic materials 0.000 claims description 22
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 22
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 21
- 238000009472 formulation Methods 0.000 claims description 19
- 239000007787 solid Substances 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 17
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 16
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 16
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 15
- 239000010949 copper Substances 0.000 claims description 15
- 125000004193 piperazinyl group Chemical group 0.000 claims description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 14
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 14
- 229910017052 cobalt Inorganic materials 0.000 claims description 14
- 239000010941 cobalt Substances 0.000 claims description 14
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 14
- 229910052802 copper Inorganic materials 0.000 claims description 14
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical group [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 14
- 229910052759 nickel Inorganic materials 0.000 claims description 14
- 239000010936 titanium Substances 0.000 claims description 14
- 229910052719 titanium Inorganic materials 0.000 claims description 14
- 238000004140 cleaning Methods 0.000 claims description 13
- 150000004696 coordination complex Chemical class 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 12
- 125000003282 alkyl amino group Chemical group 0.000 claims description 12
- XYOVOXDWRFGKEX-UHFFFAOYSA-N azepine Chemical compound N1C=CC=CC=C1 XYOVOXDWRFGKEX-UHFFFAOYSA-N 0.000 claims description 12
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical group CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 11
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 10
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- 230000000249 desinfective effect Effects 0.000 claims description 6
- 125000001624 naphthyl group Chemical group 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 5
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 4
- 229910001882 dioxygen Inorganic materials 0.000 claims description 4
- 229940095064 tartrate Drugs 0.000 claims description 4
- 150000003235 pyrrolidines Chemical class 0.000 claims description 3
- 101100212791 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) YBL068W-A gene Proteins 0.000 claims description 2
- 239000012459 cleaning agent Substances 0.000 claims description 2
- 238000004659 sterilization and disinfection Methods 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
- 239000003446 ligand Substances 0.000 abstract 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 137
- 150000003254 radicals Chemical group 0.000 description 66
- 239000000243 solution Substances 0.000 description 39
- 238000000034 method Methods 0.000 description 27
- 125000004432 carbon atom Chemical group C* 0.000 description 26
- 229910052783 alkali metal Inorganic materials 0.000 description 25
- 239000011572 manganese Substances 0.000 description 24
- 239000000460 chlorine Substances 0.000 description 22
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- 239000002253 acid Substances 0.000 description 21
- 230000008569 process Effects 0.000 description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 229910052751 metal Inorganic materials 0.000 description 17
- 239000002184 metal Substances 0.000 description 17
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 16
- 239000000975 dye Substances 0.000 description 16
- 238000005406 washing Methods 0.000 description 16
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 15
- 239000002270 dispersing agent Substances 0.000 description 15
- 229910052708 sodium Inorganic materials 0.000 description 15
- 239000011734 sodium Substances 0.000 description 15
- 229920001577 copolymer Polymers 0.000 description 14
- 229920000642 polymer Polymers 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 13
- 235000019441 ethanol Nutrition 0.000 description 13
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 12
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- 150000007513 acids Chemical class 0.000 description 11
- 125000003277 amino group Chemical group 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- 229910052748 manganese Inorganic materials 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 10
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical class C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 10
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- 229910052801 chlorine Inorganic materials 0.000 description 10
- 159000000000 sodium salts Chemical class 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 9
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- 230000000694 effects Effects 0.000 description 9
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- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N Vilsmeier-Haack reagent Natural products CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 8
- 125000000129 anionic group Chemical group 0.000 description 8
- 239000007844 bleaching agent Substances 0.000 description 8
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- 229910052700 potassium Inorganic materials 0.000 description 8
- 239000011591 potassium Substances 0.000 description 8
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- 239000000047 product Substances 0.000 description 8
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 8
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 7
- 102000004190 Enzymes Human genes 0.000 description 7
- 108090000790 Enzymes Proteins 0.000 description 7
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 7
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- 238000005160 1H NMR spectroscopy Methods 0.000 description 6
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- 238000005469 granulation Methods 0.000 description 6
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 6
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- 150000005840 aryl radicals Chemical class 0.000 description 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 5
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- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
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- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Detergent Compositions (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Plural Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02405929 | 2002-10-30 | ||
| PCT/EP2003/011636 WO2004039934A1 (en) | 2002-10-30 | 2003-10-21 | Use of metal complex compounds as oxidation catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA05004167A true MXPA05004167A (es) | 2005-06-08 |
Family
ID=32187291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA05004167A MXPA05004167A (es) | 2002-10-30 | 2003-10-21 | Empleo de compuestos de complejos metalicos como catalizadores para la oxidacion. |
Country Status (12)
| Country | Link |
|---|---|
| US (3) | US7138363B2 (enExample) |
| EP (1) | EP1556467B1 (enExample) |
| JP (1) | JP4538797B2 (enExample) |
| KR (1) | KR101004084B1 (enExample) |
| CN (1) | CN1711347B (enExample) |
| AT (1) | ATE332356T1 (enExample) |
| AU (1) | AU2003278117B2 (enExample) |
| BR (1) | BR0315869A (enExample) |
| DE (1) | DE60306672T2 (enExample) |
| ES (1) | ES2268440T3 (enExample) |
| MX (1) | MXPA05004167A (enExample) |
| WO (1) | WO2004039934A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7259122B1 (en) * | 2004-08-30 | 2007-08-21 | John Lombardi | Chemically-resistant shelter coating |
| EP1703976A2 (en) * | 2004-01-12 | 2006-09-27 | Ciba Specialty Chemicals Holding Inc. | Use of metal complex compounds comprising pyridine, pyrimidine or s-triazine derived ligands as catalysts for oxidations with organic peroxy acids and/or precursors of organic peroxy acids and h2o2 |
| CN1929921A (zh) * | 2004-01-12 | 2007-03-14 | 西巴特殊化学制品控股公司 | 包含金属络合物和聚磷酸酯的组合物作为过氧化合物用催化剂的用途 |
| EP1742634B1 (en) * | 2004-04-13 | 2010-10-27 | ICAgen, Inc. | Polycyclic pyrimidines as potassium ion channel modulators |
| KR20070004963A (ko) * | 2004-04-29 | 2007-01-09 | 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 | 경질 표면 상의 착색 얼룩을 표백하기 위한 퍼옥시화합물과의 반응에 대한 촉매로서 비스피리딜피리미딘 또는비스피리딜트리아진 리간드를 갖는 금속 착물의 용도 |
| DE102004024816A1 (de) * | 2004-05-17 | 2005-12-15 | Henkel Kgaa | Bleichverstärkerkombination für den Einsatz in Wasch- und Reinigungsmitteln |
| US20090044345A1 (en) * | 2006-02-06 | 2009-02-19 | Gunther Schlingloff | Use of Metal Complex Compounds as Oxidation Catalysts |
| EP1840198A1 (en) * | 2006-03-30 | 2007-10-03 | Unilever Plc | Bleaching composition |
| EP2173484A1 (en) * | 2007-07-23 | 2010-04-14 | Basf Se | Use of metal complex compounds as oxidation catalysts |
| EP2103735A1 (en) | 2008-03-18 | 2009-09-23 | Unilever PLC | Catalytic bleaching of substrates |
| CN103174006A (zh) * | 2011-11-24 | 2013-06-26 | 东华大学 | 双吡啶嘧啶金属配合物在纺织品低温练漂助剂中的应用 |
| CN107617418A (zh) * | 2016-07-16 | 2018-01-23 | 天津师范大学 | 基于3‑(5‑甲基‑1,3,4‑噁二唑)吡啶的硫氰酸根‑Co(II)配合物在吸附染料中的应用 |
| CN111479913B (zh) * | 2017-12-15 | 2021-12-21 | 罗地亚经营管理公司 | 含有镧系金属络合物的组合物 |
| JP7145802B2 (ja) * | 2019-03-27 | 2022-10-03 | 大阪ガスケミカル株式会社 | ２－アミノ－１，３，５－トリアジン化合物の製造方法 |
| CN115999640B (zh) * | 2023-02-06 | 2024-05-17 | 广西大学 | 一种蔗渣纤维素基-异质结有机复合光催化剂制备方法及其应用 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5362421A (en) * | 1993-06-16 | 1994-11-08 | Minnesota Mining And Manufacturing Company | Electrically conductive adhesive compositions |
| US5453450A (en) | 1993-06-16 | 1995-09-26 | Minnesota Mining And Manufacturing Company | Stabilized curable adhesives |
| PH11999002188B1 (en) | 1998-09-01 | 2007-08-06 | Unilever Nv | Method of treating a textile |
| AU4109100A (en) | 1999-04-01 | 2000-10-23 | Unilever Plc | Composition and method for bleaching a substrate |
| ATE300604T1 (de) | 1999-04-01 | 2005-08-15 | Unilever Nv | Zusammensetzung und verfahren zum bleichen eines substrats |
| DE60211884T2 (de) * | 2001-04-30 | 2006-11-23 | Ciba Speciality Chemicals Holding Inc. | Verwendung von metallkomplexverbindungen als oxidationskatalysatoren |
-
2003
- 2003-10-21 US US10/531,906 patent/US7138363B2/en not_active Expired - Fee Related
- 2003-10-21 AU AU2003278117A patent/AU2003278117B2/en not_active Ceased
- 2003-10-21 KR KR1020057007419A patent/KR101004084B1/ko not_active Expired - Fee Related
- 2003-10-21 AT AT03769428T patent/ATE332356T1/de not_active IP Right Cessation
- 2003-10-21 ES ES03769428T patent/ES2268440T3/es not_active Expired - Lifetime
- 2003-10-21 US US11/520,398 patent/US7291584B2/en not_active Expired - Fee Related
- 2003-10-21 JP JP2004547539A patent/JP4538797B2/ja not_active Expired - Fee Related
- 2003-10-21 BR BR0315869-1A patent/BR0315869A/pt not_active Application Discontinuation
- 2003-10-21 CN CN2003801026668A patent/CN1711347B/zh not_active Expired - Fee Related
- 2003-10-21 EP EP03769428A patent/EP1556467B1/en not_active Expired - Lifetime
- 2003-10-21 WO PCT/EP2003/011636 patent/WO2004039934A1/en not_active Ceased
- 2003-10-21 MX MXPA05004167A patent/MXPA05004167A/es active IP Right Grant
- 2003-10-21 DE DE60306672T patent/DE60306672T2/de not_active Expired - Lifetime
-
2007
- 2007-09-18 US US11/901,660 patent/US7612010B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US7612010B2 (en) | 2009-11-03 |
| US20070032656A1 (en) | 2007-02-08 |
| KR20050065636A (ko) | 2005-06-29 |
| DE60306672T2 (de) | 2007-06-28 |
| CN1711347B (zh) | 2010-05-26 |
| US7291584B2 (en) | 2007-11-06 |
| KR101004084B1 (ko) | 2010-12-27 |
| WO2004039934A1 (en) | 2004-05-13 |
| US20060052265A1 (en) | 2006-03-09 |
| JP2006504517A (ja) | 2006-02-09 |
| AU2003278117B2 (en) | 2009-07-30 |
| US7138363B2 (en) | 2006-11-21 |
| ES2268440T3 (es) | 2007-03-16 |
| CN1711347A (zh) | 2005-12-21 |
| JP4538797B2 (ja) | 2010-09-08 |
| BR0315869A (pt) | 2005-09-27 |
| ATE332356T1 (de) | 2006-07-15 |
| DE60306672D1 (de) | 2006-08-17 |
| EP1556467B1 (en) | 2006-07-05 |
| US20080081908A1 (en) | 2008-04-03 |
| AU2003278117A1 (en) | 2004-05-25 |
| EP1556467A1 (en) | 2005-07-27 |
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| EP1383857B1 (en) | Use of metal complex compounds as oxidation catalysts | |
| AU2005205064A1 (en) | Use of metal complex compounds comprising pyridine pyrimidine or s-triazine derived ligands as catalysts for oxidations with organic peroxy acids and/or precursors of organic peroxy acids and H2O2 | |
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| MXPA05003957A (es) | Empleo de compuestos de complejos metalicos como catalizadores para la oxidacion, que usa el oxigeno molecular o el aire. |
Legal Events
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| FG | Grant or registration |