MX9803919A - Proceso para la preparacion de alquilenglicoles. - Google Patents

Proceso para la preparacion de alquilenglicoles.

Info

Publication number
MX9803919A
MX9803919A MX9803919A MX9803919A MX9803919A MX 9803919 A MX9803919 A MX 9803919A MX 9803919 A MX9803919 A MX 9803919A MX 9803919 A MX9803919 A MX 9803919A MX 9803919 A MX9803919 A MX 9803919A
Authority
MX
Mexico
Prior art keywords
preparation
hydrogen
alkylene glycols
catalysts
metalate
Prior art date
Application number
MX9803919A
Other languages
English (en)
Inventor
Eugene Marie Godfried Kruchten
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of MX9803919A publication Critical patent/MX9803919A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
    • C07C29/106—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

En la presente invencion se describe un proceso para preparar un alquilenglicol o glicol de alquileno haciendo reaccionar un oxido de alquileno con agua, en presencia de un catalizador que incluye una sal de amonio de un organopolisiloxano polimérico que tiene una estructura o esqueleto similar al del sílice y que incluye unidades, Y y x son como se especifica en la reivindicacion 1. Se prefieren los catalizadores caracterizados porque el anion Y se selecciona de un grupo de carboxilatos que tienen de 1 a 20 átomos de carbono, hidrogenocarbonato, sulfito de hidrogeno, fosfato de hidrogeno y metalato. Esos catalizadores muestran una estabilidad mejorada en lo que respecta a la selectividad.
MX9803919A 1995-11-23 1998-05-18 Proceso para la preparacion de alquilenglicoles. MX9803919A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP95203226 1995-11-23

Publications (1)

Publication Number Publication Date
MX9803919A true MX9803919A (es) 1998-09-30

Family

ID=8220859

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9803919A MX9803919A (es) 1995-11-23 1998-05-18 Proceso para la preparacion de alquilenglicoles.

Country Status (14)

Country Link
US (1) US5874653A (es)
EP (1) EP0876315B1 (es)
JP (1) JP2000500478A (es)
KR (1) KR100447357B1 (es)
CN (1) CN1074402C (es)
AU (1) AU699927B2 (es)
CA (1) CA2237007A1 (es)
CZ (1) CZ161198A3 (es)
DE (1) DE69606723T2 (es)
ES (1) ES2142101T3 (es)
MX (1) MX9803919A (es)
NZ (1) NZ323390A (es)
SK (1) SK67398A3 (es)
WO (1) WO1997019043A1 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PE129999A1 (es) * 1997-10-30 1999-12-30 Shell Int Research Hidrolisis catalitica de oxidos de alquileno
DE19757684A1 (de) * 1997-12-23 1999-06-24 Basf Ag Verfahren zur Herstellung von Alkylenglykol
KR100558119B1 (ko) 2000-06-16 2006-03-10 가부시키가이샤 닛폰 쇼쿠바이 가교 중합체, 그것의 제조 방법 및 용도
US20040192976A1 (en) * 2003-03-24 2004-09-30 Shaorong Chen Process for hydrolyzing water-insoluble epoxides
US7134459B2 (en) * 2003-06-12 2006-11-14 Symyx Technologies, Inc. Methods and apparatus for mixing powdered samples
US6916963B2 (en) * 2003-07-14 2005-07-12 Saudi Basic Industries Corporation Process using water tolerant Lewis acids in catalytic hydration of alkylene oxides to alkylene glycols
CN1978057B (zh) * 2005-12-05 2010-11-24 中国石油天然气股份有限公司 一种用于环氧乙烷水合制备乙二醇的催化剂及其制备方法
US20100127022A1 (en) * 2008-11-21 2010-05-27 Symyx Technologies, Inc. Dispensing valve
DE102009002477A1 (de) * 2009-04-20 2010-10-21 Evonik Degussa Gmbh Quartäre-aminofunktionelle, siliciumorganische Verbindungen enthaltende Zusammensetzung sowie deren Herstellung und Verwendung
EP2421840B1 (en) * 2009-04-21 2015-12-16 Dow Technology Investments LLC Simplified method for producing alkylene oxides with a high efficiency catalyst
EP2421842B1 (en) * 2009-04-21 2018-05-30 Dow Technology Investments LLC Epoxidation reactions and operating conditions thereof
KR101730667B1 (ko) * 2009-04-21 2017-04-26 다우 테크놀로지 인베스트먼츠 엘엘씨. 고 효율 촉매에 의한 지정된 알킬렌 옥사이드 생산 파라미터의 달성 및 유지의 개선법
KR101786935B1 (ko) * 2009-12-28 2017-10-18 다우 테크놀로지 인베스트먼츠 엘엘씨. 알킬렌 옥사이드의 제조시 은 촉매 상의 은 클로라이드의 생성을 제어하는 방법
CN114433230B (zh) * 2020-10-20 2024-03-26 中国石油化工股份有限公司 用于环氧烷烃催化水合反应的催化剂及其制备方法和应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6056141B2 (ja) * 1981-02-24 1985-12-09 株式会社日本触媒 アルキレングリコールの製造方法
DE3120195C2 (de) * 1981-05-21 1986-09-04 Degussa Ag, 6000 Frankfurt Polymere Ammoniumverbindungen mit kieselsäureartigem Grundgerüst, Verfahren zu ihrer Herstellung und Verwendung
CA1314566C (en) * 1984-03-28 1993-03-16 John Howard Robson Process for the production of alkylene glycols with metalate-containing solid
US4560813A (en) * 1984-03-28 1985-12-24 Union Carbide Corporation Processes for the production of alkylene glycol in the presence of organometalate
CA1321851C (en) * 1988-01-11 1993-08-31 Kathleen Anne Hughes Process for preparing functionalized polymeric compositions
US5286885A (en) * 1990-12-19 1994-02-15 Degussa Aktiengesellschaft Process for preparing glycide by epoxidation using polymeric organosiloxane ammonium salts of oxoacids of the elements V, Nb, Ta, Mo, and W
RU2001901C1 (ru) * 1992-05-19 1993-10-30 Государственное научно-производственное предпри тие "Совинтех" Способ получени алкиленгликолей
AU681937B2 (en) * 1994-01-31 1997-09-11 Shell Internationale Research Maatschappij B.V. Process for the preparation of alkylene glycols

Also Published As

Publication number Publication date
SK67398A3 (en) 1998-10-07
EP0876315A1 (en) 1998-11-11
CN1202879A (zh) 1998-12-23
AU699927B2 (en) 1998-12-17
WO1997019043A1 (en) 1997-05-29
CA2237007A1 (en) 1997-05-29
KR19990071469A (ko) 1999-09-27
US5874653A (en) 1999-02-23
DE69606723T2 (de) 2000-08-10
DE69606723D1 (de) 2000-03-23
CN1074402C (zh) 2001-11-07
EP0876315B1 (en) 2000-02-16
JP2000500478A (ja) 2000-01-18
NZ323390A (en) 1998-12-23
CZ161198A3 (cs) 1998-09-16
AU1032097A (en) 1997-06-11
KR100447357B1 (ko) 2004-12-03
ES2142101T3 (es) 2000-04-01

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