MX9303629A - Metodo para la preparacion de acidos carboxilicos aromaticos. - Google Patents
Metodo para la preparacion de acidos carboxilicos aromaticos.Info
- Publication number
- MX9303629A MX9303629A MX9303629A MX9303629A MX9303629A MX 9303629 A MX9303629 A MX 9303629A MX 9303629 A MX9303629 A MX 9303629A MX 9303629 A MX9303629 A MX 9303629A MX 9303629 A MX9303629 A MX 9303629A
- Authority
- MX
- Mexico
- Prior art keywords
- carboxylic acid
- aromatic carboxylic
- aromatic
- product mixture
- preparation
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Se describe un método para preparar un ácido carboxílico aromático, que comprende utilizar en la fase líquida un compuesto de alimentación aromático, que contiene por lo menos un grupo alquilo o acilo con un gas que contiene oxígeno molecular, en un solvente que comprende ácido carboxílico alifático de bajo peso molecular, y en presencia de un catalizador de oxidación de metal pesado, por lo que forma una mezcla producto de la reacción de oxidación, que comprende un ácido carboxílico aromático; calentar subsiguientemente la mezcla del producto de reacción de oxidación a una temperatura de por lo menos aproximadamente 260°C para formar una segunda mezcla de producto; y recuperar de la segunda mezcla de producto del ácido carboxílico aromático. El método en esta invención se proporciona para un producto más puro de ácido carboxílico aromático de tamaño de partícula más grande.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/900,593 US5292934A (en) | 1992-06-18 | 1992-06-18 | Method for preparing aromatic carboxylic acids |
Publications (1)
Publication Number | Publication Date |
---|---|
MX9303629A true MX9303629A (es) | 1993-12-01 |
Family
ID=25412767
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX9303629A MX9303629A (es) | 1992-06-18 | 1993-06-17 | Metodo para la preparacion de acidos carboxilicos aromaticos. |
Country Status (3)
Country | Link |
---|---|
US (1) | US5292934A (es) |
MX (1) | MX9303629A (es) |
TW (1) | TW243443B (es) |
Families Citing this family (54)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5563294A (en) * | 1991-12-19 | 1996-10-08 | Amoco Corporation | Process for preparing purified 2,6-naphthalenedicarboxylic acid |
US6054610A (en) | 1995-06-07 | 2000-04-25 | Hfm International, Inc. | Method and apparatus for preparing purified terephthalic acid and isophthalic acid from mixed xylenes |
US6013835A (en) | 1995-06-07 | 2000-01-11 | Hfm International, Inc. | Method and apparatus for preparing purified terephthalic acid |
US5929274A (en) | 1995-06-07 | 1999-07-27 | Hfm International, Inc. | Method to reduce carboxybenzaldehyde isomers in terephthalic acid or isophthalic acid |
US5767311A (en) | 1995-06-07 | 1998-06-16 | Glitsch International, Inc. | Method and apparatus for preparing purified terephtalic acid |
US5616792A (en) * | 1996-02-01 | 1997-04-01 | Amoco Corporation | Catalytic purification of dicarboxylic aromatic acid |
US5756833A (en) * | 1996-02-01 | 1998-05-26 | Amoco Corporation | Catalytic purification and recovery of dicarboxylic aromatic acids |
WO1997044307A1 (fr) * | 1996-05-20 | 1997-11-27 | Mitsui Chemicals, Inc. | Particules d'acide naphthalenedicarboxylique et leur procede de production |
US6018077A (en) * | 1997-04-17 | 2000-01-25 | Mitsubishi Gas Chemical Company, Inc. | Process for producing 2,6-naphthalenedicarboxylic acid |
US6011190A (en) * | 1997-07-02 | 2000-01-04 | Kabushiki Kaisha Kobe Seiko Sho | Process for preparing dialkylnaphthalene |
US5840970A (en) * | 1997-10-03 | 1998-11-24 | Eastman Chemical Company | Process for the purification of naphthalenedicarboxylic acid |
US6018086A (en) * | 1997-10-10 | 2000-01-25 | Kabushiki Kaisha Kobe Seiko Sho | Process for preparing 2,6-dialkylnaphthalene |
US6018087A (en) * | 1997-10-10 | 2000-01-25 | Kabushiki Kaisha Kobe Seiko Sho. | Isomerization of dimethylnaphthalene to produce 2,6-dimethylnaphthalene |
US6284920B1 (en) | 1998-10-07 | 2001-09-04 | Bp Corporation North America Inc. | Aromatic acid monomers, polymers, products and processes for their manufacture |
IT1311976B1 (it) * | 1999-03-25 | 2002-03-22 | Franco Codignola | Procedimento per la produzione di acidi aromatici. |
ATE278656T1 (de) * | 1999-08-30 | 2004-10-15 | Mossi & Ghisolfi Int Sa | Ein verfahren für lösemittelfreie hydrodebromierung in der herstellung von aromatischen carbonsäuren |
EP1212277B1 (en) * | 1999-08-30 | 2004-04-21 | Mossi & Ghisolfi International S.A. | An integrated process for the production of 2,6-naphthalene dicarboxylic acid |
WO2001016066A2 (en) * | 1999-08-30 | 2001-03-08 | Mossi & Ghisolfi Overseas S.A. | Closely linking a nda process with a pen process |
EP1475365A3 (en) * | 1999-08-30 | 2006-08-23 | Mossi & Ghisolfi International S.A. | A method for solvent free hydrodebromination in the production of aromatic carboxylic acids |
CA2383359A1 (en) | 1999-08-30 | 2001-03-08 | Narayana Mysore | A process for producing diacids by carboxylation of phenolic compounds |
WO2001053246A1 (en) * | 2000-01-21 | 2001-07-26 | Bp Corporation North America Inc. | Production of high purity aromatic carboxylic acid by oxidation in benzoic acid and water solvent |
EP1591435A3 (en) * | 2004-03-26 | 2007-11-28 | Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo | Method for preparing 2,6-Naphtalene dicarboxyclic acid |
KR100621823B1 (ko) * | 2004-07-21 | 2006-09-14 | 재단법인서울대학교산학협력재단 | 2,6-디알킬테트랄린의 제조 방법 |
US7683210B2 (en) * | 2004-09-02 | 2010-03-23 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7361784B2 (en) * | 2004-09-02 | 2008-04-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7371894B2 (en) * | 2004-09-02 | 2008-05-13 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7504535B2 (en) * | 2004-09-02 | 2009-03-17 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7586000B2 (en) * | 2004-09-02 | 2009-09-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7692037B2 (en) | 2004-09-02 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7608732B2 (en) * | 2005-03-08 | 2009-10-27 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7608733B2 (en) * | 2004-09-02 | 2009-10-27 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7507857B2 (en) * | 2004-09-02 | 2009-03-24 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7568361B2 (en) * | 2004-09-02 | 2009-08-04 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US20060047153A1 (en) * | 2004-09-02 | 2006-03-02 | Wonders Alan G | Optimized liquid-phase oxidation |
US7910769B2 (en) * | 2004-09-02 | 2011-03-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7692036B2 (en) | 2004-11-29 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7381836B2 (en) * | 2004-09-02 | 2008-06-03 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7495125B2 (en) * | 2004-09-02 | 2009-02-24 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7390921B2 (en) * | 2004-09-02 | 2008-06-24 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7572932B2 (en) * | 2004-09-02 | 2009-08-11 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7741515B2 (en) | 2004-09-02 | 2010-06-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7582793B2 (en) | 2004-09-02 | 2009-09-01 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7572936B2 (en) * | 2004-09-02 | 2009-08-11 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7399882B2 (en) * | 2004-09-02 | 2008-07-15 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7589231B2 (en) * | 2004-09-02 | 2009-09-15 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7482482B2 (en) * | 2004-09-02 | 2009-01-27 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US20060205974A1 (en) * | 2005-03-08 | 2006-09-14 | Lavoie Gino G | Processes for producing aromatic dicarboxylic acids |
US7550627B2 (en) * | 2005-03-08 | 2009-06-23 | Eastman Chemical Company | Processes for producing aromatic dicarboxylic acids |
US7884232B2 (en) * | 2005-06-16 | 2011-02-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7355068B2 (en) * | 2006-01-04 | 2008-04-08 | Eastman Chemical Company | Oxidation system with internal secondary reactor |
US7358389B2 (en) * | 2006-01-04 | 2008-04-15 | Eastman Chemical Company | Oxidation system employing internal structure for enhanced hydrodynamics |
US9388110B2 (en) * | 2013-12-12 | 2016-07-12 | Saudi Arabian Oil Company | Liquid phase oxidation of aromatic feedstocks with manganate recycling to produce carboxylic acids |
KR20210027388A (ko) * | 2018-06-29 | 2021-03-10 | 비피 코포레이션 노쓰 아메리카 인코포레이티드 | 큰 기공 필터를 사용하는 고액 분리 프로세스 |
CN114032565B (zh) * | 2021-11-12 | 2023-05-30 | 万华化学集团股份有限公司 | 一种无水过氧羧酸的制备方法及应用 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3171856A (en) * | 1962-01-04 | 1965-03-02 | Socony Mobil Oil Co Inc | Acid purification process |
US3644507A (en) * | 1968-02-15 | 1972-02-22 | Celanese Corp | Thermal purification of terephthalic acid using iodine or bromine catalysts |
US3862218A (en) * | 1968-02-15 | 1975-01-21 | Celanese Corp | Purification of terephthalic acid by thermal treatment |
SU486008A1 (ru) * | 1974-02-19 | 1975-09-30 | Всесоюзный Научно-Исследовательский И Проектный Институт Мономеров | Способ очистки 2,6-нафталиндикарбоновой кислоты |
US5149867A (en) * | 1987-07-28 | 1992-09-22 | Hatco Corporation | Crystallization of water-insoluble dicarboxylic acid |
JP2874223B2 (ja) * | 1989-11-15 | 1999-03-24 | 三菱瓦斯化学株式会社 | 高純度2,6‐ナフタリンジカルボン酸の製造法 |
-
1992
- 1992-06-18 US US07/900,593 patent/US5292934A/en not_active Expired - Fee Related
-
1993
- 1993-06-14 TW TW082104712A patent/TW243443B/zh active
- 1993-06-17 MX MX9303629A patent/MX9303629A/es not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
TW243443B (es) | 1995-03-21 |
US5292934A (en) | 1994-03-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant or registration | ||
MM | Annulment or lapse due to non-payment of fees |