MX169741B - Metodo para preparar un compuesto organico polimerizable, etilenicamente - Google Patents
Metodo para preparar un compuesto organico polimerizable, etilenicamenteInfo
- Publication number
- MX169741B MX169741B MX1240088A MX1240088A MX169741B MX 169741 B MX169741 B MX 169741B MX 1240088 A MX1240088 A MX 1240088A MX 1240088 A MX1240088 A MX 1240088A MX 169741 B MX169741 B MX 169741B
- Authority
- MX
- Mexico
- Prior art keywords
- preparing
- organic compound
- ethylenically
- polymerizable
- reactant
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 150000002894 organic compounds Chemical class 0.000 title abstract 2
- 239000003112 inhibitor Substances 0.000 abstract 3
- 239000000376 reactant Substances 0.000 abstract 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 2
- 238000004821 distillation Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 150000001785 cerium compounds Chemical class 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- DAHPIMYBWVSMKQ-UHFFFAOYSA-N n-hydroxy-n-phenylnitrous amide Chemical compound O=NN(O)C1=CC=CC=C1 DAHPIMYBWVSMKQ-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/50—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente invención se refiere a un método para preparar un compuesto orgánico polimerizable etilénicamente insaturado, caracterizado porque se somete un producto reaccionante o mezcla de productos reaccionantes a una destilación para su purificación y recuperación, el mejoramiento de la destilación consiste en destilar dicho producto reaccionante o mezcla de productos en presencia de un sistema inhibidor en fase líquida conteniendo un inhibidor fenólico y un compuesto soluble de manganeso o de cerio en combinación con un inhibidor en fase vapor seleccionado del grupo consistente en óxido nítrico y una sal amónica de N-fenil-N-nitrosohidroxilamina.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8052687A | 1987-07-31 | 1987-07-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX169741B true MX169741B (es) | 1993-07-22 |
Family
ID=22157950
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX1240088A MX169741B (es) | 1987-07-31 | 1988-07-25 | Metodo para preparar un compuesto organico polimerizable, etilenicamente |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0301879A3 (es) |
| JP (1) | JPS6442443A (es) |
| AU (1) | AU1891388A (es) |
| MX (1) | MX169741B (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX170187B (es) * | 1988-11-29 | 1993-08-10 | Hoechst Celanese Corp | Metodo y composicion para inhibir la polimerizacion durante la destilacion de monomeros |
| ES2077811T3 (es) * | 1990-11-09 | 1995-12-01 | Nippon Catalytic Chem Ind | Inhibidor de polimerizacion y metodo de inhibicion de polimerizacion para un compuesto de vinilo. |
| TW407145B (en) * | 1995-10-02 | 2000-10-01 | Idemitsu Pertrochemical Co Ltd | Process for inhibiting polymerization of a vinyl compound |
| DE19725519A1 (de) * | 1997-06-17 | 1998-12-24 | Basf Ag | Stoffmischung, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
| DE19906316A1 (de) * | 1999-02-16 | 2000-08-17 | Basf Ag | Stabilisierte Zusammensetzungen von O- und N-Vinylverbindungen und Verwendung von Ammoniumsalzen als Stabilisierungsmittel |
| JP4514933B2 (ja) * | 1999-10-29 | 2010-07-28 | 株式会社日本触媒 | 蒸留方法 |
| WO2014099236A1 (en) * | 2012-12-18 | 2014-06-26 | Rohm And Haas Company | Method for reliable inhibitor delivery |
| WO2016125631A1 (ja) * | 2015-02-05 | 2016-08-11 | 株式会社日本触媒 | アクリル酸の製造方法 |
| EP3374336B1 (en) * | 2015-11-12 | 2021-05-05 | SABIC Global Technologies B.V. | Methods for using nitric oxide to inhibit popcorn polymerization during butadiene processing |
| CN119242964B (zh) * | 2024-09-27 | 2025-10-31 | 兰州大学 | 一种在稀土离子萃取分离过程中抑制变价稀土离子氧化的方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1092005B (de) * | 1958-03-27 | 1960-11-03 | Basf Ag | Stabilisierung von aethylenisch ungesaettigten, polymerisierbaren, monomeren Verbindungen gegen Polymerisation |
| US4507495A (en) * | 1983-07-05 | 1985-03-26 | Celanese Corporation | Process for production of ethyl acrylate |
| US4638079A (en) * | 1985-01-17 | 1987-01-20 | Mallinckrodt, Inc. | Inhibiting polymerization of ethylenically unsaturated monomers |
-
1988
- 1988-07-08 AU AU18913/88A patent/AU1891388A/en not_active Abandoned
- 1988-07-22 JP JP18199588A patent/JPS6442443A/ja active Pending
- 1988-07-25 MX MX1240088A patent/MX169741B/es unknown
- 1988-07-29 EP EP88306999A patent/EP0301879A3/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6442443A (en) | 1989-02-14 |
| EP0301879A3 (en) | 1990-07-25 |
| EP0301879A2 (en) | 1989-02-01 |
| AU1891388A (en) | 1989-02-02 |
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