MX9204064A - Procedimiento para la produccion de bis-arenos de vanadio a partir de oxicloruro de vanadio. - Google Patents
Procedimiento para la produccion de bis-arenos de vanadio a partir de oxicloruro de vanadio.Info
- Publication number
- MX9204064A MX9204064A MX9204064A MX9204064A MX9204064A MX 9204064 A MX9204064 A MX 9204064A MX 9204064 A MX9204064 A MX 9204064A MX 9204064 A MX9204064 A MX 9204064A MX 9204064 A MX9204064 A MX 9204064A
- Authority
- MX
- Mexico
- Prior art keywords
- arene
- vanadium
- bis
- oxychloride
- procedure
- Prior art date
Links
- ZHXZNKNQUHUIGN-UHFFFAOYSA-N chloro hypochlorite;vanadium Chemical compound [V].ClOCl ZHXZNKNQUHUIGN-UHFFFAOYSA-N 0.000 title abstract 4
- 229910052720 vanadium Inorganic materials 0.000 title abstract 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 125000002015 acyclic group Chemical group 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Polymerization Catalysts (AREA)
Abstract
Se describe un procedimiento para la preparación de un bis-areno de vanadio, [V(areno)2], iniciando a partir de oxicloruro de vanadio, metal de aluminio, tricloruro de aluminio y un areno, en donde: (a) se ponen en contacto el oxicloruro de vanadio (VOCL3), el metal de aluminio activo, y el tricloruro de aluminio entre sí, en un areno líquido, parta transformar el oxicloruro de vanadio en el compuesto complejo [V(areno)2)]+[alcl4]-, (b) se adiciona un éter cíclico o acíclico líquido al producto de reacción de paso (a) para reducir el [V(areno)2]+ al [V(areno)2]; y (c) se recupera al bis-areno de vanadio, [V(areno)2], del producto de reacción del paso (b). Los bis-arenos así obtenidos se usan en la preparación de catalizadores para la polimerización de olefinas.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT91MI1937 IT1251464B (it) | 1991-07-12 | 1991-07-12 | Produzione di vanadio bis-areni da ossicloruro di vanadio |
| IT001934 IT1251461B (it) | 1991-07-12 | 1991-07-12 | Procedimento per la produzione di vanadio bis-areni da ossicloruro di vanadio |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX9204064A true MX9204064A (es) | 1993-07-01 |
Family
ID=26330741
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX9204064A MX9204064A (es) | 1991-07-12 | 1992-07-10 | Procedimiento para la produccion de bis-arenos de vanadio a partir de oxicloruro de vanadio. |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US5210244A (es) |
| EP (1) | EP0525857B1 (es) |
| JP (1) | JPH05194556A (es) |
| KR (1) | KR950006545B1 (es) |
| CN (1) | CN1031712C (es) |
| AR (1) | AR247745A1 (es) |
| AT (1) | ATE142633T1 (es) |
| AU (1) | AU647296B2 (es) |
| BR (1) | BR9202662A (es) |
| CA (1) | CA2073634C (es) |
| DE (1) | DE69213605T2 (es) |
| DK (1) | DK0525857T3 (es) |
| DZ (1) | DZ1598A1 (es) |
| EG (1) | EG21012A (es) |
| ES (1) | ES2092012T3 (es) |
| FI (1) | FI104900B (es) |
| GR (1) | GR3021323T3 (es) |
| MX (1) | MX9204064A (es) |
| NO (1) | NO303286B1 (es) |
| RU (1) | RU2083582C1 (es) |
| TN (1) | TNSN92061A1 (es) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1269805B (it) * | 1994-05-20 | 1997-04-15 | Enichem Spa | Catalizzatore per la (co)polimerizzazione dell'etilene e procedimento per il suo ottenimento |
| IT1403290B1 (it) | 2010-12-27 | 2013-10-17 | Polimeri Europa Spa | Componente solido di catalizzatore, catalizzatore comprendente detto componente solido, e procedimento di (co)polimerizzazione delle alfa-olefine |
| ITMI20121724A1 (it) | 2012-10-12 | 2014-04-13 | Versalis Spa | Catalizzatore a base di rutenio e suo impiego nell'idrogenazione selettiva di composti aromatici o poliinsaturi |
| KR102290058B1 (ko) * | 2019-07-05 | 2021-08-18 | 주식회사 태라솔루션 | 원심력을 이용한 촉매 충진 장치 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE551488A (es) * | 1955-10-05 | |||
| US3068258A (en) * | 1958-09-22 | 1962-12-11 | Union Carbide Corp | Process for producing arene hydrocarbon-transition metal compounds |
| US4526724A (en) * | 1983-09-30 | 1985-07-02 | Standard Oil Company (Indiana) | Process for the preparation of zero valent bis-arene transition metal compounds |
| IT1227053B (it) * | 1988-09-09 | 1991-03-14 | Enichem Anic Spa | Componente di catalizzatore e gatalizzatore per la polimerizzazione di etilene e per la copolimerizzazione di etilene con alfa olefine. |
| IT1229737B (it) * | 1989-05-16 | 1991-09-07 | Enichem Anic Spa | Procedimento per la produzione di vanadio areni. |
-
1992
- 1992-07-07 AU AU19483/92A patent/AU647296B2/en not_active Ceased
- 1992-07-08 DZ DZ920088A patent/DZ1598A1/fr active
- 1992-07-08 DE DE69213605T patent/DE69213605T2/de not_active Expired - Lifetime
- 1992-07-08 FI FI923151A patent/FI104900B/fi not_active IP Right Cessation
- 1992-07-08 EP EP92202086A patent/EP0525857B1/en not_active Expired - Lifetime
- 1992-07-08 ES ES92202086T patent/ES2092012T3/es not_active Expired - Lifetime
- 1992-07-08 AT AT92202086T patent/ATE142633T1/de active
- 1992-07-08 DK DK92202086.2T patent/DK0525857T3/da active
- 1992-07-09 NO NO922709A patent/NO303286B1/no not_active IP Right Cessation
- 1992-07-09 US US07/911,286 patent/US5210244A/en not_active Expired - Lifetime
- 1992-07-10 MX MX9204064A patent/MX9204064A/es not_active IP Right Cessation
- 1992-07-10 CA CA002073634A patent/CA2073634C/en not_active Expired - Fee Related
- 1992-07-10 RU SU925052317A patent/RU2083582C1/ru not_active IP Right Cessation
- 1992-07-10 TN TNTNSN92061A patent/TNSN92061A1/fr unknown
- 1992-07-11 EG EG37992A patent/EG21012A/xx active
- 1992-07-11 KR KR1019920012375A patent/KR950006545B1/ko not_active IP Right Cessation
- 1992-07-11 CN CN92105624A patent/CN1031712C/zh not_active Expired - Lifetime
- 1992-07-13 JP JP4185409A patent/JPH05194556A/ja active Pending
- 1992-07-13 AR AR92322727A patent/AR247745A1/es active
- 1992-07-13 BR BR929202662A patent/BR9202662A/pt not_active IP Right Cessation
-
1996
- 1996-10-10 GR GR960402686T patent/GR3021323T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US5210244A (en) | 1993-05-11 |
| ES2092012T3 (es) | 1996-11-16 |
| FI923151A0 (fi) | 1992-07-08 |
| DK0525857T3 (es) | 1997-02-10 |
| CA2073634A1 (en) | 1993-01-13 |
| TNSN92061A1 (fr) | 1993-06-08 |
| NO303286B1 (no) | 1998-06-22 |
| EP0525857B1 (en) | 1996-09-11 |
| JPH05194556A (ja) | 1993-08-03 |
| CA2073634C (en) | 2002-10-22 |
| NO922709L (no) | 1993-01-13 |
| ATE142633T1 (de) | 1996-09-15 |
| AR247745A1 (es) | 1995-03-31 |
| FI923151A (fi) | 1993-01-13 |
| DE69213605T2 (de) | 1997-03-06 |
| DZ1598A1 (fr) | 2002-02-17 |
| CN1068572A (zh) | 1993-02-03 |
| KR950006545B1 (ko) | 1995-06-16 |
| AU1948392A (en) | 1993-01-14 |
| NO922709D0 (no) | 1992-07-09 |
| EG21012A (en) | 2000-09-30 |
| AU647296B2 (en) | 1994-03-17 |
| BR9202662A (pt) | 1993-03-16 |
| EP0525857A1 (en) | 1993-02-03 |
| FI104900B (fi) | 2000-04-28 |
| KR930002241A (ko) | 1993-02-22 |
| DE69213605D1 (de) | 1996-10-17 |
| CN1031712C (zh) | 1996-05-01 |
| GR3021323T3 (en) | 1997-01-31 |
| RU2083582C1 (ru) | 1997-07-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration | ||
| MM | Annulment or lapse due to non-payment of fees |