MX377075B - Proceso para la alcoxicarbonilación de olefinas en un medio que tiene baja concentración de ácido de brønsted - Google Patents

Proceso para la alcoxicarbonilación de olefinas en un medio que tiene baja concentración de ácido de brønsted

Info

Publication number
MX377075B
MX377075B MX2017009235A MX2017009235A MX377075B MX 377075 B MX377075 B MX 377075B MX 2017009235 A MX2017009235 A MX 2017009235A MX 2017009235 A MX2017009235 A MX 2017009235A MX 377075 B MX377075 B MX 377075B
Authority
MX
Mexico
Prior art keywords
alkoxycarbonylation
olefins
medium
ethylenically unsaturated
low concentration
Prior art date
Application number
MX2017009235A
Other languages
English (en)
Other versions
MX2017009235A (es
Inventor
Dieter Hess
Dirk Fridag
Frank Geilen
Helfried Neumann
Kaiwu Dong
Katrin Marie Dyballa
Matthias Beller
Ralf Jackstell
Robert Franke
Xiangjie Fang
Original Assignee
Evonik Oxeno Gmbh & Co Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Oxeno Gmbh & Co Kg filed Critical Evonik Oxeno Gmbh & Co Kg
Publication of MX2017009235A publication Critical patent/MX2017009235A/es
Publication of MX377075B publication Critical patent/MX377075B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Proceso que comprende los siguientes pasos de proceso: a) introducir un compuesto etilénicamente insaturado; b) adicionar un complejo ligando-metal que comprende Pd y un ligando bidentado de fosfina, o adicionar un ligando bidentado de fosfina y un compuesto que comprende Pd; c) adicionar un alcohol; d) suministrar CO; e) calentar la mezcla de reacción, el compuesto etilénicamente insaturado que se hace reaccionar para formar un éster, donde la mezcla de reacción se adiciona con al menos 0.1% en mol, con base a la cantidad de substancia del compuesto etilénicamente insaturado, de ácidos de Brønsted que tienen un concentración de ácido de pKa = 3, caracterizado en que el ligando de fosfina está substituido en al menos un átomo de fósforo por al menos un radical heteroarilo.
MX2017009235A 2016-07-19 2017-07-13 Proceso para la alcoxicarbonilación de olefinas en un medio que tiene baja concentración de ácido de brønsted MX377075B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP16180058.6A EP3272733B1 (de) 2016-07-19 2016-07-19 Verfahren zur alkoxycarbonylierung von olefinen in einem medium mit geringer brønstedsäurenkonzentration

Publications (2)

Publication Number Publication Date
MX2017009235A MX2017009235A (es) 2018-09-10
MX377075B true MX377075B (es) 2025-03-07

Family

ID=56497603

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017009235A MX377075B (es) 2016-07-19 2017-07-13 Proceso para la alcoxicarbonilación de olefinas en un medio que tiene baja concentración de ácido de brønsted

Country Status (11)

Country Link
US (1) US10562838B2 (es)
EP (1) EP3272733B1 (es)
JP (1) JP6571135B2 (es)
KR (1) KR102039377B1 (es)
CN (1) CN107628952A (es)
CA (1) CA2973694C (es)
ES (1) ES2722052T3 (es)
MX (1) MX377075B (es)
MY (1) MY175178A (es)
SG (1) SG10201705858UA (es)
TW (1) TWI691482B (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2787299T3 (es) 2017-12-21 2020-10-15 Evonik Degussa Gmbh Proceso para la conversión directa de alquenos en ácidos carboxílicos
US11440863B2 (en) * 2019-06-12 2022-09-13 Evonik Operations Gmbh Process for preparing an alcohol from hydrocarbons
EP3842411B1 (de) * 2019-12-17 2023-05-31 Evonik Operations GmbH 3,3',3''-(cyclohexan-1,2,4-triyl)tripropionsäuretrimethylester
EP4001256A1 (de) * 2020-11-24 2022-05-25 Evonik Operations GmbH Verfahren zur alkoxycarbonylierung von ethylenisch ungesättigter verbindungen unter einsatz von benzolbasierte diphosphinliganden und aluminiumtriflat
CN115772195A (zh) * 2021-09-06 2023-03-10 惠州凯特立斯科技有限公司 基于吡啶的膦配体化合物及其应用
CN116003467A (zh) * 2021-10-21 2023-04-25 惠州凯特立斯科技有限公司 一种新型三膦化合物及其合成方法与应用
JP7474310B2 (ja) * 2021-12-17 2024-04-24 エボニック オクセノ ゲーエムベーハー ウント コー． カーゲー Ｐｔとキサントフォスを用いるオレフィンのヒドロホルミル化方法
EP4452919A1 (de) 2021-12-23 2024-10-30 Röhm GmbH Verfahren zur herstellung von alkylmethacrylaten mit verbesserter ausbeute und verminderten emissionen flüchtiger organischer verbindungen
CN115819461B (zh) * 2022-11-02 2024-06-07 黄河三角洲京博化工研究院有限公司 一种双齿膦配体及其制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2034971A1 (en) * 1990-02-05 1991-08-06 Eit Drent Carbonylation catalyst system
BE1007422A3 (nl) 1993-08-23 1995-06-13 Dsm Nv Werkwijze voor de bereiding van een mengsel van penteenzure alkylesters.
GB9717059D0 (en) 1997-08-13 1997-10-15 Ici Plc Method of manufacturing phosphine compound
EP0967015B1 (de) * 1998-06-19 2005-01-12 Degussa AG Verwendung von Ferrocenylliganden zur katalytischen enantioselektiven Hydrierung
GB201000078D0 (en) 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
EP3121180B1 (de) 2015-07-23 2018-09-12 Evonik Degussa GmbH Butyl-verbrückte diphosphinliganden für die alkoxycarbonylierung

Also Published As

Publication number Publication date
TW201815741A (zh) 2018-05-01
MX2017009235A (es) 2018-09-10
ES2722052T3 (es) 2019-08-07
SG10201705858UA (en) 2018-02-27
CA2973694C (en) 2022-09-27
CN107628952A (zh) 2018-01-26
JP2018058818A (ja) 2018-04-12
US10562838B2 (en) 2020-02-18
US20180022686A1 (en) 2018-01-25
EP3272733B1 (de) 2019-01-02
MY175178A (en) 2020-06-12
CA2973694A1 (en) 2018-01-19
EP3272733A1 (de) 2018-01-24
KR20180009714A (ko) 2018-01-29
JP6571135B2 (ja) 2019-09-04
KR102039377B1 (ko) 2019-11-04
TWI691482B (zh) 2020-04-21

Similar Documents

Publication Publication Date Title
MX377075B (es) Proceso para la alcoxicarbonilación de olefinas en un medio que tiene baja concentración de ácido de brønsted
EA201490361A1 (ru) Способ получения пав на основе жирных ациламидокарбоновых кислот
MX375969B (es) Metodo para sintetizar compuestos de carbonilo opticamente activos.
Vogler et al. Rhodium‐Catalyzed Oxidative Homocoupling of Boronic Acids
DE60103254D1 (de) Verfahren zum carbonylieren von aethylenisch ungesättigten verbindungen
IN2015DN01081A (es)
BR112012016473A2 (pt) ligando bidentado, processo para a carbonilação de compostos etilenicamente insaturados, complexo, e, sistema catalisador
CA2476736A1 (en) Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore
MY143572A (en) A catalyst system
EA200801345A1 (ru) Карбонилирование этиленненасыщенных соединений
SG10201709110YA (en) Bisphosphites having 2,4-tert-butylphenyl units and use thereof as ligands inhydroformylation
MY167613A (en) Mathod of manufacturing magnetic recording medium and magnetic recording medium
MY165451A (en) Process for preparing amino acids or esters comprising a metathesis step
MY180915A (en) Combined synthesis of a nitrile-ester/acid and of a diester/disacid
MY189907A (en) Catalyst for production of methacrylic acid, method of producing the same, method of producing methacrylic acid, and method of producing methacrylic acid ester
Wu et al. Ruthenium-catalyzed alkoxycarbonylation of alkenes using carbon monoxide
DE602004015770D1 (de) Verfahren zur hydrocyanierung von ungesättigten verbindungen
IN2015DN01082A (es)
AR089293A1 (es) Procedimiento para la preparacion de esteres a partir de formiatos y compuestos olefinicamente insaturados
Miller et al. Influence of acetate buffers and metal ions on ketonization rates of enolpyruvate: a further test of the Marcus function
MY180866A (en) Phosphorous acid p,p'-[5,5',6,6'-tetramethyl-3,3'-bis(1-methylethyl)[1,1'-biphenyl]-2,2'-diyl] p,p,p',p'-tetrakis(2,4-dimethylphenyl) ester in hydroformylation
ATE519726T1 (de) Verbessertes verfahren zur herstellung von polyphenolen
DK2257530T3 (da) Fremgangsmåde til fremstilling af substituerede biphenylanilider
Bantchev et al. Radical‐initiated reaction of methyl linoleate with dialkyl phosphites
MY191148A (en) Catalyst precursor, method for producing catalyst, method for producing methacrylic acid and acrylic acid, and method for producing methacrylic acid ester and acrylic acid ester

Legal Events

Date Code Title Description
HC Change of company name or juridical status

Owner name: SAVANT TECHNOLOGIES LLC

FG Grant or registration