MX375491B - Composiciones de aislamiento y forro de alambre - Google Patents
Composiciones de aislamiento y forro de alambreInfo
- Publication number
- MX375491B MX375491B MX2019010167A MX2019010167A MX375491B MX 375491 B MX375491 B MX 375491B MX 2019010167 A MX2019010167 A MX 2019010167A MX 2019010167 A MX2019010167 A MX 2019010167A MX 375491 B MX375491 B MX 375491B
- Authority
- MX
- Mexico
- Prior art keywords
- wire insulation
- composite product
- product materials
- olefin
- polymer
- Prior art date
Links
- 238000009413 insulation Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title 1
- 239000002131 composite material Substances 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 150000001463 antimony compounds Chemical class 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920002959 polymer blend Polymers 0.000 abstract 1
- 239000002861 polymer material Substances 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
- C08F283/128—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes on to reaction products of polysiloxanes having at least one Si-H bond and compounds having carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/016—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K3/2279—Oxides; Hydroxides of metals of antimony
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K3/2279—Oxides; Hydroxides of metals of antimony
- C08K2003/2282—Antimonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
Se proporcionan materiales de producto compuesto de polímero libre de halógeno, que son comúnmente para uso en aplicaciones de aislamiento y forro para alambre y cable. Los materiales de producto compuesto incluyen una mezcla polimérica, que incluye un copolímero de etileno/a-olefina y poliolefina, un retardante a la flama de óxido metálico hidratado, tal como óxido de magnesio hidratado, y un compuesto de antimonio. En algunos casos, el material polimérico puede incluir un copolímero de olefina/éster insaturado.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762465509P | 2017-03-01 | 2017-03-01 | |
| PCT/US2018/019452 WO2018160460A1 (en) | 2017-03-01 | 2018-02-23 | Wire sheathing and insulation compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2019010167A MX2019010167A (es) | 2020-01-20 |
| MX375491B true MX375491B (es) | 2025-03-06 |
Family
ID=61563559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2019010167A MX375491B (es) | 2017-03-01 | 2018-02-23 | Composiciones de aislamiento y forro de alambre |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US10672535B2 (es) |
| EP (1) | EP3589690B1 (es) |
| CA (1) | CA3019186C (es) |
| CL (1) | CL2019002454A1 (es) |
| MX (1) | MX375491B (es) |
| WO (1) | WO2018160460A1 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20220102671A (ko) * | 2021-01-11 | 2022-07-21 | 엘에스전선 주식회사 | 태양광 케이블의 절연층 또는 시스층용 조성물 및 이로부터 형성된 절연층 또는 시스층을 포함하는 태양광 케이블 |
| KR20240042038A (ko) | 2021-08-11 | 2024-04-01 | 다우 글로벌 테크놀로지스 엘엘씨 | 난연성 중합체 조성물 |
| CN116836477A (zh) * | 2022-03-24 | 2023-10-03 | 江苏凯伦建材股份有限公司 | Tpo阻燃组合物及其制备方法、tpo阻燃层及tpo覆膜板 |
Family Cites Families (46)
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|---|---|---|---|---|
| GB8502928D0 (en) | 1985-02-05 | 1985-03-06 | Bicc Plc | Cross-linkable compositions |
| US4732939A (en) | 1986-01-20 | 1988-03-22 | Sumitomo Bakelite Company Limited | Flame-retardant olefinic resin compositions |
| EP0245938A3 (en) | 1986-04-03 | 1987-11-25 | BP Chemicals Limited | Polymer composition |
| EP0365289A3 (en) | 1988-10-21 | 1991-10-09 | Neste Oy | Method for producing a filled water-crosslinkable silane copolymer composition |
| US4941729A (en) | 1989-01-27 | 1990-07-17 | At&T Bell Laboratories | Building cables which include non-halogenated plastic materials |
| US5112919A (en) | 1989-10-30 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Solid feeding of silane crosslinking agents into extruder |
| US5474602A (en) | 1990-09-26 | 1995-12-12 | Alcan International Limited | Treatment of magnesium hydroxide and its use as plastics filler |
| CA2061465A1 (en) | 1991-02-25 | 1992-08-26 | Craig C. Meverden | Filled hydrolyzable copolymer compositions resistant to premature crosslinking |
| JP2603884B2 (ja) * | 1991-03-05 | 1997-04-23 | 出光エヌエスジー株式会社 | 難燃性樹脂組成物 |
| US5783638A (en) | 1991-10-15 | 1998-07-21 | The Dow Chemical Company | Elastic substantially linear ethylene polymers |
| US5284889A (en) * | 1992-11-20 | 1994-02-08 | Minnesota Mining And Manufacturing Company | Electrically insulating film backing |
| US5401787A (en) | 1994-05-04 | 1995-03-28 | Quantum Chemical Corporation | Flame retardant insulation compositions |
| US5883144A (en) | 1994-09-19 | 1999-03-16 | Sentinel Products Corp. | Silane-grafted materials for solid and foam applications |
| US6025424A (en) | 1995-12-19 | 2000-02-15 | Kyowa Chemical Industry Co Ltd | Heat deterioration resistant flame retardant, resin composition and molded articles |
| JPH09296083A (ja) | 1996-05-01 | 1997-11-18 | Nippon Unicar Co Ltd | 難燃性電線・ケーブル |
| JPH10237324A (ja) | 1996-12-27 | 1998-09-08 | Kanegafuchi Chem Ind Co Ltd | 難燃性樹脂材料、難燃性樹脂磁石材料及びこの難燃性樹脂磁石材料を用いた電子ビーム調整装置 |
| US6552112B1 (en) | 1997-07-23 | 2003-04-22 | Pirelli Cavi E Sistemi S.P.A. | Cable with self-extinguishing properties and flame-retardant composition |
| AU752421B2 (en) | 1998-09-25 | 2002-09-19 | Prysmian Cavi E Sistemi Energia S.R.L. | Low-smoke self-extinguishing electrical cable and flame-retardant composition used therein |
| US6924031B2 (en) | 1998-09-25 | 2005-08-02 | Pirelli Cavi E Sistemi S.P.A. | Low-smoke self-extinguishing electrical cable and flame-retardant composition used therein |
| CN1319860C (zh) | 1998-12-14 | 2007-06-06 | 协和化学工业株式会社 | 氢氧化镁粒子、阻燃性树脂组合物及成型制品 |
| US6495760B1 (en) | 1999-04-03 | 2002-12-17 | Pirelli Cevi E Sistemi S.P.A, | Self-extinguishing cable with low-level production of fumes, and flame-retardant composition used therein |
| DE19921472A1 (de) | 1999-05-08 | 2000-11-16 | Sued Chemie Ag | Flammgeschützte Polymerzusammensetzung |
| NL1013134C2 (nl) | 1999-09-24 | 2001-03-27 | Dsm Nv | Vlamvertragende thermoplastische samenstelling met verbeterde eigenschappen. |
| DE10035647A1 (de) | 2000-07-20 | 2002-01-31 | Martinswerk Gmbh | Vernetzbare, halogenfrei flammgeschützte Kunststoffmischung, insbesondere für Kabel |
| FR2822833B1 (fr) | 2001-03-27 | 2005-06-24 | Nexans | Procede de fabrication d'une composition a base de polymere reticule au moyen de silane, et composition obtenue par ce procede |
| DE10142555A1 (de) | 2001-08-30 | 2003-03-20 | Degussa | Mittel für die Verbesserung der Scorch-Bedingungen bei der Herstellung gepfropfter und/oder vernetzter Polymere sowie gefüllter Kunststoffe |
| DE10159952A1 (de) | 2001-12-06 | 2003-06-18 | Degussa | Verwendung flüssiger oder auf Trägermaterial aufgebrachter ungestättigter Organosilan/-mischungen zur Herstellung von feuchtigkeitsvernetzten und gefüllten Kabelcompounds |
| EP1524294B1 (en) | 2002-06-14 | 2008-05-28 | Mitsui Chemicals, Inc. | Thermoplastic resin composition, polymer composition, and molded object obtained from the composition |
| WO2004013255A1 (en) | 2002-08-01 | 2004-02-12 | Polymers Australia Pty Limited | Fire-resistant silicone polymer compositions |
| CA2520458C (en) | 2003-03-31 | 2012-08-28 | Ceram Polymerik Pty Ltd | Cable and article design for fire performance |
| US7232856B1 (en) | 2003-06-17 | 2007-06-19 | Polyone Corporation | Flame-retardant polyolefin compounds and their use in surface coverings |
| EP1673315A1 (en) | 2003-10-17 | 2006-06-28 | DSM IP Assets B.V. | Flame retardant uv cured buffered optical fibers and buffer composition |
| CA2630003A1 (en) | 2005-11-21 | 2007-05-24 | Sumitomo Electric Industries, Ltd. | Flame-retardant resin composition, and insulated wire, insulated shielded wire, insulated cable and insulating tube using the same |
| JP2008231317A (ja) | 2007-03-22 | 2008-10-02 | Yazaki Corp | ハロゲンフリー樹脂組成物、絶縁電線及びワイヤハーネス |
| US20080311328A1 (en) | 2007-06-13 | 2008-12-18 | Hitoshi Kimura | Non-halogen flame retardant resin composition and non-halogen flame retardant electric wire and cable |
| PT2183631T (pt) | 2007-07-30 | 2019-02-21 | Prysmian Spa | Cabo de telecomunicação equipado com fibras óticas tamponadas cerradas |
| JP2010540697A (ja) | 2007-09-24 | 2010-12-24 | ダウ グローバル テクノロジーズ インコーポレイティド | 湿分硬化性組成物、及びその組成物を製造するための方法 |
| US8525028B2 (en) | 2008-01-30 | 2013-09-03 | Dow Global Technologies Llc | Thermoplastic halogen-free flame retardant formulations |
| DE102008012516A1 (de) | 2008-03-04 | 2009-09-10 | Lanxess Deutschland Gmbh | Vernetzbare Zusammensetzungen, daraus erhältliche thermoplastische Elastomere und deren Verwendung |
| US8703288B2 (en) * | 2008-03-21 | 2014-04-22 | General Cable Technologies Corporation | Low smoke, fire and water resistant cable coating |
| CN101475716B (zh) | 2009-01-19 | 2010-11-24 | 大连亚泰科技新材料有限公司 | 微发泡低烟无卤阻燃铝塑复合板芯材专用料及其制备方法 |
| JP5444737B2 (ja) | 2009-01-30 | 2014-03-19 | 株式会社オートネットワーク技術研究所 | 難燃性組成物および絶縁電線ならびに難燃性組成物の製造方法 |
| US9318240B2 (en) | 2010-05-24 | 2016-04-19 | Dow Global Technologies Llc | Halogen-free, flame retardant composition comprising crosslinked silane-g-EVA |
| CN102585322B (zh) | 2012-02-27 | 2014-06-25 | 广州凯恒科塑有限公司 | 一种易加工低烟无卤阻燃热收缩标识套管及制备与应用 |
| WO2016054242A1 (en) * | 2014-10-02 | 2016-04-07 | Dow Global Technologies Llc | High frequency weldable ethylene-based polymer compositions with good flame retardancy |
| WO2016141086A1 (en) | 2015-03-03 | 2016-09-09 | General Cable Technologies Corporation | Cables formed from halogen-free compositions having fire retardant properties |
-
2018
- 2018-02-23 MX MX2019010167A patent/MX375491B/es active IP Right Grant
- 2018-02-23 US US15/903,716 patent/US10672535B2/en active Active
- 2018-02-23 CA CA3019186A patent/CA3019186C/en active Active
- 2018-02-23 EP EP18708881.0A patent/EP3589690B1/en active Active
- 2018-02-23 WO PCT/US2018/019452 patent/WO2018160460A1/en not_active Ceased
-
2019
- 2019-08-26 CL CL2019002454A patent/CL2019002454A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20180254125A1 (en) | 2018-09-06 |
| MX2019010167A (es) | 2020-01-20 |
| WO2018160460A1 (en) | 2018-09-07 |
| EP3589690B1 (en) | 2023-05-10 |
| CA3019186A1 (en) | 2018-09-07 |
| CL2019002454A1 (es) | 2020-05-08 |
| EP3589690A1 (en) | 2020-01-08 |
| US10672535B2 (en) | 2020-06-02 |
| CA3019186C (en) | 2021-06-29 |
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