MX374197B - Ligandos de 1,1´-bis (fosfino) ferroceno para alcoxicarbonilación - Google Patents

Ligandos de 1,1´-bis (fosfino) ferroceno para alcoxicarbonilación

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Publication number
MX374197B
MX374197B MX2017009233A MX2017009233A MX374197B MX 374197 B MX374197 B MX 374197B MX 2017009233 A MX2017009233 A MX 2017009233A MX 2017009233 A MX2017009233 A MX 2017009233A MX 374197 B MX374197 B MX 374197B
Authority
MX
Mexico
Prior art keywords
alkyl
cycloalkyl
aryl
heteroaryl
ùoù
Prior art date
Application number
MX2017009233A
Other languages
English (en)
Other versions
MX2017009233A (es
Inventor
Dieter Hess
Dirk Fridag
Frank Geilen
Helfried Neumann
Kaiwu Dong
Katrin Marie Dyballa
Matthias Beller
Ralf Jackstell
Robert Franke
Original Assignee
Evonik Oxeno Gmbh & Co Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Oxeno Gmbh & Co Kg filed Critical Evonik Oxeno Gmbh & Co Kg
Publication of MX2017009233A publication Critical patent/MX2017009233A/es
Publication of MX374197B publication Critical patent/MX374197B/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006—Palladium compounds
    • C07F15/0066—Palladium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5045—Complexes or chelates of phosphines with metallic compounds or metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyridine Compounds (AREA)

Abstract

Compuesto de la fórmula (I) (I), donde R2, R4 se seleccionan cada uno independientemente de - (C1-C12)-alquilo, -(C3-C12)-cicloalquilo, -(C3-C12)- heterocicloalquilo, -(C6-C20)-arilo; los radicales R1, R3 son cada uno un radical -(C3-C20)- heteroarilo; R1, R3 pueden estar cada uno sustituidos independientemente por uno o más sustituyentes seleccionado de -(C1-C12)-alquilo, -(C3-C12)-cicloalquilo, -(C3-C12)- heterocicloalquilo, -O-(C1-C12)-alquilo, -O-(C1-C12)-alquil- (C6-C20)-arilo, -O-(C3-C12)-cicloalquilo, -S-(C1-C12)-alquilo, - S-(C3-C12)-cicloalquilo, -COO-(C1-C12)-alquilo, -COO-(C3-C12)- cicloalquilo, -CONH-(C1-C12)-alquilo, -CONH-(C3-C12)- cicloalquilo, -CO-(C1-C12)-alquilo, -CO-(C3-C12)-cicloalquilo, -N-[(C1-C12)-alquil]2, -(C6-C20)-arilo, -(C6-C20)-aril-(C1-C12)- alquilo, -(C6-C20)-aril-O-(C1-C12)-alquilo, -(C3-C20)- heteroarilo, -(C3-C20)-heteroaril-(C1-C12)-alquilo, -(C3-C20)- heteroaril-O-(C1-C12)-alquilo, -COOH, -OH, -SO3H, -NH2, halógeno; R2, R4, si son -(C1-C12)-alquilo, -(C3-C12)- cicloalquilo, -(C3-C12)-heterocicloalquilo o -(C6-C20)-arilo, pueden estar cada uno sustituidos independientemente por uno o más sustituyentes seleccionados de -(C1-C12)-alquilo, -(C3- C12)-cicloalquilo, -(C3-C12)-heterocicloalquilo, -O-(C1-C12)- alquilo, -O-(C1-C12)-alquil-(C6-C20)-arilo, -O-(C3-C12)- cicloalquilo, -S-(C1-C12)-alquilo, -S-(C3-C12)-cicloalquilo, - COO-(C1-C12)-alquilo, -COO-(C3-C12)-cicloalquilo, -CONH-(C1- C12)-alquilo, -CONH-(C3-C12)-cicloalquilo, -CO-(C1-C12)-alquilo, -CO-(C3-C12)-cicloalquilo, -N-[(C1-C12)-alquilo]2, -(C6-C20)- arilo, -(C6-C20)-aril-(C1-C12)-alquilo, -(C6-C20)-aril-O-(C1- C12)-alquilo, -(C3-C20)-heteroarilo, -(C3-C20)-heteroaril-(C1- C12)-alquilo, -(C3-C20)-heteroaril-O-(C1-C12)-alquilo, -COOH, - OH, -SO3H, -NH2, halógeno. La invención también se refiere a complejos de Pd del compuesto de acuerdo con la invención, y al uso de los mismos en un proceso de alcoxicarbonilación.
MX2017009233A 2016-07-19 2017-07-13 Ligandos de 1,1´-bis (fosfino) ferroceno para alcoxicarbonilación MX374197B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP16180056.0A EP3272760B1 (de) 2016-07-19 2016-07-19 1,1'-bis(phosphino)ferrocenliganden für die alkoxycarbonylierung

Publications (2)

Publication Number Publication Date
MX2017009233A MX2017009233A (es) 2018-11-09
MX374197B true MX374197B (es) 2025-03-05

Family

ID=56497602

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017009233A MX374197B (es) 2016-07-19 2017-07-13 Ligandos de 1,1´-bis (fosfino) ferroceno para alcoxicarbonilación

Country Status (12)

Country Link
US (1) US10202409B2 (es)
EP (1) EP3272760B1 (es)
JP (1) JP6467005B2 (es)
KR (1) KR101958097B1 (es)
CN (1) CN107629093B (es)
CA (1) CA2973839C (es)
ES (1) ES2740998T3 (es)
MX (1) MX374197B (es)
MY (1) MY176426A (es)
PL (1) PL3272760T3 (es)
SG (1) SG10201705857SA (es)
TW (1) TWI673276B (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11946843B2 (en) 2017-06-26 2024-04-02 Splitrx Llc Sample filtration device
EP3502085B1 (de) * 2017-12-21 2020-03-11 Evonik Operations GmbH Verfahren zur direkten umsetzung von alkenen zu carbonsäuren
ES2785564T3 (es) * 2017-12-21 2020-10-07 Evonik Degussa Gmbh Procedimiento para la conversión directa de diisobuteno en un ácido carboxílico
USD920534S1 (en) * 2018-12-21 2021-05-25 CanaryQ, Inc. Blood sample filtration device
EP3889163B1 (de) * 2020-03-30 2023-07-19 Evonik Operations GmbH Platin-komplexe mit ferrocen-liganden für die katalyse der alkoxycarbonylierung ethylenisch ungesättigter verbindungen
EP4011892A1 (de) * 2020-12-09 2022-06-15 Evonik Operations GmbH Platin-komplexe mit ferrocen-diphosphin-liganden für die katalyse der hydroxycarbonylierung ethylenisch ungesättigter verbindungen

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1007422A3 (nl) 1993-08-23 1995-06-13 Dsm Nv Werkwijze voor de bereiding van een mengsel van penteenzure alkylesters.
BE1008018A3 (nl) 1994-01-06 1995-12-12 Dsm Nv Werkwijze voor de bereiding van een ester.
JP4290265B2 (ja) * 1999-03-02 2009-07-01 第一ファインケミカル株式会社 新規な不斉配位子
CN106632509B (zh) 2015-07-23 2020-07-07 赢创运营有限公司 膦配体和以此为基础用于烯属不饱和化合物的烷氧基羰基化的钯催化剂

Also Published As

Publication number Publication date
TW201815813A (zh) 2018-05-01
KR101958097B1 (ko) 2019-03-13
MX2017009233A (es) 2018-11-09
EP3272760B1 (de) 2019-05-15
CA2973839A1 (en) 2018-01-19
ES2740998T3 (es) 2020-02-07
KR20180009715A (ko) 2018-01-29
CN107629093B (zh) 2020-06-26
CN107629093A (zh) 2018-01-26
TWI673276B (zh) 2019-10-01
US10202409B2 (en) 2019-02-12
MY176426A (en) 2020-08-07
US20180022773A1 (en) 2018-01-25
CA2973839C (en) 2020-03-10
PL3272760T3 (pl) 2019-10-31
JP2018076284A (ja) 2018-05-17
JP6467005B2 (ja) 2019-02-06
EP3272760A1 (de) 2018-01-24
SG10201705857SA (en) 2018-02-27

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