MX377074B - Proceso para la preparación de ésteres por medio de carbonilación de éteres - Google Patents
Proceso para la preparación de ésteres por medio de carbonilación de éteresInfo
- Publication number
- MX377074B MX377074B MX2017009234A MX2017009234A MX377074B MX 377074 B MX377074 B MX 377074B MX 2017009234 A MX2017009234 A MX 2017009234A MX 2017009234 A MX2017009234 A MX 2017009234A MX 377074 B MX377074 B MX 377074B
- Authority
- MX
- Mexico
- Prior art keywords
- alkyl
- cycloalkyl
- aryl
- heteroaryl
- ùoù
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 230000006315 carbonylation Effects 0.000 title 1
- 238000005810 carbonylation reaction Methods 0.000 title 1
- 150000002170 ethers Chemical class 0.000 title 1
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 abstract 11
- 125000006652 (C3-C12) cycloalkyl group Chemical group 0.000 abstract 8
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- 125000006707 (C3-C12) heterocycloalkyl group Chemical group 0.000 abstract 3
- 125000006736 (C6-C20) aryl group Chemical group 0.000 abstract 3
- 239000003446 ligand Substances 0.000 abstract 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
- B01J27/13—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/12—Acetic acid esters
- C07C69/14—Acetic acid esters of monohydroxylic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/58—Pyridine rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La invención se refiere a un proceso que comprende los pasos de proceso de: a) cargar inicialmente un éter que tiene de 3 a 30 átomos de carbono; b) adicionar un ligando de fosfina y un compuesto que comprende Pd, o adicionar un compuesto que comprende Pd y un ligando de fosfina; c) alimentar en CO; d) calentar la mezcla de reacción, con conversión del éter; en donde el ligando de fosfina es un compuesto de la fórmula (I) VER FÓRMULA (I) donde R1, R2, R3, R4 se seleccionan cada uno independientemente de -(C1-C12)-alquilo, -(C3-C12)-cicloalquilo, -(C3-C12)-heterocicloalquilo, -(C6-C20)-arilo, - (C3-C20)-heteroarilo; al menos uno de los radicales R1, R2, R3, R4 es un radical -(C3-C20)-heteroarilo; y R1, R2, R3, R4, si son -(C1-C12)-alquilo,-(C3-C12)-cicloalquilo,-(C3-C12)-heterocicloalquilo, -(C6-C20)-aril o - (C3-C20)-heteroarilo, se pueden sustituir cada uno independientemente por uno o más sustituyentes seleccionados de -(C1-C12)-alquilo, - (C3-C12)-cicloalquilo, -(C3-C12)-heterocicloalquilo, -O-(C1-C12)-alquilo, -O-(C1-C12)-alquil-(C6-C20)-arilo, -O-(C3-C12)- cicloalquilo, -S-(C1-C12)-alquilo, -S-(C3-C12)-cicloalquilo, - COO-(C1-C12)-alquilo, -COO-(C3-C12)-cicloalquilo, -CONH-(C1- C12)-alquilo, -CONH-(C3-C12)-cicloalquilo, -CO-(C1-C12)-alquilo, -CO-(C3-C12)-cicloalquilo, -N-[(C1-C12)-alquil]2, -(C6-C20)- arilo, -(C6-C20)-aril-(C1-C12)-alquilo, -(C6-C20)-aril-O-(C1- C12)-alquilo, -(C3-C20)-heteroarilo, -(C3-C20)-heteroaril-(C1- C12)-alquilo, -(C3-C20)-heteroaril-O-(C1-C12)-alquilo, -COOH, - SO3H, -NH2, halógeno; y en donde no se adiciona alcohol a la mezcla de reacción
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16180053.7A EP3272729B1 (de) | 2016-07-19 | 2016-07-19 | Verfahren zur herstellung von estern durch carbonylierung von ethern |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2017009234A MX2017009234A (es) | 2018-11-09 |
| MX377074B true MX377074B (es) | 2025-03-07 |
Family
ID=56464081
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2017009234A MX377074B (es) | 2016-07-19 | 2017-07-13 | Proceso para la preparación de ésteres por medio de carbonilación de éteres |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10087134B2 (es) |
| EP (1) | EP3272729B1 (es) |
| JP (1) | JP6442006B2 (es) |
| KR (1) | KR101979093B1 (es) |
| CN (1) | CN107628950B (es) |
| CA (1) | CA2974127C (es) |
| ES (1) | ES2750837T3 (es) |
| MX (1) | MX377074B (es) |
| MY (1) | MY179626A (es) |
| SG (1) | SG10201705862QA (es) |
| TW (1) | TWI659038B (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109851476B (zh) * | 2019-01-03 | 2021-08-17 | 河北工业大学 | 一种甲基叔丁基醚液相羰基化制备烷基衍生物的方法 |
| CN113912646B (zh) * | 2021-11-18 | 2024-05-17 | 浙江新化化工股份有限公司 | 一种双齿膦配体的制备方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB651853A (en) * | 1945-11-19 | 1951-04-11 | Du Pont | Process for the production of esters of organic carboxylic acids |
| BE480163A (es) * | 1947-02-05 | |||
| US4810821A (en) | 1981-10-09 | 1989-03-07 | Monsanto Company | Preparation of alkylidene diesters |
| KR20000075730A (ko) | 1997-02-26 | 2000-12-26 | 윌리암 로엘프 드 보에르 | 펜테노산 유도체의 제조방법 |
| GB9717059D0 (en) | 1997-08-13 | 1997-10-15 | Ici Plc | Method of manufacturing phosphine compound |
| US7005537B2 (en) * | 1999-12-29 | 2006-02-28 | Exxonmobil Chemical Patents Inc. | Production of esters |
| US20060252959A1 (en) * | 2005-05-05 | 2006-11-09 | The Regents Of The University Of California | Process for carbonylation of alkyl ethers |
| GB201000078D0 (en) * | 2010-01-05 | 2010-02-17 | Lucite Int Uk Ltd | Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands |
| CN106632509B (zh) | 2015-07-23 | 2020-07-07 | 赢创运营有限公司 | 膦配体和以此为基础用于烯属不饱和化合物的烷氧基羰基化的钯催化剂 |
-
2016
- 2016-07-19 ES ES16180053T patent/ES2750837T3/es active Active
- 2016-07-19 EP EP16180053.7A patent/EP3272729B1/de active Active
-
2017
- 2017-07-13 MX MX2017009234A patent/MX377074B/es active IP Right Grant
- 2017-07-14 JP JP2017137961A patent/JP6442006B2/ja active Active
- 2017-07-17 TW TW106123841A patent/TWI659038B/zh active
- 2017-07-17 SG SG10201705862QA patent/SG10201705862QA/en unknown
- 2017-07-17 MY MYPI2017702625A patent/MY179626A/en unknown
- 2017-07-17 US US15/651,062 patent/US10087134B2/en active Active
- 2017-07-18 CN CN201710585225.1A patent/CN107628950B/zh active Active
- 2017-07-18 CA CA2974127A patent/CA2974127C/en active Active
- 2017-07-18 KR KR1020170090740A patent/KR101979093B1/ko active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP3272729A1 (de) | 2018-01-24 |
| US10087134B2 (en) | 2018-10-02 |
| CA2974127C (en) | 2022-07-26 |
| TW201815806A (zh) | 2018-05-01 |
| CN107628950A (zh) | 2018-01-26 |
| CN107628950B (zh) | 2020-08-04 |
| JP2018048108A (ja) | 2018-03-29 |
| JP6442006B2 (ja) | 2018-12-19 |
| MX2017009234A (es) | 2018-11-09 |
| EP3272729B1 (de) | 2019-09-04 |
| KR101979093B1 (ko) | 2019-05-15 |
| CA2974127A1 (en) | 2018-01-19 |
| SG10201705862QA (en) | 2018-02-27 |
| ES2750837T3 (es) | 2020-03-27 |
| MY179626A (en) | 2020-11-11 |
| US20180022684A1 (en) | 2018-01-25 |
| KR20180009718A (ko) | 2018-01-29 |
| TWI659038B (zh) | 2019-05-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| HC | Change of company name or juridical status |
Owner name: SAVANT TECHNOLOGIES LLC |
|
| FG | Grant or registration |