MX374196B - Proceso para la alcoxicarbonilación de éteres. - Google Patents
Proceso para la alcoxicarbonilación de éteres.Info
- Publication number
- MX374196B MX374196B MX2017009231A MX2017009231A MX374196B MX 374196 B MX374196 B MX 374196B MX 2017009231 A MX2017009231 A MX 2017009231A MX 2017009231 A MX2017009231 A MX 2017009231A MX 374196 B MX374196 B MX 374196B
- Authority
- MX
- Mexico
- Prior art keywords
- alkyl
- cycloalkyl
- aryl
- heteroaryl
- ùoù
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000007083 alkoxycarbonylation reaction Methods 0.000 title 1
- 150000002170 ethers Chemical class 0.000 title 1
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 abstract 10
- 125000006652 (C3-C12) cycloalkyl group Chemical group 0.000 abstract 8
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- 125000006707 (C3-C12) heterocycloalkyl group Chemical group 0.000 abstract 3
- 125000006736 (C6-C20) aryl group Chemical group 0.000 abstract 3
- 239000003446 ligand Substances 0.000 abstract 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
- B01J27/13—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/12—Acetic acid esters
- C07C69/14—Acetic acid esters of monohydroxylic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/58—Pyridine rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La invención se refiere a un proceso que comprende las siguientes etapas del proceso: a) introducir un éter que tiene de 3 a 30 átomos de carbono; b) agregar un ligando de fosfina y un compuesto que comprende Pd, o agregar un complejo que comprende Pd y un ligando de fosfina; c) agregar un alcohol; d) suministrar CO; e) calentar la mezcla de reacción, haciendo reaccionar el éter para formar un éster; en donde el ligando de fosfina es un compuesto de fórmula (I) [ver fórmula (I)] en donde m y n son cada uno independientemente 0 ó 1; R1, R2, R3, R4 se seleccionan cada uno independientemente de -alquilo-(C1-C12), -cicloalquilo-(C3-C12), -heterocicloalquilo-(C3-C12), -arilo-(C6-C20), -heteroarilo-(C3-C20), al menos uno de los radicales R1, R2, R3, R4 es un radical heteroarilo-(C3-C20); y R1, R2, R3, R4, si son -alquilo-(C1-C12), - cicloalquilo-(C3-C12), -heterocicloalquilo-(C3-C12), -arilo- (C6-C20) o -heteroarilo-(C3-C20), cada uno puede sustituirse independientemente por uno o más sustituyentes seleccionados de -alquilo-(C1-C12), -cicloalquilo-(C3-C12), -heterocicloalquilo- (C3-C12), -O-alquilo-(C1-C12), -O-alquilo-(C1-C12)-arilo-(C6-C20), -O-cicloalquilo-(C3-C12), -S-alquilo-(C1-C12), - cicloalquilo-(C3-C12), -COO-alquilo-(C1-C12), -COOcicloalquilo-(C3-C12), -CONH-alquilo-(C1-C12), -CONH15 cicloalquilo-(C3-C12), -CO-alquilo-(C1-C12), -CO-cicloalquilo-(C3-C12), -N-[alquilo-(C1-C12)]2, -arilo-(C6-C20), -arilo-(C6-C20)-alquilo-(C1-C12), -arilo-(C6-C20)-O-alquilo-(C1-C12), heteroarilo-(C3-C20), heteroarilo-(C3-C20)-alquilo-(C1-C12), heteroarilo-(C3-C20)-O-alquilo-(C1-C12), -COOH, -OH, -SO3H, - NH2, halógeno.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16180054.5A EP3272730B1 (de) | 2016-07-19 | 2016-07-19 | Verfahren zur alkoxycarbonylierung von ethern |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2017009231A MX2017009231A (es) | 2018-09-10 |
| MX374196B true MX374196B (es) | 2025-03-05 |
Family
ID=56464082
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2017009231A MX374196B (es) | 2016-07-19 | 2017-07-13 | Proceso para la alcoxicarbonilación de éteres. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10494326B2 (es) |
| EP (1) | EP3272730B1 (es) |
| JP (1) | JP6498727B2 (es) |
| KR (1) | KR101960176B1 (es) |
| CN (1) | CN107628949B (es) |
| CA (1) | CA2973840C (es) |
| ES (1) | ES2718747T3 (es) |
| MX (1) | MX374196B (es) |
| MY (1) | MY172666A (es) |
| SG (1) | SG10201705861SA (es) |
| TW (1) | TWI668208B (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113912646B (zh) * | 2021-11-18 | 2024-05-17 | 浙江新化化工股份有限公司 | 一种双齿膦配体的制备方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1232317A (es) * | 1968-12-30 | 1971-05-19 | ||
| GB1224518A (en) * | 1968-11-11 | 1971-03-10 | Shell Int Research | Preparation of carboxylic esters |
| US5315030A (en) * | 1993-09-29 | 1994-05-24 | Ethyl Corporation | Catalytic carbonylation of ethers and thioethers |
| US5399747A (en) | 1994-01-27 | 1995-03-21 | Albemarle Corporation | Process for preparing carboxylic acids by carbonylation of ethers and thioethers |
| GB9425911D0 (en) * | 1994-12-22 | 1995-02-22 | Ici Plc | Process for the carbonylation of olefins and catalyst system for use therein |
| KR20000075730A (ko) | 1997-02-26 | 2000-12-26 | 윌리암 로엘프 드 보에르 | 펜테노산 유도체의 제조방법 |
| GB9717059D0 (en) | 1997-08-13 | 1997-10-15 | Ici Plc | Method of manufacturing phosphine compound |
| US7005537B2 (en) * | 1999-12-29 | 2006-02-28 | Exxonmobil Chemical Patents Inc. | Production of esters |
| US20060252959A1 (en) | 2005-05-05 | 2006-11-09 | The Regents Of The University Of California | Process for carbonylation of alkyl ethers |
| GB201000078D0 (en) | 2010-01-05 | 2010-02-17 | Lucite Int Uk Ltd | Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands |
| CN106632509B (zh) | 2015-07-23 | 2020-07-07 | 赢创运营有限公司 | 膦配体和以此为基础用于烯属不饱和化合物的烷氧基羰基化的钯催化剂 |
-
2016
- 2016-07-19 ES ES16180054T patent/ES2718747T3/es active Active
- 2016-07-19 EP EP16180054.5A patent/EP3272730B1/de active Active
-
2017
- 2017-07-13 MX MX2017009231A patent/MX374196B/es active IP Right Grant
- 2017-07-14 JP JP2017137959A patent/JP6498727B2/ja active Active
- 2017-07-17 US US15/651,169 patent/US10494326B2/en active Active
- 2017-07-17 TW TW106123840A patent/TWI668208B/zh active
- 2017-07-17 SG SG10201705861SA patent/SG10201705861SA/en unknown
- 2017-07-17 CA CA2973840A patent/CA2973840C/en active Active
- 2017-07-17 MY MYPI2017702609A patent/MY172666A/en unknown
- 2017-07-18 KR KR1020170090739A patent/KR101960176B1/ko active Active
- 2017-07-18 CN CN201710585190.1A patent/CN107628949B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| KR101960176B1 (ko) | 2019-03-19 |
| EP3272730B1 (de) | 2019-01-02 |
| TW201815740A (zh) | 2018-05-01 |
| US20180022685A1 (en) | 2018-01-25 |
| TWI668208B (zh) | 2019-08-11 |
| JP6498727B2 (ja) | 2019-04-10 |
| MX2017009231A (es) | 2018-09-10 |
| US10494326B2 (en) | 2019-12-03 |
| JP2018058819A (ja) | 2018-04-12 |
| CN107628949B (zh) | 2020-08-04 |
| MY172666A (en) | 2019-12-09 |
| EP3272730A1 (de) | 2018-01-24 |
| CA2973840C (en) | 2019-06-25 |
| CA2973840A1 (en) | 2018-01-19 |
| CN107628949A (zh) | 2018-01-26 |
| KR20180009717A (ko) | 2018-01-29 |
| ES2718747T3 (es) | 2019-07-04 |
| SG10201705861SA (en) | 2018-02-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| HC | Change of company name or juridical status |
Owner name: DE-STA-CO EUROPE GMBH.* |
|
| FG | Grant or registration |