MX371466B - Aminas inhibidas estericamente y metodos asociados. - Google Patents

Aminas inhibidas estericamente y metodos asociados.

Info

Publication number
MX371466B
MX371466B MX2018004065A MX2018004065A MX371466B MX 371466 B MX371466 B MX 371466B MX 2018004065 A MX2018004065 A MX 2018004065A MX 2018004065 A MX2018004065 A MX 2018004065A MX 371466 B MX371466 B MX 371466B
Authority
MX
Mexico
Prior art keywords
sterically hindered
hindered amines
amines
present disclosure
production
Prior art date
Application number
MX2018004065A
Other languages
English (en)
Inventor
A Grigsby Robert Jr
Zhou Jingjun
Yang SU Wei-
Original Assignee
Huntsman Petrochemical Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Petrochemical Llc filed Critical Huntsman Petrochemical Llc
Publication of MX371466B publication Critical patent/MX371466B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1468—Removing hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/02—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C217/50—Ethers of hydroxy amines of undetermined structure, e.g. obtained by reactions of epoxides with hydroxy amines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/202—Alcohols or their derivatives
    • B01D2252/2023—Glycols, diols or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20405—Monoamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/2041—Diamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20426—Secondary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20484—Alkanolamines with one hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50—Combinations of absorbents
    • B01D2252/504—Mixtures of two or more absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60—Additives
    • B01D2252/606—Anticorrosion agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60—Additives
    • B01D2252/608—Antifoaming agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/20—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Gas Separation By Absorption (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Treating Waste Gases (AREA)

Abstract

Se proporcionan composiciones de aminas que comprenden aminas inhibidas estéricamente y los métodos asociados. Las composiciones de aminas de la presente descripción pueden ser útiles para la eliminación selectiva de H2S de una corriente de gas ácido. Bajo ciertas condiciones, tales como condiciones ricas en CO2 y/o alto contenido de bis-(butilaminoetoxi terciario) etano, ciertas aminas para la eliminación selectiva del gas H2S pueden convertirse en una fase separada. Un polietilenglicol de mayor peso molecular puede hacerse reaccionar con una butilamina terciaria para producir una mezcla de aminas inhibidas estéricamente que proporcione buen desempeño sin el problema de la separación de fase. Las aminas inhibidas estéricamente pueden elaborarse sin la necesidad de un solvente, simplificando con ello su producción. Los métodos de la presente descripción pueden considerarse más "amigables con el ambiente" en el sentido de que producen mayores cantidades de productos de amina deseables con producción de mínima a ninguna de subproductos indeseables, lo que también puede reducir los costos asociados con la elaboración de las aminas inhibidas estéricamente.
MX2018004065A 2010-12-01 2011-11-21 Aminas inhibidas estericamente y metodos asociados. MX371466B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US41842510P 2010-12-01 2010-12-01
PCT/US2011/061604 WO2012074807A1 (en) 2010-12-01 2011-11-21 Sterically hindered amines and associated methods

Publications (1)

Publication Number Publication Date
MX371466B true MX371466B (es) 2020-01-28

Family

ID=46172222

Family Applications (2)

Application Number Title Priority Date Filing Date
MX2018004065A MX371466B (es) 2010-12-01 2011-11-21 Aminas inhibidas estericamente y metodos asociados.
MX2013005958A MX362397B (es) 2010-12-01 2011-11-21 Aminas inhibidas estericamente y metodos asociados.

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX2013005958A MX362397B (es) 2010-12-01 2011-11-21 Aminas inhibidas estericamente y metodos asociados.

Country Status (10)

Country Link
US (3) US9352271B2 (es)
EP (2) EP3255034B1 (es)
JP (2) JP2014505022A (es)
CN (2) CN106631833A (es)
AU (1) AU2011336995B2 (es)
CA (1) CA2817994C (es)
MX (2) MX371466B (es)
MY (1) MY163068A (es)
NO (1) NO2646407T3 (es)
WO (1) WO2012074807A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX371466B (es) 2010-12-01 2020-01-28 Huntsman Petrochemical Llc Aminas inhibidas estericamente y metodos asociados.
US20130142717A1 (en) * 2011-12-02 2013-06-06 Michael Siskin Offshore gas separation process
US20130243676A1 (en) * 2012-03-14 2013-09-19 Exxonmobil Research And Engineering Company Amine treating process for acid gas separation using blends of amines and alkyloxyamines
BR112014029667A2 (pt) * 2012-05-31 2017-08-22 Shell Internationale Res Maatschappij B V E Huntsman Petrochemical Llc Processo para a absorção seletiva em alta temperatura de sulfeto de hidrogênio de uma corrente de gás
EP2854993B1 (en) * 2012-05-31 2018-12-26 Shell International Research Maatschappij B.V. A method of improving a process for the selective absorption of hydrogen sulfide
AU2013267514B2 (en) 2012-05-31 2015-11-19 Huntsman Petrochemical Llc An absorbent composition for the selective absorption of hydrogen sulfide
AU2013267517B2 (en) * 2012-05-31 2015-11-26 Huntsman Petrochemical Llc An absorbent composition for the selective absorption of hydrogen sulfide and a process of use thereof
FR3014862B1 (fr) * 2013-12-17 2016-01-01 Axens Procede de purification du gaz de synthese par voie de lavage sur des solutions aqueuses d'amines
CN106540516A (zh) * 2015-09-18 2017-03-29 中国石油化工股份有限公司 一种天然气中脱除硫醇的专用脱硫剂
CN111440076A (zh) * 2019-01-17 2020-07-24 中国石油天然气集团有限公司 一种叔丁氨基三甘醇型位阻胺及其制备方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US440581A (en) * 1890-11-11 straight
US4405583A (en) * 1982-01-18 1983-09-20 Exxon Research And Engineering Co. Process for selective removal of H2 S from mixtures containing H22 using di-severely sterically hindered secondary aminoethers
US4405811A (en) * 1982-01-18 1983-09-20 Exxon Research And Engineering Co. Severely sterically hindered tertiary amino compounds
EP0087856B1 (en) 1982-01-18 1986-02-26 Exxon Research And Engineering Company A process for the removal of h2s from gaseous mixtures using diaminoethers
US4405582A (en) * 1982-01-18 1983-09-20 Exxon Research And Engineering Co. Process for selective removal of H2 S from mixtures containing H22 using diaminoether solutions
US4471138A (en) 1982-01-18 1984-09-11 Exxon Research And Engineering Co. Severely sterically hindered secondary aminoether alcohols
US4665195A (en) * 1983-12-23 1987-05-12 Exxon Research And Engineering Company Process for preparing di-amino-polyalkenyl ethers
US4618481A (en) * 1985-08-30 1986-10-21 Exxon Research And Engineering Co. Absorbent composition containing a severely hindered amino compound and an amine salt and process for the absorption of H2 S using the same
US4894178A (en) * 1987-10-13 1990-01-16 Exxon Research And Engineering Company Absorbent composition containing severely-hindered amine mixture for the absorption of H2 S
US4961873A (en) * 1987-10-13 1990-10-09 Exxon Research And Engineering Company Absorbent composition containing a severely-hindered amine mixture with amine salts and/or aminoacid additives for the absorption of H2 S
CA2394980C (en) * 1999-12-22 2008-05-13 Shearwater Corporation Sterically hindered derivatives of water soluble polymers
JP4655349B2 (ja) * 2000-10-18 2011-03-23 日油株式会社 経口医薬用ポリエチレングリコールおよびその製造方法
US7196033B2 (en) 2001-12-14 2007-03-27 Huntsman Petrochemical Corporation Advances in amination catalysis
CA2618499C (en) * 2005-08-09 2013-08-20 Exxonmobil Research And Engineering Company Alkylamino alkyloxy (alcohol) monoalkyl ether for acid gas scrubbing process
RU2009104985A (ru) * 2006-07-14 2010-08-27 Басф Се (De) Способ получения амина
MX371466B (es) * 2010-12-01 2020-01-28 Huntsman Petrochemical Llc Aminas inhibidas estericamente y metodos asociados.

Also Published As

Publication number Publication date
WO2012074807A1 (en) 2012-06-07
MX362397B (es) 2019-01-16
US9987588B2 (en) 2018-06-05
EP2646407A4 (en) 2014-10-29
EP2646407A1 (en) 2013-10-09
EP3255034A1 (en) 2017-12-13
JP2017014190A (ja) 2017-01-19
AU2011336995A1 (en) 2013-05-30
CA2817994C (en) 2019-01-22
US20160193562A1 (en) 2016-07-07
NO2646407T3 (es) 2018-03-10
AU2011336995B2 (en) 2016-06-09
JP6412523B2 (ja) 2018-10-24
EP2646407B1 (en) 2017-10-11
MX2013005958A (es) 2013-07-29
CN103282341A (zh) 2013-09-04
US20170144102A1 (en) 2017-05-25
MY163068A (en) 2017-08-15
US20130280155A1 (en) 2013-10-24
CA2817994A1 (en) 2012-06-07
CN106631833A (zh) 2017-05-10
EP3255034B1 (en) 2019-01-09
JP2014505022A (ja) 2014-02-27
US9700832B2 (en) 2017-07-11
US9352271B2 (en) 2016-05-31

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