MX365550B - Método para prolongar la vida de un catalizador durante hidrofluoración. - Google Patents
Método para prolongar la vida de un catalizador durante hidrofluoración.Info
- Publication number
- MX365550B MX365550B MX2015015495A MX2015015495A MX365550B MX 365550 B MX365550 B MX 365550B MX 2015015495 A MX2015015495 A MX 2015015495A MX 2015015495 A MX2015015495 A MX 2015015495A MX 365550 B MX365550 B MX 365550B
- Authority
- MX
- Mexico
- Prior art keywords
- catalyst
- prolonging
- chloro
- life during
- hcfo
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- SMCNZLDHTZESTK-UHFFFAOYSA-N 2-chloro-1,1,1,2-tetrafluoropropane Chemical compound CC(F)(Cl)C(F)(F)F SMCNZLDHTZESTK-UHFFFAOYSA-N 0.000 abstract 3
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 abstract 2
- OQISUJXQFPPARX-UHFFFAOYSA-N 2-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C(Cl)=C OQISUJXQFPPARX-UHFFFAOYSA-N 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 238000003682 fluorination reaction Methods 0.000 abstract 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
- C07C17/087—Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
- C07C19/10—Acyclic saturated compounds containing halogen atoms containing fluorine and chlorine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
La invención provee un proceso mejorado para manufacturar 2-cloro-1,1,1,2-tetrafluoropropano (HCFC-244bb) haciendo reaccionar 2-cloro-3,3,3-trifluoropropeno (HCFO)-1233x1) con fluoruro de hidrógeno, en la presencia de un catalizador de fluoración en donde mediante el uso de 2-cloro-3,3,3,-trifluoropro peno (HCFO-1233xf) de alta pureza, la necesidad de agregar un agente de oxidación (normalmente cloro) para mantener el catalizador activo puede evitarse. HCFC-244bb luego se usa como un intermediario en la producción de 2,3,3,3-tetrafluoropropeno-1 (HFO-1234yf).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/825,040 US8952208B2 (en) | 2006-01-03 | 2010-06-28 | Method for prolonging a catalyst's life during hydrofluorination |
| PCT/US2011/041395 WO2012009114A2 (en) | 2010-06-28 | 2011-06-22 | Method for prolonging a catalyst's life during hydrofluorination |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX365550B true MX365550B (es) | 2019-06-07 |
Family
ID=45469996
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2015015495A MX365550B (es) | 2010-06-28 | 2011-06-22 | Método para prolongar la vida de un catalizador durante hidrofluoración. |
| MX2013000049A MX2013000049A (es) | 2010-06-28 | 2011-06-22 | Metodo para prolongar la vida de un catalizador durante hidrofluoracion. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013000049A MX2013000049A (es) | 2010-06-28 | 2011-06-22 | Metodo para prolongar la vida de un catalizador durante hidrofluoracion. |
Country Status (7)
| Country | Link |
|---|---|
| US (3) | US8952208B2 (es) |
| EP (1) | EP2585423B1 (es) |
| JP (3) | JP5868969B2 (es) |
| CN (3) | CN107011112A (es) |
| ES (1) | ES2556459T3 (es) |
| MX (2) | MX365550B (es) |
| WO (1) | WO2012009114A2 (es) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9024092B2 (en) * | 2006-01-03 | 2015-05-05 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| US20230150900A1 (en) * | 2004-04-29 | 2023-05-18 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| US8766020B2 (en) * | 2008-07-31 | 2014-07-01 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| US8952208B2 (en) * | 2006-01-03 | 2015-02-10 | Honeywell International Inc. | Method for prolonging a catalyst's life during hydrofluorination |
| US8664455B2 (en) | 2008-08-08 | 2014-03-04 | Honeywell International Inc. | Process to manufacture 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) |
| EP2091897B2 (en) | 2006-10-31 | 2021-12-01 | The Chemours Company FC, LLC | Processes for the production of fluoropropanes and halopropenes |
| US20170253545A1 (en) | 2007-01-03 | 2017-09-07 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| US9670117B2 (en) | 2007-01-03 | 2017-06-06 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| US8563789B2 (en) * | 2007-06-27 | 2013-10-22 | Arkema Inc. | Process for the manufacture of hydrofluoroolefins |
| CN101687731B (zh) | 2007-06-27 | 2013-09-04 | 阿科玛股份有限公司 | 用于制造氢氟烯烃的方法 |
| US8846990B2 (en) * | 2007-07-06 | 2014-09-30 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| US9416074B2 (en) | 2007-07-06 | 2016-08-16 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| CA3016991C (en) | 2009-12-22 | 2020-10-27 | E. I. Du Pont De Nemours And Company | Compositions comprising 2,3,3,3-tetrafluoropropene, 1,1,2,3-tetrachloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane |
| WO2011077191A1 (en) * | 2009-12-23 | 2011-06-30 | Arkema France | Catalytic gas phase fluorination of 1230xa to 1234yf |
| US8114308B2 (en) * | 2010-03-30 | 2012-02-14 | Honeywell International Inc. | Azeotrope-like composition of 2,3-dichloro-3,3-difluoropropene (HCFO-1232xf) and hydrogen fluoride (HF) |
| RU2571415C2 (ru) | 2011-01-21 | 2015-12-20 | Аркема Франс | Каталитическое газофазное фторирование |
| MX343621B (es) | 2011-01-21 | 2016-11-11 | Arkema France | Fluoracion catalitica en fase gas. |
| FR2980474B1 (fr) * | 2011-09-27 | 2013-08-30 | Arkema France | Procede de fabrication du 2,3,3,3-tetrafluoropropene |
| CN103946193B (zh) * | 2011-10-14 | 2015-11-25 | 霍尼韦尔国际公司 | 制备2,3,3,3-四氟丙烯的方法 |
| ES2791768T3 (es) * | 2011-10-14 | 2020-11-05 | Honeywell Int Inc | Proceso para producir 2,3,3,3-tetrafluoropropeno |
| WO2013055894A1 (en) | 2011-10-14 | 2013-04-18 | Selma Bektesevic | Process for producing 2,3,3,3-tetrafluoropropene |
| EP2776383B1 (en) * | 2011-11-10 | 2020-03-11 | The Chemours Company FC, LLC | Catalytic fluorination process of making hydrohaloalkane |
| US9296670B2 (en) | 2012-02-10 | 2016-03-29 | The Chemours Company Fc, Llc | Process for the manufacture of 2,3,3,3-tetrafluoropropene |
| KR102071701B1 (ko) * | 2012-02-29 | 2020-01-31 | 허니웰 인터내셔날 인코포레이티드 | 2,3,3,3-테트라플루오로프로펜의 제조 방법 |
| WO2013141409A1 (en) | 2012-03-22 | 2013-09-26 | Daikin Industries, Ltd. | Process for preparing 2-chloro-3,3,3-trifluoropropene |
| CN103880590B (zh) * | 2012-12-19 | 2016-10-05 | 中化蓝天集团有限公司 | 一种制备1,3,3,3-四氟丙烯的工艺 |
| WO2014164611A1 (en) | 2013-03-12 | 2014-10-09 | Honeywell International Inc. | A method for mitigating hfc-245cb formation during hcfo-1233xf hydrofluorination to hcfc-244bb |
| JP2016511284A (ja) * | 2013-03-13 | 2016-04-14 | ハネウェル・インターナショナル・インコーポレーテッド | 段階的フッ素化方法及び反応器システム |
| US9353029B2 (en) | 2013-03-14 | 2016-05-31 | Honeywell International, Inc. | Fluorination process and reactor |
| HUE068290T2 (hu) * | 2013-03-15 | 2024-12-28 | Honeywell Int Inc | Eljárás 2-klór-1,1,2-tetrafluor-propán (HCFC-244bb) elõállítására |
| CN105102402B (zh) * | 2013-04-18 | 2019-06-18 | 霍尼韦尔国际公司 | 生产氟化有机物的反应体系和方法 |
| CN103524293B (zh) * | 2013-09-28 | 2015-06-24 | 西安近代化学研究所 | 2,3-二氯-1,1,1,2-四氟丙烷的制备方法 |
| JP2017512133A (ja) * | 2014-02-10 | 2017-05-18 | ハネウェル・インターナショナル・インコーポレーテッド | 液相フッ素化のための反応器デザイン |
| US9663425B2 (en) * | 2014-03-31 | 2017-05-30 | Honeywell International Inc. | Method to produce 1,1,2,3-tetrachloropropene with high yield |
| PT3142993T (pt) | 2014-05-16 | 2018-12-18 | Occidental Chem Co | Método para preparar 1,1,3,3-tetracloropropeno |
| CN104140355B (zh) * | 2014-08-07 | 2016-03-02 | 西安近代化学研究所 | 一种合成2-氯-1,1,1,2-四氟丙烷的方法 |
| TWI848259B (zh) | 2014-10-16 | 2024-07-11 | 捷克商史波克專業化學杭尼維洛普合股公司 | 用於製造高純度氯化烷烴的方法 |
| WO2016058569A1 (en) | 2014-10-16 | 2016-04-21 | Spolek Pro Chemickou A Hutni Vyrobu, Akciova Spolecnost | Process |
| JP6210073B2 (ja) | 2015-01-21 | 2017-10-11 | ダイキン工業株式会社 | フルオロプロペンの製造方法 |
| CN107635955A (zh) | 2015-05-21 | 2018-01-26 | 科慕埃弗西有限公司 | 通过SbF5进行的1233xf至244bb的氢氟化 |
| GB2540428B (en) * | 2015-07-17 | 2017-09-13 | Mexichem Fluor Sa De Cv | Process for preparing 3,3,3-trifluoropropene |
| US10029962B2 (en) | 2015-08-19 | 2018-07-24 | Spolek Pro Chemickou A Hutni Vyrobu A.S. | Process for producing C3 chlorinated alkane and alkene compounds |
| JP6935423B2 (ja) | 2016-04-13 | 2021-09-15 | アルケマ フランス | 2,3,3,3−テトラフルオロプロペンの製造方法 |
| KR102389623B1 (ko) | 2016-04-13 | 2022-04-25 | 스폴케미 제브라, 에이.에스. | 방법 |
| JP6979066B2 (ja) * | 2016-11-02 | 2021-12-08 | ハネウェル・インターナショナル・インコーポレーテッドHoneywell International Inc. | 精製した2,3,3,3−テトラフルオロプロペン(HFO−1234yf)を製造する方法 |
| GB201712775D0 (en) * | 2017-08-09 | 2017-09-20 | Mexichem Fluor Sa De Cv | Compositions and uses thereof |
| FR3078700B1 (fr) * | 2018-03-07 | 2020-07-10 | Arkema France | Procede de production du 2,3,3,3-tetrafluoropropene |
| FR3078699B1 (fr) * | 2018-03-07 | 2020-02-21 | Arkema France | Procede de production du 2,3,3,3-tetrafluoropropene |
| ES3032685T3 (en) * | 2018-07-09 | 2025-07-23 | Chemours Co Fc Llc | Methods for an integrated 2,3,3,3-tetrafluoropropene manufacturing process |
| US11904301B2 (en) * | 2018-09-07 | 2024-02-20 | The Chemours Company Fc, Llc | Fluorine removal from antimony fluorohalide catalyst using chlorocarbons |
| WO2021036060A1 (en) * | 2019-08-29 | 2021-03-04 | Fujian Yongjing Technology Co., Ltd | Process for preparing fluorobenzene and catalyst therefore |
| CN115141231B (zh) * | 2022-06-17 | 2025-07-11 | 浙江蓝天环保高科技股份有限公司 | 一种六氟环三磷腈的连续制备方法 |
| CN116178333A (zh) * | 2023-01-06 | 2023-05-30 | 鲁北超能新材料产业(山东)有限公司 | 一种氟代碳酸乙烯酯的制备方法 |
| CN121181396B (zh) * | 2025-11-25 | 2026-02-03 | 山东联创聚合物有限公司 | 含氟烯烃的制备方法及其所使用的装置 |
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| LU36877A1 (es) * | 1958-05-21 | |||
| JPH01207250A (ja) * | 1988-02-12 | 1989-08-21 | Daikin Ind Ltd | 含フツ素オレフインの製造方法 |
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| BE1011765A3 (fr) * | 1998-02-26 | 2000-01-11 | Solvay | Procede d'hydrofluoration d'hydrocarbures. |
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| US9005467B2 (en) * | 2003-10-27 | 2015-04-14 | Honeywell International Inc. | Methods of replacing heat transfer fluids |
| US7592494B2 (en) * | 2003-07-25 | 2009-09-22 | Honeywell International Inc. | Process for the manufacture of 1,3,3,3-tetrafluoropropene |
| US8058486B2 (en) | 2004-04-29 | 2011-11-15 | Honeywell International Inc. | Integrated process to produce 2,3,3,3-tetrafluoropropene |
| US20090182179A1 (en) * | 2008-01-15 | 2009-07-16 | Honeywell International Inc. | Hydrofluorination of 2-chloro-3,3,3-trifluoropropene to 2-chloro-1,1,1,2-tetrafluoropropane with catalysts of sbcl3, sbcl5, sbf5, ticl4, sncl4, cr2o3 and fluorinated cr2o3 |
| EP1740518A1 (en) * | 2004-04-29 | 2007-01-10 | Honeywell International, Inc. | Processes for synthesis of 1,3,3,3-tetrafluoropropene |
| US8084653B2 (en) * | 2004-04-29 | 2011-12-27 | Honeywell International, Inc. | Method for producing fluorinated organic compounds |
| US8071825B2 (en) * | 2006-01-03 | 2011-12-06 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| SI3336074T1 (sl) * | 2006-01-03 | 2025-09-30 | Honeywell International Inc. | Postopek za proizvodnjo fluoriranih organskih spojin |
| US8952208B2 (en) * | 2006-01-03 | 2015-02-10 | Honeywell International Inc. | Method for prolonging a catalyst's life during hydrofluorination |
| US8664455B2 (en) * | 2008-08-08 | 2014-03-04 | Honeywell International Inc. | Process to manufacture 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) |
| US8324436B2 (en) * | 2006-01-03 | 2012-12-04 | Honeywell International Inc. | Gas phase synthesis of 2,3,3,3-tetrafluoro-1-propene from 2-chloro-3,3,3-trifluoro-1-propene |
| CN101687731B (zh) * | 2007-06-27 | 2013-09-04 | 阿科玛股份有限公司 | 用于制造氢氟烯烃的方法 |
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| US7795480B2 (en) * | 2007-07-25 | 2010-09-14 | Honeywell International Inc. | Method for producing 2-chloro-3,3,3,-trifluoropropene (HCFC-1233xf) |
| US9035111B2 (en) | 2007-08-22 | 2015-05-19 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| CN101492342A (zh) * | 2008-01-15 | 2009-07-29 | 霍尼韦尔国际公司 | 用催化剂SbCl3、SbCl5、SbF5、TiCl4、SnCl4、Cr2O3和氟化Cr2O3将2-氯-3,3,3-三氟丙烯氢氟化为2-氯-1,1,1,2-四氟丙烷 |
| US8546624B2 (en) * | 2008-03-06 | 2013-10-01 | Honeywell International Inc. | Azeotrope-like composition of 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf) and hydrogen fluoride (HF) |
| US7803283B2 (en) | 2008-03-31 | 2010-09-28 | Honeywell Internationl Inc. | Azeotrope-like compositions of 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf) and 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) |
| ES2926707T3 (es) * | 2008-05-07 | 2022-10-27 | Chemours Co Fc Llc | Composiciones |
| GB2489628B (en) | 2008-06-13 | 2013-02-13 | Schlumberger Holdings | Wellbore instruments using magnetic motion converters |
| US8916733B2 (en) | 2008-06-17 | 2014-12-23 | Honeywell International Inc. | Processes for hydrofluorination of 2-chloro-3,3,3-trifluoropropene to 2-chloro-1,1,1,2-tetrafluoropropane |
| ES2365303T3 (es) * | 2008-08-08 | 2011-09-28 | Honeywell International Inc. | Proceso mejorado para fabricar 2-cloro-1,1,1,2-tetrafluoropropano (hcfc-244bb). |
| WO2010095764A1 (en) | 2009-02-23 | 2010-08-26 | Daikin Industries, Ltd. | Process for preparing fluorine-containing alkyne compound |
| US8618340B2 (en) * | 2009-11-03 | 2013-12-31 | Honeywell International Inc. | Integrated process for fluoro-olefin production |
-
2010
- 2010-06-28 US US12/825,040 patent/US8952208B2/en active Active
-
2011
- 2011-06-22 WO PCT/US2011/041395 patent/WO2012009114A2/en not_active Ceased
- 2011-06-22 CN CN201610862139.6A patent/CN107011112A/zh active Pending
- 2011-06-22 CN CN201510413522.9A patent/CN105037080B/zh not_active Expired - Fee Related
- 2011-06-22 EP EP11807245.3A patent/EP2585423B1/en not_active Not-in-force
- 2011-06-22 JP JP2013518481A patent/JP5868969B2/ja active Active
- 2011-06-22 ES ES11807245.3T patent/ES2556459T3/es active Active
- 2011-06-22 CN CN2011800415822A patent/CN103052614A/zh active Pending
- 2011-06-22 MX MX2015015495A patent/MX365550B/es unknown
- 2011-06-22 MX MX2013000049A patent/MX2013000049A/es active IP Right Grant
-
2015
- 2015-01-26 US US14/604,867 patent/US10005704B2/en active Active
- 2015-11-13 JP JP2015222772A patent/JP6188767B2/ja not_active Expired - Fee Related
-
2017
- 2017-04-21 JP JP2017084262A patent/JP2017160231A/ja active Pending
-
2018
- 2018-06-25 US US16/017,526 patent/US20190194097A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| MX2013000049A (es) | 2013-02-15 |
| WO2012009114A3 (en) | 2012-04-05 |
| EP2585423A4 (en) | 2013-11-27 |
| CN105037080A (zh) | 2015-11-11 |
| EP2585423A2 (en) | 2013-05-01 |
| JP6188767B2 (ja) | 2017-08-30 |
| US20190194097A1 (en) | 2019-06-27 |
| JP2013533877A (ja) | 2013-08-29 |
| JP2016053075A (ja) | 2016-04-14 |
| US10005704B2 (en) | 2018-06-26 |
| CN107011112A (zh) | 2017-08-04 |
| ES2556459T3 (es) | 2016-01-18 |
| CN103052614A (zh) | 2013-04-17 |
| US20100331583A1 (en) | 2010-12-30 |
| US8952208B2 (en) | 2015-02-10 |
| WO2012009114A2 (en) | 2012-01-19 |
| EP2585423B1 (en) | 2015-09-30 |
| JP2017160231A (ja) | 2017-09-14 |
| US20150152028A1 (en) | 2015-06-04 |
| US20140100393A9 (en) | 2014-04-10 |
| CN105037080B (zh) | 2018-11-30 |
| JP5868969B2 (ja) | 2016-02-24 |
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|---|---|---|
| MX365550B (es) | Método para prolongar la vida de un catalizador durante hidrofluoración. | |
| MX2009008451A (es) | Proceso mejorado para fabricar 2-cloro-1,1,1,2-tetrafluoropropano (hcfc244bb). | |
| MX2009003492A (es) | Composiciones azeotropicas de 2-cloro-3,3,3-trifluoropropeno (hcfc-1233xf), 2-cloro-1,1,1,2-tetrafluoropropano (hcfc-244bb), y fluoruro de hidrogeno (hf). | |
| MX2009002967A (es) | Proceso integrado para producir 2, 3, 3, 3-tetrafluoropropeno. | |
| MX2010000768A (es) | Método mejorado para producir 2-cloro-3,3,3-trifluoropropeno (hcfc-1233xf). | |
| MX344948B (es) | Proceso para producir 2,3,3,3-tetrafluoropropeno. | |
| MX343621B (es) | Fluoracion catalitica en fase gas. | |
| MX2013002465A (es) | Azeotropos para el proceso de 1,3,3,3-tetrafluoropropeno con hf. | |
| WO2010123154A3 (en) | Process for preparation of 2,3,3,3-tetrafluoropropene | |
| MX2009002515A (es) | Composicion tipo azeotropo de 2-cloro-3,3,3-trifluoropropeno (hcfc-1233xf) y fluoruro de hidrogeno (hf). | |
| MX2023009585A (es) | Isomerizacion catalitica de z-1,1,1,4,4,4-hexafluoro-2- buteno a e-1,1,1,4,4,4-hexafluoro-2-buteno. | |
| WO2012148695A3 (en) | INTEGRATED PROCESS TO CO-PRODUCE 1,1,1,3,3-PENTAFLUOROPROPANE, TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE and TRANS-1,3,3,3-TETRAFLUOROPROPENE | |
| MX346307B (es) | Proceso mejorado para la fabricación de 2, 3, 3, 3 - tetrafluoropropeno. | |
| MX341767B (es) | Fluoracion catalitica en fase gas. | |
| MX2010009081A (es) | Procesos para separar 1,3,3,3-tetrafluoropropeno de fluoruro de hidrogeno mediante destilacion azeotropica. | |
| IN2015DN02406A (es) | ||
| MX2009001988A (es) | Composicion semejante a azeotropo de 2-cloro-1,1,1,2-tetrafluoropr opano (hcfc-244 bb) y fluoruro de hidrogeno (hf). | |
| ATE500197T1 (de) | Verfahren zur herstellung von chlor durch gasphasenoxidation | |
| MX345304B (es) | Proceso para la fluorhidracion de 2 - cloro - 3, 3, 3 - trifluoropropeno a 2 - cloro - 1, 1, 1, 2 - tetrafluoropropano. | |
| MX2014003659A (es) | Proceso para producir 2,3,3,3 - tetrafluoropropeno. | |
| EA201100568A1 (ru) | Способ получения карбида кремния высокой чистоты из углеводородов и оксида кремния с помощью прокаливания | |
| MX355075B (es) | Procedimiento para producir 2-cloro-3, 3, 3-trifluoropropeno. | |
| MX2013009366A (es) | Proceso para cis-1-cloro-3,3,3-trifluoropropeno. | |
| MX2015010460A (es) | Un metodo para mitigar la formacion de hfc-245cb durante hidrofluoracion de hcfo-1233xf a hcfc-244bb. | |
| MX2013013386A (es) | Metodo para mitigar la formacion de subproductos durante la produccion de compuestos haloalcano. |