MX2022005287A - Procesos para la recuperación de rodio procedente de un proceso de hidroformilación. - Google Patents

Procesos para la recuperación de rodio procedente de un proceso de hidroformilación.

Info

Publication number
MX2022005287A
MX2022005287A MX2022005287A MX2022005287A MX2022005287A MX 2022005287 A MX2022005287 A MX 2022005287A MX 2022005287 A MX2022005287 A MX 2022005287A MX 2022005287 A MX2022005287 A MX 2022005287A MX 2022005287 A MX2022005287 A MX 2022005287A
Authority
MX
Mexico
Prior art keywords
hydroformylation process
catalyst
aqueous phase
organic phase
organophosphorous ligand
Prior art date
Application number
MX2022005287A
Other languages
English (en)
Inventor
Thomas C Eisenschmid
Michael A Brammer
Glenn A Miller
George R Phillips
Marinus A Bigi
Amarnath Singh
Original Assignee
Dow Technology Investments Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Technology Investments Llc filed Critical Dow Technology Investments Llc
Publication of MX2022005287A publication Critical patent/MX2022005287A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4092—Regeneration or reactivation of catalysts containing metals involving a stripping step, with stripping gas or solvent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

La presente invención generalmente se refiere a procesos para la recuperación de rodio de una corriente de purga de catalizador de un proceso de hidroformilación de olefinas C6 o superior. En una modalidad, el proceso comprende (a) tratar una corriente de purga líquida que contiene el catalizador del proceso de hidroformilación, en donde el catalizador comprende un metal precioso y un ligando organofosforado, con un oxidante en presencia de una fase acuosa líquida separada que comprende un ácido libre de haluros a una temperatura suficiente para efectuar la oxidación de la mayoría del ligando organofosforado contenido, en donde el ácido libre de haluros es un ácido orgánico C1-C6 o un ácido fosforoso; (b) recuperar la fase acuosa; (c) poner en contacto la fase acuosa con una fase orgánica separada mediante la mezcla de las dos fases bajo una atmósfera de gas de síntesis, en donde la fase orgánica separada comprende un ligando organofosforado hidrolizable e insoluble en agua y la olefina reciclada de un proceso de hidroformilación; y (d) separar la fase orgánica a reciclar de regreso a un proceso de hidroformilación.
MX2022005287A 2019-11-05 2020-10-20 Procesos para la recuperación de rodio procedente de un proceso de hidroformilación. MX2022005287A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201962930833P 2019-11-05 2019-11-05
PCT/US2020/056414 WO2021091687A1 (en) 2019-11-05 2020-10-20 Processes for recovery of rhodium from a hydroformylation process

Publications (1)

Publication Number Publication Date
MX2022005287A true MX2022005287A (es) 2022-08-02

Family

ID=73402148

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2022005287A MX2022005287A (es) 2019-11-05 2020-10-20 Procesos para la recuperación de rodio procedente de un proceso de hidroformilación.

Country Status (10)

Country Link
US (1) US20220288574A1 (es)
EP (1) EP4054762A1 (es)
JP (1) JP2023501124A (es)
KR (1) KR20220130096A (es)
CN (1) CN114728278A (es)
BR (1) BR112022008189A2 (es)
MX (1) MX2022005287A (es)
TW (1) TW202126385A (es)
WO (1) WO2021091687A1 (es)
ZA (1) ZA202204869B (es)

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Also Published As

Publication number Publication date
US20220288574A1 (en) 2022-09-15
TW202126385A (zh) 2021-07-16
KR20220130096A (ko) 2022-09-26
JP2023501124A (ja) 2023-01-18
ZA202204869B (en) 2023-11-29
EP4054762A1 (en) 2022-09-14
WO2021091687A1 (en) 2021-05-14
CN114728278A (zh) 2022-07-08
BR112022008189A2 (pt) 2022-07-12

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