MX2022000910A - Elastómeros de tiol-acrilato para impresión 3d. - Google Patents

Elastómeros de tiol-acrilato para impresión 3d.

Info

Publication number
MX2022000910A
MX2022000910A MX2022000910A MX2022000910A MX2022000910A MX 2022000910 A MX2022000910 A MX 2022000910A MX 2022000910 A MX2022000910 A MX 2022000910A MX 2022000910 A MX2022000910 A MX 2022000910A MX 2022000910 A MX2022000910 A MX 2022000910A
Authority
MX
Mexico
Prior art keywords
thiol
resin
printing
acrylate
acrylate elastomers
Prior art date
Application number
MX2022000910A
Other languages
English (en)
Inventor
Benjamin R Lund
Jesse Huffstetler
Original Assignee
Adaptive 3D Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Adaptive 3D Tech Llc filed Critical Adaptive 3D Tech Llc
Publication of MX2022000910A publication Critical patent/MX2022000910A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/067—Polyurethanes; Polyureas
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041—Optical brightening agents, organic pigments
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C08K5/08—Quinones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • C08K5/378—Thiols containing heterocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
    • C08K5/405—Thioureas; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/45—Heterocyclic compounds having sulfur in the ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/112—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using individual droplets, e.g. from jetting heads

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

La presente divulgación se refiere a composiciones de resina fotopolimerizable de tiol-acrilato. Las composiciones de resina se pueden utilizar para fabricación aditiva. Una modalidad de la invención incluye una resina fotopolimerizable para fabricación aditiva, la resina que comprende: un oligómero de acrilato; un monómero de metacrilato; y un tiol en donde la resina se puede configurar para reaccionar mediante exposición a luz para formar un material curado. La resina puede comprender además uno o más aditivos oligoméricos. Por ejemplo, aditivos oligoméricos de poliéter tal como politetrahidrofurano.
MX2022000910A 2019-07-23 2020-07-23 Elastómeros de tiol-acrilato para impresión 3d. MX2022000910A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201962877832P 2019-07-23 2019-07-23
PCT/US2020/043326 WO2021016481A1 (en) 2019-07-23 2020-07-23 Thiol-acrylate elastomers for 3d printing

Publications (1)

Publication Number Publication Date
MX2022000910A true MX2022000910A (es) 2022-05-10

Family

ID=74192710

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2022000910A MX2022000910A (es) 2019-07-23 2020-07-23 Elastómeros de tiol-acrilato para impresión 3d.

Country Status (9)

Country Link
US (1) US20220356363A1 (es)
EP (1) EP4003709A4 (es)
JP (1) JP2022544012A (es)
KR (1) KR20220065759A (es)
CN (1) CN114761204A (es)
AU (1) AU2020315857A1 (es)
CA (1) CA3145257A1 (es)
MX (1) MX2022000910A (es)
WO (1) WO2021016481A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2020010168A (es) * 2018-03-28 2021-03-09 Benjamin Lund Polímeros de triol-acrilato, métodos de síntesis de los mismos y uso en tecnologías de fabricación por adición.
JP2022551930A (ja) * 2019-10-09 2022-12-14 ポリ－メッド インコーポレイテッド 硬化性ポリマー組成物
US20220213329A1 (en) * 2021-01-05 2022-07-07 Formlabs, Inc. Water-breakable resin formulation
TW202342678A (zh) * 2022-01-28 2023-11-01 德商漢高股份有限及兩合公司 具有改良的表面固化之(甲基)丙烯酸系光學透明黏著劑

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4179531A (en) * 1977-08-23 1979-12-18 W. R. Grace & Co. Polythiol effect, curable monoalkenyl aromatic-diene and ene composition
US5679719A (en) * 1993-03-24 1997-10-21 Loctite Corporation Method of preparing fiber/resin composites
US8962709B2 (en) * 2003-10-22 2015-02-24 The Regents Of The University Of Colorado, A Body Corporate Resin systems for dental restorative materials and methods using same
US7964248B2 (en) * 2007-04-13 2011-06-21 Huntsman Advanced Materials Americas Llc Dual photoinitiator, photocurable composition, use thereof and process for producing a three dimensional article
KR101001656B1 (ko) * 2008-08-26 2010-12-15 에스에스씨피 주식회사 광중합형 수지 조성물 및 이를 사용하여 제조되는 광섬유
WO2011123180A1 (en) * 2010-04-03 2011-10-06 Praful Doshi Medical devices including medicaments and methods of making and using same
US20130237629A1 (en) * 2010-11-22 2013-09-12 Showa Denko K.K. Curable resin composition
WO2012126695A1 (en) * 2011-03-23 2012-09-27 Huntsman Advanced Materials (Switzerland) Gmbh Stable curable thiol-ene composition
WO2014069027A1 (ja) * 2012-11-01 2014-05-08 新田ゼラチン株式会社 光硬化性シーリング用材料、シーリング方法、シーリング材およびそれを用いる筐体
JP5994618B2 (ja) * 2012-12-14 2016-09-21 デクセリアルズ株式会社 光硬化性樹脂組成物及びそれを用いた画像表示装置の製造方法
KR20170023977A (ko) * 2014-06-23 2017-03-06 카본, 인크. 3차원 물체의 제조에 사용하기 위한, 다중 경화 메커니즘을 갖는 폴리우레탄 수지
WO2017051182A1 (en) * 2015-09-25 2017-03-30 Photocentric Limited Methods for making an object and formulations for use in said methods
EP4215594A1 (en) * 2016-04-07 2023-07-26 3D Systems, Incorporated Thiol-ene inks for 3d printing
WO2018091891A1 (en) * 2016-11-16 2018-05-24 Photocentric Limited Methods for making a metal, sand or ceramic object by additive manufacture and formulations for use in said methods

Also Published As

Publication number Publication date
WO2021016481A1 (en) 2021-01-28
JP2022544012A (ja) 2022-10-17
US20220356363A1 (en) 2022-11-10
CA3145257A1 (en) 2021-01-28
AU2020315857A1 (en) 2022-03-03
EP4003709A4 (en) 2023-08-16
KR20220065759A (ko) 2022-05-20
CN114761204A (zh) 2022-07-15
EP4003709A1 (en) 2022-06-01

Similar Documents

Publication Publication Date Title
MX2022000910A (es) Elastómeros de tiol-acrilato para impresión 3d.
MX2020010168A (es) Polímeros de triol-acrilato, métodos de síntesis de los mismos y uso en tecnologías de fabricación por adición.
CL2018002304A1 (es) Agente de curado para composiciones de resinas epoxi de baja emisión
BR112017013230A2 (pt) composição de resina epóxi
ATE509053T1 (de) Dimethylformamidfreie formulierungen mit dicyanadiamid als härtemittel für wärmehärtende epoxidharze
MX2022002698A (es) Recubrimientos de curado rapido de alto rendimiento.
MY176586A (en) Photoluminescent coating material composition
BR112016023872A2 (pt) composição de resina adequada para impressão e método de impressão com o uso da mesma
MX2019001073A (es) Mezclas de polimero para composiciones de resinas epoxi.
MY182723A (en) Radical-polymerizable, water-containing resin composition, curing method thereof, and method for producing radical-polymerizable, water-containing resin composition
EP3932906A4 (en) NEW COMPOUND, COMPOSITION CONTAINING SUCH COMPOUND, AND CURED OBJECT
WO2018165408A3 (en) Blue led light cure on demand compositions
BR112018009837A8 (pt) composição catalítica e composição curável
MX2020009706A (es) Composicion fotocromica curable.
WO2019074270A8 (ko) 항균성 고분자 코팅 조성물 및 항균성 고분자 필름
WO2014114556A3 (de) 2,2',6,6'-tetramethyl-4,4'-methylenbis(cyclohexylamin) als härter für epoxidharze
EP3950761A4 (en) CURING RESIN COMPOSITION
WO2013043363A3 (en) Epoxy-functional resin compositions
BR112016016632A2 (pt) Composições com flexibilidade realçada
MX2022001616A (es) Composicion de resina epoxica estable al almacenamiento.
PH12020551415A1 (en) Storage stable and curable resin compositions
BR112021012808A2 (pt) Composição curável
EP3957662A4 (en) CURABLE RESIN COMPOSITION AND CURED OBJECT MADE THEREOF
IN2014CN04434A (es)
ZA200706708B (en) Coating compositions