MX2021001556A - Proceso de remocion de sulfuro de hidrogeno. - Google Patents

Proceso de remocion de sulfuro de hidrogeno.

Info

Publication number
MX2021001556A
MX2021001556A MX2021001556A MX2021001556A MX2021001556A MX 2021001556 A MX2021001556 A MX 2021001556A MX 2021001556 A MX2021001556 A MX 2021001556A MX 2021001556 A MX2021001556 A MX 2021001556A MX 2021001556 A MX2021001556 A MX 2021001556A
Authority
MX
Mexico
Prior art keywords
hydrogen sulfide
sulfur dye
treatment solution
catalyst
dye catalyst
Prior art date
Application number
MX2021001556A
Other languages
English (en)
Inventor
David Jackson
Jeffrey Bruce Gomach
Preshit Gawade
E Cole Nelson
K Michael Hardy
Original Assignee
Merichem Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Merichem Co filed Critical Merichem Co
Publication of MX2021001556A publication Critical patent/MX2021001556A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/28—Organic compounds not containing metal atoms containing sulfur as the only hetero atom, e.g. mercaptans, or sulfur and oxygen as the only hetero atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1468—Removing hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/0005—Degasification of liquids with one or more auxiliary substances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/0068—General arrangements, e.g. flowsheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/73—After-treatment of removed components
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • E—FIXED CONSTRUCTIONS
    • E21—EARTH OR ROCK DRILLING; MINING
    • E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/01—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells specially adapted for obtaining from underwater installations
    • E—FIXED CONSTRUCTIONS
    • E21—EARTH OR ROCK DRILLING; MINING
    • E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/34—Arrangements for separating materials produced by the well
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/10—Inorganic absorbents
    • B01D2252/103—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60—Additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/70—Non-metallic catalysts, additives or dopants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4062—Geographical aspects, e.g. different process units form a combination process at different geographical locations

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mining & Mineral Resources (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fluid Mechanics (AREA)
  • Physics & Mathematics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Treating Waste Gases (AREA)

Abstract

Un proceso se presenta para tratar una corriente de proceso que contiene un hidrocarburo (aceite y/o gas) y sulfuro de hidrógeno con una solución de tratamiento líquida que contiene un catalizador de tinte de azufre. La corriente de proceso puede estar dentro de una tubería, perforación, tubería submarina o una cabeza de pozo que contiene sulfuro de hidrógeno donde la solución de tratamiento líquida se inyecta en un punto predeterminado para definir una zona depuradora tal que el catalizador de tinte de azufre en la solución de tratamiento líquida que causa que el azufre del sulfuro de hidrógeno reaccione con el catalizador de tinte de azufre agotado que luego puede ser alimentado en un recipiente de oxidación donde se pone en contacto con un gas que contiene oxígeno que causa que el sulfuro oxide a tiosulfato y convierte el catalizador de tinte de azufre agotado al catalizador de tinte de azufre regenerado. El tiosulfato puede ser recuperado, y el catalizador de tinte de azufre regenerado se puede reciclar como parte de la solución de tratamiento líquida.
MX2021001556A 2018-10-15 2019-09-17 Proceso de remocion de sulfuro de hidrogeno. MX2021001556A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US16/160,549 US10787614B2 (en) 2018-10-15 2018-10-15 Hydrogen sulfide removal process
PCT/US2019/051445 WO2020081179A1 (en) 2018-10-15 2019-09-17 Hydrogen sulfide removal process

Publications (1)

Publication Number Publication Date
MX2021001556A true MX2021001556A (es) 2021-08-18

Family

ID=68281914

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2021001556A MX2021001556A (es) 2018-10-15 2019-09-17 Proceso de remocion de sulfuro de hidrogeno.

Country Status (5)

Country Link
US (2) US10787614B2 (es)
CN (2) CN112739445B (es)
CA (1) CA3107804C (es)
MX (1) MX2021001556A (es)
WO (1) WO2020081179A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020086599A1 (en) * 2018-10-22 2020-04-30 Chevron U.S.A. Inc. Ph control in fluid treatment
US11697757B2 (en) 2021-11-23 2023-07-11 Halliburton Energy Services, Inc. Polymeric swellable scavengers for acidic gases
CN114737944B (zh) * 2022-04-21 2024-04-26 东营达成石油科技有限公司 一种油井采出液超高含硫化氢治理方法
CN116159549B (zh) * 2023-04-26 2023-07-11 西安博探石油工程有限公司 一种硫化氢气体吸附材料及其制备方法和应用

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1105484A (fr) 1954-04-07 1955-12-05 Raffinage Cie Francaise Procédé d'oxydation des mercaptans
GB827151A (en) * 1955-03-01 1960-02-03 Gas Council Removing hydrogen sulphide from gases
GB827153A (en) * 1956-02-10 1960-02-03 Gas Council Removing hydrogen sulphide from gases
US2975026A (en) 1957-11-18 1961-03-14 Gas Council Removing hydrogen sulphide from gases
US3098033A (en) * 1959-02-13 1963-07-16 Raffinage Cie Francaise Process for refining petroleum products
US3104951A (en) 1961-03-03 1963-09-24 Universal Oil Prod Co Oxidation of hydrogen sulfide
JPS4910324B1 (es) * 1968-09-30 1974-03-09
US4579727A (en) * 1984-12-04 1986-04-01 The M. W. Kellogg Company Oxidative removal of hydrogen sulfide from gas streams
US4992078A (en) 1989-02-23 1991-02-12 Sandoz Ltd. Sulfur dyes and method of preparing same: membrane process
US5128049A (en) * 1991-01-22 1992-07-07 Gatlin Larry W Hydrogen sulfide removal process
CA2087557C (en) * 1992-07-31 2000-04-25 Matthew Raskin Method for removing catalyst
JP3684269B2 (ja) * 1996-05-31 2005-08-17 東洋紡績株式会社 消臭性繊維製品
JP2002521181A (ja) * 1998-07-21 2002-07-16 クリスタテック インク． ガス流から硫化水素を除去するプロセスのための改良再生方法
US6083472A (en) * 1999-01-28 2000-07-04 U.S. Filter/Gas Technology Products Method for continuously producing thiosulfate ions
GB0030555D0 (en) * 2000-12-14 2001-01-31 Amerada Hess Ltd Hydrogen sulphide scavenging method
WO2003002455A1 (en) * 2001-06-27 2003-01-09 Ray Michael F Process for aqueous phase oxidation of sulfur or sulfide to thiosulfate, bisulfite or sulfite ions using air
CA2558116A1 (en) * 2002-12-18 2004-07-01 Ismael Touri A system and apparatus for removal of unwanted substances in a gas flow
US7988767B2 (en) * 2006-08-31 2011-08-02 Fluor Technologies Corporation Hydrocarbon based sulfur solvent systems and methods
AU2008267751B2 (en) * 2007-06-22 2013-07-18 Gomtech Pty Ltd Selective removal of a target liquid constituent from a multi-component liquid
CN101513584B (zh) * 2009-03-04 2011-11-09 中国科学院过程工程研究所 一种基于碱性离子液体催化剂的氧化脱硫方法
US10112853B2 (en) 2015-09-15 2018-10-30 William Moseley Archer, Iii Method for treating sulfides in waste streams
US10661220B2 (en) * 2018-02-27 2020-05-26 Merichem Company Hydrogen sulfide removal process

Also Published As

Publication number Publication date
CA3107804C (en) 2023-08-01
CN115895714A (zh) 2023-04-04
US20200332203A1 (en) 2020-10-22
WO2020081179A1 (en) 2020-04-23
US10787614B2 (en) 2020-09-29
CN112739445A (zh) 2021-04-30
US11072746B2 (en) 2021-07-27
US20200116003A1 (en) 2020-04-16
CN112739445B (zh) 2023-01-24
CA3107804A1 (en) 2020-04-23

Similar Documents

Publication Publication Date Title
MX2021001556A (es) Proceso de remocion de sulfuro de hidrogeno.
MX2020013125A (es) Proceso de remocion de sulfuro de hidrogeno mediante el uso de un catalizador de tinte de azufre.
JP6358631B2 (ja) Ｂｔｅｘを含む低〜中モルパーセント硫化水素ガス供給をクラウスユニットで処理するための改良型硫黄回収工程
AR027472A1 (es) Proceso para eliminar el mercurio de los hidrocarburos.
MY161572A (en) Reactor, a structured packing, and a method for improving oxidation of hydrogen sulfide or polysulfides in liquid sulfur
MX357271B (es) Método y sistema para remover sulfuro de hidrógeno de aceite corrosivo y de agua ácida.
AR101094A1 (es) Proceso para la eliminación de mercurio
RU2015125643A (ru) Способ обработки углеводородов
EA201290682A1 (ru) Удаление кислотных газов из газового потока при улавливании и изолировании со
WO2006041684A3 (en) Process for sulfur removal suitable for treating high-pressure gas streams
MX2019000422A (es) Proceso para producir petroleo renovable que contiene oxigeno, bajo en azufre.
EA201300779A1 (ru) Способ удаления серосодержащих загрязнений из газообразного потока
MA43074A1 (fr) Procédé in situ pour la production d'hydrogène à partir de réservoirs d'hydrocarbures souterrains
WO2010005797A3 (en) Method of treating natural gas with high carbon dioxide concentration using aqueous ammonia
NZ586653A (en) Removal of sulfur compounds from a gas stream utilising a zinc containing sorbent
JP2014522900A5 (es)
WO2017105245A3 (en) Removal of sulfur compounds from gas streams via precipitation using a metal cation and forming a metal sulphide precipitate/mercaptide
ZA202202870B (en) A method and a system for abating h2s and co2 from h2s and co2 rich gas mixtures such as geothermal non-condensable gas mixtures
US2432301A (en) Conversion of hydrosulfides to neutral sulfur compounds
EA201990898A1 (ru) Обработка сероводорода в аэробных условиях
RU2016119642A (ru) Способы очистки углеводородных потоков, содержащих меркаптаны
GB201213760D0 (en) improved sulphur dioxide treatment
EP2452923A3 (en) Process for decontamination of hazardous sulfur compounds in oilfield produced water
EA202090158A1 (ru) Композиции и способы для удаления сероводорода и других загрязнений из жидкостей на основе углеводородов и водных растворов
EA201800231A1 (ru) Способ очистки углеводородных сред от сероводорода и меркаптанов